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Removal of Heavy Metals from Aqueous Solution by a Column Packed with Peat-Humin (Peat-Humin 충전 칼럼을 이용한 수용액 중의 중금속 제거)

  • Shin, Hyun-Snag;Lee, Chang-Hoon;Lee, Yo-Snag;Kang, Ki-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.535-541
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    • 2005
  • Peat humin(p-Humin) extracted from Canadian Sphagnum peat moss was packed in a column and removal of heavy metal ions such as Cd, Cu and Pb from aqueous solution under flow conditions was studied. The metal ions were removed not only from single-element solutions but also from a multi-metal solution. Column kinetics for metal removal were described by the Thomas model. For single-component metal solutions, the maximum adsorption capacities of the p-Humin for Pb, Cu and Cd were 138.8, 44.66 and 41.61 mg/g, respectively. The results of multi-component competitive adsorption showed that adsorption affinity was in the order of Pb $\gg$ Cu > Cd. The adsorbed metal ions were easily deserted from the p-Humin with 0.05 N $HNO_3$ solution. It is apparent that 95% of the heavy metal ions were recovered from the saturated column. This investigation provides possibility to clean up heavy-metal contaminated waste waters by using the natural biomass, p-Humin as an environmentally friendly and cost-effective new biosorbents.

Effect of Hollow Sphere Size on Heat Shield Properties of hollow TiO2/polyacrylate Composites (중공구의 크기에 의한 hollow TiO2/polyacrylate 복합체의 열차단 특성)

  • Kim, Jong Seok
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.690-694
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    • 2021
  • Carbon spheres (CS) were fabricated using glucose as a precursor in the hydrothermal method. Hollow TiO2 (H-TiO2) spheres with 200 nm, 500 nm, and 1,200 nm were synthesized by CS/TiO2 core-shell particles via a sol-gel and calcination method. H-TiO2 spheres with nano and micron sizes were characterized using FE-SEM, HR-TEM, and X-ray diffraction. The CIE color coordinate, solar reflectance, and heat shield temperatures of H-TiO2/polyacrylate (PA) composite film were investigated using a UV-Vis-NIR spectrometer and homemade heat insulation temperature measuring device. H-TiO2/PA composites exhibit excellent thermal insulation since the hollow structure filled with dry air has low thermal conductivity and near infrared light reflecting performance. The thermal insulation increased with increasing the hollow sphere (HS) size on H-TiO2/PA composites. The PA composite film mixed with H-TiO2 filled with 1200 nm HS reduced the heat shield temperature by 26 ℃ compared to that of the transparent glass counterpart.

Analysis of Fire Suppression Efficiency for Intermittent Water Spray Pattern by Fire Dynamics Simulator (FDS를 이용한 교번식 미분무방식의 소화 성능 분석)

  • Jee, Moon-Hak;Lee, Byung-Kon
    • Fire Science and Engineering
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    • v.22 no.3
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    • pp.216-220
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    • 2008
  • Water mist fire suppression system utilizes the fire suppression features such as cooling of fire source, dilution of ambient oxygen, and shielding of radiation heat with the evaporation of microscopic water droplets. The momentum of water mist is relatively lower than that of larger water droplet and the infiltration of water mist to the fire source is not effective. Contribution of evaporated water vapor is liable to decline to limited portion of fire source due to its light weight and sparse density. On the other hand, the cycling water mist pattern is expected to improve the penetration force of water mist as well as the air expelling capability with the stratified spray characteristics. At this paper, we present the analyzed fire suppression capability of intermittent water spray pattern by use of FDS which is computational fire dynamics fire model. We expect this analysis can support the basic concept to the development of the prototype of water mist nozzle.

Material Topology Optimization of FGMs using Homogenization and Linear Interpolation Methods (균질화 및 선형보간법을 이용한 기능경사 내열복합재의 물성분포 최적설계)

  • 조진래;박형종
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.14 no.4
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    • pp.495-503
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    • 2001
  • In a functionally graded materials(FGM), two constituent material particles are mixed up according to a specific volume fraction distribution so that its thermoelastic behavior is definitely characterized by such a material composition distribution. Therefore, the designer should determine the most suitable volume fraction distribution in order to design a FGM that optimally meets the desired performance against the given constraints. In this paper, we address a numerical optimization procedure, with employing interior penalty function method(IPFM) and FDM, for optimizing 2D volume fractions of heat-resisting FGMs composed of metal and ceramic. We discretize a FGM domain into finite number of homogenized rectangular cells of single design variable in order for the optimization efficiency. However, after the optimization process, we interpolate the discontinuous volume fraction with globally continuous bilinear function in order to enforce the continuity of volume fraction distributions.

