• 제목/요약/키워드: 단분자막

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수정진동자를 이용한 Viologen Self-Assembly 단분자막의 전기화학적 특성 (The electrochemical study on Viologen SA monolayer using QCM)

  • 김정명;윤희찬;송성훈;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 센서 박막재료 반도체재료 기술교육
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    • pp.21-23
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    • 2002
  • In this paper, the electrochemical behavior of Viologen self assembly monolayer has been investigated with QCM, which has been known as nano-gram order mass detector. The self assemvly process of Viologen was monitored using resonant frequency $({\Delta}F)$ and resonant resistance(R). QCM measurements indicated a mass adsorption for Viologen assembling on the gold sufrace with a frequency change about 135[Hz] and calculated its surface coverage($\Gamma$) to be $3.5273{\times}10^{-9}[mol/cm^{2}]$. Also reversible redox process was observed and analyzed with ionic interaction at the Viologen/solution interface using ${\Delta}F$.

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변위전류법에 의한 지질 단분자막의 $\pi$-A특성 ($\pi$-A properties of phospholipid monolayers by Maxwell-displacement-current-measuring technique)

  • 이경섭;전동규;권영수;국상훈
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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    • pp.120-123
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    • 1995
  • Maxwell-Displacement-Currnt-Measuring Technique(MDCM) is a simple system for displacement current measuring which consist with two electrodes to the electrometer, With this method, the displacement current flow only when the electric flux density change by the displacement of molecules or charge particles of membrance on the water surface. Thus, It is Possible to detect dynamic behavior of molecules of membrane without any electrical contact with molecule membrane. In this paper, We measure surface pressure, displacement current and dipole moment of phospholipid monolayers on the wafer surface with applied pressure by MDCM and We measured DTA(differential thermal analysis).

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모델 시스템을 이용한 생분해성 고분자의 분해거동 연구

  • 이원기;전상익;이진국
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2004년도 봄 학술발표회 발표논문집
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    • pp.401-402
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    • 2004
  • 생분해성 고분자 재료들은 지구환경 보호측면에서 다양한 분야, 즉, 1회용 재료, 농업용 필름 및 생체적합성 재료(약물 방출, 봉합사) 등에서 실용화되거나 활발한 연구가 진행되고 있다. 이들 재료의 상업적응용은 물성, 분해능, 제조가격, 대량생산 등에 의해 좌우 될 수 있다. 이들 중 특히, 분해 메커니즘의 규명은 본질적인 응용에서 가장 중요한 위치를 차지하고 있다. 분해 속도의 규명 및 조절은 제품의 수명을 제어할 수 있고 응용 분야를 넓힐 수 있다. 본 연구에서는 분해매채에 따른 생분해성 고분자의 분해 메커니즘 및 속도를 단결정과 단분자막 기법을 이용하여 연구하였다. 결정성영역에서는 분해매체의 크기가 작은 알칼리 이온에 의해 표면 및 측면 분해가 일어나고 크가가 큰 효소는 비규칙성을 가진 영역에서 선호적 분해가 일어남을 두 모델 시스템으로부터 확인하였다.

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PBLG와 PBDG단분자막의 전기특성에 관한 연구 (A Study on the Electrical Properties of PBLG and PBDG monolayers)

  • 김병근;조수영;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.92-94
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    • 2003
  • Recently, the study on development of electrical and electronic device is done to get miniature, high degrees of integration and efficiency by using inorganic materials, the study of Langmuir-Boldgett(LB) method that uses organic materials because of the limitation for the ultra small size. In this paper, detected displacement current using PBLG and PBDG, deposition and observed the electrical characteristics to each 1, 3, 5, 7, 9 layers by LB method. Maximum value of change ratio of displacement current by the detected speed and temperature appeared almost lineally, could confirm that it are in comparison relation each other speed-temperature and displacement current. The structure of manufactured device is MIM. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. The insulation property of a thin film is better as the distance between electrodes is larger.

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기능성 LB단분자막의 변위특성에 관한 연구 (A Study on the Displacement Properties of Functional LB Monolayers)

  • 송진원;최영일;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.114-116
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    • 2003
  • Monolayers of lipids on a water surface have attracted much interest as models of biological membranes, but also as precursors of multilayer systems promising many technical applications. Until now, many methodologies have been developed in order to gain a better understand. Photoisomerization in monolayers of a novel azobenzene compound, azobenzene dendrimer, was investigated for the first time by means of the absorption spectrum and Maxwell displacement current (MDC) technique. Dendrimers are well-defined macromolecules exhibiting a tree-like structure, first derived by the cascade molecule approach. According to the absorption spectrum, trans-to-cis conversion ratio was estimated to the third generation of azobenzene dendrimer deposited onto a glass substrate. Temperature-dependent induced charge with trans-cis isomerization was also measured by means of MDC technique.

