• Title/Summary/Keyword: 무기공정

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The Comparison Study in the Extraction of Inorganic Priority Pollutants from Solid Wastes (고체 폐기물 시료 중의 무기 Priority Pollutants 추출법 비교 연구)

  • Ahn, Tae-Ho;Lee, Huk-Hee;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.10 no.6
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    • pp.395-402
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    • 1997
  • The comparison study between EPA method 3050 and the test method offered by Ministry of Environment in Korea was performed to investigate a matrix effect on extraction. In this study, 12 inorganic priority pollutants(Cd, Cr, Cu, Pb, Ni, Zn, As, Sb, Se, Hg, Be, Tl) were spiked to the sludges and estuary sediment samples. The extracts were analyzed by AAS, HG-AAS, and ICP/MS. Results were discussed in terms of recoveries, relative standard deviations, and the method detection limits. Mean recovery of the elements except As, Sb, and Se was 93% when the procedure of EPA method was applied. The Korean extraction method, however. showed a significant matrix effect to give very poor recoveries.

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The Synthesis of Hydrated Aluminum Sulfate from Kaolin Using Microwave Energy (카올린으로부터 마이크로파 에너지를 이용한 무기고분자인 수화 황산 알루미늄의 합성)

  • Park, Seong Soo;Hwang, Eun Hee;Park, Hee Chan
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.481-485
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    • 1998
  • Hydrated aluminum sulfate, an inorganic polymer, was synthesized from kaolin in $H_2SO_4$ solution using microwave energy. The maximum rates of alumina extracted from calcined kaolin were 72.8% in a conventional process ($80^{\circ}C$, 1M, and 180min) and 99.9% in a microwave process ($90^{\circ}C$, 1M, and 60 min). Compared with the conventional one, the hydrated aluminum sulfate synthesized under the microwave process had layer structure consisting of plate-shaped large grains. After synthesis and then calcination at $1100^{\circ}C$, both products on conventional and microwave processes were ${\gamma}-Al_2O_3$ with agglomerated powders of spherical shape. The specific area of the products in conventional and microwave processes were 113.5 and $106.6m^2/g$, and their average grain sizes were 46.5 an $26.3{\mu}m$, respectively.

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Food Component Characteristics of Plain Dried Anchovies on the Market (시판 소건멸치의 식품성분 특성)

  • 김진수;양수경;허민수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.1
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    • pp.20-25
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    • 2000
  • This study was conducted to evaluate the quality of the plain dried anchovies on the market by determining chemical components, and compared with those of boiled-dried anchovy. The nutritional(total amino acid contents, mineral contents and fatty acid compositions) and favorite properteis (extratives nitrogen content, color and appearance) of plain dried anchovies were superior to those of boiled-dried anchovy. On the other hand, the lipid properties (peroxide value and acid value), food sanitary properteis (volatile basic nitrogen content) and sensory properties (odor) of plain dried anchovies were inferior to boiled-dried anchovy. These results indicated that the plain dried anchovy was classified into lower grade goods by food quality standards.

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The Preparation and Properties of Petroleum Sulfonate Dispersant (열분해 잔유를 원료로 한 분산제의 제조 및 특성)

  • Choi, Sang-Won;Kim, Eun-Young;Chang, Woo-Seok;Kim, Viktor;Moon, Jang-Soo
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.490-494
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    • 2007
  • Dispersants were prepared from petroleum pyrolysis residual oil (PPRO) through sulfonation. Without employing a conventional polynaphthalene sulfonate formaldehyde condensate (PNS) process, the dispersants (NPS) were synthesized by a simpler process only in 2 h. The chemical structure of new dispersant, which has various naphthalene derivative groups, was similar to PNS conformed by UV-visible spectroscopy curves. The new dispersants demonstrated high dispersing ability in inorganic suspension ; cement, $Fe_2O_3$, and $CaCO_3$.

