• Title/Summary/Keyword: 메탄생성

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Hydrocarbon Source Rock Potential of Eocene Forearc and Subduction Zone Strata, Southern Oregon Coast Range, U.S.A. (미국 오레곤 남부 에오세 전호상 및 섭입대 퇴적층의 탄화수소 근원암 가능성)

  • Ryu, In-Chang
    • The Korean Journal of Petroleum Geology
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    • v.11 no.1 s.12
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    • pp.27-41
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    • 2005
  • The hydrocarbon source rock potential of the Eocene units in the southern Oregon Coast Range was evaluated by using the Rock-Eval pyrolysis. Most Eocene units in southern Oregon Coast Range are thermally immature and contain lean, gas-prone Type III kerogen. However, some beds(coals) are sufficiently organic-rich to be sources of biogenic and thermogenic methane discovered in numerous seeps. The overall hydrocarbon source rock potential of the southern Oregon Coast Range is moderately low. Several requirements for commercial accumulations of hydrocarbon, however, probably exist locally within and adjacent areas. Three speculative petroleum systems are identified. The first includes the southern part of the Oregon Coast Range near the border with the Mesozoic Klamath Mountains and is related to a proposed subduction zone maturation mechanism along thrust faults. The second is centered in the northern part of the range and may be associated with basin-centered gas in an over-pressured zone. The third occurs near the eastern border of the range where maturation is related heating by sills and migration of hydrothermal fluids associated with mid-Tertiary volcanism in the Western cascade arc.

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Combustion Characteristics of Volume Variation of Torch in a CVCC (토치 점화 장치의 체적에 따른 연소특성 파악)

  • Kwon, Soon-Tae;Kim, Hyeong-Sig;Choi, Chang-Hyeon;Park, Chan-Jun;Ohm, In-Young
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2010.04a
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    • pp.166-170
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    • 2010
  • Six different size of torch-ignition device were applied in a constant volume combustion chamber for evaluating the effects of torch-ignition on combustion. The torch-ignition device was designed six different volumes and same orifice size. The combustion pressures were measured to calculate the mass burn fraction and combustion enhancement rate. In addition, the flame propagations were visualized by shadowgraph method for the qualitative comparison. The result showed that the combustion pressure and mass burn fraction were increased when using the torch ignition device. And the combustion duration were decreased. The combustion enhancement rates of torch-ignition cases were improved in comparison with conventional spark ignition. Finally, the visualization results showed that the torch-ignition device the torch-ignition induced faster burn than conventional spark ignition due to the earlier transition to turbulent flame and larger flame surface, during the initial stage. And the initial flame propagation was effected torch-ignition volume.

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Anticancer and Immuno-activity of Methanol Extract from Onion Kochujang (양파고추장 메탄올추출물의 항암 및 면역활성)

  • Kim Jae-Yong;Park Kyung-Wook;Yang Hyun-Sook;Cho Young-Sook;Jeong Chang-Ho;Shim Ki-Hwan;Yee Sung-Tae;Seo Kwon-Il
    • Food Science and Preservation
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    • v.12 no.2
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    • pp.173-178
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    • 2005
  • Antitumor activities of methanol extract from onion Kochujang (MEOK) were investigated by using aflatoxin $B_{1}-mediated$ Salmonella typhimurium mutagenicity and the model of cytotoxicity on the cancer cell lines. Their immune activities were also investigated using mouse spleen cells and macrophage cell lines, respectively. MEOK showed the enhanced antimutagenicity in a dose-dependent manner. relative to the control group. MEOK decreased over $20\%$ of the proliferation of the A549(lung cancer cell) and MCF(breast cancer cell) cell lines at $1,000\;{\mu}g/mL$ concentration compared with the control cells. The proliferation of mouse spleen cells and the NO production in marcrophage cell lines treated MEOK were increased in a dose-dependent manner, respectively. The activities were higher than that of the control(no added onion) Kochujang.