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Massive Parallel Processing Algorithm for Semiconductor Process Simulation (반도체 공정 시뮬레이션을 위한 초고속 병렬 연산 알고리즘)

  • 이제희;반용찬;원태영
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.3
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    • pp.48-58
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    • 1999
  • In this paper, a new parallel computation method, which fully utilize the parallel processors both in mesh generation and FEM calculation for 2D/3D process simulation, is presented. High performance parallel FEM and parallel linear algebra solving technique was showed that excessive computational requirement of memory size and CPU time for the three-dimensional simulation could be treated successively. Our parallelized numerical solver successfully interpreted the transient enhanced diffusion (TED) phenomena of dopant diffusion and irregular shape of R-LOCOS within 15 minutes. Monte Carlo technique requires excessive computational requirement of CPU time. Therefore high performance parallel solving technique were employed to our cascade sputter simulation. The simulation results of Our sputter simulator allowed the calculation time of 520 sec and speedup of 25 using 30 processors. We found the optimized number of ion injection of our MC sputter simulation is 30,000.

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Application of Stable o/w Nanoemulsions with Skin Depigmenting Agent for Integration Type of Cosmetics (피부 미백제를 함유한 안정한 o/w 나노에멀젼의 융복합형 화장품 이용)

  • Cho, Wan-Goo
    • Journal of Digital Convergence
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    • v.13 no.4
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    • pp.417-423
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    • 2015
  • Oil-in-water(o/w) nanoemulsions were prepared in the system of water/Span 80-Tween 80/long-chain paraffin oil via PIC method. With the increase of preparation temperature from 30 oC to 80 oC, the diameter of emulsion droplets decreased from 150 nm to 40 nm. By varying the HLB of mixed surfactants, we found that there was an optimum HLB around 13.0~14.0 corresponding to the minimum droplet size. The size of emulsion droplets increased upon increasing the ratio of oil/emulsifying agent. At $f{\leq}0.15$, the size of nanoemulsions could be kept constant more than 2 months. The increase in preparation temperature makes it possible for producing monodisperse nanoemulsions. Once the nanoemulsion is produced, the stability against Ostwald ripening is outstanding due to the extremely low solubility of the liquid paraffin oil in the continuous phase.

Fabrication of Piezoelectric Cantilever with Microcone Tip for Sensing Local Stiffness of Biological Tissue (생체 조직의 국소 강도 측정을 위한 마이크로 콘 팁을 가진 압전 캔틸레버 제작)

  • Roh, Hee Chang;Yang, Dasom;Ryu, WonHyoung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.11
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    • pp.743-748
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    • 2017
  • For diseases that are difficult to detect by conventional imaging techniques, the development of a diagnostic method that allows sensors to be inserted into the human body to aid the diagnosis of local spots of the target tissue, is highly desirable. In particular, it is extremely difficult to determine whether vulnerable plaque can later develop into atherosclerosis using only imaging techniques. However, vulnerable plaques are expected to have slightly different mechanical properties than healthy tissue. In this study, we aim to develop a piezoelectric cantilever-type sensor that can be inserted into the human body and can detect the local mechanical properties of the target tissue. A piezoelectric polymer composite based on $BaTiO_3$ nanoparticles was optimized for fabrication of a piezoelectric cantilever. Next, a micro-cone tip was fabricated at the end of the piezoelectric cantilever by thermal drawing. Finally, stiffness of biological tissue samples was measured with the piezoelectric cantilever sensor for verifying its functionality.

Retrogradation Properties of Waxy Starches (찰 전분의 노화특성에 관한 연구)

  • Kim, Hyong-Soo;Lee, Mi-Sook;Woo, Ja-Won
    • Korean Journal of Food Science and Technology
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    • v.20 no.6
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    • pp.794-800
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    • 1988
  • The retrogradation properties of waxy starches isolated from waxy rice(Shin sun, Tong il), waxy barley(Suwon # 227), waxy indian millet. waxy millet and Jobs tears(Yullmoo) were investigated. The extent of retrogradation determined by the glucoamyase method during freeze-thaw treatment and storage in low temperature$(0{\sim}5^{\circ}C)$ showed that six kinds of waxy starches were very slowly retrograded. The order of the retrogradation tendencies of these starches were waxy indian millet > Suwon # 227 Waxy millet > Yullmoo > Tong il > Shin sun. Waxy indian millet and Suwon # 227 starches were distinctively retrograded compared with other starches. Retrogradation properties observed during freeze-thaw 30 cycles were similar to those of storage for 30 days at $0{\sim}5^{\circ}C$. Suwon # 227, which has been the only recommened variety in our nation, was composed of 15% of non-waxy starch and 85% of waxy starch granule.

