• Title/Summary/Keyword: 단위 격자 구조

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Ferroelectric properties of the $Ba(La_{1/2}Nb_{1/2})O_3-Pb(Zr_yTi_{1-y})O_3$ceramics with $PbZrO_3$ contents (투광성 $Ba(La_{1/2}Nb_{1/2})O_3-Pb(Zr_yTi_{1-y})O_3$ 세라믹의 $PbZrO_3$조성에 따른 강유전 특성)

  • 류기원;이성갑;배선기;이영희
    • Electrical & Electronic Materials
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    • v.6 no.3
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    • pp.241-247
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    • 1993
  • 본 연구에서는 투광성 0.085Ba(L $a_{1}$2/N $b_{1}$2/) $O_{3}$- 0.915Pb(Z $r_{y}$ $Ti_{1-y}$) $O_{3}$(0.45.leq.y.leq.0.70)세라믹을 2단 소성법으로 제작한 후, PbZr $O_{3}$조성 및 온도에 따른 구조적, 강유전적특성을 측정하였다. XRD측정 결과, PbZr $O_{3}$조성이 감소할수록 결자상수 및 단위격자 체적은 감소하였으며 시편의 결정구조는 입방정계에서 능면체정계, 정방정계로 변화되었다. 8.5/60/40시편의 경우 포화분극, 잔류분극 및 항전계가 각각 33.28[.mu.C/$cm^{2}$], 4.15[kV/cm]로 전형적인 메모리 특성을 나타내었으며 PbZr $O_{3}$조성이 증가함에 따라 강유전 이력곡선은 slim loop특성을 나타내었다. 잔류분극은 온도가 증가함에 따라 감소하였으며 특히 PE-FE상경계 부근에 위치한 조성의 경우, 상전이 온도 이하의 온도에서 급격히 감소하는 경향을 나타내었다.다.

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MLP-based 3D Geotechnical Layer Mapping Using Borehole Database in Seoul, South Korea (MLP 기반의 서울시 3차원 지반공간모델링 연구)

  • Ji, Yoonsoo;Kim, Han-Saem;Lee, Moon-Gyo;Cho, Hyung-Ik;Sun, Chang-Guk
    • Journal of the Korean Geotechnical Society
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    • v.37 no.5
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    • pp.47-63
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    • 2021
  • Recently, the demand for three-dimensional (3D) underground maps from the perspective of digital twins and the demand for linkage utilization are increasing. However, the vastness of national geotechnical survey data and the uncertainty in applying geostatistical techniques pose challenges in modeling underground regional geotechnical characteristics. In this study, an optimal learning model based on multi-layer perceptron (MLP) was constructed for 3D subsurface lithological and geotechnical classification in Seoul, South Korea. First, the geotechnical layer and 3D spatial coordinates of each borehole dataset in the Seoul area were constructed as a geotechnical database according to a standardized format, and data pre-processing such as correction and normalization of missing values for machine learning was performed. An optimal fitting model was designed through hyperparameter optimization of the MLP model and model performance evaluation, such as precision and accuracy tests. Then, a 3D grid network locally assigning geotechnical layer classification was constructed by applying an MLP-based bet-fitting model for each unit lattice. The constructed 3D geotechnical layer map was evaluated by comparing the results of a geostatistical interpolation technique and the topsoil properties of the geological map.

A Study on the Population Estimation of Small Areas using Explainable Machine Learning: Focused on the Busan Metropolitan City (해석가능한 기계학습을 적용한 소지역 인구 추정에 관한 연구: 부산광역시를 대상으로)

  • Yu-Hyun KIM;Donghyun KIM
    • Journal of the Korean Association of Geographic Information Studies
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    • v.26 no.4
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    • pp.97-115
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    • 2023
  • In recent years, the structure of the population has been changing rapidly, with a declining birthrate and aging population, and the inequality of population distribution is expanding. At this point, changes in population estimation methods are required, and more accurate estimates are needed at the subregional level. This study aims to estimate the population in 2040 at the 500m grid level by applying an explainable machine learning to Busan in order to respond to this need for a change in population estimation method. Comparing the results of population estimation by applying the explainable machine learning and the cohort component method, we found that the machine learning produces lower errors and is more applicable to estimating areas with large population changes. This is because machine learning can account for a combination of variables that are likely to affect demographic change. Overestimated population values in a declining population period are likely to cause problems in urban planning, such as inefficiency of investment and overinvestment in certain sectors, resulting in a decrease in quality in other sectors. Underestimated population values can also accelerate the shrinkage of cities and reduce the quality of life, so there is a need to develop appropriate population estimation methods and alternatives.

