• Title/Summary/Keyword: 메커니즘 생성

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Research and Development Trends in Seawater Electrolysis Systems and Catalysts (해수 수전해 시스템 및 촉매 연구 개발 동향)

  • Yoonseong Jung;Tuan Linh Doan;Ta Nam Nguyen;Taekeun Kim
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.567-575
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    • 2023
  • Water electrolysis is undergoing active research as one of the promising technologies for producing effective green hydrogen. Using seawater directly as a raw material for a water electrolysis system can solve the problem of the limitations of existing freshwater raw materials, as seawater accounts for approximately 97% of the water on Earth. At the same time, abundant by-product materials can be obtained, representative examples of which are Cl2, ClO-, Br2, and Mg(OH)2 produced during electrolysis, depending on their composition and pH environment. In order to develop a successful seawater electrolysis system and oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) catalysts, it is necessary to understand the causes and consequences of reactions that occur in the seawater environment. Therefore, in this paper, we will investigate the reaction mechanism and characteristics of the seawater electrolysis system as well as the research and development trends of electrochemical catalysts used in anode and cathode electrodes.

A Study for Analyzing the Mechanism of Enhanced Cementitious Reactivity of Bottom Ash by Using Functional Grinding Agent (기능성 분쇄조제를 통한 건조저회의 시멘트 반응성 메커니즘 분석 연구)

  • Ahyeon Lim;Hyunuk Kang;Juhyuk Moon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.3
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    • pp.271-280
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    • 2024
  • In this study, commercially available chemical activator was utilized as a grin din g agen t for bottom ash to develop bottom ash blended cement. The hydration characteristics of the bottom ash blended cement were analyzed using X-ray diffraction and thermogravimetric analysis. In particular, the PONKCS method was employed to quantify the amorphous C-S-H and bottom ash. The use of chemical activator delayed the hydration reaction of the cement and reduced the reactivity of the bottom ash. However, appropriate delay of hydration and enhanced reaction of aluminate successfully led to the formation of a substantial amount of monocarboaluminate. Consequently, the use of chemical activator greatly improved the compressive strength of the bottom ash blended cement, resulting in the 20240713development of high-performance bottom ash blended cement.

Trusted Execution Environment (TEE)-Based Blockchain Offline Payment Protocol (신뢰실행환경(TEE) 기반의 블록체인 오프라인 결제 프로토콜)

  • Donghyun Jeong;Beomjoong Kim;Junghee Lee
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.34 no.5
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    • pp.1021-1035
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    • 2024
  • This paper proposes the TEE-BOP (Trusted Execution Environment-Based Blockchain Offline Payment) protocol for blockchain-based offline payments. TEE-BOP securely manages offline balances within a Trusted Execution Environment (TEE) and efficiently verifies initial deposit proofs recorded on the blockchain using Merkle trees. Additionally, it ensures secure and tamper-proof transactions in offline environments by guaranteeing the reliability of keys and the system through TEE Attestation. Unlike previous studies, TEE-BOP enhances real-world applicability by eliminating dependence on central authorities and avoiding assumptions of ideal models. The protocol solves the double-spending problem through multi-layered defense mechanisms and addresses forgery prevention by allowing recipients to directly verify data consistency between the TEE and the blockchain. This enables reliable blockchain-based offline payments in areas with unstable network infrastructure. It demonstrates that this research can expand the application of blockchain technology and contribute to improving access to financial services in developing countries or disaster situations.

Anti-Inflammatory Effects of Extracts from Ligustrum ovalifolium H. Leaves on RAW264.7 Macrophages (RAW264.7 대식세포에서 왕쥐똥나무잎 추출물의 항염증 효과)

  • Kim, Yon-Suk;Lee, Seung-Jae;Hwang, Jin-Woo;Kim, Ee-Hwa;Park, Pyo-Jam;Jeong, Jae-Hyun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.9
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    • pp.1205-1210
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    • 2012
  • This study investigated the anti-inflammatory effects of Ligustrum ovalifolium H. (LOH) leaf extracts on RAW264.7 macrophages. Cell toxicity was determined by MTT assay. We evaluated the anti-inflammatory effects of LOH extracts by measuring nitric oxide (NO), reactive oxygen species (ROS), inducible NOS (iNOS) production, and cyclooxygenase-2 (COX-2) expression by Western blotting. LOH ethanolic extracts (0.05, 0.1, and 0.2 mg/mL) significantly suppressed LPS-stimulated production of NO. The intracellular ROS level also significantly decreased. LOH ethanolic extracts reduced the expression of iNOS and COX-2 proteins. The present results show that LOH ethanol extract has potent anti-inflammatory effects on RAW264.7 macrophages. These results also suggest that the anti-inflammatory effects of LOH extracts may be related to the inhibition of LPS-stimulated ROS and NO production. Therefore, ethanolic extracts of LOH leaves may be utilized as a good source of functional foods for protection against inflammatory diseases.

