• Journal of the Korean Chemical Society
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• v.35 no.6
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• pp.617-624
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• 1991

Nonstoichiometric solid solutions of $Y_{1-x}A_xFeO_{3-y}$ (A = Ca, Sr) systems with perovskite structure were prepared for x = 0.00, 0.25, 0.50, 0.75 and 1.00 at 1200$^{\circ}C$ under atmospheric pressure, respectively. Crystallographic structures of the solid solutions of all compositions have been determined by the analysis of X-ray diffraction patterns. Reduced lattice volume of the $Y_{1-x}Ca_xFeO_{3-y}$ system was decreased with increasing x value and that of the $Y_{1-x}Sr_xFeO_{3-y}$ system was increased with increasing the x value. The mole ratios of $ Fe^{4+}$ to $ Fe^{3+}$, ${\tau}$, values in the solid solutions have been determined by Mohr salt's method of analysis and then the mixed valency was identified by Mossbauer spectroscopic analysis at 298 K. The y values were calculated from the x and ${\tau}$, and then nonstoichiometric chemical formulas were fixed. The conduction mechanism could be explained by hopping model of the conduction electrons between the mixed valence states.

• Journal of the Korean Chemical Society
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• v.35 no.2
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• pp.99-104
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• 1991

Nonstoichiometric solid solutions of Sr$_{1+x}Er _{1-x} FeO _{4-y}$ system (x = 0.00, 0.25, 0.50, 0.75 and 1.00) with layered $K_2NiF_4$ type structure were prepared at 1350$^{\circ}$C under atmospheric pressure. By the analysis of X-ray diffraction, the crystallographic structures of the solid solution of all compositions were found to be pseudo-tetragonal system. Nonstoichiometric chemical formulas have been determined by Mohr salt analysis. It shows that the amount of Fe$^{4+}$ increases with increasing x up to 0.50 and then decreases, and the value of oxygen nonstoichiometry increases with increasing x value. Mixed valency states of Fe$^{3+}$ and Fe$^{4+}$ in the sample were identified again by Mossbauer spectroscopic analysis at 298 K. Electrical conductivity varied within the semiconductivity range of 10-2 ∼ 10-7(${\Omega}$-1cm-1), activation energy for electrical conduction decreased with the increment of the mole ratio of Fe$^{4+}$ or ${\tau}$ value. The conduction mechanism could be explained by the hopping model of the conduction electrons between the valency states of Fe$^{3+}$ and Fe$^{4+}$.

• Journal of the Korean Chemical Society
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• v.37 no.11
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• pp.923-928
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• 1993

The series of solid solutions in the $Sr_{1+x}Ho_{1-x}FeO_{4-y}$ (x = 0.00, 0.25, 0.50, 0.75 and 1.00) systems with $K_2NiF_4$ type structure have been prepared at 1550$^{\circ}$C under an atmospheric air pressure. The X-ray powder diffraction spectra of these samples assign that the crystallographic phases are tetragonal system over the whole x range. The lattice volume was increased with increasing the substitution amount of the $Sr^{2+}$ ion. The mole ratio of the $Fe^{4+}$ ion to total iron ions or ${\tau}$ value has been determined by Mohr salt titration of the sample and then the y value was calculated from x and ${\tau}$ values. The ${\tau}$ and y values have been increased with x values. The nonstoichiometric chemical formula are formulated from the general formula of $Sr_{1+x}Ho_{1-x}Fe^3_{1-}\;^+_{\tau}Fe_{\tau}^{4+}O_{4-y}$ replaced by x,${\tau}$ and y values. Mossbauer spectra show the mixed valence state and coordination state of $Fe^{3+}\;and\;Fe^{4+}$ ions. It is found out that the magnetic property of the samples is paramagnetic at room temperature. Electrical conductivity varied within the semiconductivity range of 1.0 to 1 ${\times}\;10^{-9}{\Omega}^{-1}cm^{-1}$. Activation energy of the electrical conductivity was decreased with the $\tau$ value. The conduction mechanism should be explained by the hopping model of the conduction electrons between the valence states of $Fe^{3+}\;and\;Fe^{4+}$ ions.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05b
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• pp.473-480
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• 1996

