• Title/Summary/Keyword: 무기탄소

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Soil Organic Carbon Determination for Calcareous Soils (석회암 유래 토양의 토양유기탄소 분석법 연구)

  • Jung, Won-Kyo;Kim, Yoo-Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.396-402
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    • 2006
  • Soil organic carbon has long been considered as the most critical factor to evaluate the soil quality, fertility, and fertilizer prescription. In addition, soil organic carbon may impact on greenhouse gas effects and global warming. Because of that, the management of soil organic carbon is increasingly important not only for improving soil quality but also for managing soil as a greenhouse gas source. Both wet and dry combustion have been used to determine soil organic carbon. Many benefits, such as automation and less labor, could the dry combustion method become more popular. Inorganic form of carbon could overestimate soil organic carbon when the dry combustion method was applied. Determination of soil inorganic carbon may contribute to the improved accuracy of soil organic carbon analysis using dry combustion method. Objectives of this research were 1) to develop soil inorganic carbon determination method using modified digital pressure calcimeter and 2) to evaluate soil organic carbon from calcareous soils using the dry and wet combustion method. Results showed that the significant linear relationship was found between soil inorganic carbon content and pressure calcimeter output. Inorganic carbon ranged from 22% to 28% of total carbon in the calcareous soil samples. Soil organic carbon content by dry combustion for calcareous soil was determined by subtracting inorganic carbon measured by the digital pressure calcimeter from total carbon. Soil organic carbon determined by dry combustion method was significantly correlated with that by wet combustion method. In conclusion, the digital pressure calcimeter may use to improve soil organic carbon determination for the calcareous soils by subtracting of soil inorganic carbon from total carbon determined by dry combustion method.

A Study on Transport Characteristics of Organic and Inorganic Carbons in the Open Estuary of the Tamjin River, Korea (탐진강 열린하구에서 탄소물질의 성상별 이동 특성 연구)

  • Park, Hyung-Geun;Ock, Giyoung
    • Korean Journal of Environmental Biology
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    • v.36 no.4
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    • pp.665-671
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    • 2018
  • This paper represents an investigation into the pattern of carbon transportation and composition on an open estuary in the transition zone between the river and marine environment in Tamjin River where stream water flows into the Gangjin Bay. To conduct the study, seven plots were established along an environmental gradient from river and estuary to the ocean. Surface water samples were collected thrice during the summer rainfalls and non-flooding seasons in 2017. The samples were then measured for the concentrations of dissolved organic carbon ([DOC]), particulate organic carbon ([POC]) and dissolved inorganic carbon ([DIC]). An analysis of the results showed that [POC] did not increase in the river even during the summer rainfall. However, [DOC] increased resulting in a higher [DOC]:[POC] ratios for the non-flooding season compared to summer rainfall events. On the other hand, the marine site of the estuary bay showed the highest [DIC] which was stable relative to those of river sites. The results suggest that in an open estuary zone, river and ocean supplied the open estuary zone with different types of carbon materials; mainly DOC supplied from the river and DIC sourced from the ocean.

Effects of Mineral Media, Carbon Sources and Phytohormones on Micropropagation of Alnus hirsuta (물오리나무(Alnus hirsuta)의 기내증식에 미치는 기본배지, 탄소원 및 식물호르몬의 영향)

  • 김경희
    • Journal of Plant Biology
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    • v.35 no.2
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    • pp.135-142
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    • 1992
  • Shoot tip explants from germinated seeds of Alnus hirsuta were cultured on NT (Nagata and Takebe, 1971) mineral salts medium supplemented with 6% glucose, MS (Murashige and Skoog, 1962) vitamin mixture, polyvinylpyrrolidone (PVP) and $0-50\;\mu\textrm{M}$ 6-benzylaminopurine (BAP). Five $\mu\textrm{M}$ BAP was found to give the highest shoot multiplication rate. Accordingly about 200 shoots were obtained for further experiments by multiplying shoots on this medium for 4-5 months. Regardless of carbon sources, NT mineral medium produced 3-12 times of shoots than MS mineral medium did. On NT mineral medium, 3% sucrose, 3% glucose and 6% glucose yielded no significant differences. It was observed that media consisting of 1/4-1/2 strength NT mineral salts, 3% sucrose and $1-8\;\mu\textrm{M}$ IBA produced about 100% rooting rate. Almost 100% of the resulting plantlets survived after transfer to the soil by decreasing humidity stepwise.epwise.

