• Title/Summary/Keyword: 단일 성분

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Fabrication of Ti-Al-X(Cr, Si, B, V) single alloying target material for the formation nanocomposite coating and the properties of the coating formed by Ti-Al-X single alloying target material (나노복합 코팅 형성을 위한 Ti-Al-X(Cr, Si, B, V) 계 단일 합금 타겟 제조 및 이를 이용해 형성한 코팅 특성 평가)

  • Pyeon, Jin-Ho;Lee, Han-Chan;Mun, Gyeong-Il
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.78-79
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    • 2015
  • PVD 공정에서 다성분으로 이루어진 나노복합 코팅을 형성하는 것은 원소들간의 합금화 문제로 인해 어렵다. 따라서 일반적으로 두 개 이상의 원소타겟 또는 멀티타겟을 이용한 PVD+PECVD 의 융합공정에 의해 제조된다. 하지만 멀티타겟을 사용한 공정은 공정의 복잡화가 뒤따르며 신뢰성이 떨어진다. 본 연구에서는 멀티타겟의 단점을 보완하기 위해 Ti-Al-X(Cr, Si, B, V) 단일 합금 타겟을 제작하여 나노복합 코팅을 형성하고자 하였다. 기계적 합금화법을 통해 합금분말을 제조하였으며, 방전플라즈마소결법으로 합금 타겟을 제작하였다. 제작된 타겟을 이용하여 스퍼터링 장치를 통해 박막을 형성 하였다. 그 결과 분말은 밀링 시간 20시간에서 정상상태에 도달하였으며, 더 이상 분말의 입자는 줄어들지 않았다. 이때 분말의 입자크기는 $5{\sim}6{\mu}m$ 이었으며 결정립의 크기는 16~20nm 이었다. 소결을 통해 99% 이상의 진밀도를 갖는 합금타겟을 제작하였으며, 이때 결정립의 크기는 매우 미세하였다. 박막의 경우 모두 30GPa 이상의 고경도 특성을 나타냈다.

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Spectral Analysis of Transient Elastic Waves Generated by Point Source in Glass and Unidirectional CFRP Plates (유리판과 단일방향 탄소섬유강화 플라스틱판에서 점원에 의해 발생된 과도적 탄성파의 주파수 해석)

  • Lee, Jeong-Ki;Kim, Ho-Chul;Choi, Myoung-Seon;Kim, Young-Hwan
    • The Journal of the Acoustical Society of Korea
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    • v.13 no.6
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    • pp.50-59
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    • 1994
  • Spectral analysis of transient elastic waves were carried out in order to identify the propagation modes in glass and unidirectional carbon fibre reinforced plastic (CFRP) plates. Pencil leads were broken on the surface of plates to generate elastic waves, and two broad band transducers of 6.35 mm in diameter and 10 MHz center frequency were placed at the linear location from the source. The frequency spectra of detected signals showed that the wave propagation in the plates obeyed the Lamb wave dispersion relation. The transient signals were the fast propagating modes around maximum group velocity of the lowest and first order symmetric $modes(S_{0} and S_{1}),$ and first order antisymmetric $mode(A_{1})$. The transient signals were not severely distorted due to relatively small dispersion of those modes around the maximum group velocity. The fastest propagating mode in the plates was shown to be $S_{0}$ mode less the than cut-off frequency of $A_{1}$ mode.

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Corrosive control of the water produced by SWRO and Application to small dimensional Pilot Plant (SWRO 생산수의 부식성 제어를 위한 목표 수질 연구 및 소규모 Pilot Plant 적용)

