• Title/Summary/Keyword: 도금법

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Preparation of Pt-Black Absorber by Electroplating (전기도금법에 의한 백금 흑 수광체 제조)

  • Bae, Seong-Ho;Lee, Sang-Man;Lee, Mun-Ho
    • Korean Journal of Crystallography
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    • v.7 no.2
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    • pp.133-146
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    • 1996
  • Morphology and infrared absorbing characteristics of Pt-black prepared by electroplating have been investigated with XRD, SEM, and IR spectrophotometer. The Pt later was coated on Au-coated alumina/glass substrates for 1-5 min at pH 1.0-1.5, where a solution of platinum chloride and lead acetate was used as the electrolyte. At the electrical current density of 20-50 mA/㎠, the Pt-black showed a dendritic growth which was characterized by a "tree" shape. Absorptivity of above 90% at IR radiation of 10 m was observed for the Pt absorbing layer with an area density of ≥1.3mg/㎠.

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Copper Via Filling Using Organic Additives and Wave Current Electroplating (유기물 첨가제와 펄스-역펄스 전착법을 이용한 구리 Via Filling에 관한 연구)

  • Lee, Suk-Ei;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.3
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    • pp.37-42
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    • 2007
  • Copper deposition studies have been actively studied since interests on 3D SiP were increased. The defects inside via can be easily formed due to the current density differences on entrance, bottom and wall of via. So far many different additives and current types were discussed and optimized to obtain void-free copper via filling. In this research acid cupric sulfate plating bath containing additives such as PEG, SPS, JGB, PEI and wave current applied electroplating were examined. The size and shape of grain were influenced by the types of organic additives. The cross section of specimen were analyzed by FESEM. When PEI was added, the denser copper deposits were obtained. Electroplaing time was reduced when 2 step via filling was employed.

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Recovery of Nickel from Electroless Plating Wastewater by Electrolysis Method (전기분해법(電氣分解法)을 이용(利用)한 무전해(無電解) 니켈 도금폐액(鍍金廢液)으로부터 니켈 회수(回收))

  • Lee, Hwa-Young
    • Resources Recycling
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    • v.21 no.2
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    • pp.41-46
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    • 2012
  • An investigation on the recovery of nickel from spent electroless plating solutions has been performed using the electrowinning method. For this aim, nickel in spent electroless plating solutions was separated as nickel hydroxide through the addition of caustic soda. Nickel hydroxide was completely dissolved with sulfuric acid and an electrolysis was performed for electrowinning of nickel from nickel solutions. As a result, it was found that more than 99% of nickel in spent electroless plating solutions could be precipitated as nickel hydroxide above pH 10 with the addition of caustic soda. As far as the current efficiency in electrowinning of nickel was concerned, it was decreased with increase in the current density.

Deposition Kinetics and Properties of Cu Films Deposited on the TiN Substuate (TiN 기판위에 형성된 Cu막의 성장양상 및 막특성)

  • Gwon, Yeong-Jae;Lee, Jong-Mu
    • Korean Journal of Materials Research
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    • v.6 no.1
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    • pp.116-123
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    • 1996
  • CVD와 무전해 도금법을 이용하여 TiN 기판상에 구리막을 성장시켰고 그 각각에 대해 증착조건에 따른 성장막의 morphology, 성장기구 및 비저항, 막의 치밀성 등의 물리적 특성을 조사하였다. CVD 증착막의 결정립 크기와 입간의 기공은 막두께에 비례하여 커지는 경향을 나타내었으며 비저항은 4.7$\mu$$\Omega$cm로 구리의 체적비저항값과 거의 비슷한 것으로 나타났다. 무전해 도금막은 초기에는 layer-by-layer mode로 나중에는 is-land growth mode로 성장하는 경향을 보였다. CVD구리막의 막질은 후열처리 분위기에 따라서도 상당한 차이를 보였다. CVD구리막의 막질은 후열처리 분위기에 따라서도 상당한 차이를 보였으며, 활성화 에너지로부터 35$0^{\circ}C$를 기준으로 증착기구가 변하는 것을 확인할 수 있었던 반면, 무전해 도금은 60-8$0^{\circ}C$의 온도 구간에서 증착기구는 변하지 않았으나 도금 온도가 높을수록 막표면이 거칠어지는 경향을 나타내었다. 7:1 BHF 에칭 실험의 결과 무전해도금에 의한 구리막에 비해 CVD구리막의 에칭속도가 더 빨랐으며 막질도 덜 치밀한 것으로 나타났다.

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The Effects of Electroplating Parameters on the Mechanical Properties of Nickel-Iron Alloy Electrodeposits (Ni-Fe 합금 도금층의 기계적 물성에 영향을 미치는 도금인자)

  • Ko, Yeong-Kwon;Yim, Tai-Hong;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.4
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    • pp.71-76
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    • 2008
  • The mechanical properties of Ni-Fe alloy were varied with the current type, current density and bath conditions such as concentrations and temperature. The effect of electroplating parameters on the surface hardness, mechanical strength, residual stress and wear properties were investigated. The mechanical properties of electrodeposits with PC plating is superior to those with DC plating. Ni-Fe electrodeposits with PC has approximately 50% lower residual stress than that of DC plating. The tensile strength of PC electroplated specimen was 15% higher than that of DC electroplated specimen. The wear resistance of PC specimen was 30% improved relative to that of DC specimen.

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