Disposal of Polychlorinated Biphenyls(PCBs) by a Combined Chemical with Thermal Treatment (화학 및 열적 처리를 이용한 폴리염화바이페닐(PCB)의 제거)

  • Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.286-293
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    • 1999
  • A comnprehensive process which combines chemical with thermal treatment by controlled counterflow oxidation has been developed for disposal of PCBs in transformer oil. PCBs which not completely removed by chemical treatment, after being filtered with appropriate adsorbent during the oil circulations, was thermally treated. Destruction efficiencies of better than 99.99% was obtained, with no measurable formation of PCDDs (polychlorinated dibenzo-p-dioxins) or PCDFs (polychlorinated dibenzofurans). The combination also permits high recovery of oil and inorganic supports from scrap power transformers. The process is environmentally benign, easy to use and less capital intensive than other available technologies.

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용액공정 기반의 Zinc Oxide 박막 트랜지스터의 제작 및 특성 평가

  • Hwang, Yeong-Hwan;Seo, Seok-Jun;Jeon, Jun-Hyeok;Bae, Byeong-Su
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.25.2-25.2
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    • 2009
  • 최근 아연산화물과 같은 무기산화물 박막 트랜지스터를 디스플레이의 구동 소자, RFID, 스마트 창으로 활용하기 위한 연구가 많이 이루어지고 있다. 특히, 산화아연 박막 트랜지스터는 기존의 비정질 실리콘이나 저온 제작된 다결정 실리콘을 active layer로 사용해 제작된 소자에 비하여 AMOLED나 AMLCD를 구동하기 충분한 전자 이동도, 환경적으로 안정한 특성을 보이고 비교적 저렴한 가격으로 제작 가능하며 넓은 밴드갭으로 인하여 가시광선 영역에서 투명한 특성을 보인다. 본 연구에서는 Zinc acetate dehydrate를 전구체로 사용하고 ethanolamine 을 솔 안정화제로 사용하여 간단하고 경제적인 솔-젤 방법을 통하여 Zinc Oixde (ZnO)를 active layer로 사용한 박막 트랜지스터를 제작하였다. ZnO 박막 트랜지스터는 전구체 용액을 기판 위에 스핀 코팅한 후 열처리 과정을 통하여 제작되었고 제작된 ZnO 박막 트랜지스터는 가시광선 영역에서 높은 투과도 (>90%) 를 보였다. 산화 아연 박막 트랜지스터의 특성을 향상 시키기 위하여 전구체 용액의 농도 조절, ZnO 박막의 두께 조절, 열처리 온도의 조절 등과 같은 연구를 수행하였다. 여러 공정 조건의 변화를 통하여 최적화된 ZnO 박막 트랜지스터는 전하 이동도가 9.4 cm^2/Vs, sub-threshold slope이 3.3 V/dec 그리고 on-to-off current ratio가 5.5${\times}$10^5로 디스플레이 소자를 구동하기 충분한 특성을 보였다.

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Study on Materials and Process Systems for $CO_2$ separation from Combustion of Fossil Fuels (배기가스에서 이산화탄소 분리를 위한 재료 및 공정에 대한 이론적 고찰)

  • Han, Sang-Il;Hwang, Kyu-Suk
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.375-386
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    • 2014
  • Carbon dioxide ($CO_2$) is a green-house gas which causes the global warming problems. Anthropogenic emissionspredominantly from the combustion of coal, oil, and natural gas in electricity generations are expected to increase continuously in the future, resulting in increased $CO_2$ concentration in the atmosphere. In this study, we investigated materials properties and process systems for $CO_2$ separation with an emphasis of the post-combustion process.

Determination of the Coagulant Injection Methods for Efficient Treatment of Industrial Wastewater (산업폐수의 효율적 처리를 위한 응집제의 주입방법 결정)