$CH_4-H_2-N_2 $ 기체계에서 MW-PACVD를 이용한 결정상의 합성

  • 김도근;백영준;성태연
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.54-54
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    • 1999
  • 다이아몬드 합성시 질소 첨가는 Cn 화합물의 합성가능성을 비롯하여 다이아몬드의 질소 도핑, 성장 속도 및 결정성 변화 등 다양한 관점에서 중요한 의미를 가지고 있다. 본 연구에서는 다이아몬드의 일반적인 합성조건에서 질소를 첨가하여 합성된 막의 형상 및 상 변화에 대해 고찰하였다. 막은 다이아몬드 전처리시킨 Si 기판위에 microwave plasma CVD 장치를 이용하여 합성하였다. 유입되는 혼합가스(CH4+H2+N2)에서 N2 첨가량을 0-95%까지 변화시켰다. 이때 CH4 농도는 5%로 고정하였고, 합성온도는 90$0^{\circ}C$-115$0^{\circ}C$까지 변화시켰다. 이와 같이 합성된 막의 표면조직 및 성장 두께를 측정하기 위해 주사전자현미경을 이용하였다. 상의 분석은 Raman, XRD 및 TEM 분석을 이용하였으며, 조성분석을 위해 XPS 및 AES를 사용하였다. 질소 첨가량에 따라 합성된 막은 첨가하지 않은 경우에 다이아몬드 결정에서 시작하여 질소첨가에 따라 결정면이 깨지는 것으로 나타났다. 그러나 30%, 45%의 경우는 다시 결정면이 나타났다. 다량의 질소가 첨가되었을 때, 다시 결정면을 보이는 다이아몬드가 합성된 것은 매우 흥미로운 결과이다. 한편 질소와 메탄만의 기체하에서는 다시 결정면이 관찰되지 않았다. 이들 상의 구조는 XRD 및 TED 분석을 통해 모두 다이아몬드로 확인되었다. 기체내의 질소의 첨가에 관계없이 고상내에 질소는 확인되지 않았다. 따라서 이방법에 의한 CN 화합물의 합성은 힘든 것으로 보여진다. 이들 실험 결과를 근거로 온도 및 조성에 따른 기체의 열역학적 계산을 통하여 합성거동과의 연관성을 검토하였다. anode는 매우 높은 충전용량을 갖는데 첫 번째 방전시에 Li2O를 생성하여 비가역적 반응을 나타내고 계속되는 충방전 동안 Li-Sn 합금이 생성되어 2차전지의 가역적 반응을 가능하게 한다. SnO2 는 대기중에서 Li 금속보다 안정하기 때문에 전지의 제작 공정 및 사용 면에서 매우 우수한 물질이지만 아직까지 SnO2 구조적 특성과 전지의 충, 방전 특성에 대한 관계의 규명을 위한 정확한 정설은 제시되고 있지 못하다. 본 연구에서는 TFSB anode 물질로써 SnOx박막을 상온에서 여러 전도성 콜렉터 위에 증착하여 그 충, 방전 특성을 보고하였다. 증착된 SnOx박막의 표면은 SEM, AFM으로 분석하였으며 구조의 분석은 XR와 Auger electron spectroscope로 하였다. 충, 방전 특성을 분석하기 위하여 리늄 foil을 대극과 참조 전극으로 하여 EC:DMC=1:1, 1M LiPF6 액체 전해질을 사용한 Half-Cell를 구성하여 100회 이상의 정전류 충, 방전 시험을 행하였다. Half-Cell test 결과 박막의 구조, 콜렉터의 종류 및 Sn/O비에 따라 서로 다른 충, 방전 거동을 나타내었다.다. 거의 없었다. 5mTorr 일 때가 가장 좋았다.수 있음을 알 수 있었다. 그러므로, RNA바이러스의 하나인 BVDV의 viral replicon을 이용하여 다양한 종류의 포유동물 세포에 유전자 발현벡터로써 사용할 수 있음으로 post-genomics시대에 다양한 종류의 단백질 기능연구에 맡은 도움이 되리라 기대한다.다양한 기능을 가진 신소재 제조에 있다. 또한 경제적인 측면에서도 고부가 가치의 제품 개발에 따른 새로운 수요 창출과 수익률 향상, 기존의 기능성 안료를 나노(na

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Removal of tar and particulate from gasification process using pre-coating technology (바이오매스 가스화 공정의 생성가스 중 타르 및 입자 제거를 위한 pre-coating 기술 연구)

