• Title/Summary/Keyword: 무기공정

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유기소자의 Encapsulation 박막으로 사용된 원자층 및 분자층 증착 $Al_2O_3$/Alucone 박막의 특성 연구

  • Park, Min-U;Yeo, Dong-Hyeon;Won, Beom-Hui;Lee, Ji-Hye;Lee, Chae-Min;Ha, Myeong-Hun;Jeong, Dong-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.443-443
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    • 2013
  • 유기광전자소자는 아주 얇은 두께로 제작 가능하여 휘어지는 소자를 구현할 수 있다. 이런 장점 때문에 플렉서블 디스플레이, 플렉서블 태양전지 구현에 가장 적합한 소자로 각광받고 있다. 하지만 수분이나 산소에 의한 소자내의 유기물과 금속의 열화로 소자의 수명이 줄어들기 때문에 산소 및 수분 침투를 방지하는 봉지기술(encapsulation)이 필요하다. 본 연구는 원자층 증착법을 이용한 무기박막층과 분자층 증착법을 이용한 폴리머박막의 적층구조를 이용하여 유기소자에 적용할 수 있는 수분 투과 방지막을 제작하였다. 무기박막층으로는 trymethylaluminum (TMA)과 $H_2O$를 사용하여 $Al_2O_3$를 제작하였고 폴리머층으로는 TMA와 ethylene glycol를 사용하여 alucone박막을 제작하였다. 폴리머층으로 사용된 alucone박막의 X-선 광전자 분광 스펙트럼은 대기중 수분과 산소에 의한 화학결합구조의 변화를 보였지만, $Al_2O_3$와 적층구조로 사용되었을 때, 배리어특성을 증가시키고 휘어짐에 따른 보호막의 열화현상을 줄여줄 수 있는 것을 Ca-test를 통해 확인하였다. 이러한 현상은 alucone막을 적층함으로써 $Al_2O_3$를 침투한 소량의 수분과 산소가, alucone박막을 지나면서 다음 $Al_2O_3$ 층으로 침투하기 전까지의 경로를 늘려주기 때문이라 사료된다.

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The Study of opto-electrics characteristics of Inorganic EL(Electro luminescent) Device with combination of high dielectric constant layer (강유전체를 적용한 무기전계발광소자의 광전특성연구)

  • Lee, Gun-Sub;Lee, Seong-Eui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.407-407
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    • 2008
  • 무기EL 디스플레이는 고체재료에 전계를 가했을 때 발광하는 현상을 이용한소자로서, 급속도로 발전을 거듭하고 있으나, 유전체층에 강한전계를 가하여 발광하여야 하므로 낮은 Breakdown voltage와 효율의 한계로 인하여 휘도가 낮고 풀 컬러화 디스플레이 등 의 응용에는 적용되고 있지 못하는 실정이다. 본 연구에서는 강유전체 Perovskite 구조를 가지는 ABO3 물질 중 PMN(Lead Magnesium niobate) 과 PZT (Lead Zirconate titanate) 후막을 제조하여 Inorganic EL(Electro Luminance)에 적용하고 소자의 광전특성을 평가하였다. 소자에 사용된 기판은 고온소성에 알맞은 알루미나(Al2O3)기판을 채택 하였으며, 그 위 하부전극으로는 고온소성에 따른 화학적 안정성이 우수한 Au전극을 Screen Printing 하였다. 제조 되어진 PMN후막 페이스트는 PMN(Pb(Mg1/2 Nb2/3)O3) + Glass Frit(Pb-Zn-B) + BaTiO3(99.99%) 로 합성되었으며 하부전극위에 인쇄하였다. 그 다음 PZT sol-gel을 Spin coating으로 도포 하였다. 형광체로 ZnS:Cu.Cl 을 Screen Printing을로 형성하였으며, 평탄화를 위하여 유기물 충을 Screen Printing 공정으로 성막 하였다. 상부전극으로는 DC sputter로 ITO를 증착하여 EL소자 완성 후 Spectro - Chroma meter로 소자특성을 측정하였다. 평탄화를 통한 유기물층에 변화되는 Capacitance를 Oscilloscope로 전압 전류 pulse의 변화에 따른 opto-electronic 특성을 평가하였다.

