• Title/Summary/Keyword: 대체석

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Mineralogy and Genetic Environments of the Seongdo Pb-Zn deposit, Goesan (괴산 성도 연-아연 광상의 산출광물과 생성환경)

  • Ahn, Seongyeol;Shin, Dongbok
    • Economic and Environmental Geology
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    • v.50 no.5
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    • pp.325-340
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    • 2017
  • The Seongdo Pb-Zn deposit, located in the northwestern part of the Ogcheon Metamorphic Belt, consists of skarn ore replacing limestone within the Hwajeonri Formation of Ogcheon Group and hydrothermal vein ore filling the fracture of host rock. Skarn minerals comprise mostly hedenbergitic pyroxene, garnet displaying oscillatory zonal texture composed of grossular and andradite, and a small amount of wollastonite, tremolite, and epidote, indicating reducing condition of formation. Ore minerals of skarn ore include sphalerite and galena with a small amount of pyrite, pyrrhotite, and chalcopyrite. In hydrothermal vein ore, arsenopyrite, sphalerite, chalcopyrite, and pyrite occur with a small amount of galena, native Bi, and stannite. Chemical compositions of sphalerite vary from 17.4 mole% FeS in average for dark grey sphalerite, 3.6 mole% for reddish brown sphalerite in skarn ore, and to 10.3 mole% FeS in hydrothermal vein ore. In comparison with representative metallic deposits in South Korea on the FeS-MnS-CdS diagram, skarn and hydrothermal vein ore plot close to the field of Pb-Zn deposits and Au-Ag deposits, respectively. Arsenic contents of arsenopyrite in hydrothermal vein ore decrease from 31.93~33.00 at.% in early stage to 29.58~30.21 at.% in middle stage, and their corresponding mineralizing temperature and sulfur fugacity are $441{\sim}490^{\circ}C$, $10^{-6}{\sim}10^{-4.5}atm$. and $330{\sim}364^{\circ}C$, <$10^{-8}atm$. respectively. Phase equilibrium temperatures calculated from Fe and Zn contents for coexisting sphalerite and stannite in hydrothermal vein are $236{\sim}254^{\circ}C$. Sulfur isotope compositions are 5.4~7.2‰ for skarn ore and 5.4~8.4‰ for hydrothermal vein ore, being similar or slightly higher to magmatic sulfur, suggesting that ore sulfur was mostly of magmatic origin with partial derivation from host rocks. However, much higher sulfur isotope equilibrium temperatures of $549^{\circ}C$$487^{\circ}C$, respectively for skarn ore and hydrothermal ore, than those estimated from phase equilibria imply that isotopic equilibrium has not been fully established.

Mineral Compositions and Distribution in the Drilling Cores from the Miocene Pohang Basin, Korea (마이오세 포항분지 시추코어의 구성광물과 분포특성)

  • Lee, Jinhyun;Hwang, Jinyeon;Son, Moon;Son, Byeong Seo;Oh, Jiho;Lee, Hyomin
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.3
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    • pp.113-126
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    • 2017
  • In order to investigate the geological storage potential of $CO_2$, X-ray diffraction analysis were conducted for drilling core samples collected from the two drilling sites located in Yonil group of the Miocene Pohang Basin. As a result, various minerals were identified such as quartz, plagioclase, orthoclase opal-CT, smectite, mica, illite, kaolin mineral, chlorite, calcite, gypsum, pyrite, dolomite, and siderite. Smectite was detected in almost all of core samples, and relatively large amounts of smectite were observed in the cores from deeper strata. Opal-CT, mainly occurred in the upper interval of cores, was formed by diagenesis of amorphous diatoms. It shows a tendency that d101 value of cristobalite decreases with depth from $4.10{\AA}$ to $4.05{\AA}$. The almost identical variations in mineral composition with depth are observed at the two sites. This fact indicates that rocks distributed at the two sites were probably deposited in the similar depositional environments. It is determined that the strata in the study area can play roles of cap-rock for $CO_2$ storage, because the considerable amounts of smectite were contained in the rocks through the cores.