  • Kim, Joon-Yub;Choi, Byoung-Kwon;Jo, Young-Min;Kim, Sang-Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.804-815
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    • 2019
  • Due to the depletion and environmental problems of fossil fuel, biomass has arisen as an alternative energy source. Biomass is a renewable and carbon-neutral source. However, it is moister and has lower energy density. Therefore, biomass needs thermal chemical conversion processes like gasification, and it does not only produce a flammable gas, called 'syngas', which consists of CO, H2, and CH4, but also some unwanted byproducts such as tars and some particulates. These contaminants are condensed and foul in pipelines, combustion chamber and turbine, causing a deterioration in efficiency. Thus this work attempted to find a method to remove tars and particles from syngas with a filter which adopts a pre-coating technology for preventing blockage of the filter medium. Hydrated limestone powder and activated carbon(wood char) powder were used as the pre-coat materials. The removal efficiency of the tars was 86 % and 80 % with activated carbon(wood char) coating and hydrated limestone coating, respectively.

Modeling Residual Chlorine and THMs in Water Distribution System (배급수계통에서 잔류염소 및 THMs 분포 예측에 관한 연구)

  • Ahn, Jae-Chan;Lee, Su-Won;Rho, Bang-Sik;Choi, Young-Jun;Choi, Jae-Ho;Kim, Hyo-Il;Park, Tae-Jun;Park, Chang-Min;Park, Hyeon;Koo, Ja-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.6
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    • pp.706-714
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    • 2007
  • This study suggested a method for prediction of residual chlorine and THMs in water distribution system by measurement of residual chlorine, THMs, and other parameters, estimation of chlorine decay coefficients and THM formation coefficients, and simulation of water qualities using pipe network analysis. Bulk decay coefficients of parallel first-order were obtained by bottle tests, and pipe wall decay coefficients of first-order were estimated through evaluation of 5 models, which showed the lowest values of 0.03 for MAE(mean absolute error) and 0.037 MAE in comparison with the observed in field. And bottle tests were conducted to model first-order reaction of THM formation by nonlinear least square regression and the resultant coefficients were compared with the observed in field. As a result, the coefficients of determination$(R^2)$ for the observed and the predicted values were 0.98 in September and 0.82 in November, and the formation of THMs was predicted by modeling.

Analysis of Nitrosamines Concentration in Condom by using LC-MS/MS (LC-MS/MS를 이용한 콘돔에 함유된 니트로사민류 농도 분석)

  • Park, Na-Youn;Kim, Sungmin;Jung, Woong;Kho, Younglim
    • Journal of the Korean Chemical Society
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    • v.62 no.3
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    • pp.181-186
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    • 2018
  • Nitrosamines are the nitrosocompounds which are produced by nitrosation reactions of the secondary amine and nitrite, and has been found to be produced through the vulcanization process during the production of rubber products Recently, nitrosamines have been detected in rubber products and become a major topic. Condoms are disposable medical devices, so safety is important because they come into direct contact with the skin and mucous membranes. In this study, we developed an analytical method for nitrosamines in condoms by applying ISO 29941 method. The samples were eluted by distilled water, and target compounds were extracted by liquid-liquid extraction with dichloromethane. And then after concentrated, and quantitatively analyzed by LC-MS/MS. The accuracies of the analytical method were ranged from 85.8 to 108.7%, precisions were lower than 11.5%, and the detection limits were from 0.11 (NDPA and NDBA) to 0.48 (NPYR) ng/mL. Among the 31 condom samples, NDBA was detected from 2 cases by extraction of distilled water, and NDMA were detected from 1 case, NDEA from 4 cases and NDBA from 26 cases by extraction of artificial saliva (pH 4.5). The total amount of nitrosamines in all samples were less than $500{\mu}g/kg$.

