• Title/Summary/Keyword: 대기오염 물질

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Characterization of contribution of vehicle emissions to ambient NO2 using stable isotopes (안정동위원소를 이용한 이동오염원에 의한 대기 중 NO2의 거동특성 연구)

  • Park, Kwang-Su;Kim, Hyuk;Yu, Suk-Min;Noh, Seam;Park, Yu-Mi;Seok, Kwang-Seol;Kim, Min-Seob;Yoon, Suk Hee;Kim, Young-Hee
    • Analytical Science and Technology
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    • v.32 no.1
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    • pp.17-23
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    • 2019
  • Sources of NOx are both anthropogenic (e.g. fossil fuel combustion, vehicles, and other industrial processes) and natural (e.g. lightning, biogenic soil processes, and wildfires). The nitrogen stable isotope ratio of NOx has been proposed as an indicator for NOx source partitioning, which would help identify the contributions of various NOx sources. In this study, the ${\delta}^{15}N-NO_2$ values of vehicle emissions were measured in an urban region, to understand the sources and processes that influence the isotopic composition of NOx emissions. The Ogawa passive air sampler was used to determine the isotopic composition of $NO_2$(g). In urban tunnels, the observed $NO_2$ concentration and ${\delta}^{15}N-NO_2$ values averaged $3809{\pm}2656ppbv$ and $7.7{\pm}1.8$‰, respectively. The observed ${\delta}^{15}N-NO_2$ values are associated with slight regional variations in the vehicular $NO_2$ source. Both $NO_2$ concentration and ${\delta}^{15}N-NO_2$ values were significantly higher near the expressway ($965{\pm}125ppbv$ and $5.9{\pm}1.4$‰) than at 1.1 km from the expressway ($372{\pm}96ppbv$ and $-11.5{\pm}2.9$‰), indicating a high proportion of vehicle emissions. Ambient ${\delta}^{15}N-NO_2$ values were used in a binary mixing model to estimate the percentage of the ${\delta}^{15}N-NO_2$ value contributed by vehicular NOx emissions. The calculated percentage of the ${\delta}^{15}N-NO_2$ contribution by vehicles was significantly higher close to the highway, as observed for the $NO_2$ concentration and ${\delta}^{15}N-NO_2$.

The study for VOCs analysis in long path by open path FT-IR spectrometer (Open path FT-IR spectrometer를 사용한 원거리의 VOCs 측정에 관한 연구)

  • Cho, Nam Wook;Cho, Won Bo;Kim, Hyo Jin
    • Analytical Science and Technology
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    • v.27 no.2
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    • pp.108-113
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    • 2014
  • The harmful materials as volatile organic compounds (VOCS) that is easy for gas to be changed from liquid on ambient temperature, those should be controlled by Korea Chemicals Management Association. The VOCs samples should be collected directly in place so that those could be analyzed. Generally but it couldn't avoid to have the risk of analyst. Moreover, if there is the place limited to entrance, it is impossible to collect directly and measure. Owing to such problem, it tried to be solved by open path FT-IR spectrometer that could be studied on the combustion gases within long path and VOCs samples were tried to measure to large volume by remote and real time. Firstly, it was to investigate optimized measured length between the system and benzene sample of VOCs. As result, The optimized measured length was confirmed with 15 meter length and the qualitative analysis could be measured on seven VOC samples. The calibration curve as quantitative analysis of benzene samples could be worked. On the basis of the result, the system as remote monitor could show to have potentiality.