A Study on the Improvement of Efficiency and Linearity of Power Amplifier using PBG Structure (PBG 구조를 이용한 전력 증폭기의 효율 및 선형성 개선에 관한 연구)

  • 김병희;박천석
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.12 no.7
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    • pp.1182-1190
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    • 2001
  • In this paper, microstrip photonic bandgap (PBG) structure with special perforation patterns etched on the line itself is analyzed and optimized in shape, then used for harmonic tuning of power amplifier. This PBG has an advantage in being fabricated and grounded. The dimension of unit lattice is enlarged vertically, but its input and output line maintain 50 Ω using tapered line. This modification from original structure can lessen possible error in etching PCB. The analysis and design of PBG structure are acquired from using EM simulation. The measured insertion loss of the final structure is 0.3 ∼0.4 dB, and its bandwidth of stopband is 6∼7 GHz. Measured results of improved characteristics by using PBG structure at the output of the power amplifier are 0.72∼0.99 dB in output power, 1.14∼7.8 % in PAE, and 1 dBc in the third IMD.

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Stable Defect Structure of La2O3-Modified BaTiO3 (La$_2O_3$-변형 BaTi$O_3$의 안정한 결함구조)

  • Kim, Jeong Su;Park, Hyu Beom;An, Tae Ho;Kim, Si Jung
    • Journal of the Korean Chemical Society
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    • v.38 no.4
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    • pp.309-318
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    • 1994
  • The stable defect structure and the single phase region of La$_2O_3$-modified BaTi$O_3$ have been studied by X-ray diffractometer and scanning electron microscope. The stable defect structure of La$_2O_3$-modified BaTi$O_3$ has been identified as [($Ba^x_{Ba})_{1-2x}(La{\cdot}_{Ba})_{2x}][Ti^x_{Ti})_{1-x/2}(V""_{Ti})_{x/2}]O_3$ which consists of La$^{3+}$ ion substitution for Ba$^{3+}$ ion in the lattice structure and the formation of Ti vacancies for the charge compensation. When 3 mol% of La$_2O_3{\cdot}3/2TiO_3$ was added to BaTi$O_3$, the unit cell structure was transformed from tetragonal to cubic and the solubility limit was about 14 mol%. When La$_2O_3{\cdot}3/2TiO_2$ was added above this solubility limit, the second phase, La$_4Ba_2Ti_5O_{18}$, was formed. In the La$_2O_3$-modified BaTi$O_3$, it was found by the liquid phase sintering process that the sinterability was decreased by excess BaO but increased by excess Ti$O_2$.

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Growth and Characterization of Catalyst-Free InAs Nanowires on Si (111) by MBE