  • Kim, Min-Chul;Hwang, Kyu-Won;Woo, Dal-Sik;Yoon, Seok-Min;Moon, Jung-Gi;Kwak, Moung-Hwa
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.1042-1045
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    • 2009
  • 역삼투식 해수담수화 (Sea Water Reverse Osmosis, SWRO) 공정에 의한 생산수는 pH가 낮고, 해수 내 존재하는 경도성분인 Ca, Mg 이온이 대부분 제거되기 때문에 상대적으로 매우 강한 부식성을 지니고 있다. 이를 음용수 및 공업용수로 이용 시 설비 및 배관계통에 심각한 부식문제를 유발할 수 있으며, 이를 방지하기 위한 처리공정과 부식성 제어 기술의 지속적인 개발이 요구되는 실정이다. SWRO 1단으로 처리 시 생산수의 전기전도도는 $150{\mu}S/cm$ 정도의 범위를 보이며, 2단 SWRO 과정을 거칠 시 전기전도도는 $100{\mu}S/cm$ 이하의 범위를 나타내는 것으로 알려져 있다. 본 연구에서는 SWRO 2단 처리수를 가정한 $20{\mu}S/cm{\sim}25{\mu}S/cm$ 범위의 전기전도도를 지닌 물을 실험 원수로 사용하여, 기존 방식제의 성분과 생산수의 특성을 고려한 효율적인 알칼리성 수처리제를 적용하고 그에 대한 부식성 제어 연구를 수행하였다. SWRO 생산수를 대상으로 부식방지기술을 개발하기 위해서는 부식제어와 관련된 수질 인자인 pH, 칼슘경도, 알칼리도의 조절과 LSI(Langelier Saturation Index)를 설정하는 것이 무엇보다도 중요하다. 본 연구에서는 해수담수화 공정의 생산수를 음용수 및 공업용수로 이용하기 위한 목표 수질을 pH 7.5~7.8, LSI 0 이상, 부가적으로 전기전도도는 $250{\mu}S/cm$ 이하로 설정하였으며, 연구목표 수질을 달성할 수 있는 부식억제제 및 알칼리성 수처리제의 적용을 통해 목표 수질에 대한 설정 근거를 마련하고자 하였다.

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Prediction of Sorption Characteristics by Mass Balance Concept (함량비례 개념에 의한 수분흡습 특성의 예측)

  • Yoon, Heeny H.N.;Kim, H.;Shin, Y.D.;Yoo, M.Y.
    • Korean Journal of Food Science and Technology
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    • v.18 no.2
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    • pp.77-81
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    • 1986
  • The water sorption isotherms of individual insoluble components of corn starch, isolated soybean protein (ISP) and casein and their binary mixtures of corn starch-lSP and corn starch-casein were measured and analyzed. BET monolayer values and Smith plot parameters from the results of sorption isotherms were calculated by mass balance concept . The comparisons between experimental and predicted values resulted in an error of 2.29% for equilibrium moisture content and an error of 2.95% in monolayer value for the mixture 50% corn starch-50% ISP. On the other hand , for the mixture 50% corn starch-50% casein the errors were 2.66% and-5.34%, respectively.

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Dynamic Characteristics Improvement of Three-phase PWM Converter for Arc Welding Machine Using Feedforward Compensator (전향보상기를 이용한 아크용접기용 3상 PWM 컨버터와 동특성 향상)

  • 구영모;최해용;목형수;최규하;김규식;원충연
    • The Transactions of the Korean Institute of Power Electronics
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    • v.5 no.5
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    • pp.419-426
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    • 2000
  • Generally diode rectifier has been used as Preregulator of arc- welding machine. Its defect is the generation of high current harmonics which result In utility pollution. In this parer, using the three-phase PWM converter, the input performance of arc-welding machine is improved by increasing the input power factor. When the diode rectifier in the arc-welding machine is replaced with three-phase PWM converter, PWM converter should control DC voltage of the output side. If PI controller is used for the output DC voltage regulator, the output DC voltage has high ripple voltage due to the instantaneous load variation in the arc-welding machine. In this paper, the feedforward compensator has been introduced to reduce the DC voltage ripple. It lessens the influence of load current which is the disturbance of the output DC voltage regulator. Theoretical prediction of this analysis has been verified by comparing with experimental data

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Very High Linearity of High Power Amplifier by Reduction of $2^{nd}$, $3^{rd}$ Harmonics and Predistortion of $3^{rd}$ IMD (3차 혼변조 신호의 전치왜곡과 2, 3차 고조파 억제를 통한 고선형성 고출력 전력 증폭기에 관한 연구)

  • Lee, Chong-Min;Seo, Chul-Hun
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.48 no.1
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    • pp.50-54
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    • 2011
  • In this article, the linearity of single power amplifier is improved by suppress $2^{nd}$ and $3^{rd}$ harmonics at output port of high power amplifier and by cancelling of $3^{rd}$ IMD. The matching network in order to suppress harmonics consists of metamaterial like the CRLH. The $2^{nd}$ and $3^{rd}$ harmonics are suppressed over 27 dBc, respectively. A phase of generated $3^{rd}$ IMD at output of DPA (drive power amplifier) has changed in order to offset the $3^{rd}$ IMD of HPA (high power amplifier). The harmonics of the proposed PAM suppress over 6 dB than single HPA. The PAM has a 36.98 dBm of the output power, 21.6 dB of the power gain and 29.4 % of the PAE. The harmonics is a -53 dBc about PAM. This result indicate that a harmonic level is lower 20 dB than reference power amplifier.