Comparison of heavy metal uptake of LID and roadside plants (도로변 및 LID 시설 식재 식물의 중금속 축적량 비교)

  • Lee, YooKyung;Choi, Hyeseon;Reyes, Nash Jett;Kim, Leehyung
    • Journal of Wetlands Research
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    • v.23 no.1
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    • pp.44-53
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    • 2021
  • Urban stormwater runoff contains heavy metals that accumulate in on-site treatment systems, thus resulting to facility deterioration and maintenance problems. In order to resolve these problems, low impact development (LID) technologies that promote natural materials circulation are widely used. LID facilities are capable of treating heavy metals in the runoff by means of plant uptake; however, the uptake or phytoremediation capabilities of plants have not been studied extensively, making it difficult to select the most suitable plant species for a certain LID design. This study investigated the vegetative components of an LID facility, roadside plants, and plants in landscape areas with different heavy metal exposure and frequency to determine the uptake capabilities of different plant species. The plants harvested inside the LID facilities and roadsides with high vehicular traffic exhibited greater heavy metal concentrations in their tissues as compared with the plants in landscape areas. Generally, the accumulation of heavy metals in the plant tissues were found to be influenced by the environmental characteristics (i.e. influent water quality, air pollution level, etc.). Dianthus, Metasequoia, Rhododendron lateritium, and Mugwort were found to be effective in removing Zn in the urban stormwater runoff. Additionally, Dianthus, Metasequoia, Mugwort, and Ginkgo Biloba exhibited excellent removal of Cu. Cherry Tree, Metasequoia, and mugwort efficiently removed Pb, whereas Dianthus was also found to be effective in treating As, Cr, and Cd in stormwater. Overall, different plant species showed varying heavy metal uptake capabilities. The results of this study can be used as an effective tool in selecting suitable plant species for removing heavy metals in the runoff from different land use types.

Improvement of Building-Construction Algorithm for Using GIS data and Analysis of Flow and Dispersion around Buildings (GIS 자료사용을 위한 건물 구축 알고리즘 개선 및 건물 주변 흐름과 확산 분석)

  • Kwon, A-Rum;Kim, Jae-Jin
    • Korean Journal of Remote Sensing
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    • v.30 no.6
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    • pp.731-742
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    • 2014
  • In this study, we developed a new algorithm which can construct model buildings used as a surface boundary in numerical models using GIS with latitudinal and longitudinal information of building vertices. The algorithm established the outer boundary of a building first, by finding segments passing neighboring two vertices of the building and connecting the segments. Then, the algorithm determined the region inside the outer boundary as the building. The new algorithm overcame the limit that the algorithm developed in the previous study had in constructing concave buildings. In addition, the new algorithm successfully constructed a building with complicated shape. To investigate effects of the modification in building shape caused by the building-construction algorithm on flows and pollutant dispersion around buildings, a computational fluid dynamics model was used and three kinds of building type were considered. In the downwind region, patterns in flow and pollutant dispersion were little affected by the modification in building shape caused. However, because of reduction in air space resulted from the building-shape modification, vortex structure was not resolved or smaller vortex was resolved near the buildings. The changes in flow pattern affected dispersion patterns of scalar pollutants emitted around the buildings.

Feasibility Evaluation of Co-Incineration with MSW for Efficient Recycling of the Rejects after Separation Processes in MRF (재활용 기반시설에서 발생하는 선별 잔재물의 자원화를 위한 도시생활폐기물과의 혼합소각 가능성 평가)

  • Shin, Taek-Soo;Sung, Baek-Nam;Yeon, Ik-Jun;Cho, Byung-Yeol;Kim, Kwang-Yul
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.10
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    • pp.767-773
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    • 2011
  • The purpose of this study was to investigate the possibility of an alternative fuel resource by incinerating a mix of combustible MSW (municipal solid waste) and offals after separating recyclable material at the MRF (material recovery facilities) location. We analyzed the physical and chemical properties including the 3-contents, the calorific value, and chemical compositions of the separation rejects in MRF, and compared the results with combustible MSW. Moreover, we experimented the trend of combustible properties and the concentration change of air pollutants at mixed incineration in the MSW incinerator. According to the results of the experiment, the separation rejects showed higher heating value (5,865 kcal/kg), and lower moisture and ash content than combustible MSW. Since we have incinerated MSW in the MSW incinerator mixing the offals at 30% and 50% respectively, we know that the change of the concentration of dust, $SO_2$, $NO_2$, and CO did not appear significant, and not exceed the pollutants emission regulation. But, considering the enhancement of the HCl emission concentration (max. 33.7 ppm) at the co-incineration of the 50% offals, we believe that the proper mixing ratio of the separation rejects would become within 30%.