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Carbon Mineralization in different Soils Cooperated with Barley Straw and Livestock Manure Compost Biochars (토양 종류별 보릿짚 및 가축분 바이오차 투입이 토양 탄소 무기화에 미치는 영향)

  • Park, Do-Gyun;Lee, Jong-Mun;Choi, Eun-Jung;Gwon, Hyo-Suk;Lee, Hyoung-Seok;Park, Hye-Ran;Oh, Taek-Keun;Lee, Sun-Il
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.4
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    • pp.67-83
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    • 2022
  • Biochar is a carbon material produced through the pyrolysis of agricultural biomass with limited oxygen condition. It has been suggested to enhance the carbon sequestration and mineralization of soil carbon. Objective of this study was to investigate soil potential carbon mineralization and carbon dioxide(CO2) emissions in different soils cooperated with barely straw and livestock manure biochars in the closed chamber. The incubation was conducted during 49 days using a closed chamber. The treatments consisted of 2 different biochars that were originated from barley straw and livestock manure, and application amounts were 0, 5, 10 and 20 ton ha-1 with different soils as upland, protected cultivation, converted and reclaimed. The results indicated that the TC increased significantly in all soils after biochar application. Mineralization of soil carbon was well fitted for Kinetic first-order exponential rate model equation (P<0.001). Potential mineralization rate ranged from 8.7 to 15.5% and 8.2 to 16.5% in the barely straw biochar and livestock manure biochar treatments, respectively. The highest CO2 emission was 81.94 mg kg-1 in the upland soil, and it was more emitted CO2 for barely straw biochar application than its livestock biochar regardless of their application rates. Soil amendment of biochar is suitable for barely straw biochar regardless of application rates for mitigation of CO2 emission in the cropland.

A Study on the Quantitative Recovery of Dissolved Inorganic Carbonates in Ground Water for Radiocarbon Measurement (방사성탄소 측정을 위한 지하수 중에 용존된 무기탄소 화합물의 정량적 회수 연구)

  • Chun, Sang-Ki;Woo, Hyung-Joo;Cho, Soo-Young;Kim, Nak-Bae;Lee, Jong-Dae
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.284-289
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    • 1999
  • Dissolved inorganic carbonates in ground water were quantitatively recovered by using gas evolution method. Gas evolution method was found to be less time-consuming, less susceptible to the contamination fromatmospheric $CO_2$ and little affected by the sulfate ions in comparison to the direct precipitation method. Extraction efficiency of nearly 99% could be achieved by gas evolution method in two hours using recirculated gas at a sweeping rate of 4 liter per minute. Samples for carbon isotope fractionation study were collected in three fractions with collection times. The evolution time for the first fraction was one hours, and then second and third fractions were collected at intervals of 30 minutes, respectively. A small portion of each fraction was analyzed to evaluate ${\delta}^{13}C$ values, which were measured to be -7.9‰, -3.0‰ and +0,4‰ for the each fraction. The result clearly indicated that gas evolution method generates isotopically lighter carbon at the beginning of the purging process and heavier isotopes at the end. However, this isotope fractionation effect could be neglected by the almost complete recovery of carbonates.

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국내 A 쓰레기 매립지의 침출수와 생성가스와 지구화학적 특성

  • Lee Gwang-Sik;Go Gyeong-Seok;Kim Jae-Gon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.433-436
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    • 2005
  • 국내 A군에서 운영중인 한 쓰레기 매립지에서 배출되는 침출수와 주변 지하수를 채취하여 화학분석과 동위원소 분석을 실시하였다. 그리고 생활 쓰레기가 분해되는 과정에서 생성되는 가스들을 채집하여 동위원소 분석을 실시하였다. 유기물 분해로 생성된 이산화탄소는 일차적으로 침출수의 알칼리도를 높이고 이차적으로 일어나는 이산화탄소의 환원작용에 의하여 메탄가스가 형성되었다. 이러한 과정에서 침출수내의 용존무기탄소(DIC)의 탄소 동위원소 조성이 부화되었으며, 아울러 생성된 메탄과의 수소 동위원소 교환반응에 의하여 침출수의 수소 동위원소 조성이 크게 부화되는 특징이 관찰 되었다. 쓰레기장에서 발생되는 혼합가스에서 이산화탄소를 분리하여 탄소 동위원소 조성을 분석해 본 결과 새로운 매립지 보다 오래된 매립지에서 배출되는 이산화탄소의 탄소 동위원소 조성이 부화되는 특징이 관찰되었다.