A Study on Three-dimensional Dynamic Analysis of a Towing Cable for Marine Survey Instruments (해양탐사장비 예인케이블의 3차원 동적해석에 관한 연구)

  • 정동호;김종규;박한일
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.2
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    • pp.203-209
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    • 2003
  • In this study, the configuration and tension of a towing cable for side-scan sonar are predicted in an ambient flow and at an unsteady towing condition. The governing equation of three-dimensional dynamic analysis for a flexible cable is solved using a finite difference method. We successfully predict the configuration and tension of a side-scan sonar and designed the towing system. It is found in static analyses that the side-scan sonar must be towed to keep a its stable depth at a reasonable speed. The study also reveals in the transient analyses that the dominant component affecting the top tension is the tangential drag force for the larger towing speed than the critical speed, and the soft weight of a towed instrument for the smaller towing speed than. It should be maneuvered for a towing vessel with good consideration for the impact effect in a cable due to tension peak when a towing speed is suddenly increase. The developed program can be applicable for three-dimensional dynamic analysis of a towing system for various marine survey instruments.

Visualization of Stage Calculations in Quaternary Reactive Distillation with Multiple Reactions (4성분계 다중반응증류 공정의 시각화)

  • Kang, Dohyung;Lee, Jae W.
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.713-719
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    • 2014
  • When multiple reactions of quaternary mixtures take place in a reactive distillation column, the behavior of composition trajectory is analyzed by a visual-aided method. By adding additional vectors of multiple reactions and visualizing them in composition space, the composition of each component and extent of each reaction on an arbitrary stage can be easily estimated in terms of the composition trajectory and reaction cascade difference points. Moreover, for a given operating conditions, the number of total stages and position of optimum reaction zone can be determined by the visual-aided method. In this study, ethylene glycol synthesis with a side reaction is taken as an example and analyzed by the proposed graphical method. Through this method, the quaternary reactive distillation with multiple reactions can be analyzed without numerous experiments and simulations.

A Study on the Recovery of Nitric Acid from Spent Nitric Etching Solutions by Solvent Extraction (질산 Etching 폐액으로부터 용매추출법에 의한 질산의 회수에 관한 연구)

  • 안재우
    • Resources Recycling
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    • v.7 no.5
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    • pp.46-51
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    • 1998
  • A study has been on the recovery of nitric acid and valuable metals such as Fe, Cu, Sn, Pb, from spent nitric etching solutions. The effects of extractant of extractant type, concentrations, phase raios and selectivity from Fe, Cu, Sn, Pb on nitric acid extraction were studied. The results showed that TBP as an extractant for recovering of nitric acid was more effective than Alamine336, and the optimal concentration of TBP was found to be 60~70% of organic phase. Also, the nitric acid were only extracted by TBP from the spent etching solutions and the heavy metals such as Fe, Cu, Sn, Pb were not extracted above 0.1N nitric acid in spent etching solutions, From the analysis of McCabe-Thiele diagram, the extraction of 95% nitric acid is attained at a ratio of O/A=3 with five stages by 60% TBP and the stripping of 98% nitric acid from 80 g/l nitric acid in organic phase is attained at a ratio of O/A=1 with four stages by distilled water.

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The Effect of Organic Acids in Decontamination Solution on Ion Exchange of Metal Ions (제염용액내 유기산이 금속이온 이온교환에 미치는 영향)

  • Yang, Yeong-Seok;Kang, Young-Ho;Jheong, Gyeong-Rak
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.171-177
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    • 1993
  • In decontamination process to remove radioactive materials of reactor cooling system, the metal ions dissolved by organic acids in decontamination solution are separated by use of ion exchange resin in the column. However, organic acids in decontamination solution decrease the apparent affinity of the resin to metal ions. In light of this, some experiments were carried out on the Amberlite IRN-77 cation resin with cobalt and iron to gain a better understanding of the complexation effects on the ion exchange process. Experimental results showed that EDTA among organic acids used as chemical decontaminants predominantly caused reduction of ion exchange capacity of cobaltous ion to resin since this reagent formed the complex with the cobaltous ion stronger than that with the ferrous ion. In contrast, the effects of oxalic acid and citric acid were found to be negligible. And, single and two-component nonlinear equilibrium relationships of the metal ions were established using experimental data.

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