• 한국염색가공학회지
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• 제25권4호
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• pp.262-270
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• 2013

Temporarily solubilized reactive disperse dyes containing ${\beta}$-sulfatoethylsulfonyl group were applied to 100% meta-aramid knitted fabric and their dyeing properties were investigated. Reactive disperse dyes showed relatively high K/S values on meta-aramid fabric when compared with conventional disperse dye or reactive dye, which showed very low K/S values. Color yields of reactive disperse dyes were highly dependent on dyeing pH and optimum results were obtained at pH 6. Percent exhaustion of reactive disperse dye on meta-aramid fabric was over 80% at 2% o.w.f of dye concentration. Wash fastness of pyridone-based reactive disperse dyes was very good to excellent while that of aminoazobenzene reactive disperse dyes was medium to good. Light fastness of all the reactive disperse dyes was very poor which seems to be due to the low photostability of meta-aramid fiber itself.

• 한국염색가공학회지
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• 제32권3호
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• pp.128-134
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• 2020

Heat and flame protecting cloth is usually made of meta aramid fiber because of its own properties. But the high inter molecular hydrogen bonding and high Tg is the reason of the difficulty to dye meta aramid fiber. Recently, it was commercialized that the easily dyeable meta aramid fiber(AMD) for improving dyeability. In this study, the dyeing properties of AMD dyed with cationic dyes were investigated. The K/S values of AMD were 5~10% higher than these of general meta aramid fiber(AM) in the case of 1%owf caused by the lower crystallinity of AMD. The difference between K/S values of AMD and AM was increased as increasing dyeing concentration. The washing and rubbing fastness grade of AM and AMD were similar and good to very good.

• 한국염색가공학회지
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• 제33권3호
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• pp.97-104
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• 2021

In this study, the dyeability of m-aramid fabric with various cationic dyes using two bath two step dyeing method were investigated. The exhaustion properties of Doracryl series recommend for aramid(Doracryl^® Red GL 100%(DR), Doracryl^® Blue GL 300%(DB), Doracryl^® Yellow XGRL 200%(DY)) and commercial cationic Synocryl series(Synocryl^® Red GRL ED(SR), Synocryl^® Blue GSL ED(SB), Synocryl^® Yellow 3RL ED(SY)) for acrylic were measured by using Dye-O-meter. In the presence of carrier, the exhaustions of Doracryl series were higher to those of Synocryl series and the opposite phenomenon was observed in the absence of carrier. And the severe migrations of cationic dyes to acetate, nylon and wool fabrics were observed without carrier.

• 한국염색가공학회지
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• 제29권1호
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• pp.18-24
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• 2017

Meta-aramid fabric has been widely used as the reinforcement of composites due to its high flame resistance and tearing strength. Functionality such as abrasion resistance of fabric is very important for specialty fabrics used in car racing suits. In this study, to improve abrasion resistance property of meta-aramid fabric, silicon deposition was conducted by utilizing RF magnetron sputtering. The sputtering process parameters effects were investigated as sputtering power and substrate temperature. The obtained results suggest that the silicon deposition on the meta-aramid fabric has obvious effect upon increasing the abrasion resistance, the thermal insulation and the electric resistance condition for silicon deposition was established. In conclusion, the results of this study have made it possible to manufacture meta-aramids with higher abrasion strength.

• 한국염색가공학회지
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• 제25권4호
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• pp.292-302
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• 2013

Cotton fabrics treated with hybrid materials were developed and prepared. A halogen-free flame retardant and an aromatic amide were blended and applied to cotton fabrics. Thermal and physical properties of the treated cotton fabrics were investigated. The surface of the pure and coated cotton fabrics was characterized by Fourier transform infrared spectroscopy. The elemental composition of the coated surface of the cotton fabric was measured using X-ray photoelectron spectroscopy and compared with that of pure cotton fabric. After being solved in N,N-dimethylacetamide, m-aramid and triphenylphosphine oxide (TPP) were applied to cotton fabrics through a dip-pad-coagulation process. The treated cotton fabrics with recycled m-aramid/TPP resulted in increased limited oxygen index values and thermal resistance.

• 한국염색가공학회지
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• 제29권3호
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• pp.131-138
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• 2017

Most of high performance fabrics for the car racing protective clothing have been developed to have thermal resistance, flame retardant property, impact resistance and anti-frictional properties to protect the racer from the crucial accident. In this study, the meta-aramid fabric, which has inherent flame retardant, was coated with nanoparticles of SiC to enhance the impact resistance and anti-friction properties. Uniform coating of the nanoparticles onto the fabrics was obtained by using tape casting method. As the experimental parameters, size and content of the SiC nanoparticle were varied with the coating conditions of the fabric surface. The effects of the nanoparticle coating on the properties of meta-aramid fabric were examined with various instrumental analyses such as SEM, tensile strength and abrasion test.

• 한국염색가공학회지
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• 제34권3호
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• pp.157-164
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• 2022

This study tried to analyze the heat resistance properties by blending epoxy and phenolic resin in a certain ratio, and to analyze the adhesive properties at the time of metal-polymer hetero-adhesion by applying Epoxy-phenolic resin between a silicon steel sheet and m-aramid sheet, the viscosity, adhesive peel strength, and adhesive cross section were measured using a rotational rheometer, a tensile tester(UTM), and a field emission scanning electron microscopy(FE-SEM). The thermal stability and heat resistance were confirmed by measuring the mass loss according to the temperature increase using Thermogravimetric analysis(TGA). After blending with epoxy and Phenolic resin(1:0.25 ratio) curing at 110℃ for 10 min, high adhesive strength was improved more than 40% compared to the adhesive strength using epoxy alone. When the space between the silicon steel sheet and m-aramid sheet, which is created during curing of the E-P blend, is cured with a slight weight, it is possible to control the empty space and improve adhesion.

• 폴리머
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• 제34권3호
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• pp.202-209
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• 2010

열적 안정성과 기계적 강도에서 우수한 장점을 지니고 있는 메타계 aramid segment와 제막 특성이 우수하고 내가수분해성이 우수한 sulfone segment로 이루어진 공중합체를 이용하여 연료 전지용 막으로서의 응용가능성을 연구하였다. 아라미드 고분자의 solubility와 processability를 향상시키기 위해 아민기를 갖는 sulfonated ether sulfone단량체와 m-phenylene diamine 그리고 isophthaloyl chloride를 반응시켜 아민으로 말단화된 랜덤공중합체를 합성하고 이것을 acryloyl chloride와 반응시켜 양 말단에 2중 결합이 도입된 고분자전구체를 합성하였다. 얻어진 고분자전구체는 열 가교를 통해 고분자 전해질 막으로 제조되었으며, 전구체의 합성을 비롯한 각 단계의 반응은 $^1H$ NMR, FTIR, 및 적정에 의하여 확인되었다. 얻어진 전해질막은 이온교환용량과 함수율, 수소이온전도도, 열적 특성 등이 측정되었으며, sulfonated ether sulfone 단량체의 함유량이 증가할수록 이온교환용량, 함수율, 수소이온전도도가 증가하는 것이 관찰되었다. Sulfonic acid sulfone segment를 30 몰%로 갖는 고분자 전해질 막의 경우 이온교환용량이 1.57 meq/g, 함수율은 44 wt% 이하의 수치를 보였으며, 가장 높은 수소이온전도도의 값은 상대습도 100%, $25^{\circ}C$에서 $3.93{\times}10^{-2}S/cm$이었다.