• Journal of Korean Society of Environmental Engineers
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• v.30 no.11
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• pp.1087-1094
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• 2008

Diazinon is a phosphorothiate insecticide widely used in the world including Korea. This study investigates the feasibility of photolysis and photocatalysis processes for the degradation of diazinon in water. Both photolysis and photocatalysis reactiosn were effective in degrdading diazinon, however lower TOC removals were achieved. In case of photocatalysis, approximately 40% of nitrogen from diazinon was recovered as NO$_3^-$, and less than 5% of phosphorus as PO$_4{^{3-}}$. However, the sulfur in diazinon molecule was completely recovered to SO$_4{^{2-}}$ from photocatalysis reaction, and the recovery from photolysis was 50%, indicating that P=S bond easily breaks first during photolysis and photocatalysis. The poor recoveries of ionic byproducts and TOC from photolysis and photocatalysis indicate the presence of other organic intermediates during reactions. The formation of organic intermediates were identified during reactions using GC/MS and LC/MS/MS, and the main degradation products were diazoxon, and 2-isopropyl-4-methyl-6-hydroxypyrimidine (IMP), respectively. Finally, the acute 48-hr toxicity test using Daphnia magna were employed to measure the toxicity reduction during photocatalysis of degradation. The results showed that the toxicity increased until 180 min of the photocatalysis reaction (from EC$_{50}$ (%) of 69.6 to 13.2%), however, acute toxicity completely disappeared (>100%) after 360 min. The toxicity results showed that the intermediates from photocatalysis such as diazoxon were more toxic than diazinon itself, however these intermediates can be degraded or mineralized with further reaction.

• Journal of the Korean Society of Food Science and Nutrition
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• v.34 no.10
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• pp.1593-1598
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• 2005

These studies were carried out to investigate the possibility for utilization of waste articles and the production of function characteristics Pork by feeding unshiu orange byproducts. The samples consisted of the pork not fed with unshiu orange byproduct (TP-0), the pork fed with 3$\%$ and 5$\%$ unshiu orange byproduct during growing and finishing period, respectively (TP-1), and the pork fed with 6$\%$ and 10$\%$ unshiu orange byproduct growing and finishing period, respectively (TP-2). The moisture, crude protein, crude fat and crude ash were not significantly different among samples. It was found that TP-1 had the highest calorie. The cholesterol content was lowest in TP-2 (p < 0.05). It was found that TP-2 had the lowest Na among minerals. Vitamin $B_{1}$ and $B_{2}$ were not significantly different among samples. The total amino acid contents of TP-0, TP-1 and TP-2 were 18.86$\%$, 20.03$\%$ and 20.44$\%$, respectively. Total free amino acid and saturated fatty acid vs. unsaturated fatty acid of Pork loins were not significantly different mong samples. The sensory scores were not influenced by feeding of unshiu orange byproduct.

• Polymer(Korea)
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• v.28 no.5
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• pp.391-396
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• 2004

In order to overcome drawbacks in the conventional preparation of epoxy/silica nanocomposites, such as formation of micro voids and dimensional instability caused by evolution of volatile by-products during curing reaction, a novel preparation method using Si-N precursor has been proposed. When prepared through in-situ reaction of epoxy curing reaction with sol-gel reaction of Si-N precursor, methyltripiperidinylsilane (MTPS) which does not produce by-products during reaction, epoxy/silica nanocomposites of extremely even dispersion of inorganic phase could be successfully prepared, resulting in high enhancement of mechanical and thermal properties as well as outstanding transparency.

• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.67-83
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• 2022

Biochar is a carbon material produced through the pyrolysis of agricultural biomass with limited oxygen condition. It has been suggested to enhance the carbon sequestration and mineralization of soil carbon. Objective of this study was to investigate soil potential carbon mineralization and carbon dioxide(CO₂) emissions in different soils cooperated with barely straw and livestock manure biochars in the closed chamber. The incubation was conducted during 49 days using a closed chamber. The treatments consisted of 2 different biochars that were originated from barley straw and livestock manure, and application amounts were 0, 5, 10 and 20 ton ha^-1 with different soils as upland, protected cultivation, converted and reclaimed. The results indicated that the TC increased significantly in all soils after biochar application. Mineralization of soil carbon was well fitted for Kinetic first-order exponential rate model equation (P<0.001). Potential mineralization rate ranged from 8.7 to 15.5% and 8.2 to 16.5% in the barely straw biochar and livestock manure biochar treatments, respectively. The highest CO₂ emission was 81.94 mg kg^-1 in the upland soil, and it was more emitted CO₂ for barely straw biochar application than its livestock biochar regardless of their application rates. Soil amendment of biochar is suitable for barely straw biochar regardless of application rates for mitigation of CO₂ emission in the cropland.