  • Hwang, Jeong-U;Park, Dong-U;Ha, Jae-Du;An, Heung-Bae;Kim, Jin-Su;Kim, Jong-Su;No, Sam-Gyu;Kim, Yeong-Heon;Lee, Sang-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.353-353
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    • 2012
  • InAs nanowires (NWs)는 나노소자스케일의 전자소자나 광전자소자를 위한 기본 단위(building block)로 사용될 수 있고, 1차원적 나노구조를 가지면서 나타나는 특별한 전기적, 광학적 특성으로 인해 전계효과 트랜지스터, 레이저, 광발광 다이오드, 가스 검출 센서 등의 많은 응용소자로 활용을 위한 연구가 진행되 있으며 주로 실리콘, 갈륨비소 기판 위에 금속유기기상 증착(MOCVD) 또는 분자선 증착 (MBE)을 이용하여 선택적 수직배열 성장 조절을 위한 연구와 특성 평가 연구가 주로 이뤄지고 있다. 본 연구에서는 InAs NWs를 MBE 장치를 이용하여 Si(111) 기판 위에 Au와 같은 촉매를 사용하지 않고 Si과 InAs의 큰 격자 불일치로 인하여 성장되는 Volmer-weber 성장 모드를 이용 하였다. InAs NW 성장모드는 Si ($5.4309{\AA}$)과 InAs ($6.0584{\AA}$) 사이에 큰 격자상수 차이를 이용하게 되는데 촉매를 사용하여 성장하는 일반적인 이종 화합물 반도체 성장 모드와 달리 액상상태가 존재하지 않고 바로 In과 As이 Si 기판 위를 이동하여 수직방향으로 성장이 이루어지는 vaporsolid(VS) 모드이다. InAs NW V-S 성장 모드는 Si 기판과의 격자 상수차에 의한 스트레스를 이용해야 하므로 Si기판 위에 존재하는 native oxide는 완벽히 제거되어야 한다. InAs NW 최적 성장 조건을 찾기위해 V/III raitio, 성장 온도, 기판표면처리 등의 성장 변수를 변화 시켜가며 실험을 수행하였다. Native oxide를 제거하기 위하여 HF와 buffered oxide etchant (BOE)를 사용하였다. InAs NWs 성장조건은 Indium flux를 고정 시키고 V/III ratio는 50~400까지 변화를 주었다. V/III ratio를 200으로 고정을 시키고 성장온도를 $375{\sim}470^{\circ}C$에서 성장 하였다. 이 때 InAs NWs는 $430^{\circ}C$에서 가장 높은 밀도와 aspect ratio를 얻을 수 있었다. Arsenic flux에 대해서는 많을 수록 좋은 aspect ratio를 얻을 수 있었다. 하지만 InAs 구조의 절대 부피는 거의 같다는 것을 확인 할 수 있었고 이는 온도와 V/III ratio가 Indium adatom의 surface migration length에 대하여 중요한 요소로 작용되는 것을 알 수 있었다.

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Fabrication of [320×256]-FPA Infrared Thermographic Module Based on [InAs/GaSb] Strained-Layer Superlattice ([InAs/GaSb] 응력 초격자에 기초한 [320×256]-FPA 적외선 열영상 모듈 제작)

  • Lee, S.J.;Noh, S.K.;Bae, S.H.;Jung, H.
    • Journal of the Korean Vacuum Society
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    • v.20 no.1
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    • pp.22-29
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    • 2011
  • An infrared thermographic imaging module of [$320{\times}256$] focal-plane array (FPA) based on [InAs/GaSb] strained-layer superlattice (SLS) was fabricated, and its images were demonstrated. The p-i-n device consisted of an active layer (i) of 300-period [13/7]-ML [InAs/GaSb]-SLS and a pair of p/n-electrodes of (60/115)-period [InAs:(Be/Si)/GaSb]-SLS. FTIR photoresponse spectra taken from a test device revealed that the peak wavelength (${\lambda}_p$) and the cutoff wavelength (${\lambda}_{co}$) were approximately $3.1/2.7{\mu}m$ and $3.8{\mu}m$, respectively, and it was confirmed that the device was operated up to a temperature of 180 K. The $30/24-{\mu}m$ design rule was applied to single pixel pitch/mesa, and a standard photolithography was introduced for [$320{\times}256$]-FPA fabrication. An FPA-ROIC thermographic module was accomplished by using a $18/10-{\mu}m$ In-bump/UBM process and a flip-chip bonding technique, and the thermographic image was demonstrated by utilizing a mid-infrared camera and an image processor.