영광 3/4호기 mid-loop 운전중 잔열제거(RHR) 기능 상실사고시 열수력적 현상을 최적 전산코드인 CATHARE2를 이용하여 해석하였다. 이러한 사고시 열수력적 현상은 일,이차측 냉각재 방출유로와 계통내 비응축성 가스의 거동에 의해 크게 영향을 받는다. 본 연구에서는 2개의 경우를 모의하였는데, 하나는 계통내 방출유로가 있는 경우이며 다른 하나는 방출유로가 없는 경우를 계산하였다. 이 때 사용된 가정은 다음과 같다. (가) 계통은 부분충수 운전 상태로 상부에 비응축성 가스나 증기로 가득 차 있다. (나) 증기발생기는 1대만이 이용 가능하고 이차측은 습식보관 상태이며, 보조급수는 공급되지 않고 이차측 압력은 대기압 상태이다 (다) 사고는 원자로 정지후 2일후 발생한다. 이와같은 조건하에서 사고시 계통 최대압력은 방출유로가 있는 경우 사고후 6,000 초에 0.27 MPa이며, 방출유로를 통한 유량은 총 2.4 kg/s이다. 이 방출유량을 외삽하여 계통수위가 고온관 바닦까지 도달하는데 걸린 시간은 사고후 약 5.67시간이다. 증기발생기 U-튜브를 통한 열전달에 의해 이차측 증기 발생으로 이차측 수위가 하락하면 증기발생기 reflux cooling은 제한을 받을 수 있다. 이 경우 이차측 수위가 U-튜브의 active 영역 상부까지 도달하는데 걸리는 시간은 사고후 약 10시간으로 계산되었다. 그러므로 이 경우 보조급수 공급 여유시간보다 노심 노출시간이 더 빨리 도달하여 노심을 손상시킨다. 사고시 수위지시계는 계통감압에 큰 영향을 주지 못하기 때문에 가능한 빨리 닫아 계통 inventory를 유지하는 것이 이차측 보조급수공급보다 우선한다.합한 설계방안으로 분석되었다.크다는 단점이 있다.TEX>$_2$O$_3$ 흡착제 제조시 TiO$_2$ 함량에 따른 Co$^{2＋}$ 흡착량과 25$0^{\circ}C$의 고온에서 ZrO$_2$와 $Al_2$O$_3$의 표면에 생성된 코발트 화합물을 XPS와 EPMA로 부터 확인하였다.인을 명시적으로 설명할 수 있다. 둘째, 오류의 시발점을 정확히 포착하여 동기가 분명한 수정대책을 강구할 수 있다. 셋째, 음운 과 정의 분석 모델은 새로운 언어 학습시에 관련된 언어 상호간의 구조적 마찰을 설명해 줄 수 있다. 넷째, 불규칙적이며 종잡기 힘들고 단편적인 것으로만 보이던 중간언어도 일정한 체계 속에서 변화한다는 사실을 알 수 있다. 다섯째, 종전의 오류 분석에서는 지나치게 모국어의 영향만 강조하고 다른 요인들에 대해서는 다분히 추상적인 언급으로 끝났지만 이 분석을 통 해서 배경어, 목표어, 특히 중간규칙의 역할이 괄목할 만한 것임을 가시적으로 관찰할 수 있 다. 이와 같은 오류분석 방법은 학습자의 모국어 및 관련 외국어의 음운규칙만 알면 어느 학습대상 외국어에라도 적용할 수 있는 보편성을 지니는 것으로 사료된다.없다. 그렇다면 겹의문사를 [-wh]의리를 지 닌 의문사의 병렬로 분석할 수 없다. 예를 들어 누구누구를 [주구-이-ν가] [누구누구-이- ν가]로부터 생성되었다고 볼 수 없다. 그러므로 [-wh] 겹의문사는 복수 의미를 지닐 수 없 다. 그러면 단수 의미는 어떻게 생성되는가\

• Journal of Environmental Impact Assessment
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• v.22 no.6
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• pp.547-556
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• 2013

Recently, golf courses have increased over the years because golf became popular leisure sport. Various environmental problems have been then issued by a golf course during constructing and running them. A problem of pesticide, which is serious among various environmental problems, from golf course has harmful effect on surrounding area and makes human suffer from acute and chronic diseases. Pesticides are used for the cost-effective managing of golf course and the amount of pesticides also increases as the number of golf course increase. Since the assessment of pesticides on near-by surrounding has been focused on water and soil media, studies related to atmospheric dispersion have been hardly attempted. The method to assess an impact of pesticide nearby agricultural production by the atmospheric dispersion using AGDISP(AGricultural DISPersal) model was developed and applied to the actual planned golf course located in Hongcheon, Gangwon. For implementing AGDISP, parameters were investigated from the golf course's land use planning map, pesticide spray device, Hong-Cheon weather station and etc. First of all, a kind of pesticide, a form of spraying pesticide, geographical features, weather data, and distance(golf course to plantation) were investigated to understand how to work these parameters in AGDISP. Restricted data(slope angle, droplet size distribution and solar insolation) sensitivity analysis of these parameters to estimate effect of pesticide nearby a plantation and a high relative contribution data of analyzed data was selected for input data. Ethoprophos was chosen as the pesticide used in the golf course and the amounts of pesticide deposition per annual agricultural productions were predicted. The results show that maximum amount of pesticide deposition through atmospheric dispersion was predicted $2.32{\mu}/m^2$ at 96 m where the nearest organic plantation exists. The residues of pesticide were also estimated based on the annul production of the organic and the deposition amount of the pesticide. Consequently, buckwheat, wheat and millet were likely to exceed maximum residue limits for pesticides in foods(MRL) and sorghum, corn and peanut were likely to exceed MRL by organic farming as well.

