• Korean Journal of Food Science and Technology
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• v.24 no.4
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• pp.335-340
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• 1992

The amounts of salt diffused into radish after immersing in various concentrations of salt solution at different temperatures were measured and the changes of radish texture by the salt diffusion were estimated with the viscoelastic constants of a 3 element solid model determined by a stress relaxation test. The amount of salt diffused through radish was increased with increasing the salt concentration and soaking temperature. While the instantaneous stress, equilibrium elastic solid content and viscoelastic constants of radish were decreased as salt concentration and soaking temperature increased, the stress relaxed fast. Viscoelastic constants as well as the diffusivity were influenced by salt concentration more than by soaking temperature. The rheological equations for the predictable stress changes of radish after immersed in the salt solution at various conditions (temperature, salt concentration and impure salt) were suggested as a function of time.

• Resources Recycling
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• v.20 no.6
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• pp.28-36
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• 2011

The adsorption of nickel(Ni) from sulfuric acid solution was carried out by ion exchange method. A series of batch tests in synthetic solutions were carried out using Lewatit Monoplus TP 220 resin. The following experimental parameters, such as temperature, shaking rate, reaction time, pH, resin dosage and concentration of nickel ions etc. were investigated to establish the effective optimum conditions of nickel adsorption. The solution pH(2.0~5.0) and shaking rate had little effects on the adsorption of nickel and adsorption time of 72hours was required to reach equilibrium. The experimental results show a good agreement with Feundlich isotherm and pseudo-second order reaction. The adsorption behavior of Ni obtained from synthetic solution was compared with that of waste electroplating solution. Elution of nickel from loaded resin increased with increase in $H_2SO_4$ concentration.

• Geophysics and Geophysical Exploration
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• v.18 no.3
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• pp.143-153
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• 2015

Polymer flooding for enhancing hydrocarbon production injects into a reservoir polymer solution that is viscous. It is very important to monitor the behavior pattern of the polymer solution in order to evaluate the effectiveness of polymer flooding. To monitor the distribution of polymer solution and thus fluid substitution within the reservoir, we first construct seismic and resistivity rock physics models (RPMs), which are functions of reservoir parameters such as rocks and type of fluid, fluid saturation. For the seismic and resistivity RPMs, responses of seismic and electromagnetic (EM) tomography are numerically simulated as polymer injection, using two dimensional (2D) staggered-grid finite difference elastic modeling and 2.5D finite element EM modeling algorithms, respectively. In constructing RPM for EM tomography, three different reservoir rocks are considered: clean-sand, dispersed shale-sand, and sand-shale lamination rocks. The polymer solution is assumed to have 2 wt% of polymer as normally generated, while water is freshwater or saltwater. Further, neutron logging is also considered to check its sensitivity to polymer flooding. The techniques discussed in the paper are important in monitoring not only hydrocarbon but also geothermal reservoirs.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.5
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• pp.535-541
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• 2005

Peat humin(p-Humin) extracted from Canadian Sphagnum peat moss was packed in a column and removal of heavy metal ions such as Cd, Cu and Pb from aqueous solution under flow conditions was studied. The metal ions were removed not only from single-element solutions but also from a multi-metal solution. Column kinetics for metal removal were described by the Thomas model. For single-component metal solutions, the maximum adsorption capacities of the p-Humin for Pb, Cu and Cd were 138.8, 44.66 and 41.61 mg/g, respectively. The results of multi-component competitive adsorption showed that adsorption affinity was in the order of Pb $\gg$ Cu > Cd. The adsorbed metal ions were easily deserted from the p-Humin with 0.05 N $HNO_3$ solution. It is apparent that 95% of the heavy metal ions were recovered from the saturated column. This investigation provides possibility to clean up heavy-metal contaminated waste waters by using the natural biomass, p-Humin as an environmentally friendly and cost-effective new biosorbents.

• Journal of the Korean Society of Groundwater Environment
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• v.6 no.2
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• pp.95-100
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• 1999

Hydrocarbon compounds in vadose zone soils caused by adsorption onto the surfaces of solid particles are generally considered to show retardation effect. In this study, we investigated the retardation effect on the transport of Benzene in a sandy soil by conducting batch and column tests. The batch test was conducted by equilibrating dry soil mass with Benzene solutions of various initial concentrations. and by analyzing the concentrations of Benzene in initial and equilibrated solutions using HPLC. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used KCl and Benzene solutions with the concentration of 10 g/L and 0.88 g/L as a tracer, and injected them into the inlet boundary of the soil sample as a square pulse type respectively, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and HPLC. From the batch test, we obtained a distribution coefficient assuming that a linear adsorption isotherm exists and calculated the retardation factor based on the bulk density and porosity of the column sample. We also predicted the column BTC curve using the retardation factor obtained from the distribution coefficient and compared with the measured BTC of Benzene. The results of the column test showed that i) the peak concentration of Benzene was much smaller than that of KCl and ⅱ) the travel times of peak concentrations for the two tracers were more or less identical. These results indicate that adsorption of Benzene onto the sand panicles occurred during the pulse propagation but the retardation of Benzene caused by adsorption was not present in the studied soil. Comparison of the predicted with the measured BTC of Benzene resulted in a poor agreement due to the absence of the retardation phenomenon. The only way to describe the absolute decrease of Benzene concentration in the column leaching experiment was to introduce a decay or sink coefficient in the convection-dispersion equation (CDE) model to account for an irreversible sorption of Benzene in the aqueous phase.

