• Transactions of the Korean Society of Automotive Engineers
• /
• v.3 no.3
• /
• pp.129-139
• /
• 1995

This study investigates the combustion characteristics of methane-hydrogen-air premixture in a constant volume combustion chamber. Primary factors of the combustion characteristics of methane- hydrogen-air premixture are the equivalence ratio and hydrogen supplement rate. In the case of $\phi$= 1.1, maximum combustion pressure and heat release rate have peaks, and they increase as the initial pressure and hydrogen supplement rate increase. The total burning time is also the shortest at the $\phi$= 1.1, it shorten by lowering the initial pressure and by increasing the hydrogen supplement rate. The maximum flame temperature is shown at the $\phi$= 1.0, and increasing the initial pressure and hydrogen supplement rate, it increases. The concentration of NO reveals the highest value at the $\phi$= 0.9, and it increases by increasing the initial pressure and hydrogen supplement rate. It is also found that the limit of lean inflammability of methane-hydrogen-air premixture is greatly widened by increasing the hydrogen supplement rate.

• Journal of the Korean Society of Safety
• /
• v.17 no.2
• /
• pp.112-117
• /
• 2002

The effects of shield gas on the structure of methane-air nonpremixed counterflow flames were numerically investigated. The near extinction flame of a low global strain rate 20 $s^{-1}$ of 19% methane diluted by 81% nitrogen by volume and undiluted air was computed. The flame shape, centerline temperature and axial velocity profiles were compared for different velocity of the shield gas and with and without the shield gas. The effects of the velocity of the shield gas were negligible for $V_{S}/V_{F}{\leq}2$ in normal gravity. Under normal gravity conditions, the flame shape and its position with the shield gas were different from those of the flame without the shield gas, whereas no discernible effects of the shield gas along the centerline were observed in zero gravity.

• Journal of the Korean Society of Combustion
• /
• v.4 no.2
• /
• pp.63-74
• /
• 1999

The effects of EGR and premixedness on NO formation have been numerically investigated. The flame structure is classified into three categories; premixed flame($=1)$, rich/lean premixed flame(${\alpha}=0.6$ and 0.8) and diffusion flame(${\alpha}=0$). NO formation/destruction mechanisms are assorted to thermal, reburn and Fenimore mechanisms. The temperature of unburned gas is arranged to 298 and 500 K to have access to the condition in a real internal combustion engine. The results show that all three NO formation/destruction reaction rates in the fuel rich flame zone could be decreased by EGR for rich/lean premixed flames, while those in the fuel lean flame zone are not significantly changed. Near the stagnation plane, however, only the thermal NO reaction rate is decreased. The contribution of reburn and Fenimore mechanisms for the net NO production becomes less significant as the premixedness of a flame increases. The larger amount of NO reduction with EGR is expected under the higher temperature and/or higher fuel/air premixedness conditions due to the increased contribution of the thermal mechanism. The role of Fenimore and reburn mechanisms could be important for rich premixed and diffusion flames; therefore, the effect of EGR on NO reduction could vary with fuel/air premixedness. The premixedness of a partially premixed flame changes the flame structure and could affect the NO production characteristics.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2012.05a
• /
• pp.318-323
• /
• 2012

This study is conducted to scrutinize agitation effects of an ultrasonic standing wave on the dynamic behavior of methane/air premixed flame. The propagating flame is caught by high-speed schlieren images, through which flame front and local flame velocity are analyzed and obtained, too. It is revealed that the propagation velocity with ultrasonic standing wave is larger than the case without excitation except around the flammability limits. Also, vertical locations of distortions and depth of dents of the front are constant, unless the ultrasonic standing wave characteristics are not changed.

• Journal of Advanced Marine Engineering and Technology
• /
• v.35 no.4
• /
• pp.406-413
• /
• 2011

Recently the fuel cell has been spotlighted as a technology to reduce greenhouse gases emission from a ship. In this research, internal reforming 500kW solid oxide fuel cell stacks fueled by methane for a ship were developed. Characteristics of power and efficiency depending on the number of cells in the stack, hydrogen conversion ratio, and active area of the cell are evaluated. Also the effects of air and methane supplying conditions on performance are analyzed. As a result, as the number of cells, hydrogen conversion ratio, active area of the cell, or supplied air flow rate increase, the stack power and efficiency increase. When the methane flow rate increases, the power increases. However the efficiency decreases. In addition, the case at the current of 976.4 A, voltage of 529.1 V, with corresponding power of 516.6 kW shows that the efficiency of fuel cell stack is 42.91%.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.35 no.4
• /
• pp.431-438
• /
• 2011

Flame lift-off conditions determine the operating conditions of burners. It is known that a flame can be lifted when the Schmidt number (Sc), which is the ratio of the dynamic viscosity to the mass diffusivity, is greater than unity. In this study, the flame lift-off characteristics of non-premixed flames of propane (Sc > 1) and methane (Sc < 1) in a coaxial outer air tube were experimentally compared. The experimental results indicated that stable lifted flames could be obtained even when Sc < 1 in a confined air tube. On the basis of the results of a simple numerical analysis, it was confirmed that a new flame stabilization mechanism exists in the tube. A velocity field is preferentially developed upstream of the flame, and it results in a new stabilization condition. This result can be very useful in explaining the stabilization of the flames of ordinary burners in which a flame is produced in a confined space.

