• Title/Summary/Keyword: 매체별 배출량

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A Study and Analysis on Tritium Radioactivity and Environmental Behavior in Domestic NPPs (국내 원전 삼중수소 방사능 배출 및 환경 거동에 대한 분석 및 고찰)

  • Han, Sang Jun;Lee, Kyeong Jin;Yeom, Jeong Min;Shin, Dae Tewn
    • Journal of Radiation Protection and Research
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    • v.40 no.4
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    • pp.267-276
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    • 2015
  • Several analyses on tritium that is the largest release of gas or liquid radioactive waste from domestic PWR and PHWR NPPs were carried out, such as release comparison, directional frequency of wind and tritium behavior changes in environmental samples. First of all, analysis result showed that tritium released from PHWR was more than ten times as gas and double to three times as liquid in comparison to PWR in 2013. Independent release management in NPP units is needed to precisely control and analyze tritium, since there were 2 units of some NPPs having the same amount of release during analysis. In analysis on frequency of wind direction, average range showed 1.7 to 11.5% by 16-point compass. In case of analysis on sampling points by wind direction, Result showed most of the sampling points are right in places. However, There are some areas needed to examine. In analysis on tritium concentration changes in environmental samples, tritium concentration near NPPs was higher than one far away from NPPs. In case of environmental samples far from PWR, a trace of tritium occur. While, tritium concentration near NPPs was more than or equal to one further from PHWR. In conclusion, tritium occurs considerably in PHWR and is lower than standard in samples. but, it is still detected. Therefore, it is needed to strengthen control in system in NPPs and to consistently monitor tritium in environment.

The Environmental Hazard Assessment of Siting Restricted Industries from Industrial Complex in Rural Area Applied by Chemical Ranking and Scoring System (화학적 등급화기법을 적용한 농공단지 입주제한업종의 환경유해성 평가)

  • Hong, Sang-Pyo
    • Journal of Environmental Impact Assessment
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    • v.24 no.6
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    • pp.549-560
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    • 2015
  • The priorities of siting restriction was derived from quantification of environmental hazard according to industrial classification based on 'Chemical Ranking and Scoring System(CRS)' which is handling the discharge characteristics of 31 industrial classifications regulated from locating at 'Industrial Complex in Rural Area(ICRA)'. CRS that is utilizing the data of 'Pollutant Release and Transfer Registers(PRTR)' is applied to determine human health risk and ecological risk which are calculated by discharged amount and materials $LC_{50}$ according to water, soil and air media based on industrial classification. From this process, exposure assessment and toxicity assessment for integrating the adverse environmental impact and the mitigation effect of environmental risk according to the development of environmental technologies into establishing the rational landuse management method for the 31 industrial classifications regulated from locating at ICRA was analyzed. From the assessment result of the siting restriction removal at ICRA for 31 industrial classifications, based on 2012 year reference 6 industries that includes Manufacture of Guilt Coloration Surface Processing Steel Materials, Manufacture of Biological Product, Manufacture of Smelting Refining and Alloys of Copper, Dyeing and Finishing of Fibers and Yarns, Manufacture of Other Basic Iron and Steel n.e.c., Rolling Drawing and Extruding of Non-ferrous Metals n.e.c. are calculated as having relatively lower environmental hazards, thus it is judged that the siting restriction mitigation at ICRA is possible for the 6 industrial classifications that are not discharging the specific hazardous water contaminants during manufacturing process.

Fate Analysis and Impact Assessment for Vehicle Polycyclic Aromatic Hydrocarbons (PAHs) Emitted from Metropolitan City Using Multimedia Fugacity Model (다매체거동모델을 이용한 대도시 자동차 배출 Polycyclic Aromatic Hydrocarbons (PAHs) 거동 해석 및 영향평가)

  • Rhee, Gahee;Hwangbo, Soonho;Yoo, ChangKyoo
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.479-495
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    • 2018
  • This study was carried out to research the multimedia fate modeling, concentration distribution and impact assessment of polycyclic aromatic hydrocarbons (PAHs) emitted from automobiles, which are known as carcinogenic and mutation chemicals. The amount of emissions of PAHs was determined based on the census data of automobiles at a target S-city and emission factors of PAHs, where multimedia fugacity modeling was conducted by the restriction of PAHs transfer between air-soil at the impervious area. PAHs' Concentrations and their distributions at several environmental media were predicted by multimedia fugacity model (level III). The residual amounts and the distributions of PAHs through mass transfer of PAHs between environment media were used to assess the health risk of PAHs at unsteady state (level IV), where the sensitivity analyses of the model parameter of each variable were conducted based on Monte Carlo simulation. The experimental result at S-city showed that Fluoranthene among PAHs substances are the highest residual concentrations (60%, 53%, 32% and 34%) at all mediums (atmospheric, water, soil, sediment), respectively, where most of the PAHs were highly accumulated in the sediment media (more than 80%). A result of PAHs concentration changes in S-city over the past 34 years identified that PAHs emissions from all environmental media increased from 1983 to 2005 and decreased until 2016, where the emission of heavy-duty vehicle including truck revealed the largest contribution to the automotive emissions of PAHs at all environment media. The PAHs concentrations in soil and water for the last 34 years showed the less value than the legal standards of PAHs, but the PAHs in air exceeded the air quality standards from 1996 to 2016. The result of this study is expected to contribute the effective management and monitoring of toxic chemicals of PAHs at various environment media of Metropolitan city.