B-site Cationic Ordering Structures of Donor-Doped Relaxor Ferroelectric $Pb({Mg_{1/3}}{Nb_{2/3})}O_3$ (전자 주게가 첨가된 완화형 강유전체 $Pb({Mg_{1/3}}{Nb_{2/3})}O_2$의 B자리 양이온 질서배열구조)

  • Cha, Seok-Bae;Kim, Byeong-Guk;Je, Hae-Jun
    • Korean Journal of Materials Research
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    • v.10 no.7
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    • pp.478-481
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    • 2000
  • Single phase $Pb(Mg_{1/3}Nb_{2/3})O_3$ ceramics doped by 10 mol% of electron donors such as $La^3,\; Pr^{3+,4+},\; Nd^{3+},\; Sm^{3+}$, were synthesized and their B-site cationic ordering structures were investigated by XRD and TEM. In the XRD patterns, only fundamental reflections were observed for the undoped $Pb(Mg_{1/3}Nb_{2/3})O_3$, while the (h/2 $\textsc{k}$/2ι/2)(h,$\textsc{k}$,ι all odd) superlattice reflections resulting from the 1:1 ordering induced unit cell doubling were also observed for the donor-doped $Pb(Mg_{1/3}Nb_{2/3})O_3$. In the TEM selected area diffraction patterns, the (h/2 k/2 l/2)(h,k,l all odd) superlattice reflection spots as well as the fundamental reflection spots were observed for all the samples, but the relative intensities of the superlattice reflection spots to the fundamental reflection spots were significantly enhanced by the donor-doping. In the TEM dark-field images, antiphase boundaries were observed only for the donor-doped $Pb(Mg_{1/3}Nb_{2/3})O_3$. It was therefore experimentally verified that doping by electron donors such as $La^3,\; Pr^{3+,4+},\; Nd^{3+},\; Sm^{3+}$, enhances the B-site cationic 1:1 ordering in $Pb(Mg_{1/3}Nb_{2/3})O_3$. These experimental results were interpreted in terms of the charge compensation mechanism.

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Liquid Crystalline Properties of Schiff Base Mono- and Dimesogenic Compounds (Schiff Base 단일- 및 이메소제닉화합물의 액정성)

  • Park, Joo-Hoon;Choi, Ok-Byung;Lee, Jin-Seok;Kang, Keun-Myoung;Shin, Joo-Cheol;Kim, Ki-Hwan;Kim, Hak-Jin;Lee, Chang-Joon;So, Bong-Keun;Lee, Soo-Min
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.176-180
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    • 2005
  • The liquid crystalline properties of a series of main chain liquid crystalline polymers and four series compounds consisting of aromatic type Schiff base mesogenic units and polymethylene flexible spacers were studied. The thermal and liquid crystalline properties were investigated by differential scanning calorimetry and on the hot stage of a polarizing microscope. The nature of the liquid crystalline phase of the polymers and compounds depended greatly on the length of the central polymethylene spacer and on the terminal alkoxy groups. Polymers I and Series III exhibited an even-odd effect in melting and isotropization temperatures but Series II and Series IV exhibited an even-odd effect in isotropization temperatures. They formed nematic and smectic mesophases in melts as judged by their optical textures observed through a polarizing microscope.

Hot Place Detection Based on ConvLSTM AutoEncoder Using Foot Traffic Data (유동인구를 활용한 ConvLSTM AutoEncoder 기반 핫플레이스 탐지)

  • Ju-Young Lee;Heon-Jin Park
    • The Journal of Bigdata
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    • v.8 no.2
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    • pp.97-107
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    • 2023
  • Small business owners are relatively likely to be alienated from various benefits caused by the change to a big data/AI-based society. To support them, we would like to detect a hot place based on the floating population to support small business owners' decision-making in the start-up area. Through various studies, it is known that the population size of the region has an important effect on the sales of small business owners. In this study, inland regions were extracted from the Incheon floating population data from January 2019 to June 2022. the Data is consisted of a grid of 50m intervals, central coordinates and the population for each grid are presented, made image structure through imputation to maintain spatial information. Spatial outliers were removed and imputated using LOF and GAM, and temporal outliers were removed and imputated through LOESS. We used ConvLSTM which can take both temporal and spatial characteristics into account as a predictive model, and used AutoEncoder structure, which performs outliers detection based on reconstruction error to define an area with high MAPE as a hot place.