• Journal of Broadcast Engineering
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• v.25 no.4
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• pp.560-568
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• 2020

In recent years, as network technology develops, the usage of streaming services by users is increasing. However, the complexity of streaming services is also increasing due to various terminal environments. Even when streaming the same content, it is necessary to re-encode the content according to the type of service. In order to solve the complexity and latency of the streaming service, Moving Picture Experts Group (MPEG) has standardized the Common Media Application Format (CMAF). In addition, as content transmission using a communication network becomes possible, the Republic of Korea's Ultra High Definition (UHD) broadcasting standard has been enacted as a hybrid standard using a broadcasting network and a communication network. The hybrid service enables various services such as transmitting additional information of contents or providing user-customized contents through a communication network. The Republic of Korea's UHD transmission standard utilizes MPEG Media Transport (MMT), and Mobile MMT is an extension of MMT to provide mobile network-specific functions. This paper proposes a method of inserting CMAF contents suitable for various streaming services using signaling messages of MMT and Mobile MMT. In addition, this paper proposes a model for content insertion system in heterogeneous network environment using broadcasting and communication networks, and verifies the validity of the proposed technology by checking the result of content insertion.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.7
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• pp.773-778
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• 2015

Global warming has recently become an issue that has resulted in a growing trend to minimize environmental pollution. The International Maritime Organization (IMO) has shown that the majority of marine atmospheric pollution occurs as a result of emissions from marine vessels. Therefore, the environmental regulations and emission standards regarding marine vessels have gradually become stricter, and the research and development in this area is experiencing significant progress. In this study, a nozzle for a fuel oil scrubber was investigated using computational fluid dynamics (CFD) and particle imaging velocimetry (PIV). Experiments were conducted on scaled-down model of the scrubber to determine its performance, which was then compared with CFD results. Based on the experimental results, it was found that at a spray angle of $66^{\circ}$, the spray velocity at the nozzle was 20.1 m/s. From this comparison, a full-scale scrubber model was analyzed using CFD, and the effect of the positioning of the nozzle was studied.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.6
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• pp.658-665
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• 2014

Natural gas for marine diesel engine is considered as an important and clean source of energy because of simultaneously reducing the emission of NOx, SOx and GHG. Especially with a appearance of shale gas, the using of natural gas has been investigated aggressively and expected to expand rapidly. By the reports, gas engine and diesel engine were both in a similar performance in the power aspect, and the SFOC of gas engine was shown a little better than that of diesel engine. But the characteristics of exhaust gas emission were different according to various combustion technologies. And with lean burn technology, the emission of NOx could be reduced to 85% lower than that of diesel engine. In this paper, it was described that a simulation program has been developed to predict NOx emission. The developed program is adopted two-zone model and Wiebe function for combustion in cylinder. The effects of premixed and diffusive combustion could be simulated by using the excess air ratio as input data. And it was confirmed that the results of simulation were agreed with the general trends of exhaust gas emission according to various combustion conditions such as lean burn, premixed and diffusive combustion.

• The KIPS Transactions:PartC
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• v.11C no.1
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• pp.141-148
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• 2004

Recently, the demand of broadband communications such as high-speed internet, HDTV, 3D-HDTV and ATM backbone network has been increased drastically. For transmitting the broad-bandwidth data using wireless network, it is needed to use ka-band frequency. However, the use of this ka-band frequency is seriously affected to the received data performance by rain fading and atmospheric propagation loss at the Ka-band satellite communication link. So, we need adaptive MODEM to endure the degraded performance by channel environment. In this paper, we will present the structure and design of the 155Mbps adaptive Modem adaptively compensated against channel environment. In order to compensate the rain attenuation over the ka-band wireless channel link, the adaptive coding schemes with variable coding rates and the multiple modulation schemes such as trellis coded 8-PSK, QPSK, and BPSK are adopted. And the blind demodulation scheme is proposed to demodulate without Information of modulation mode at the multi-mode demodulator, and the fast phase ambiguity resolving scheme is proposed. The design and simulation results of adaptive Modem by SPW model are provided. This 155Mbps adaptive MODEM was designed and implemented by single ASIC chip with the $0.25\mu{m}$ CMOS standard cell technology and 950 thousand gates.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.12
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• pp.608-613
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• 2019

NOx (Nitrogen oxide) in the exhaust gas from vehicle engines is considered one of the most harmful substances in air pollution problems. NOx is made when combustion occurs under high temperature conditions and EGR (exhaust gas recirculation) is normally used to lower the combustion temperature. As the EGR ratio increases, the NOx level becomes low, but a high EGR ratio makes the combustion unstable and causes further air pollution problems, such as CO and unburned hydrocarbon level increase. This study showed that fuel droplets could move more freely by the radiation of sonic wave for the stable combustion. In addition, the engine performance improved with increasing EGR ratio. As a basic study, the effect of sonic wave radiation on the velocity of fuel droplets was studied using CFD software. The results showed that the velocity of small droplets increased more under high frequency sonic wave conditions and the velocity of the large droplets increased at low frequency sonic wave conditions. In addition, an engine analysis model was used to study the effects of the increased combustion stability. These results showed that a 15% increase in EGR ratio in combustion resulted in a 45% decrease in NOx and a 10% increase in thermal efficiency.