• Title/Summary/Keyword: 단전지

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Characterization of $SiO_2-R_2O_3$-RO with compositions changes of $R_2O_3$, RO on Sealant ($SiO_2-R_2O_3$-RO계에서 $R_2O_3$, RO 변화에 따른 밀봉재 특성)

  • Yang, Sang-Jin;Choi, Byung-Hyun;Lee, Mi-Jai;Lee, Hong-Lim;Yoo, Young-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.23-23
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    • 2007
  • 고체산화물연료전지(SOFC)는 연료가 갖는 화학에너지를 연소과정 없이, 공기와 $H_2$, CO, $CH_4$와 같은 환원성 가스를 공급받아 $700^{\circ}C-850^{\circ}C$에서 전기화학적 반응을 통하여 직접 전기를 얻는 방식이다. SOFC는 여러장의 단위 셀을 적층하여 스택을 구성하는데, 스택 제조시 단전지에 공급되는 산화, 환원 가스의 누출이나 흡입을 막기 위하여 밀봉재를 사용한다. 이러한 밀봉재는 완벽한 밀봉, 열에 대한 안정성, 충격에 견디는 저항성 등의 기계적인 특성 및 구성요소와의 최소한의 열팽창계수차를 가져야 한다. 따라서 본 연구에서는 $SiO_2-R_2O_3$-RO계에서 $R_2O_3$, RO의 변화에 따른 밀봉 특성 및 열팽창계수에 미치는 영향을 조사하였다.

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Construction of Low Magnetic Standard System using a Multi-layer Solenoid with Single-current (단전류-다층 솔레노이드 방법을 사용한 저자장 표준시스템 제작)

  • 박포규;김영균
    • Journal of the Korean Magnetics Society
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    • v.11 no.1
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    • pp.38-44
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    • 2001
  • The magnetic field standard below 1 mT with the resolution of 0.26 nT has been established. Earth magnetic field (EMF) is compensated automatically down to 0.1 nT/10 min. by a closed feedback system with Cs optical pumping magnetometer and 3-axis Helmholtz coils in nonmagnetic facilities. A multi-layer precision solenoid with the optimized single-current method generates the uniform magnetic field better than 1.0$\times$10$\^$-7/ within $\pm$ 1 cm region at its center. The coil constant of solenoid determined from Helium optical pumping magnetometer is 1.231 058 9 mT/A, and temperature coefficient is 0.38 nT/$\^{C}$. This standard system is used for calibration of low field magnetometers and testing relates to low field.

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The Paper on The Martialarts Acting System for Action Acting Technic (효율적인 액션연기를 위한 '무예武藝연기술시스템' 의 논의)

  • Kim, Sunam
    • The Journal of the Korea Contents Association
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    • v.15 no.7
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    • pp.57-74
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    • 2015
  • This paper will concentrates on martialarts acting system. I will sugest a kind of actor's training system for the safe method of action acting. In this study I solve the following problems. First, what is main factors to interfere with performer to act and how do they get rid of factors. Second, what is very economic and effective challenge to develope the new acting system for action acting performers. For this discussion I studied four parts. The first, I gives purpose and direction of the safe for martialarts actor. The second, I traces the development of contemporary idea of acting such as Stanislavsky and Meyerhold. The third I introduces Korean martialarts training system. The last I conclude which refer to effective action acting by result of training 'Korean traditional martialarts acting system'.

Sintering and Creep Characteristics of the Ni-Al Alloy Anode for Molten Carbonate Fuel Cells (용융탄산염 연료전지용 Ni-Al 합금 anode의 소결 및 creep 특성)

