• Polymer(Korea)
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• v.38 no.5
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• pp.602-612
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• 2014

Polyurethanes containing poly(dimethyl siloxane) (PDMS) unit, PU-Si, were synthesized and their thermal and shape memory properties were investigated. Various amounts of PDMS units were incorporated via a solution polymerization method using mixed diols of poly(tetramethylene ether glycol) (PTMEG) and PDMS-diol as the soft segment (SS) and methylene diphenyl diisocyanate and 1,4-butanediol as the hard segment (HS). Two series of PU-Si samples with an HS content of 23% or 32% were prepared and analyzed. For PU-Si with an HS content of 23%, both the cold crystallization temperature ($T_{cc}$) and melt crystallization temperature of the SS domain moved higher temperature with increasing PDMS content, while the melting temperature ($T_m$) of the SS domain remained unaffected. The increase in HS content from 23% to 32% resulted in the increased $T_m$ and disappearance of $T_{cc}$. The shape recovery of PU-Si flim with an HS content of 32% increased while its shape retention decreased as PDMS content increased.

• Journal of the Korean Society of Costume
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• v.67 no.2
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• pp.68-87
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• 2017

The New Look, which Christian Dior presented in 1947, has been a source of inspiration for contemporary fashion designers, as well as designers for the House of Dior, and has a great influence on them. The purpose of this study is to compare and analyze the aesthetic characteristics of Christian Dior's New Look and the New Look that Christian Dior House designers reinterpreted. The subject and the scope of this study were limited to Christian Dior and the New Look designed by Gianfranco $Ferr\acute{e}$, John Galliano, and Raf Simons who are regarded as worthy successors. The research method was a literature review on previous studies on Christian Dior and related literatures to examine the history of the House of Dior and the aesthetic characteristics of the New Look presented by Christian Dior. Then, an empirical study was conducted through the analysis of collection photographs from 1989 to 2016 that were gathered from the Mode et Mode and Hi Fashion, and websites (British Vogue, Firstview). The results of the study were as follows. First, the aesthetic characteristics of Christian Dior's New Look in 1947 used femininity to express an elegant and beautiful woman, structural property to render the contours of a woman's body, and innovation that changed the formal and gloomy social atmosphere in the post-war years. Second, the aesthetic characteristics of the New Look by Christian Dior were compared with those of the New Look made by designers for the House of Dior. The elegant femininity of Dior can be seen as gorgeous femininity, and sensual femininity, minimalistic femininity, structurality is represented by the spatial structurality of Dior and $Ferr\acute{e}$, the organic structure of Galliano, and the orthodox structure of Simons. Moreover, Dior's retro innovativeness appeared to be $Ferr\acute{e}^{\prime}s$ androgyny innovation, Galliano's deconstructive innovation, and Simons' romantic futuristic innovation.

• Applied Chemistry for Engineering
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• v.30 no.1
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• pp.17-22
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• 2019

In this study, cationic gemini surfactants were synthesized by increasing the length of the hydrophobic chain and using 1,4-butanediol as a spacer, and the result was confirmed by $^1H-NMR$. The synthesized surfactant was a white powder, and Kraffts point was below $0^{\circ}C$. Surface tension measurements revealed that the evaluated critical micelle concentration (c.m.c) was $1.8{\times}10^{-3}{\sim}6.5{\times}10^{-4}mol/L$ with a surface tension of 22.5~26.1 dyne/cm at the c.m.c. The initial foam height for CG 14-6E-14 estimated by Ross-Miles method was 16 cm and after 5 minutes the height was 14 cm. It was confirmed that the initial foam force and foam stability were the highest. The foam test and emulsion stability of synthesized gemini cationic surfactants were also compared to those of cetyltrimethylammonium bromide (CTAB), a commoly used surfactant.

• Fashion & Textile Research Journal
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• v.22 no.6
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• pp.716-726
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• 2020

This study presents methods and alternative examples for fashion brands to effectively use video-based communication channels to form brand identity that analyzes the definition, status and type of YouTube channel fashion films as well as enables the ability to derive brand identity characteristics. Literature studies focused on Christian Dior's official website and related previous studies. The temporal range of the case studies was from October 7, 2010, the date when the first fashion film was uploaded to current Christian Dior YouTube to July 17, 2020 (the survey date), and there are a total of 550 subjects for quantitative analysis. The succession of the couture spirit means that Christian Dior's craftsmanship was created and passed down by Musée Christian Dior to act as a contemporary key element of brand identity. The iconic expression of femininity is Dior's core design philosophy that began when the woman image of a new era was presented through a new look, and Dior's femininity means a woman that reflects the character of the times as is interpreted as her own personality from the perspective of modernism through the creative directors of future generations. The brand's core identity code 'Miss Dior' expresses the brand's vision and eternity through perfume as well as targets Z generation male consumers through an emotional approach based on forms that used emotional images such as movie-type films.