Numerical Study of Combustion Characteristics by Pressure and Oxygen Concentration in Counter-Flow Diffusion Flame Model (대향류 확산 화염 모델에서의 압력 및 산소분율에 따른 연소 특성 변화에 관한 수치해석 연구)

  • Park, Jinje;Lee, Youngjae
    • Clean Technology
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    • v.27 no.1
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    • pp.93-103
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    • 2021
  • As the seriousness and necessity of responding to climate change and reducing carbon emissions increases, countries around the world are continuing their efforts to reduce greenhouse gases. Among various efforts, research on CCUS, capturing and utilizing carbon dioxide generated when using carbon-based fuels, is actively being conducted. Studies on pressurized oxy-fuel combustion (POFC) that can be used with CCUS are also being conducted by many researchers. The purpose of this study is to analyze basic information related to the flame structure and pollutant emissions of pressurized oxy-fuel combustion. For this, a counter-flow diffusion flame model was used to analyze the combustion characteristics according to pressure and oxygen concentration. As the pressure increased, the flame temperature increased and the flame thickness decreased due to a reaction rate improvement caused by the activation of the chemical reaction. As oxygen concentration increased, both the flame temperature and the flame thickness increased due to an improvement to the reaction rate and diffusion because of a change in oxidizer momentum. Analyzing the related heat release reaction by dividing it into three sections as the oxygen concentration increased showed that the chemical reaction from the oxidizer side was subdivided into two regions according to the mixture fraction. In addition, the emission index of NO classified according to the NO formation mechanism was analyzed. The formation trend of NO according to each analysis condition was presented.

Proposal of a Pilot Plant (2T/day) for Solid Fuel Conversion of Cambodian Mango Waste Using Hybrid Hydrothermal Carbonization Technology (하이브리드 수열탄화기술을 이용한 캄보디아 망고 폐기물 고형연료화 실증플랜트 (2T/day) 제안)

  • Han, Jong-il;Lee, Kangsoo;Kang, Inkook
    • Journal of Appropriate Technology
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    • v.7 no.1
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    • pp.59-71
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    • 2021
  • Hybrid hydrothermal carbonization (Hybrid HTC) technology is a proprietary thermochemical process for two or more organic wastes.The reaction time is less than two hours with temperature range 180~250℃ and pressure range 20~40bar. Thanks to accumulation of the carbon of the waste during Hybrid HTC process, the energy value of the solid fuel increases significantly with comparatively low energy consumption. It has also a great volume reduction with odor removal effect so that it is evaluated as the best solid fuel conversion technology for various organic wastes. In this study of the hybrid hydrothermal carbonization, the effect on the calorific value and yield of Cambodian mango waste were evaluated according to changes in temperature and reaction time. Through the study, parameter optimization has been sought with improving energy efficiency of the whole plant. It is decomposed in the Hydro-Carbonation Technology to Generate Gas. At this time, it is possible to develop manufacturing and production technologies such as hydrogen (H2) and methane (CH4). Based on the results of the study, a pilot plant (2t/day) has been proposed for future commercialization purpose along cost analysis, mass balance and energy balance calculations.

Study of Imaging of Submarine Bubble Plume with Reverse Time Migration (역시간 구조보정을 활용한 해저 기포플룸 영상화 연구)

  • Dawoon Lee;Wookeen Chung;Won-Ki Kim;Ho Seuk Bae
    • Geophysics and Geophysical Exploration
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    • v.26 no.1
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    • pp.8-17
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    • 2023
  • Various sources, such as wind, waves, ships, and gas leaks from the seafloor, forms bubbles in the ocean. Underwater bubbles cause signal scattering, considerably affecting acoustic measurements. This characteristic of bubbles is used to block underwater noise by attenuating the intensity of the propagated signal. Recently, researchers have been studying the large-scale release of methane gas as bubble plumes from the seabed. Understanding the physical properties and distribution of bubble plumes is crucial for studying the relation between leaked methane gas and climate change. Therefore, a water tank experiment was conducted to estimate the distribution of bubble plumes using seismic imaging techniques and acoustic signals obtained from artificially generated bubbles using a bubble generator. Reverse time migration was applied to image the bubble plumes while the acquired acoustic envelope signal was used to effectively estimate bubble distribution. Imaging results were compared with optical camera images to verify the estimated bubble distribution. The water tank experiment confirmed that the proposed system could successfully image the distribution of bubble plumes using reverse time migration and the envelope signal. The experiment showed that the scattering signal of artificial bubble plumes can be used for seismic imaging.