• Proceedings of the Optical Society of Korea Conference
• /
• 2009.10a
• /
• pp.18-19
• /
• 2009

• Polymer(Korea)
• /
• v.26 no.2
• /
• pp.209-217
• /
• 2002

We studied the mechanism of orientation of polyimide molecules which were irradiated by polarized UU (PUV) using polarized Fourier transform infrared (FT-IR) spectroscopy and ultraviolet (UV) spectroscopy, According to the measured UV spectra, we found PI films mainly absorb UV light less than 350 nm wavelength, therefore, UV light less than 360 nm induces photochemical reaction of PI. PUV irradiation of PI films caused decrease of all peak intensities in the FT-IR spectra. except the newly formed broad peak at $3244 cm^{-1}$, due to degradation of the PI molecules. The remaining PI molecules after photo-degradation showed predominantly perpendicular molecular orientation to the irradiated PUV polarization direction, due to the preferential degradation of PI molecules parallel to irradiated PUV polarization direction. However the rubbing of PI films induced reorientation of the PI molecules parallel to the rubbing direction. We also investigated the alignment of the liquid crystal by rubbing or PUV irradiation. Liquid crystals align perpendicular to the PUV polarization direction and parallel to the rubbing direction.

• Korean Journal of Optics and Photonics
• /
• v.20 no.5
• /
• pp.281-287
• /
• 2009

The optical anisotropy of rubbed PI(polyimide) film on patterned LCD glass substrate is analyzed using polarimetry. The direction of the optic axis and the magnitude of the very small retardation ($\sim$ 0.4 nm or less) is precisely measured by using a transmission ellipsometer. The variation of the optical anisotropy is presented as the curve of the optic axis versus the magnitude of the phase retardation and it is explained by using a simple optical model.

• Polymer(Korea)
• /
• v.26 no.4
• /
• pp.431-438
• /
• 2002

We studied the orientation behavior and thermal stability of polyimide (PI) molecules under irradiation of polarized UV (PUV) using polarized fourier transform infrared (FTIR) spectroscopy. In the case of PUV-exposed PI films, the remaining PI molecules after photo-degradation showed molecular orientation perpendicular to the irradiated PUV polarization direction predominantly, due to the preferential degradation of PI molecules parallel to the irradiated PUV Polarization direction. On the other hand, the rubbing of PI films induced reorientation of the PI molecules parallel to the rubbing direction. We also investigated the thermal stability of the alignment layers furled by rubbing and PUV irradiation on the PI films using Polarized FTIR. The thermal stability of the PUV irradiated PI alignment layer is lower than that of the rubbed PI layer due to the fragmentation reaction of the PI by PUV.

• Polymer(Korea)
• /
• v.30 no.4
• /
• pp.362-366
• /
• 2006

It was found by polarized FTIR spectroscopic studies that pentacene molecules are arranged with their molecular axes perpendicular to the substrate surface when pentacene films are deposited on a polyimide alignment layer. The ring plane in a pentacene molecule is arranged parallel to the rubbing direction of the polyimide alignment film while no specific arrangement of vertically deposited pentacene molecules was found for the film without rubbing. The pentacene band at $1296cm^{-1}$ which has a transition dipole moment parallel to the ring plane is much stronger in a polarized IR spectrum of parallel to the rubbing direction, whereas the band at $908cm^{-1}$ whose transition dipole align normal to the ring plane shows much stronger intensity in a spectrum of perpendicular to the rubbing direction. These findings indicate that orientation of polyimide chains affects the arrangement of pentacene molecules when they are deposited on a polyimide alignment film.

• Journal of Satellite, Information and Communications
• /
• v.10 no.1
• /
• pp.67-70
• /
• 2015

We studied the state of the dual liquid crystal (LC) alignment which displays both homeotropic and homogeneous alignment on blended polyimide (PI) layer. The research was conducted using rubbing method at different imidizing temperatures and the blended PI was made using homeotropic PI having an alkyl side chain and homogeneous PI without the side chain. The uniform LC alignments were achieved, and have thermal stability. The results of contact angles were similar to that of pretilt angles.

• Proceedings of the KIEE Conference
• /
• 1996.07c
• /
• pp.1603-1605
• /
• 1996

We have studied the static electricity and optical retardation generated by rubbing the surfaces of polyimide (PI) and polyamide (PA) films. The static electricity increases with the rubbing strength (RS) and varies with the different PI films. We also investigated how the differences in the rubbing fabric affects the magnitude of the induced static electricity; the order of this effect is nylon > rayon > cotton. The induced static electricity is not only directly related to the values of the specific resistivity of the rubbed PI films, but also the RS and the ability of the rubbing fabric to generate and add a static electric charge. The order of the optical retardation produced by the rubbing fabraic on rubbed PI films is nylon > rayon > cotton, coinciding with the order of the generated static electricity.

• Proceedings of the Optical Society of Korea Conference
• /
• 2003.02a
• /
• pp.304-305
• /
• 2003

파장 355 nm인 Nd：YAG 레이저의 3차 고조파 자외선 레이저빔을 이용하여 색소첨가 폴리이미드 필름을 광배향시키고 이것을 사용하여 액정셀을 제작하였다. 광배향으로 제작된 액정셀의 특성을 알아보기 위하여 정렬성, 광투과곡선, 응답시간 둥을 측정하여 러빙에 의한 액정셀과 비교하였다. 그 결과 광배향 액정셀은 러빙에 의한 액정셀에 비하여 정렬성, 선경사각, 광투과도 등의 특성은 떨어지나 낮은 문턱전압과 빠른 응답시간 특성을 가진 것으로 나타났다.

• Korean Journal of Optics and Photonics
• /
• v.26 no.4
• /
• pp.195-202
• /
• 2015

We developed a reflection ellipsometer so that one can measure the extremely small optical anisotropy of a rubbed polyimide alignment layer, without being disturbed by the residual anisotropy of the substrate. The optical anisotropy of the alignment layer was measured as rubbing strength was increased, and the measured anisotropy was compared to the retardation obtained by using a transmission-type ellipsometer, to confirm the reliability of our reflection ellipsometer. With this measured anisotropy we could verify the formation of an alignment layer by rubbing, and could quantitatively evaluate the formation of the alignment layer.

• Polymer(Korea)
• /
• v.32 no.3
• /
• pp.290-294
• /
• 2008

Induction mechanism of molecular orientations for a rubbed polymer film as an alignment layer was investigated using polarized UV/Vis spectroscopic experiments for polyimide and polyvinylcinnamate whose conjugated electrons are located along main chain and side chain, respectively. By determining anisotropy formed in the rubbed film, LC director formed in the LC cell, and orientation direction of deposited pentacene molecules, it was found that LC orientation was induced mainly by molecular interactions whereas surface microgrooves formed by the rubbing process affect the orientation direction of deposited pentacene molecules.