Calcination Properties of Cement Raw Meal and Limestone with Oxidation/Reduction Condition (산화/환원 소성분위기에서 석회석 및 시멘트 원료물질의 소성거동 특성)

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Jin-Sang;Cho, Kye-Hong
    • Resources Recycling
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    • v.29 no.5
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    • pp.64-72
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    • 2020
  • When the multi-stage combustion process is applied to the cement kiln to reduce nitrogen oxide emissions in the cement industry, oxidation/reduction section that can increase combustion efficiency by reducing NOx to NO and completely burning unburned materials is essential In this study, when applied the oxidation/reduction system of the cement kiln preheater and calciner, the optimal oxidation/reduction calcination crisis that can secure the quality stability of the final product, cement clinker, was to be observed macroscopically, and the mass change of raw materials according to the burning conditions, decarbonation rate, and calcination rate were investigated. The results showed that the thermal decomposition of raw materials tends to be promoted in the oxidation condition rather than in the reduction condition, and that the thermal decomposition of limestone, which has a relatively high CaO content, is carried out later than that of cement raw meal, which is thought to be caused by the CO2 fractionation in the kiln. The thermal decomposition properties of raw materials according to oxidation/reducing burning condition showed a relatively large difference in temperature range lower than normal limestone themal decomposition temperature, which is thought to be expected to improve the thermal efficiency of raw materials according to the formation of oxidation condition in the section 750℃ of burning temperature. However, for this study, lab scale. Because there is a difference from the field process as a scale study, it is deemed necessary to verify the actual test results of the pilot scale.

Analysis of Information Education Related Theses Using R Program (R을 활용한 정보교육관련 논문 분석)

  • Park, SunJu
    • Journal of The Korean Association of Information Education
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    • v.21 no.1
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    • pp.57-66
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    • 2017
  • Lately, academic interests in big data analysis and social network has been prominently raised. Various academic fields are involved in this social network based research trend, which is, social network has been actively used as the research topic in social science field as well as in natural science field. Accordingly, this paper focuses on the text analysis and the following social network analysis with the Master's and Doctor's dissertations. The result indicates that certain words had a high frequency throughout the entire period and some words had fluctuating frequencies in different period. In detail, the words with a high frequency had a higher betweenness centrality and each period seems to have a distinctive research flow. Therefore, it was found that the subjects of the Master's and Doctor's dissertations were changed sensitively to the development of IT technology and changes in information curriculum of elementary, middle and high school. It is predicted that researches related to smart, mobile, smartphone, SNS, application, storytelling, multicultural, and STEAM, which had an increased frequency in period 4, would be continuously conducted. Moreover, the topics of robots, programming, coding, algorithms, creativity, interaction, and privacy will also be studied steadily.

A Study on the Service Satisfaction of University Library Portal for Chinese Students in Korea (중국 유학생의 대학도서관 포털 서비스 만족도에 관한 연구)

  • Lee, Soo-Sang;Wei, Cheng-Guang
    • Journal of the Korean Society for Library and Information Science
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    • v.41 no.4
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    • pp.113-134
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    • 2007
  • This study deals with the role and responsibility of university library in multicultural society. For this purpose, centered the Chinese students in Pusan University, with internet questionnaire surveys on customer satisfaction to the current library portal service and set up a effective digital library evaluation model. In the meanwhile we borrowed evaluation methods and items from LibQUAL+ in part, a world wide famous model, and use Tsinghua University Library's evaluation statistic norms. To summarize the results of this survey, Chinese student's service satisfaction about Pusan University library is still fairly low. Undergraduate and graduate students(including doctor courses) group follows, undergraduates student's satisfaction level is lower than graduate. By analyzing simple satisfaction we can know that library portal service maintained low importance or influence to the user, to internet space user's satisfaction is a relatively high level. And compared with other dimension, statistic data show out that internet space user's satisfaction still maintained a relative high level.