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Comparison of Instrument Characteristics on the Total Organic Carbon Analysis Method in Water Samples (수질분야 총유기탄소 분석방법에 따른 장비별 특성 비교)

  • Hye-Sung Kim;Eun-Tae Hwang;Chan-Geun Lee;Young-Cheol Cho
    • Journal of Environmental Impact Assessment
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    • v.32 no.5
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    • pp.353-362
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    • 2023
  • TOC, which can measure more than 90% of organic substances, can be measured quickly and easily,replacing BOD and COD, which were indicators of organic pollutants. According to water quality pollution control standards, when measuring TOC, if the inorganic carbon ratio in the sample is over 50%, the NPOC (Non-Purgeable Organic Carbon) method should be used. If volatile organic compounds (VOCs) are present at a certain concentration, the TC-IC (subtracting inorganic carbon from total carbon) method should be used. To validate the limitations of these analytical conditions, experiments were conducted by varying the ratio of TOC to IC in purified water and measuring the concentration of TOC in test solutions. The results showed no significant difference between the TC-IC method and the NPOC method. When measuring samples with added VOC standard solutions, it was observed that the carbon loss due to purging was not significant when using the NPOC method. Therefore, it is concluded that the choice of analytical method does not lead to significant differences when VOCs are present in the sample. To account for potential variations in results based on water quality pollution control standards and regulations regarding the approval and testing of environmental measurement devices, a comparison of field sample concentration values was made using two widely used types of TOC analyzers in Korea. The results showed variations of 0.02 to 0.83 mg/L between methods depending on the manufacturer, highlighting the need for caution when selecting an instrument.

광물질 (I)

  • 최진호
    • KOREAN POULTRY JOURNAL
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    • v.24 no.5 s.271
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    • pp.131-135
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    • 1992
  • 광물질(minerals)이란 일명 무기질이라고도 하는데 원자량 16이하인 수소(H), 탄소(C), 질소(N), 산소(O)를 제외한 나머지 원소들을 말한다. 지금까지 공부해온 영양소 즉 탄수화물, 지방, 단백질 및 비타민들은 유기화합물에 속하는 영양소들인데 비해서 광물질은 그것이 유기화합물의 일부 구성요소일 수도 있고 또는 무기화합물로 존재할 수도 있고 때로는 독립된 원소상태로 존재할 수도 있는데 우리가 영양소로서의 광물질을 언급할 때에는 화합물을 말하는 것이 아니고 그 화합물을 구성하고 있는 원소 그 자체를 의미한다. 중요한 영양소의 하나인 물($H{_2}O$)은 즉, 수소(H)와 산소(O)는 광물질로 분류되지 않는다. 한편 탄산칼슘(Ca$CO{_3}$)과 같은 화합물은 무기화합물로서 칼슘(Ca). 탄소(C) 및 산소(O)의 3가지 원소로 구성되어 있다. 동물체내에서 발견되는 광물질에는 30여 종류가 있는데 이들의 총 함량은 2$\~$5$\%$ 정도이다.

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국내 A 쓰레기 매립장의 침출수에서 보여지는 동위원소 특성

  • 이광식;김을영;신동복;유동준;엽병우;고경석
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.455-457
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    • 2004
  • 환경동위원소 기법을 쓰레기 매립장의 침출수 및 주변 지하수에 적용해본 결과 미생물의 활동에 의한 유기물의 분해과정에 대한 정보를 얻을 수 있었다. 특히 유기물 분해로 생성된 이산화탄소는 일차적으로 침출수의 알칼리도를 높이고 이차적으로 일어나는 이산화탄소의 환원작용에 의하여 메탄가스가 형성되었다. 이러한 과정에서 침출수에 잔류하는 용존무기탄소(DIC)의 탄소 동위원소 조성이 크게 부화되었으며, 아울러 생성된 메탄과의 수소동위원소 교환반응에 의하여 물의 수소 동위원소 조성이 크게 부화되는 특징이 국내에서 처음 관찰되었다.

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