• Economic and Environmental Geology
• /
• v.36 no.3
• /
• pp.149-157
• /
• 2003

Deep sea core samples were taken in the southwestern part of the Ulleung Basin in order to characterize the properties of shallow gases in the sediment. Amount of shallow gases in the sediments were calculated by head space techniques, and chemical and isotopic compositions of hydrocarbon gases were analyzed. Geochemical analyses were carried out on the gas bearing sediments to find out relationship between natural gas contents and organic characteristics of the sediments. Seismic characteristics of shallow gases in the sediments were also examined in this study. The amount of the hydrocarbon gases in the sediments range from 0.01% to 11.25%. Calculation of volume of gas per volume of wet sediment varies from 0.1 to 82.0 ml HC/L wet sediment. Methane consists 98% of the total hydrocarbon gases except for two samples. Based on the methane content and isotopic composition$(\delta^{13}c)$: -94.31$\textperthousand$~-55.5$\textperthousand$), the hydrocarbon gases from the sediments are generated from bacterial activities of methanogenic microbes. Contents of hydrocarbon gases are variable from site to site. Volume of shallow gases in the sediments shows no apparent trends vs. either characteristics of organic matter or particle sizes of the sediments. Gas concentration is high in the area of seismic anomalies such as blanking zone or chimney structures in the section. Physicochemically the pore water and the formation water systems are saturated with gases in these areas. Concentration of hydrocarbon gases in the sediments in these area shows favorable condition for generation of gas hydrate, as far as the other conditions are satisfied.

• Applied Chemistry for Engineering
• /
• v.9 no.5
• /
• pp.619-623
• /
• 1998

The influences of reaction temperature, HF/DCM mole ratio, contact time and catalyst type on activity and selectivity of difluoromethane synthesis via hydrofluoriation of dichloromethane over fluorinated catalyst have been studied. It has been found that fluorinated $Cr/Al_2O_3$ catalysts, show better performance compared to pure fluorinated $Al_2O_3$ catalyst and then, non-treated catalysts demonstrate better than catalysts pretreated with hydrogen and air. The results show that the optimum reaction conditions are found as follows : reaction temperature at $340^{\circ}C$, mole ratio of HF/DCM 5 or above and contact time 20 sec. or above. With these conditions the maximum attainable yield of difluoromethane has been found to be greater than 80%. In particular, the activity and the selectivity of difluoromethane do not change with the reaction time on stream up to 8 hours.

• Journal of Power System Engineering
• /
• v.13 no.6
• /
• pp.22-28
• /
• 2009

열역학 제 2법칙의 관점의 열역학적 가용에너지인 엑서지 해석법을 적용하여 가솔린, 메탄올, M90 연료를 사용한 전기점화 기관의 성능해석을 수행하였다. 열역학적 사이클 해석을 위하여 사이클을 구성하는 각 과정은 열역학적 모델로 단순화하였고, 크랭크 각도에 따른 실린더의 압력과 작동유체를 구성하는 연료, 공기 및 연소생성물의 열역학적 물성 값들을 이용하여 각 과정에서의 엑서지와 손실 일을 계산하였다. 실험데이터는 단기통 전기점화기관을 가솔린, 메탄올과 M90(메탄을 90%+부탄 10%의 혼합연료)을 연료로 WOT(Wide Open Throttle), MBT(Minimum advanced spark timing for Best Torque), 2500rpm 조건으로 운전하여 측정하였다. 계산에 이용한 자료는 실험으로 측정한 크랭크 각도에 따른 연소실의 압력, 흡입공기와 연료유량, 흡입공기 온도, 냉각수 온도와 배출가스 온도 등이다. 이를 이용하여 각 과정에서의 엑서지와 손실 일을 계산하였으며 각 과정에서의 손실 일은 연소과정에서 가장 크며 팽창과정, 배출과정, 압축과정 및 흡입과정 순으로 크게 나타났다.

• Journal of the Korean Institute of Gas
• /
• v.8 no.2 s.23
• /
• pp.42-47
• /
• 2004

The axisymmetric methane-air counterflow flame in microgravity was simulated to investigate effects of the global strain rate on the flame structure. The flame shapes and profiles of temperature and the axial velocity for the mole fraction of methane in the methane-nitrogen fuel stream, Xm= 20, 50, $80\%$, and the global strain rate, ag= 20, 60, 90 $s^{-1}$ each mole fraction were compared. The profiles of the temperature and axial velocity of the axisymmetric simulations were in good agreement with those of OPPDIF, an one-dimensional flamelet code. It was confirmed that the flame is stretched more and the flame radius increases and the flame thickness decreases as the global strain rate increases.