• Journal of the Korean Society of Costume
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• v.57 no.9
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• pp.32-48
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• 2007

This study analyzed image components of make-up image between fashion and advertisement of Christian Dior, also, this study examined, compared and analyzed their aesthetic characters. Then, it researched whether brand image was shaped exactly as the same method or not. The study was theoretical and established method; using more than a graduate student-major in clothing and make up, survey$(2004.5{\sim}6.)$ and SPSS 10 program statistics method. As the results, in Dior fashion and make-up, this study analyzed the factors of shape, color, material and texture, and both of them indicated the aspects of chic, classic, gorgeous and romantic image. Also, consumers understood them as a same image. This demonstrated that Christian Dior fashion and make-up have been shaping toward a same image as a same meaning.

• Journal of the Korean Society of Costume
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• v.57 no.1 s.110
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• pp.83-92
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• 2007

The modern society has been experiencing a cultural quickening that is accompanied by the rapid social, political and economical changes. In the dim chaos where the future is uncertain, the modern women are gradually discovering the value and meaning of their existences in the society. The fashion and make-up Christian Dior presented in the Haute Couture collections suggest us various genres from which the remarkable creative and artistic accomplishments canbe found. This study is to examine the characteristics of make-up techniques used by Christian Dior for the Haute Couture collections after 2003 S/S. The conclusion of this study is as follows. The make-up trend in the Haute Couture collections suggest that the make-up today is not simply to decorate a face beautifully. The make-up has become a new art form for the modern women to express their various originality and creativity while linking it to the social and cultural elements.

• Journal of the Korean Applied Science and Technology
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• v.37 no.1
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• pp.49-55
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• 2020

In this study, isophorone diisocyanate (IPDI) and dimethylolbutanoic acid (DMBA) were used on the basis of poly caprolactone diol (3M, 3.5M, 4M, 4.5M) for the synthesis of water-based polyurethanes for coating on skin layers of leather. Tensile strength, elongation, and adhesive strength of the prepared samples were measured. As a result of measuring the tensile strength, the tensile strength was found to be 4.09 kgf / ㎟ when 3 moles were applied, and 1.071 kgf / ㎟ when 4.5 moles were applied. Elongation was 366 % when 3 moles of PCL were applied, and 709 % at 4.5 moles. Adhesive strength was 2.887 kgf / cm when 3 moles of PCL was applied and 0.998 kgf / cm when 4.5 moles were applied.

• Applied Chemistry for Engineering
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• v.25 no.5
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• pp.503-509
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• 2014

The carbon/porous silica composite membrane was fabricated in a simple manner, which could be successfully for the simultaneous separation and production of chiral epoxides and 1,2-diols, based on their differences in hydrophilic/hydrophobic natures. The chiral Co(III)-$BF_3$ salen catalyst adopted in the membrane reactor system has given the very high enantioselectivity and recyclability in hydrolysis of terminal epoxides such as ECH, 1,2-EB, and SO. The optically pure epoxide and the chiral catalyst were collected in the organic phase after hydrolysis reaction. The hydrophilic water-soluble 1,2-diol product hydrolyzed by chiral salen diffused into the aqueous phase through the SBA-16 or NaY/SBA-16 silica composite layer during the reaction. The water acted simultaneously as a reactant and a solvent in the membrane system. One optical isomer was obtained with high purity and yield, and furthermore the catalysts could be recycled without observable loss in their activity in the continuous flow-type membrane reactor.

• Clean Technology
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• v.24 no.3
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• pp.190-197
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• 2018

Various waterborne polyurethanes (WPU) with three different types of polyol such as ester type polyol [adipic acid (A)/BD/3-methyl-1,5-pentandiol (MPD) and A/BD]//carbonate type polyol (C/HD/MPD, C/HD, C/BD)//ether type polyol (PTMG) were prepared in this study. This study focused on the effect of polyol type on the properties of WPU. Soft segment Tg (Tgs), 100% elastic modulus and tensile strength were highest when using carbonate polyol, followed by ester polyol and ether polyol, while those of elongation showed the opposite trend. The WPU synthesized with MPD - containing polyol showed lower Tgs, 100% elasticity and strength, and higher elongation than MPD - free WPU. The % transmittance and transparency of the WPU film containing the MPD component was superior to that of the WPU film containing no MPD component, and it was found that the film based on carbonate polyol was slightly better than the film based on ester polyol and ether polyol.

• Elastomers and Composites
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• v.44 no.4
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• pp.447-454
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• 2009

We synthesized polyester-diol containing Cloisite 30B which is exfoliated during the synthesis. First, esterification was conducted with excess adipic acids and two 2-hydroxyethyl groups of the tertiary ammonium tethered to Cloisite 30B silicate layer. Due to the small molecular size of adipic acid ($d{\approx}3.0\;{\AA}$, $L{\approx}9.3\;{\AA}$), it penetrated into the interlayer of Cloisite 30B, reacted with the 2-hydroxyethyl groups, and produced the tertiary ammonium that has the two ethyl-ester adipic acid groups, one methyl group, and one hydrogenated alkyl group. Through the esterification, the molecular size of the tertiary ammonium increased and as the result, the basal space of Cloisite 30B increased from $18.4\;{\AA}$ to more than $58.3\;{\AA}$. The produced ethyl-ester adipic acid and unreacted adipic acid reacted with excess diethylene glycol ([COOH]/[OH]${\approx}0.6$) to be polyester-diol. The COOH conversion calculated from the acid value of the reactant mixture was 94%. The number average molecular weight and PDI of the produced polyester-diol were 830 g/mol and 1.2, respectively.