Characteristics of Atmospheric Speciated Gaseous Mercury in Chuncheon, Korea (춘천시 대기 중 가스상 수은 종 농도 특성에 관한 연구)

  • Gan, Sun-Yeong;Yi, Seung-Muk;Han, Young-Ji
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.5
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    • pp.382-391
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    • 2009
  • Atmospheric speciated mercury concentrations including total gaseous mercury (TGM) and reactive gaseous mercury (RGM) were measured in Chuncheon from March 2006 to November 2008. Average concentrations were 2.10 ${\pm}$ 1.50 ng/$m^3$ and 3.00 ${\pm}$ 3.14 pg/$m^3$ for TGM and RGM, respectively. RGM concentrations were higher during daytime than nighttime probably because of high photochemical activities. We found that RGM concentration considerably increased as ozone increased when fog occurred, indicating that ozone was the important oxidant for $Hg^0$ in aqueous phase. TGM concentration showed positive correlations with CO and $PM_{10}$ which can transport in long-range, but there was no correlation with $NO_2$. Considering that major source of mercury is combustion process, this result showed that local sources did not significantly impact on TGM concentration in Chuncheon. Five-day backward trajectories were calculated for the samples representing high and low concentrations of TGM, and determined that industrialized area of China including Shenyang and Beijing influenced TGM concentrations in Chuncheon.

A Study on Environmental and Economic Analysis for Each Treatment of Sewage Sludge(III) - Results of Environmental Assessment - (하수슬러지 처리방법별 환경성 및 경제성 분석에 대한 연구(III) - 환경성 분석 중심으로 -)

  • Bae, Jisu;Lee, Suyoung;Cho, Yuna;Kwon, Younghyun;Lee, Dongjin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.3
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    • pp.5-13
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    • 2016
  • This study investigated the environmental and economical assessment for sewage sludge treatment options including biogasification, incineration, carbonization, drying, and solidification. For the economical feasibility the 30 plants with anaerobic digestion treatment and the 17 plants without anaerobic digestion treatment were investigated. In regarding to the environmental assessment, the air emission pollutants (SOx, NOx, etc) from incineration and carbonization plants were assessed and 1~34 % of emission limits was emitted. Drying and solidification plants emitted about 30 % of odour limits. And the rest of the pollutants were emitted either at not-detectable level or at below the limits. When the by-products from the solidification treatment was used as landfill cover materials, the unconfined compression strength could be below the limit and it could cause an unsafe condition for those passing vehicles and the possibility of the ground subsidence. There has been a maintenance difficulty due to frequent blockage and operational failure. The result of the comparison of sewage sludge treatment options showed that anaerobic digestion+incineration was the most economically feasible considering incineration and drying. For smaller treatment capacity, solidification was the most economically feasible considering carbonization and solidification and anaerobic digestion+carbonization was the most economically feasible considering carbonization and solidification.

Challenges of Medical Waste Treatment in Fiji (피지국에서의 의료폐기물 처리현황과 문제점)

  • Kim, Daeseon;Bolaqace, Josefa;Rafai, Eric;Lee, Chulwoo
    • Journal of Appropriate Technology
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    • v.6 no.1
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    • pp.37-44
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    • 2020
  • Medical waste is any kind of waste that contains infectious material and recommended not to be transferred for infection control. As a means of disposal, incineration has better points than dumping or landfill in the quantity reduction, odorless and nonhazardous. However, open burning and incineration of health care wastes under bad circumstances, can result in the emission of environmental pollutants to air. A burial of biological waste brings pollution of soil and water. Most of sub divisional hospitals in Fiji transfer their medical wastes to divisional hospitals for incineration. In 2011, 62,518 kg of medical waste was incinerated in the three divisional hospitals. However, some medical wastes are considered as general waste and burnt or sent to landfill site, some are buried on site in some sub-divisional hospitals. In this regards, urgent education is necessary for awareness promotion to relevant personnel in medical waste treatment. On site incineration using small scale incinerator is more recommended than transportation of medical wastes treatment in Fiji. Moreover, remotely controllable and fixable small scale of incinerator is more desirable in sub-divisional hospitals. It is recommended that Fiji government to set up a legal framework for medical waste management (MWM), to develop specific guidelines for MWM, to set up a training system for MWM to ensure that all relevant personnel are trained, to develop a monitoring and supervision system for MWM, to clarify the future financing of MWM activities, and to improve the MWM infrastructure.