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Comparison of Memoryless Anti-collision Protocols for Tag Identification (태그 인식을 위한 무기억 충돌 방지 프로토콜의 비교 분석)

  • Yang, Eui-Sik;Lim, In-Taek
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • v.9 no.1
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    • pp.565-568
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    • 2005
  • RFID system allows contactless identification of objects, where small tags are attached to objects and information of objects are transferred using radio frequency. In recent years, industries have incorporated several identification systems to its production processes, which allow collecting automatically information about goods. In order to communicate with a single tag out of a group of tags, the target tag has to be identified. Therefore the read has to attempt to obtain the unique identification code of each tag within its read range. This paper presents performance results of QT and QT-sl protocols, which are tag identification protocols incorporating memoryless property. The memoryless property is that the current response of each tag only depends on the current query of the reader but not on the past history of the reader's queries.

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Development of Environmental-friendly Nontoxic Organic.Inorganic Complex Pigment (환경친화적 무독성 유.무기 복합안료 개발연구)

  • Do, Young-Woong;Hong, Zhao;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1739-1744
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    • 2008
  • Non-toxic orgarnic inorgarnic complex green pigment using Fluidized Bed Vapor Deposition(FB-VD) process was developed to alternate green pigment used heavy metals chrome and lead in present domestic. Kaolin materials and $CaCO_3$ were used as supporter of pigment and surface and compositions of supporters were characterized by SEM and EDXS, respectively. Various kind of surface active agents(surfactants) were also used to optimize the dry condition or color revelation. Results showed that anion type surfactant is most suitable for dry and color revelation of pigment.

Preparation of UV-Curable Polyurethane Modified $Acrylate/SiO_2$ Hybrid Film Using Sol-Gel Process (졸-젤 공정을 이용한 광경화형 폴리우레탄 변형 아크릴레이트/실리카 하이브리드 필름의 제조)

  • Nam, Dae-Woo;Nam, Byeong-Uk;Cha, Bong-Jun;Kim, Baek-Jin
    • Polymer(Korea)
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    • v.31 no.2
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    • pp.111-116
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    • 2007
  • Polyurethane modified acrylate $(PUA)/SiO_2$ hybrid films were prepared by ultraviolet curing and their surface properties were investigated by hardness and adhesion test. The films were examined by the manipulation of mole-ratio of organic to inorganic components. Under the silica content controlled, highly desirable films were achieved and scratch resistance and hardness property of film were also enhanced, which indicates that the crosslinked silica particles are homogeneously dispersed within PUA film.

Effect of Solubility Parameter of Solvent Additives on the Self-Assembly Behavior of Conjugated Polymers (용매 첨가제의 용해도 계수가 공액고분자의 자기조립 거동에 미치는 영향)

  • Kwon, Eun Hye;Lee, Jeong Ik;Park, So Young;Hahm, Yea Eun;Park, Yeong Don
    • Prospectives of Industrial Chemistry
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    • v.23 no.5
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    • pp.21-32
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    • 2020
  • 유기전자소자는 용액공정을 통한 대량생산이 가능하기 때문에 기존 무기전자소자에 비해 제조비용이 저렴하고 대면적 생산이 가능하며, 유기분자의 본연 특징으로 인해 유연하고 가벼운 소자를 구현할 수 있다. 그러나 무기 반도체에 비하여 현저히 낮은 전하이동도 특성은 유기전자소자의 상용화에 걸림돌이 되고 있다. 따라서 공액고분자의 결정화도, 모폴로지, 분자배향 최적화를 통한 자기조립 박막 제조는 전하이동을 원활히 하기 때문에 유기전자소자의 개발에 필수적이다. 본 기고에서는 유기전자소자의 활성층으로 사용되는 공액고분자의 자기조립을 유도하기 위한 다양한 특성을 갖는 용매 첨가제의 효과에 대해서 알아보고, 특히 첨가제의 용해도 계수가 공액고분자의 자기조립 거동에 미치는 영향에 대해 자세히 논의하고자 한다.

