• Title/Summary/Keyword: 무전해 니켈

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Thermal Barrier Efficiency and Endurance of Ni-Cr Coating in Liquid Rocket Engine Combustor (액체로켓엔진 연소기에 적용된 니켈-크롬 코팅의 열차폐 효율과 내구성)

  • Lee, Kwang-Jin;Lim, Byoung-Jik;Kim, Jong-Gyu;Han, Yeoung-Min;Choi, Hwan-Seok
    • Aerospace Engineering and Technology
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    • v.8 no.1
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    • pp.138-143
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    • 2009
  • Thermal barrier efficiency and endurance of coatings in liquid rocket engine combustor were evaluated for air plasma spray coating and electro/electroless plating. The result of firing tests has revealed occasional occurrence of local delamination of $ZrO_2$, NiCrAlY coating obtained by the method of air plasma spray in the region of supersonic flow and it necessitated a new coating method as a substitution. It was found that Ni-Cr coating by means of electro/electroless plating can substitute $ZrO_2$, NiCrAlY coatings of air plasma spray in terms of thermal barrier efficiency and endurance.

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Prevention of Running Blots between the Patterns during the Electroless Nickel Electroless Palladium Immersion Gold (ENEPIG) Surface Finish (무전해 니켈·팔라듐·금도금 표면처리 공정의 도금 번짐 불량 및 개선)

  • Eom, Ki Heon;Seo, Jung-Wook;Won, Yong Sun
    • Clean Technology
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    • v.19 no.2
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    • pp.84-89
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    • 2013
  • The running blots between patterns during electroless nickel electroless palladium immersion gold (ENEPIG) surface finish of printed circuit board (PCB) are investigated and a proper solution is presented. Computational chemistry is first employed to understand the process and experiments are then designed to verify the proposed ideas. A $PdCl_2$ activator which has relatively weak chemical bonding to the epoxy resin is introduced to prevent the formation of palladium seeds on the epoxy resin and a couple of operational measures such as increasing HCl concentration and lowering the temperature of Pd activation process are executed to prevent a further hydrolysis of $PdCl_2$ to more stable $Pd(OH)_2$ in aqueous solution. Computational chemistry provides thermodynamic backgrounds for experiments and their results. This combined approach is expected to be very useful in the research of relevant processes.

Mechanical Properties of Monodisperse Polymer Particles and Electroless Ni Plated Monodisperse Polymer Particles (단분산 가교고분자 미립자 및 그의 무전해 니켈도금체의 기계적 물성 연구)

  • Kim Dong-Ok;Jin Jeong-Hee;Shon Won-IL;Oh Seok-Heon
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.332-337
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    • 2006
  • Monodisperse polymer particles were prepared via one-step seeded polymerization using PMMA seed particles and HDDA (or EGDMA) as crosslinking monomer. For the study, the effects of 1) the ratio of the absorbed monomer or monomer mixture to the seed polymer particles (swelling ratio), 2) the ratio of EGDMA in absorbed monomer mixture, 3) the dosage of initiator, and 4) electro less Ni plating on the variation of mechanical properties of monodisperse polymer particles, such as recovery rate, K-values, breaking strength and breaking displacement, were investigated by using MCT (micro compression test). It was observed that monomer swelling ratio influenced only breaking strength, but EGDMA ratio in monomer mixture, dosage of initiator and electroless Ni plating affected both K-values and breaking strength.

A study on Manufacture of EMI Composite Powder by the Electroless Ni Plating Method (무전해 니켈도금방법을 이용한 EMI 복합분말제조에 관한 연구)

  • Joung, I.;Yoon, S.R.;Han, S.N.;Na, J.H.;Kim, C.W.
    • Korean Journal of Materials Research
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    • v.8 no.5
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    • pp.444-449
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    • 1998
  • There are various shielding materials that have been considered; the use of a metallic plate or the layering of a conductive material on a plastic surface and the insertion of filler in plastics. All of these methods have shown their merits and weakness. Therefore, many studies have concentrated on developing materials that effectively cut down EMI without increase in weights of housing materials. In these respects, this study has focused on investigations of the shielding effect of materials that have electroless nickel plating on the lamella structured micro particles surface with low specific gravity. When a film of electroless nickel were plated on a micro particle surfaces and then mixed with paint, the electromagnetic shielding effects were measured as 63dB. Although these effects were less than that 90dB of the copper plate, trials in a series of 6 times increased the shielding effect by IOdB and is applicable to wide range of EMI shielding.