  • Oh, In-Hwan;Han, Jae-Il;Yun, Seong Pil;Lim, Tae Hoon;Nam, Suk Woo;Ha, Heung Yong;Hong, Seong Ahn
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.1
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    • pp.24-33
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    • 2002
  • 기존 Ni-10w/o Cr 연료극과 성능은 대등하면서 creep 저항성이 뛰어난 연료극을 제조하기 위하여 Ni-5w/o Al 합금 연료극의 제조 공정을 연구하였다. 소성 분위기에 따라 완전산화 방법과 부분산화 방법으로 나누어 제조된 전극들의 미세구조 변화를 관찰하였으며, 실험 결과 부분산화 방법으로 제조한 Ni-5w/o Al 합금 연료극이 가장 우수한 소결 및 creep 저항성을 나타내었다. 이는 연료극이 산화물 분산강화 구조를 갖기 때문으로 부분산화 방법으로 제조한 Ni-5w/o Al 합금 연료극을 장착한 단전지의 경우 기계적 안정성 및 전극 안정성이 향상되었다.

A Basic Study on the Stress Field in the Electrode Interface of the Planar SOFC Single Cell (평판형 SOFC 단전지 전극계면에서 발생되는 응력장에 관한 기초적 연구)

  • Park, Chul Jun;Kwon, Oh Heon;Kang, Ji Woong
    • Journal of the Korean Society of Safety
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    • v.28 no.5
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    • pp.5-9
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    • 2013
  • Recently, eco-friendly sources of energy by fuel cells that use hydrogen as an energy source has emerged as the next generation of energy to solve the problem of environmental issues and exhaustion of energy. A solid oxide fuel cell(SOFC) classified based on the type of ion transfer mediator electrolyte has actively being researched. However, the reliability according to the thermal cycle is low during the operation of the fuel cell, and deformation problem comes from the difference in thermal expansion coefficient between the electrode material, the components made of ceramic material is also brittle, which means disadvantages in terms of the strength. Therefore, in this study, considering the states of the manufacturing and operating of SOFC single cells, the stress analyses in the each of the interfacial layer between the anode, electrolyte and the cathode were performed to get the basic data for reliability assessment of SOFC. The obtained results show that von Mises stress according to the thickness direction on operating state occurred maximum stress value in the electrolyte layer. And also the stresses inside the active area on a distance of 1 ${\mu}m$ from the electrode interface were estimated. Futhermore the evaluation was done for the variation of the stress according to the stage of the operation divided into three stages of manufacturing, stack, and operating.

The Properties of the Manufactured SOFC Unit Cell using Decalcomania Method (전사법을 이용하여 제조한 SOFC 단전지의 특성 분석)

  • Lee, Mi-Jai;Kim, Bit-Nan;Lim, Tae-Young;Kim, Sei-Ki;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.520-524
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    • 2011
  • The properties of manufactured SOFC unit cell using decalcomania method were investigated. The decalcomania method that used in ceramics, dish, vessel and etc. was the very simple process. The SOFC unit cell manufacturer using decalcomania method is very simple process. Especially, the decalcomania method was the most suitable manufacturing method for the segmented type SOFC. The cathode, prevent diffusion layer (PDL), anode functional layer (AFL) and electrolyte were manufactured using decalcomania method on porous anode support. The sintered electrolyte at 1450$^{\circ}C$ for 2 h using decalcomania method was very dense, and the thickness was about 10 ${\mu}m$. The cathode, the PDL and the AFL were manufactured using decalcomania method and was sintered at 1250$^{\circ}C$ for 2 h, and the sintered electrodes were the porous. As a result, with humidified hydrogen used as fuel, the cell with an 15 ${\mu}m$-thick AFL exhibited maximum power densities of 0.246, 0.364, 0.504W/$cm^2$ at 700, 750, 800$^{\circ}C$, respectively.

Characterization of Passive Direct Methanol Fuel Cells (수동형 직접 메탄올 연료전지의 특성 연구)

  • Kho, B.K.;Kim, Y.J.;Oh, I.H.;Hong, S.A.;Ha, H.Y.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.1
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    • pp.23-27
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    • 2003
  • In this study investigations have been carried out for the evaluation of small DMFCS under passive operation conditions for use in portable powers. Under passive conditions, a maximum performance was obtained at a methanol concentration of 4 M and at a catalyst loading of $8mg/cm^2$ on both electrodes. By optimizing various parameters, we could achieve the highest performance of $55mW/cm^2$ at 1 attn and at R.T.A monopolar stack consisting of 6 unit cells with active area of $4.5cm^2/cell$ was prepared and it showed a uniform voltage distribution all over the cells and it had a power output of 1 watt and a power density of $37mW/cm^2$ A monopolar stack which consisted of 16 cells and produced a 2.4W power was also fabricated and was tested for operation of a miniature car.