The Study on the Causes and Solutions of Work-family Conflict: With a focus on Employees' Resilience and Perceived Organizational Support (직장-가정 갈등 발생의 원인 및 해결방안에 대한 연구: 구성원들의 회복탄력성, 조직지원인식을 중심으로)

  • Da-Yeon, Choi;Hyung-Seog, Lee;Insuk Lee;Hyun-Kue, Lee;Seung-Jin, Kim
    • Journal of Industrial Convergence
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    • v.21 no.5
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    • pp.31-41
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    • 2023
  • We examine the relationship between abusive supervision and work-family conflict, and the moderating effects of employee's resilience and perceived organizational support. We collected the employees' sample(n=136) and conducted multiple hierarchical regression analysis. Abusive supervision has a significant positive effect on work-family conflict. Subordinate's resilience has a buffer effect on the main relationship, but perceived organizational support has no significant moderating effect. This study will be helpful for employees who are suffered from work-family conflict.

Mineralogical and Chemical Characteristics of the Oyster Shells from Korea (국내산 굴 패각의 광물학적 화학적 특성)

  • Ha, Su Hyeon;Cha, Min Kyung;Kim, Kangjoo;Kim, Seok-Hwi;Kim, Yeongkyoo
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.4
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    • pp.149-159
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    • 2017
  • We investigated the mineralogical and chemical characteristics of oyster shell as the possible substitute for the limestone used as an absorbent of $SO_2$ gas. The oyster shells from Taean and Tongyeong were used for the comparison with limestone and those from Boyreong and Yeosu were additionally investigated. XRD results show that all shells are composed of calcite with the exception of the myostracum layer attached to adductor muscle and ligament, which is composed of aragonite. The marine sediments as impurities exist on the surface of shells or as inclusions in the shells. Calcite is the main mineral composition of the shell of barnacle which is also one of the impurities. The oyster shell is composed of three main layers; prismatic, foliated, and chalk. The oyster shell from Tongyeong with the largest shell size, has the smallest thickness of prismatic and foliated layers which contain protein called conchiolin, whereas that from Taean with the smallest shell size has the largest prismatic and foliated layers. The sizes of those two layers of the shells from Boryeong and Yeosu are larger than that from Tongyeong but smaller than Taean. Those differences are supposed to be due to the different growth environments because the oysters from Tongyeong are cultured under the sea while those from Taean are in the tidal zone. The oyster shells generally show higher amount of sulfur and phosphorus than limestone, mainly due to the composition of protein. Some elements such as Mg show significant variations in different layers. As for trace elements, Li shows much higher amount in oyster shells than limestone, suggesting the influence of the composition of the sea water on the formation of the oyster shells.

Mineralogical Analysis of Calcium Silicate Cement according to the Mixing Rate of Waste Concrete Powder (폐콘크리트 미분말 치환율에 따른 이산화탄소 반응경화 시멘트의 광물상 분석)

  • Lee, Hyang-Sun;Song, Hun
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.2
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    • pp.181-191
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    • 2024
  • In the realm of cement manufacturing, concerted efforts are underway to mitigate the emission of greenhouse gases. A significant portion, approximately 60%, of these emissions during the cement clinker sintering process is attributed to the decarbonation of limestone, which serves as a fundamental ingredient in cement production. Prompted by these environmental concerns, there is an active pursuit of alternative technologies and admixtures for cement that can substitute for limestone. Concurrently, initiatives are being explored to harness technology within the cement industry for the capture of carbon dioxide from industrial emissions, facilitating its conversion into carbonate minerals via chemical processes. Parallel to these technological advances, economic growth has precipitated a surge in construction activities, culminating in a steady escalation of construction waste, notably waste concrete. This study is anchored in the innovative production of calcium silicate cement clinkers, utilizing finely powdered waste concrete, followed by a thorough analysis of their mineral phases. Through X-ray diffraction(XRD) analysis, it was observed that increasing the substitution level of waste concrete powder and the molar ratio of SiO2 to (CaO+SiO2) leads to a decrease in Belite and γ-Belite, whereas minerals associated with carbonation, such as wollastonite and rankinite, exhibited an upsurge. Furthermore, the formation of gehlenite in cement clinkers, especially at higher substitution levels of waste concrete powder and the aforementioned molar ratio, is attributed to a synthetic reaction with Al2O3 present in the waste concrete powder. Analysis of free-CaO content revealed a decrement with increasing substitution rate of waste concrete powder and the molar ratio of SiO2/(CaO+SiO2). The outcomes of this study substantiate the viability of fabricating calcium silicate cement clinkers employing waste concrete powder.