• Resources Recycling
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• v.25 no.4
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• pp.23-31
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• 2016

It was found that there was no problem in recycling by-products (waste rock and tailings) from Yangyang iron mine themselves through matter conversion because they are not hazardous according to results of KSLT method. In case of using tailings as sub-materials of cement, it recommended the use of less than 3% tailings dosage not to exceed 0.6% of total alkali ($R_2O$) content based on standard quality of portland cement (KS L 5201). Non sintered eco-brick corresponding to class 1 quality of recycled clay brick (KS I 3013) can replace 15% of cement with tailings and 100% of general fine aggregate with waste rock from iron mine. As mentioned above, recycling the by-products (waste rock and tailings) as sub-materials of cement and non sintered eco-brick could gain both environmental and economic benefits, that is, reduction of scale and maintenance cost of tailing ponds, decrease of energy use and $CO_2$ emission.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.3
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• pp.296-308
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• 2010

The peroxone process overcomes many of the limitations associated with conventional and advanced water treatment systems using chlorine disinfection and ozone oxidation processes. Ozone and hydrogen peroxide generate highly reactive hydroxyl free radical which oxidize various organic compounds and has highly removal efficiency. The key issue to operate peroxone process is developing the method to achieve high process effectiveness when scavengers that inhibit generation of OH radicals or consume OH radicals are co-existing in the process. Also many studies, to minimize inorganic oxidative by-products such as bromate and to reduce disinfection by-products after chlorination behind peroxone process, are needed. And we should consider the excess residual hydrogen peroxide in the water. On-line instruments and control strategies need to be developed to ensure effective and robust operation under conditions of varying load. If problems above mentioned are solved, peroxone process will be applied diversely for water treatment.

• Journal of Life Science
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• v.20 no.9
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• pp.1358-1364
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• 2010

In this study, the effects of feeding citrus by-products on the quality and fatty acid compositions of chicken eggs were investigated. Two samples of chicken eggs were used for this study: T0 (eggs of chickens that were not fed citrus byproducts) and T1 (eggs of chickens that were fed 4% citrus byproducts). There was no statistically meaningful difference between T0 and T1 in terms of various properties, such as chemical composition, cholesterol content, minerals, vitamins, pigments, and total structural amino acid. The caloric content of the egg yolk was higher in T1 than in T0, and total free amino acid of egg albumin and egg yolk was higher in T1 than in T0 (p<0.05). There was a not significant difference in SFA:UFA ratio between T0 and T1, but the linolenic acid content was higher in T1 than in T0 (p<0.05). The results of this study show that citrus by-products can be used for feed for laying hens by adding them to general feed.

• Korean Journal of Organic Agriculture
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• v.18 no.2
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• pp.271-282
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• 2010

This study was conducted to investigate the effects of concentrated pig slurry and byproduct liquid fertilizer on the growth and yield of chinese cabbage. The experiment was conducted in a rain-shelter house which was installed in the agriculture farm. Plants were fertilized with concentrated slurry (CS), byproduct fertilizer (BF), mixture of concentrated slurry and byproduct liquid fertilizer (CS+BF), combined organic and chemical fertilizer (CS+BF+BF) and chemical fertilizer (CF) as control. 1. The pH level of byproduct liquid was decreased from the 3rd to the 7th day and increased 9 day to 14th day, but pH of concentrated slurry (CS) was not greatly varied. EC of concentrated slurry (CS) and byproduct liquid was increased gradually during the fermentation. 2. The concentrated slurry (CS) was low in phosphorus, calcium, magnesium, rich in potassium and unbalanced as a low nitrogen and high potassium. But byproduct liquid fertilizer was balanced in nitrogen and potassium ratio. 3. The leaf number, head height, head width of chinese cabbage in treatment with organic and chemical fertilizer (CS+BF+N) showed significant difference compared with control. The plant and head weight of chinese cabbage in treatment of concentrated slurry was severely decreased, but that in treatment organic and chemical fertilizer (CS+BF+N) were increased 8, 10% compared with control chemical fertilizer (CF), respectively. 4. The content of $K_2O$ in plant tissue and in soil was increased after using concentrated slurry. On the other hand, mineral content of except $K_2O$ did not differ significantly between any of the treatments. In conclusion, organic and chemical fertilizer (CS+BF+N) could improve growth and head weight of chinese cabbage.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.65-66
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• 2012

The cement used in the construction industry of the manufacturing process, large amounts of the greenhouse gas, CO₂ and is currently being studied for cement substitutes that reduce greenhouse gas issue. Therefore, the this study as a replacement for cement industrial by-product of blast furnace slag, red mud, silica fume and alkali-activator, using only inorganic composites without high-temperature calcination process were manufactured. The waste gypsum board micro powder added to compensate for the shrinkage cracks, the compressive strength and flow, and length change characteristics were investigated. Consequently, The setting time was shortened as GB added And liquidity was reduced. GB 2%, 7 days curing the added strength of specimens was the highest. Came out, and change the length of the Plain least.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.3
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• pp.250-258
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• 2016

Until now, the construction material industry has been recognized as a typical environmental destruction industry. However, recently, in order to reduce $CO_2$ emission, the main cause of environmental problems, lots of studies have been done about recycling industrial by-products and construction wastes. Therefore, the purpose of this study is to confirm whether it is possible to use as an alternative material in cement production process as a part of the development of recycled cement using an inorganic construction waste. For this study, the inorganic construction wastes was collected and analyzed each chemical component by XRF(X-ray Fluorescene). Also, the inorganic construction wastes were combined based on the chemical component of the cement, to perform this analysis. As a result, when the inorganic construction wastes was properly combined, it is possible to consider the development of the recycled cement used the inorganic construction wastes.