• The Korean Journal of Rheology
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• v.2 no.2
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• pp.45-55
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• 1990

분자량이 큰 고분자의 구조가 점탄성에 미치는 영향을 설명하기 위해 선형-선형 고 분자 블랜드에 적용되었던 equivalent primitive chain 모델을 블랜드의 긴 완화시간을 갖는 사슬이 엉킴이중용한 star 고분자를 포함하는 고농도 용액에 까지 확장한다. 긴 완화시간을 갖는 사슬의 완화현상에서 이 사슬의 국부에서 주의 사슬들의 제약이 해제되므로서 일어나 는 현상의 고려하여 분자량과 사슬구조는 다르나 화학적 성질은 같은 이성분계 고분자 블랜 드의 유변학적 거동을 설명한다.

• Polymer Science and Technology
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• v.15 no.3
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• pp.274-285
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• 2004

콜로이드 결정 (Colloid crystal)이란 용액 상에서 부유 하는 작은 입자들의 자기 조립 (self-assembly)에 의해 형성된 주기적인 2차원 혹은 3차원 구조를 말한다. 이러한 결정 구조는 광학 필터나 스위치, 광 밴드 갭 재료, 바이오 센서 등의 과학 기술적인 응용을 비롯하여 액화 물질의 상 변화 등과 같은 물리적 현상을 규명함에 있어서 중요한 모델을 제시한다. 특히 최근에 콜로이드의 자기 조립체는 자연적으로 갖게 되는 주기적인 유전율 변화 때문에 빛의 진행 방향이나 특성을 조절할 수 있는 광자 결정 (Photonic Crystal) 구조 제작의 경쟁력 있는 접근 방법으로 각광 받고 있다. (중략)

• Proceedings of the Korean Nuclear Society Conference
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• 1996.11a
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• pp.140-144
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• 1996

Trickle bed를 이용하여 고분가 촉매에 의한 용존산소 제거반응을 수행하였다. 고분자 촉매는 폴리스티렌-디비닐 벤젠의 공중합체로 이루어진 담체를 제조하여 백금 용액을 함침시킨 후 수소로 환원하여 제조하였다. trickle bed는 수소 및 산소로 포화되어 있는 물을 향류식으로 접촉할 수 있도록 설계하였다. 이 경우는 액상 실험 장치와 달리 포화기가 없기 때문에 장치는 비교적 단순하였으나 컬럼내에 축적되는 액상의 축적이 중요한 운전변수로 나타났다. trickle bed에서의 용존산소 제거 거동을 semi-empirical relation으로 나타내어 실험치와 비교한 결과 예측된 모델과 매우 잘 일치하는 것으로 나타났다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.3 no.2
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• pp.141-145
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• 2002

Successive ion Exchange Column model was developed with the combination of mass action law and mole balance equation. consuming that ions entering the ion exchange bed pass the resin layer via consecutive ion exchange equilibrium. The application of the model to condensate polishing demineralizer in nuclear power plants indicates that the leakage of $Na^+$ and $Cl^-$ depends upon the degree of resin regeneration and that the ratio of specific ion concentration in Influent to in effluent is subject to the characteristics of resin and solution. The model can account for the local in-equilibrium with the correction of resin concentration and also can be applicable to a competitive ion exchange.

• Journal of the Korean Society of Marine Environment & Safety
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• v.12 no.4 s.27
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• pp.253-259
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• 2006

This paper investigated on anti-corrosion characteristic in chemical decontamination at extremely severe condition{process model-2) of stainless steels used with reactor coolant pump. The electrochemical properties of stainless steel{STS) 304 with the lapse qf cycle is better than those of STS 415 and STS 431. The STS 304 in process model-1 and process model-2 present the lowest weightloss ratio. The experiment results for STS 304, STS 415, and STS 431 in process model-2 solution, it was ascertained that weightloss ratio of process model-2 solution for process model-1 solution show 2..908, 2.572, and 2.370 times, respectively. The reason suggests that process model-2 is higher concentration of chemical and temperature compare to process model-1.