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Residual Strain Characteristics of Nickel-coated FBG Sensors (니켈이 코팅된 FBG 센서의 잔류 변형률 특성)

  • Cho, Won-Jae;Hwang, A-Reum;Kim, Sang-Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.7
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    • pp.613-620
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    • 2017
  • A metal-coated FBG (fiber Bragg grating) sensor has a memory effect, which can recall the maximum strains experienced by the structure. In this study, a nickel-coated FBG sensor was fabricated through electroless (i.e., chemical plating) and electroplating. A thickness of approximately $43{\mu}m$ of a nickel layer was achieved. Then, we conducted cyclic loading tests for the fabricated nickel-coated FBG sensors to verify their capability to produce residual strains. The results revealed that the residual strain induced by the nickel coating linearly increased with an increase in the maximum strain experienced by the sensor. Therefore, we verified that a nickel-coated FBG sensor has a memory effect. The fabrication methods and the results of the cycle loading test will provide basic information and guidelines in the design of a nickel-coated FBG sensor when it is applied in the development of structural health monitoring techniques.

Electroless Nickel Plating on Porous Carbon Substrate (다공성 탄소전극기지상의 무전해 니켈도금에 관한 연구)

  • Chun, So-Young;Rhyim, Young-Mok;Kim, Doo-Hyun;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.1
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    • pp.75-80
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    • 2010
  • Electroless nickel plating on porous carbon substrate was investigated. The pore sizes of carbon substrates were 16-20 ${\mu}m$ and over 20 ${\mu}m$. The carbon surface was changed from hydrophobic to hydrophilic after immersing the substrate in an ammonia solution for 40 min at $60^{\circ}C$. The contact angle of water was decreased from $85^{\circ}$ to less than $20^{\circ}$ after ammonia pretreatment. The content of phosphorous in nickel deposit was decreased with increasing pH and then deposits became crystallized. The thickness of nickel deposit was increased with increasing pH. The minimum concentration of $PdCl_2$ for the electroless nickel plating was 5 ppm and the thickness of nickel was not significantly affected by the concentration of $PdCl_2$.

무전해 Ni도금박막 형성에 DMAB가 미치는영향

  • Kim, Hyeong-Cheol;Kim, Na-Yeong;Baek, Seung-Deok;Na, Sa-Gyun;Lee, Yeon-Seung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.204.1-204.1
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    • 2014
  • 스마트폰과 같은 통신기기 및 각종 전자제품에 있어 크기의 축소와 간소화 추세에 따라 인쇄회로기판(PCB)의 초미세회로설계 기술이 요구됨에 따라, 인쇄회로기판과 첨단 전자부품 사이의 접합 신뢰성을 향상시키기 위해 무전해 니켈 도금이 널리 사용되고 있다. 일반적으로, 무전해 Ni도금은 강산, 강염기성 용액을 이용하여 수행되고 있다. 따라서, 공정과정 중에 기판의 손상을 초래하기도 할뿐만 아니라, 환경적으로도 문제시 되고 있다. 본 연구에서는 친환경적 도금공정의 개발을 위해 중성에서 N-(B)무전해 도금을 시행하였다. 중성의 무전해 도금공정은 어떠한 기판을 사용하여도 기판의 손상없이 도금이 가능하다는 장점을 가지고 있고, Boron(B)은 Ni을 비정질화 시키는 물질로 알려져 있다. B가 첨가된 무전해 Ni도금 박막에 있어 B의 영향을 알아보기 위하여 중성조건에서 B를 포함한 DMAB의 첨가량을 조절하였다. Ni-(B) 무전해 도금 시 도금조의 온도는 $40^{\circ}C$로 하였고, 무전해 도금액의 pH는 7(중성)로 유지하였다. Cu Foil기판을 사용하여 DMAB의 양에 따라 성장된 Ni-B무전해 도금 박막의 특성을 분석하기 위해 X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FE-SEM), Optical microscope (OM), X-ray Photoelectron Spectroscopy (XPS), X-ray Absorption Spectroscopy (XAS)을 이용하였다.

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Electroless Nickel Plating (무전해 니켈도금에 대하여(II))

  • 지태촌;여운관
    • Journal of the Korean institute of surface engineering
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    • v.15 no.2
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    • pp.57-67
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    • 1982
  • Electroless Ni-plating is often utilized in industries due to its physical and mechanical characteristics in contrast to conventional electroplatings. Thus, electroless Ni-plating will be broadly applicated in many fields. However, The physial and mechanical properties of this depositss depend largely on the structure and P content of film and heat treatment. And here discused about the important results of those past research.

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