Performance Charateristics of Direct Borohydrides Fuel Cell with Novel Catalyst (귀금속 촉매를 사용한 직접 보로하이드라이드 연료전지의 특성 연구)

  • Jung, M.K.;Shin, D.R.;Seol, Y.K.;Jung, D.H.
    • Journal of the Korean Electrochemical Society
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    • v.8 no.1
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    • pp.6-11
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    • 2005
  • Direct borohydrides fuel cell (DBFC) was emerged to complement the problem of DMFC's low performance and methanol crossover to the cathode and to apply the fuel cell to portable and mobile devices. In this study, the characteristics of novel catalysts was tested to establish the electrode preparation process of DBFC. Pt black and carbon supported-Pt by paste method were used as the cathode catalysts. Pt black, carbon supported-Au and $AB_5$ alloy were used as the anode catalysts. The characteristics of the electrodes were analyzed by XRD, SEM, EDS. The performance test of single cell using the electrodes were carried out in order to evaluate the electrode performance. In the result, the maximum power output was obtained as 366 mW/mg when using Pt/C as anode and cathode catalysts.

Fabrication of Solid Oxide Fuel Cells via Physical Vapor Deposition with Electron Beam: II. Unit Cell Performance (전자빔 물리증착을 이용한 고체 산화물 연료전지의 제조: II. 단전지 성능)

  • Kim, Hyoung-Chul;Park, Jong-Ku;Jung, Hwa-Young;Son, Ji-Won;Kim, Joo-Sun;Lee, Hae-Weon;Lee, Jong-Ho
    • Journal of the Korean Ceramic Society
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    • v.43 no.5 s.288
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    • pp.299-303
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    • 2006
  • In this paper, anode supported SOFC with columnar structured YSZ electrolyte was fabricated via Electron Beam Physical Vapor Deposition (EBPVD) method. Liquid condensation process was employed for the preparation of NiO-YSZ substrate and the high power electron beam deposition method was used for the deposition of YSZ electrolyte film. Double layered cathode with LSM-YSZ and LSM was printed on electrolyte via screen-printing method and fired at $1150^{\circ}C$ in air atmosphere for 3 h. The electrochemical performance and the long-term stability of $5{\times}5cm^2$ single cell were investigated with DC current-voltage characteristics and AC-impedance spectroscopy. According to the investigation, $5{\times}5cm^2$ sized unit cell showed the maximum power density of around $0.76W/cm^2$ at $800^{\circ}C$ and maintained the stable performance over 400 h.

AC Impedance Study of Oxygen Electrode in Phosphoric Acid Fuel Cell (교류 임피던스법에 의한 인산형 연료전지의 산소전극 특성 연구)

  • Song Rak-Hyun;Kim Chang-Soo;Shin Dong-Ryul
    • Journal of the Korean Electrochemical Society
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    • v.3 no.4
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    • pp.191-195
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    • 2000
  • Electrochemical properties of the oxygen electrode in phosphoric acid fuel cell have been studied using AC impedance method as a function of applied potential, operating temperature and teflon content in the electrode. The oxygen electrode reaction in the $105wt.\%$ phosphoric acid is characterized by a parallel resistive component, $R_p$ and a capacitive component, $C_p$ with serial electrolyte resistance, $R_s$. The conductivity of the phosphoric acid is found to be 0.31-0.47 S/cm in the range of $130\;to\;190^{\circ}C$ from the measured impedance. The increase of applied potential and temperature produced the decreased RP and the increased $C_p$, which means the increase of the oxygen electrode reaction rate. The single cells with the cathode of various teflon contents were tested, and the cathode with $40wt.\%$ teflon showed good performance, which is considered to be related to an optimized impedance behavior.