Effects of Resveratrol and Resveratryl Triacetate on The Inflammatory Responses of Human Epidermal Keratinocytes Exposed to Airborne Particulate Matter PM10 (대기 미립자 물질 PM10에 노출된 인간 표피 각질형성세포의 염증 반응에 대한 레스베라트롤과 레스베라트릴 트라이아세테이트(RTA)의 영향)

  • Choi, Min A;Seok, Jin Kyung;Lee, Jeong-won;Lee, Shin Young;Kim, Young Mi;Boo, Yong Chool
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.3
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    • pp.249-258
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    • 2018
  • Airborne pollution causes oxidative damage, inflammation, and premature aging of skin. Resveratrol is a polyphenol compound that has various biological activities such as antioxidant, anti-inflammation, and anti-melanogenic activities but it is unstable to heat and light. Resveratryl triacetate (RTA) is a new cosmetic ingredient that is more stable than resveratrol and its skin safety and whitening efficacy have been reported previously. The purpose of this study was to examine the effects of resveratrol and resveratryl triacetate (RTA) on the inflammatory responses of human epidermal keratinocytes (HEKs) exposed to airborne particulate matters with a diameter of < $10{\mu}m$ (PM10). Cultured HEKs were exposed to PM10 in the absence or presence of resveratrol and RTA. Assays were undertaken to determine cell viability, the production of reactive oxygen species (ROS), and the expression of inflammatory cytokines. PM10 treatment decreased cell viability, and increased the expression of pro-inflammatory cytokines such as tumor necrosis $factor-{\alpha}$ ($TNF-{\alpha}$), $interleukin-1{\beta}$ ($IL-1{\beta}$), interleukin-6 (IL-6), and interleukin-8 (IL-8). Resveratrol and RTA reduced cell death and ROS production induced by PM10. PM10-induced mRNA expression of the inflammatory cytokines was either attenuated (IL-6), or enhanced ($IL-1{\beta}$), or unaffected ($TNF-{\alpha}$ and IL-8) by resveratrol and RTA. PM10-induced IL-6 protein expression was attenuated by resveratrol and RTA. This study suggests that resveratrol and RTA have activities regulating cell damage and inflammatory responses of the skin exposed to airborne particulate matters.

Nutrient Dynamics and Water Quantity of Throughfall and Stemflow in Natural Oak Stands in Korea (우리나라 참나무 천연림에 있어서 임내우의 수량변화 및 양분동태)

  • Jin, Hyun-O;Son, Yo-Whan
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.1
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    • pp.61-70
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    • 2007
  • This study was conducted to investigate nutrient dynamics and water quantity of throughfall and stemflow in natural oak stands in Korea. The ratio of the total throughfnll and stemflow to the amount of precipitation varied with locations. It was considered that the ratio was affected not only by the characteristics of tree species but also by regional, weather and other environmental conditions. It was, therefore, necessary to set up a water control system to launch a tending project for natural oak stands. Comparisons of nutrient amount in throughfall among regions reflected regional characteristics. $Ca^{2+},\;Mg^{2+}$ and $K^+$ ions were leached from the canopy and yellow sand accumulation. $Na^+$ and $Cl^-$ were marine-borne. $NO_3^-$ and $SO_4^{2-}$ resulted from dry deposition of air pollutants. Nutrient amount in the stemflow was as low as about 10% of that in the total throughfall and stemflow. The pH of stemflow in natural oak stands in urban areas ranged from 3 to 5. Influx of the acidic stemflow to soil could, in the long term, affect pH in soil solution and nutrient dynamics around root zones.