Variation of Yield and Oxygen Content of SiC-Based Ceramics with the Conversion Processes of PCS (PCS의 전환공정에 따른 SiC세라믹스 수율 및 산소 함량 변화)

  • Kim, Joung-Il;Kim, Weon-Ju;Park, Ji-Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.188-192
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    • 2005
  • The conversions to SiC-based ceramics of a polycarbosilane (PCS) with and without oxidation curing were carried out. A yield and an oxygen content of conversed SiC-based ceramics were evaluated. The weight losses of conversed SiC-based ceramics by both processes analyzed to estimate the high temperature stability after heat treatment at high temperature in vacuum. The yield of SiC­based ceramics after oxidation curing was higher than that without curing process. However, the weight loss of SiC-based ceramics with oxidation curing was larger than that without curing process after heat treatment.

Determination of Main Factors Affecting the Electrodialysis of Succinate by Using Design of Experiment Method (실험계획법을 이용한 숙신산염 탈염의 주요 공정변수 결정)

  • Shin, Seunghan;Chang, Eugene;Lee, Do-Hoon;Kim, Sangyong
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.179-184
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    • 2008
  • The separation and purification of succinate are necessary for the succinic acid production by a fermentation process. Among the purification processes, desalination of succinate is inevitable. In this work, electrodialysis was selected as a desalination method and its operating parameters affecting the degree of desalination and energy consumption were examined. Commercialized electrodialysis apparatus was used in this work and its optimum operating parameters were determined by using design of experiment (DOE) method. Voltage, concentration of succinate, and pH were selected as main parameters. Among them, voltage seemed to be the most important one. The final conversion of succinate to succinic acid was calculated when the operating parameters were optimized. Finally, the effect of impurities, such as corn steep oil, yeast extract, and dextrose on the electrodialysis efficiency was also studied.

Recent Trends in Low-Temperature Solution-Based Flexible Organic Synaptic Transistors Fabrication Processing (저온 용액 기반 유연 유기 시냅스 트랜지스터 제작 공정의 최근 연구 동향)

  • Kwanghoon Kim;Eunho Lee;Daesuk Bang
    • Journal of Adhesion and Interface
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    • v.25 no.2
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    • pp.43-49
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    • 2024
  • In recent years, the flexible organic synaptic transistor (FOST) has garnered attention for its flexibility, biocompatibility, ease of processability, and reduced complexity, which arise from using organic semiconductors as channel layers. These transistors can emulate the plasticity of the human brain with a simpler structure and lower fabrication costs compared to conventional inorganic synaptic devices. This makes them suitable for applications in next-generation wearable devices and soft robotics technologies. In FOST, the organic substrate is sensitive to the device preparation temperature; high-temperature treatment processes can cause thermal deformation of the organic substrate. Therefore, low-temperature solution-based processing techniques are essential for fabricating high-performance devices. This review summarizes the current research status of low-temperature solution-based FOST devices and presents the problems and challenges that need to be addressed.

An Impurity Quantitative Study for Pavement Application in Recycled Waste Aggregates (재생골재의 도로적용을 위한 이물질 정량화 연구)

  • Park, Jun-Young;Cho, Yoon-Ho;Lim, Nam-Woong
    • International Journal of Highway Engineering
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    • v.7 no.1 s.23
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    • pp.21-29
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    • 2005
  • One way to recycle the construction wastes is to use the waste concrete aggregates as the pavement materials. Although there are many studies and technical developments about waste concrete aggregates, the impurities produced in the process of the aggregate production prevent the use of the waste concrete aggregates in the pavement construction. In this study, the impurities included in the recycled waste aggregates were classified into inorganic and organic ones according to their characteristics, and the influences of each impurities on the pavement performance were presented. It was also showed that the limit of impurity content in the lean concrete base through the correlation between the inorganic impurity content and the compressive strength, and that in the granuler subbase layer through the correlation between the organic impurity content and the modified CBR. In conclusion, it is possible to apply waste concrete aggregates for the pavement when inorganic impurity content is less than 10% in the lean concrete base, and organic impurity content is less than 2% in granular subbase.

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