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방전 플라즈마 소결 공법을 이용한 FSW-Tool 용 $WC-5Mo_2C-5Co$ 소결체 제조와 기계적 특성 평가

  • Yun, Hui-Jun;Park, Hyeon-Guk;Lee, Seung-Min;Bang, Han-Seo;Bang, Hui-Seon;O, Ik-Hyeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.40.2-40.2
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    • 2011
  • 초경합금은 경도가 높은 재료를 말하며 일반적으로는 탄화텅스텐(WC)계 재료를 말한다. 국내 현재 초경합금 동향은 반도체 산업, 내마모성 공구, 절삭공구, 금형 등 많은 분야에 사용되어지고 있다. 또한 최근 들어 FSW (Friction Stir Welding, FSW)기술이 발전함에 따라 접합기술개발이 다양화되면서 FSW Tool의 고성능의 초경 재료가 요구되어지며 장수명의 Tool개발이 되어야 한다. 국내에서는 초경 합금 재료로 사용되어지고 있는 텅스텐 카바이드(WC)와 코발트(Co)를 이용하여 많은 연구가 진행되었다. 본 실험에서는 텅스텐 카바이드와 코발트 및 몰르브덴 카바이드를 혼합하여 소결체를 제조하였다. 실험에 사용된 텅스텐 카바이드는 높은 경도를 가지고 강한 취성을 나타내며, 소결에 어려운 단점이 있다. 이러한 단점을 코발트와 몰리브덴 카바이드를 첨가하여 소결온도를 낮춰주는 역할과 액상 소결시 텅스텐카바이드 입자사이에 침투하여 액상소결에 의한 치밀화가 가능하게 해주며 인성이 향상되어 고인성 재료를 만들 수 있었다. 본 실험에서는 합성과 치밀화가 동시에 진행되는 SPS (Spark Plasma Sintering:SPS) 장비를 이용하여 실험을 진행하였다. 이 방법은 방전플라즈마 소결 공법으로, 기존의 연소법과 열간 가압기술(Hot-press, HIP)을 결합한 방식으로 단 시간, 단일공정으로 치밀한 소결체를 얻을 수 있는 장점이 있다. 본 연구에서는 $WC-5Mo_2C$-5wt%Co 소결체 제조를 위해 원소 분말을 Horizontal ball milling 혼합하였다. 균일하게 혼합된 분말을 흑연다이에 충진하여 펄스전류와 기계적 압력을 동시에 가하여 $WC-5Mo_2C-5Co$ 복합재료를 제조하고 소결체의 밀도, 순도, 상변태, 미세조직 등을 분석 및 평가하였다. SPS공정 조건은 고진공하에서 $1,200^{\circ}C$-60MPa, 펄스비 12:1 조건으로 수행하였으며, 얻어진 $WC-5Mo_2C-5Co$ 소결체의 상대 밀도는 98%이상 이였다. 또한, 결정립 크기는 약 400 nm였으며, 경도는 $2,453kg/mm^2$를 나타내었다.

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Suggested Method for Determining a Complete Set of Micro-Parameters Quantitatively in PFC2D (PFC2D 활용을 위한 정량적 미시변수 결정법)

  • Jong, Yong-Hun;Lee, Chung-In
    • Tunnel and Underground Space
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    • v.16 no.4 s.63
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    • pp.334-346
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    • 2006
  • The discrete element code in 2-D, PFC2D, has been used as a tool to simulate various phenomena in rock mechanics and rock engineering. However, the code has an disadvantage that procedure to determine micro-parameters, namely properties of particles and contacts is repetitive and time-consuming. In this study, we analyzed the effect of micro-parameters(for generation of a contact-bonded model) on macro-properties(that were measured numerically by uniaxial compressive test). Based on the analysis, also, the time-saving and reliable method was suggested to determine a complete set of micro-parameters. In order to verify the suggested method, numerical specimens were generated in PFC2D for 10 different rock types at home and abroad. By the two trials for each specimen, in the result, the Young's modulus, Poisson's ratio and uniaxial compressive strength could be reproduced with being in relative error by about 5% to the values obtained by laboratory tests.