A Boundary Matching and Post-processing Method for the Temporal Error Concealment in H.264/AVC (H.264/AVC의 시간적 오류 은닉을 위한 경계 정합과 후처리 방법)

  • Lee, Jun-Woo;Na, Sang-Il;Won, In-Su;Lim, Dae-Kyu;Jeong, Dong-Seok
    • Journal of Korea Multimedia Society
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    • v.12 no.11
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    • pp.1563-1571
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    • 2009
  • In this paper, we propose a new boundary matching method for the temporal error concealment and a post processing algorithm for perceptual quality improvement of the concealed frame. Temporal error concealment is a method that substitutes error blocks with similar blocks from the reference frame. In conventional H.264/AVC standard, it compares outside pixels of erroneous block with inside pixels of reference block to find the most similar block. However, it is very possible that the conventional method substitutes erroneous block with the wrong one because it compares only narrow spatial range of pixels. In this paper, for substituting erroneous blocks with more correct blocks, we propose enhanced boundary matching method by comparing inside and outside pixels of reference block with outside pixels of erroneous block and setting up additional candidate motion vector in the fixed search range based on maximum and minimum value of candidate motion vectors. Furthermore, we propose a post processing method to smooth edges between concealed and decoded blocks without error by using the modified deblocking filter. We identified that the proposed method shows quality improvement of about 0.9dB over the conventional boundary matching methods.

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Cellulosic Ethanol as Renewable Alternative Fuel (신재생 대안 에너지로서의 셀룰로스 에탄올)

  • Cho, Woo-Suk;Chung, Yu-Hee;Kim, Bo-Kyung;Suh, Su-Jeoung;Koh, Wan-Soo;Choe, Sung-Hwa
    • Journal of Plant Biotechnology
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    • v.34 no.2
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    • pp.111-118
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    • 2007
  • Global warming crisis due primarily to continued green house gas emission requires impending change to renewable alternative energy than continuously depending on exhausting fossil fuels. Bioenergy including biodiesel and bioethanol are considered good alternatives because of their renewable and sustainable nature. Bioethanol is currently being produced by using sucrose from sugar beet, grain starches or lignocellulosic biomass as sources of ethanol fermentation. However, grain production requires significant amount of fossil fuel inputs during agricultural practices, which means less competitive in reducing the level of green house gas emission. By contrast, cellulosic bioethanol can use naturally-growing, not-for-food biomass as a source of ethanol fermentation. In this respect, cellulosic ethanol than grain starch ethanol is considered a more appropriate as a alternative renewable energy. However, commercialization of cellulosic ethanol depends heavily on technology development. Processes such as securing enough biomass optimized for economic processing, pretreatment technology for better access of polymer-hydrolyzing enzymes, saccharification of recalcitrant lignocellulosic materials, and simultaneous fermentation of different sugars including 6-carbon glucose as well as 5-carbon xylose or arabinose waits for greater improvement in technologies. Although it seems to be a long way to go until commercialization, it should broadly benefit farmers with novel source of income, environment with greener and reduced level of global warming, and national economy with increased energy security. Mission-oriented strategies for cellulosic ethanol development participated by government funding agency and different disciplines of sciences and technologies should certainly open up a new era of renewable energy.