A Heatmap-based Leakage Location Estimation Algorithm for Circulating Fluidized Bed Boiler Tube Using Acoustic Emission Sensors (음향방출 센서를 이용한 히트맵기반 순환유동층 보일러 튜브 누설 위치 추정 알고리즘)

  • Kim, Jaeyoung;Kim, Jong-Myon
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2018.07a
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    • pp.51-52
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    • 2018
  • 화력발전용 순환유동층 보일러는 환경오염의 주요인인 질소산화물(NOx)과 황산화물(SOx)의 배출량이 적은 친환경 화력발전용 보일러로 화력발전 업계에서 각광받고 있는 추세이다. 그러나 순환유동층 보일러의 연료인 유동매체는 미분탄과 같이 작지만 단단한 고체이므로 유동매체의 타격으로 인해 워터월(waterwall) 튜브의 마모는 물론 누설까지 야기할 수 있다. 순환유동층 보일러 튜브에서 누설된 증기는 보일러 내부에 클링커(Clinker)를 발생시키고 이는 순환유동층 보일러 튜브 표면에 응고되어 열전도율을 감소시킬 뿐만 아니라 보일러 운전정지의 원인이 된다. 따라서 본 논문에서는 음향방출 센서를 이용하여 화력발전용 순환유동층 보일러 튜브의 누설 위치를 추정하는 방법을 제안한다. 제안 방법에서는 매질의 분자단위 이동에 의해 발생되는 탄성파를 감지할 수 있는 음향방출 센서를 이용하고, 보일러 워터월 튜브의 멤브레인 용접부와 비용접부(seamless)의 감쇠율을 고려한 위치별 센서 감도 추정 알고리즘을 통해 워터월 튜브의 위치별 진폭 크기를 히트맵으로 표현할 수 있다.

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Environmental Fate Tracking of Manure-borne NH3-N in Paddy Field Based on a Fugacity Model (Fugacity 모델에 기초한 논토양에서의 액비살포에 따른 암모니아성 질소 거동추적)

  • Kim, Mi-Sug;Kwak, Dong-Heui
    • Journal of Korean Society on Water Environment
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    • v.35 no.3
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    • pp.224-233
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    • 2019
  • Nitrogen components in liquid manure can reduce safety and quality of environment harmfully. To minimize the environmental risks of manure, understanding fate of manure in environment is necessary. This study aimed at investigating applicability of a simplified Level III fugacity model for simulating $NH_3-N$ component to analyze environmental fate and transport of $NH_3-N$ in liquid manure and to provide basis for improving management of N in the liquid manure system and for minimizing the environmental impacts of N. The model simulation conducted for four environmental compartments (air, water, soil, and rice plants) during rice-cropping to trace $NH_3-N$ component and provided applicability of the Level III fugacity model in studying the environmental fate of $NH_3-N$ in manure. Most of $NH_3-N$ was found in water body and in rice plants depending upon the physicochemical properties and proper removal processes. For more precise model results, the model is needed to modify with the detailed removal processes in each compartment and to collect proper and accurate information for input parameters. Further study should be about simulations of various N-typed fertilizers to compare with the liquid manure based on a modified and relatively simplified Level III fugacity model.

Attrition Characteristics of Catalysts for a High Efficiency Water Gas Shift Process (고효율 수성가스 공정을 위한 촉매 마모 특성)

  • Jo, Jun Beom;Kim, Jae Ho;Lee, See Hoon
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.111-114
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    • 2010
  • In the attrition reactor for the American Society for Testing and Materials (ASTM) D5757-95, the attrition characteristics of catalysts for water gas shift reaction were investigated. The effects of attrition characteristics of low temperature shift catalysts (LTS) and high temperature shift catalysts (HTS) on fluidization phenomena and average particle size were investigated and compared with the attrition characteristics of sand particles. The particle size of catalysts was decreased and particle size distribution in attrition tube was changed due to the effect of gas injection. About 40~50 wt% samples of original catalyst particles were entrained and lost. The amount of fly ash of LTS catalyst was less than that of HTS. Also, the weight of entrained particles which had original particle size of $212{\sim}300{\mu}m$ was lower than any other cases.