  • Park, Se-Jin;Jung, Byung-Gil
    • Journal of the Korean Society for Environmental Technology
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    • v.19 no.6
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    • pp.570-575
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    • 2018
  • The various of raw wastewater inflows to the industrial wastewater treatment plants everyday. This makes it difficult to operate the coagulation and flocculation efficiently as a pretreatment process for the industrial wastewater treatment. Additionally, it causes loads on evaporation and membrane facilities which are the posttreatment and alternative processes. For this reason, this study sampled raw wastewater before and after the NaOH injection. An experiment was conducted to compare the coagulation characteristics according to the methods of coagulant injection (single injection, simultaneous injection, consecutive injection, and inverse injection) aiming at efficient treatment of industrial wastewater. The coagulation experiment was conducted using a jar tester. The TDS removal efficiency by the coagulant injection methods increased in the order of consecutive injection (2.8 %) < single injection (3.9 %) < simultaneous injection(8.1 %) < inverse injection(9.6 %); the TOC removal efficiency grew in the order of single injection (84.3 %) < inverse injection (86.2 %) < consecutive injection (88.6 %) < simultaneous injection (89.1 %); the turbidity removal efficiency grew from single injection (99.7 %) < consecutive injection (99.8 %) ${\fallingdotseq}$ inverse injection (99.8 %) < simultaneous injection (99.9 %). These results show that the simultaneous inorganic coagulant-polymer coagulant injection method was more efficient than the consecutive injection method (inorganic coagulant ${\rightarrow}$ polymer coagulant).

Reinforcement of Calcium Phosphate Bioceramics through Microstructure Control

  • Yun, Gyeong-Min;Gong, Yeong-Min;Jeong, Dae-Yong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.42.2-42.2
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    • 2009
  • 인체의 치아 및 뼈는 무기질 성분과 단백질로 구성되어 있다. 생체세라믹스의 일종인 수산화아파타이트(Hydroxyapatite, HA; $Ca_{10}(PO_4)_6(OH)_2$)는 결정학적, 화학적으로뼈의 무기질 성분과 거의 유사하여 실제 체내에 들어가면 주위 뼈와 화학적 반응을 하여 단단한 결합을 이루는 생체활성(bioactive)을 가진 것으로 알려져 있다. 또한, 인산삼칼슘(Tri-Calcium Phosphate, TCP; $Ca_3(PO_4)_2$)은 체내에 이식 시 체액에 용해되어 신생골을 유도하는 생체흡수성(bioresorbable) 세라믹스로 알려져 있다. 상기 2종류를 포함한 인산칼슘계 화합물은 우수한 생체친화성에도 불구하고 역학 특성이 낮아, 하중을 거의 받지 않는 분야에만 사용되고 있는 실정이며, 하중을받는 분야(load-bearing part)에 적용하기 위해서는 고강도/고인성의 세라믹스와의 micro-composite이나 인산칼슘계화합물을 금속 표면에 코팅한 macro-composite의 형태로 사용되고 있다. 하중을 거의 받지 않는 분야, 예를 들어 치아 결손부를 보충할 dental shot과 같은 인산칼슘계 다공질 골충전재의 경우에도 취급 시 잘게 파손되는 문제점이 있어 치과의사들이 어려움을 호소하고 있는 실정이다. 본 연구에서는 HA, TCP의 역학특성을 증진시키고자 소결 공정 제어를 통하여 미세조직을 변화시켰으며, 미세조직 변화에 따른 세포반응성을 골포세포주를 이용하여 평가하였다.

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Thermally Curable Organic-inorganic Hybrid Coatings on Ophthalmic Lenses by the Sol-Gel Method (졸-겔법에 의한 안경렌즈의 열경화형 유-무기 하이브리드 코팅)

  • Yu Dong-Sik;Lee Ji-Ho;Ha Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.3
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    • pp.465-470
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    • 2006
  • Coating are needed on ophthalmic lenses to enhance both the mechanical durability of the relatively soft plastic surface and the optical performance of lenses. Organic-inorganic hybrid materials as molar ratio of 3-glycidoxypropyltrimethoxysilane(GPTS), methyltrimethoxysilane(MTMS) and tetraethyl orthosilicate(TEOS) were used to improve the surface characteristics and the optical properties on allyl diglycol carbonate lenses. Coating for these plastics were at $140^{\circ}C$ for 4hrs, applied using the sol-grl process flow-coating technique. The coated lens properties of transmittance, adhesion, pencil hardness, abrasion resistance, hot water resistance and chemical resistance were investigated. The optimum properties was obtained when the ratio of GPTS : MTMS : TEOS was 1:1:2, respectively.

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