Ozone Oxidation of PAHs in the Presence of Soil (I): Ozonation of Soil Slurry Phase (Ozone에 의한 PAHs 오염토양 복원 연구(I): 토양슬러리상 오존 산화)

  • Lim, Hyung-Nam;Kim, Ji-Yeon;Choi, Heechul
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.869-877
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    • 2000
  • A mechanism of ozonation of simulated soil slurry contaminated by phenanthrene and benzo[a]pyrene has been studied under various conditions. The effects of soil media(BS, S, GB), radical scavenger, ozone input ratio(0.17~0.73mg/min), bicarbonate ion, and humic acid were investigated, BS showed the highest removal efficiency in media tested. The generation of OH-radical via the catalytic decomposition of ozone on active sites of the natural sand was confirmed by OH-radical scavenger experiments. The enhanced removal efficiency by OH-radical was indirectly quantified to be about 22%. As initial concentration of humic acid(as sodium salt) was increased, pseudo first-order rate constant ($k_o$) of phenanthrene was decreased from $1.37{\times}10^{-2}s^{-1}$ to $0.53{\times}10^{-2}s^{-1}$. The amount of ozone required to oxidize 80% of the initial mass of phenanthrene(10mg/kg) and benzo[a]pyrene(10mg/kg) was 67.2mg/kg-soil and 48.0mg/kg-soil, respectively.

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Mechanisms of Korean red ginseng and herb extracts(KTNG0345) for anti-wrinkle activity (홍삼 생약 복합물(KTNG0345)의 피부 주름개선에 관한 작용기전)

  • So, Seung-Ho;Lee, Seong-Kye;Hwang, Eui-Il;Koo, Bon-Suk;Han, Gyeong-Ho;Chung, Jin-Ho;Lee, Min-Jung;Kim, Na-Mi
    • Journal of Ginseng Research
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    • v.32 no.1
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    • pp.39-47
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    • 2008
  • UV irradiation causes skin-aging involving coarse wrinkles, thickening, dyspigmentation, and rough skin surface. These phenomena in complex skin tissue is controlled with receptor of cell surface growth factor and cytokine receptors. The activation of receptors induces multiple downstream signaling pathways including expression of MMPs (matrix metalloproteinases). This study was aimed to elucidate the mechanism for anti-wrinkle activity of Korean red ginseng, Torilis fructus and Corni fructus mixture (KTNG0345). In this animal study, we have investigated decreasing effects of Korean red ginseng mixture on MMP-3 synthesis through diminishing $TNF-{\alpha}$ signaling that express MMP-1, -3, and -9. c-Jun and c-fos as a component of transcription factor AP-1 (activator protein-1) were analyzed the expression level using real time PCR and western blotting. c-Jun was decreased dose dependent manner both gene and protein level where as cfos was not changed. In upstream, JNK and PAK was not changed, but p38 was decreased in down stream. MMP-3, final product in this pathway was significantly decreased in dose dependent manner. These results suggest that Korean red ginseng mixture have a anti-wrinkle activity through $TNF-{\alpha}$ mediated MMPs expression pathway.

An Analysis on the Roles and Strategies of Imagistic Simulation Observed in Mental Simulation about Problematic Situations of Prediction (예측의 문제 상황에 대한 멘탈 시뮬레이션에서 나타난 심상 시뮬레이션의 역할과 전략 분석)

  • Ko, Min-Seok;Yang, Il-Ho
    • Journal of The Korean Association For Science Education
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    • v.34 no.3
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    • pp.247-260
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    • 2014
  • Purpose of this study is to analyze the roles and strategies of imagistic simulation observed in mental simulation about problematic situation of prediction, and thereby identify the process of generating prediction, explanation and sophistication. For this study, a framework for mental simulation process and strategy based on literary research was developed and content was validated from four experts of science education. This study was participated by 10 preliminary elementary school teachers, and a total of 20 cases were gathered for two thought experiment tasks based on the think-aloud method. The results were as follows: First, mental simulation process described based on the seven elements of 'perception,' 'interpretation,' 'statement of initial representation,' 'running imagistic simulation,' 'identifying result of simulation,' 'identifying alignment' and 'restatement structured representation.' The study confirmed that initial representation by interpreting related concepts and running imagistic simulation a number of times to develop explanation and prediction. Second, the study identified the use of strategies to enhance simulation such as 'zoom in,' 'partition,' 'dimensional enhancement,' 'dimensional reduction,' 'remove,' 'replace' and 'extreme case.' Running spatial transformation that uses strategy to enhance simulation contributed to discovering mechanism elements in problematic situations.