저니토중 polychlorinated biphenyls(PCBs) 분석법에 관한 연구

  • 신호상;오윤숙
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.06a
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    • pp.99-107
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    • 1998
  • 전 세계에서 다양한 환경 매체를 통해 광범위하게 검출되고 있는 대표적 환경오염물질 (environmental pollutants)인 polychlorinated biphenyls(PCBs)의 국내 4대강 주요 하천 저니토양과 모공단 하천수 및 저니토중 오염도를 각 congener별로 또는 총량으로서 GC/MS 를 사용하여 정량하였다. 그 결과 4대강의 주요 지천중 낙동강의 사상공단근처의 저니토에서 총 PCBs가 가장 높은 290.87$\mu\textrm{g}$/kg이었고 한강의 왕숙천도 비교적 높은 221.l1$\mu\textrm{g}$/kg이었다. 모공단 하천수 및 저니토 중 PCBs를 분석한 결과 전 시료에서 검출되었으며 하천수 및저니토에서의 총 PCBs 농도(mean$\pm$S.D.)는 0.1069$\pm$0.0179$\mu\textrm{g}$/L 및 908.80$\pm$462.30$\mu\textrm{g}$/kg였으며, 이때 저니토에서의 농축계수는 0.85$\times$$10^4$였다. 저니토중 총 유기물함량과 저니토중 PCBs 잔류량의 조사에서 서로간 상관관계 (상관계수=0.7084)가 있음을 알 수 있었으나 PCBs 배출원에 의한 영향이 커서 정확한 상관관계를 얻기가 어려웠다. Congener-specific analysis에 의해 하천수 및 저니토 시료에서 공통적으로 검출된 대표적 congener는 52, 95, 101, 99,87, 110, 118, 149, 153, 138, 180 였다. 본 연구결과 하천수에서는 triCBs와 tetraCBs 가 비교적 높은 농도로 검출되었던 반면 저니토에서는 hexaCBs 및 heptaCBs가 다른 poylCBs에 비해 비교적 높은 농도로 검출되었다. 이상의 연구결과를 통해 모공단 하천수 및 저니토가 PCBs에 의해 심하게 오염되어 있음을 알 수 있고 국내의 주요 하천의 경우도 계속적인 모니터링이 필요함을 알 수 있다.

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Residue and risk assessment of veterinary antibiotics in manure-based composts and agricultural soils (가축분뇨 유래 퇴비 및 농경지 중 축산용 항생제의 잔류 및 위해성 평가)

  • Paik, Min-Kyoung;Ryu, Song-Hee;Kim, Sung-Chul;Hong, Young-Kyu;Kim, Jin-Wook;Kim, Jeong-Gyu;Kwon, Oh-Kyung
    • Journal of Applied Biological Chemistry
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    • v.64 no.2
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    • pp.177-184
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    • 2021
  • While veterinary antibiotics are used only in a part of the dose administered, the rest are excreted as urine or feces. Residual antibiotics enter the adjacent agricultural environments by spraying manure-based composts on farmlands and lead to secondary pollution. Therefore, it is necessary to develop the technique for post management such as regulatory levels of antibiotics in the agricultural environments. This study was conducted to compare by different matrices the amount of residual antibiotics such as tetracyclines and sulfonamides, which are known to be frequently used in Korea and to practice risk assessment by different antibiotics in soils before and after application of composts. Pre-treatment with modified typical method using buffer and solid phase extraction showed the recovery of composts and soils was more than 70% at ppb level and the limits of detection were 0.13-0.46 and 0.05-0.25 ㎍/kg, respectively. Analysis of manure-based composts revealed concentrations from 5.38 to 196.0 ㎍/kg for tetracyclines, from below the detection of limit (BDL) to 259.0 ㎍/kg for sulfonamides. In case of agricultural soils, residual concentrations of selected veterinary antibiotics were ranged 0.30-53.3 ㎍/kg, BDL-4.16 ㎍/kg respectively and the concentration level of tetracyclines, which had higher soil distribution coefficient (Kd) values, was higher than that of sulfonamides. There was a difference in human risk assessment by different antibiotics in soil before and after application of composts. But, it was indicated that detection values of all of 5 antibiotics were very safe on the basis that Hazard Quotient was safe below 1.

Mania Construction and Constitution based on Animation 'Full metal Alchemist's Character (애니메이션 '강철의 연금술사' 의 캐릭터를 중심으로 한 매니아 형성과 구조)

  • Park, Yoon-Sung;Kim, Hye-Sung;Lee, Ga-Young
    • The Journal of the Korea Contents Association
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    • v.6 no.12
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    • pp.253-260
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    • 2006
  • As media and product became variety, the propensity of the people is be coming various. From diversity, there we could search for some popularity is called 'the mania.' When Mania takes shape, the product will being longer even masses in these days only have short-term life. Also there are hundreds of animations that has short-term life whom people forgot everyday they watch. However, the animations could lasting its value which has the Mania. This thesis is a studies on the constitution of Mania from animation 'Fullmetal Alchemist's Character The BONES had made. We can learn that the audience were not just like the animation, but get crazy for it by comparing Japanese animation industry in those days; before it has been shrinking and manufacturing various contents from Fullmetal Alchemist means there is enough consumtions. There are many reasons to form Mania group, but specially the character symbols at the works as a whole. From this study is to know a cause of how the animation 'Fullmetal Alchemist' made huge Mania group, and significance value of the work those group left.

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