Development of GML Map Visualization Service and POI Management Tool using Tagging (GML 지도 가시화 서비스 및 태깅을 이용한 POI 관리 도구 개발)

  • Park, Yong-Jin;Song, Eun-Ha;Jeong, Young-Sik
    • Journal of Internet Computing and Services
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    • v.9 no.3
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    • pp.141-158
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    • 2008
  • In this paper, we developed the GML Map Server which visualized the map based on GML as international standard for exchanging the common format map and for interoperability of GIS information. And also, it should transmit effectively GML map into the mobile device by using dynamic map partition and caching. It manages a partition based on the visualization area of a mobile device in order to visualize the map to a mobile device in real time, and transmits the partition area by serializing it for the benefit of transmission. Also, the received partition area is compounded in a mobile device and is visualized by being partitioned again as four visible areas based on the display of a mobile device. Then, the area is managed by applying a caching algorithm in consideration of repetitiveness for a received map for the efficient operation of resources. Also, in order to prevent the delay in transmission time as regards the instance density area of the map, an adaptive map partition mechanism is proposed for maintaining the regularity of transmission time. GML Map Server can trace the position of mobile device with WIPI environment in this paper. The field emulator can be created mobile devices and mobile devices be moved and traced it's position instead of real-world. And we developed POIM(POI Management) for management hierarchically POI information and for the efficiency POI search by using the individual tagging technology with visual interface.

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Role of Electrode Reaction of Electrolyte in Electrokinetic-Fenton Process for Phenanthrene Removal (동전기-펜턴 공정에서 전해질의 전극반응이 처리효율에 미치는 영향)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.11 no.1
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    • pp.7-13
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    • 2006
  • The effects of electrolytes were investigated on the removal efficiency when several different electrolytes were used to change the electrode reaction in an electrokinetic (EK)-Fenton process to remediate phenanthrene-contaminated soil. Electrical potential gradient decreased initially due to the ion entrance into soil and then increased due to the ion extraction from soil under the electric field. Accumulated electroosmotic flow was $NaCl>KH_2PO_4>MgSO_4$ at the same concentration because the ionic strength of $MgSO_4$ was the highest and $Mg(OH)_2$ formed near the cathode reservoir plugged up soil pore to inhibit water flow. When hydrogen peroxide was contained in electrolyte solution, removal efficiency increased by Fenton reaction. When NaCl was used as an electrolyte compound, chlorine ($Cl_2$) was generated at the anode and dissolved to form hypochlorous acid (HClO), which increased phenanthrene removal. Therefore, the electrode reaction of electrolyte in the anode reservoir as well as its transport into soil should be considered to improve removal efficiency of EK-Fenton process.

Key Update Protocols in Hierarchical Sensor Networks (계층적 센서 네트워크에서 안전한 통신을 위한 키 갱신 프로토콜)

  • Lee, Joo-Young;Park, So-Young;Lee, Sang-Ho
    • The KIPS Transactions:PartC
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    • v.13C no.5 s.108
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    • pp.541-548
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    • 2006
  • Sensor network is a network for realizing the ubiquitous computing circumstances, which aggregates data by means of observation or detection deployed at the inaccessible places with the capacities of sensing and communication. To realize this circumstance, data which sensor nodes gathered from sensor networks are delivered to users, in which it is required to encrypt the data for the guarantee of secure communications. Therefore, it is needed to design key management scheme for encoding appropriate to the sensor nodes which feature continual data transfer, limited capacity of computation and storage and battery usage. We propose a key management scheme which is appropriate to sensor networks organizing hierarchical architecture. Because sensor nodes send data to their parent node, we can reduce routing energy. We assume that sensor nodes have different security levels by their levels in hierarchy. Our key management scheme provides different key establishment protocols according to the security levels of the sensor nodes. We reduce the number of sensor nodes which share the same key for encryption so that we reduce the damage by key exposure. Also, we propose key update protocols which take different terms for each level to update established keys efficiently for secure data encoding.