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Kanamycin 및 Kanendomycin이 인공 stearic acid 단분자막에 미치는 영향 (Effects of Kanendomycin, Kanamycin on Stearic Acid Monolayer)

  • 이승일;강두희
    • The Korean Journal of Physiology
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    • 제9권2호
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    • pp.1-5
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    • 1975
  • It has been reported that kanamycin lowers osmotic fragility and mechanical fragility by ultrasonification of human red cells. In the present study, we therefore investigated effects of $Ca^{++}$, kanendomycin and kanamycin on stearic acid monolayer using a langmuir trough and found fellowing results 1) $Ca^{++}$ added to the subphase condensed stearic acid monolayer, confirming earlier reports. 2) Likewise, kanendomycin and kanamycin condensed the stearic acid monolayer, the effects being dose dependent. The possible modes of action of kanamycin and kanendomycin on biological membrane were discussed and compared with those of $Ca^{++}$ and local anesthetics

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아조벤젠이 기능화된 덴드리머 유기단분자막의 광학적 성질과 특성 (Characteristics and Optical Properties of the Azobenzene Functionlized Dendrimer in Organic Thin Monolayers)

  • 손정호;윤회찬;김정명;김병상;신훈규;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.182-185
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    • 2001
  • The functionlized dendrimer containing 48 azobenzene was synthesized. Many isolated featureless domains were explicitly observed even at the air-water interface. Also, these monolayers were representatively observed, showing the change of surface pressure with irradiation time and wavelength. In AFM images. the larger domains irregularly shaped structures on the top while the smaller ones were free from such defects. In the optical absorption spectra of the LB films by UV irradiation and heat treatment, only photoisomerization of the G4-48Az monolayers was observed, a decrease of absorbance peak without change of the spectral shape. This suggests that optical behavior and morphological change are affected by the functional group and the symmetric chain.

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변위전류법에 의한 지질단분자막의 전기특성에 관한 연구 (A study on the electrical properties of lipid monolayers by displacement current method)

  • 이경섭;권영수
    • E2M - 전기 전자와 첨단 소재
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    • 제9권5호
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    • pp.450-454
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    • 1996
  • Maxwell-Displacement-Current(MDC) measuring technique has been applied to the study of monolayers of Dilauroylphosphatidylcholine (L-.alpha.-DLPC) and Dimyristoylphosphatidylcholine (L-.alpha.-DMPC). The displacement current was generated from monolayers on a water surface by monolayer compression. Displacement current was generated when the area per molecule was about 250.angs.$^{2}$, 280.angs.$^{2}$. Displacement current was generated in the gas state, gas/liquid state, and liquid state in the course of monolayer compression. The orientational change of molecules in monolayers was discussed on the basis of the MDCs obtained. Finally, we measured differential thermal analysis of sample.

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STM을 이용한 Dipyridinium 유기 단분자막의 모폴로지 관찰 및 전기적 특성 연구 (Study on the Mophology Observation and Electrical Properties of Dipyridinium Organic Monolayer Using STM)

  • 이남석;신훈규;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제54권2호
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    • pp.51-54
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    • 2005
  • In this work, the attempt has been made to investigate the morphology of self-assembled dipyridinium dithioacetate on Au(111) substrate by Scanning Tunneling Microscopy(STM). Also, we measured electrical properties(I-V) using Scanning Tunneling Spectroscopy(STS). Sample used in this experiment is dipyridinium dithioacetate, which contains thiol functional group, this structure that can be self-assembled easily to Au(111) substrate. The self-assembly procedure was used for two different concentrations, 0.5 mM/ml and 1 mM/ml. Dilute density of sample by 0.5 mM/ml, 1 mM/ml and observed dipyridinium dithioacetate's image by STM after self-assembled on Au(111) substrate. The structure of STM tip-SAMs-Au(111) substrate has been used measurement for electrical properties(I-V) using STS. The current-voltage(I-V) measurement result, observed negative differential resistance(NDR) properties.

메로시아닌 색소 LB 단분자막의 광메모리 특성에 관한 정성적 연구 (A qualitative study of photomemory characteristics of the LB monolayer films of merocyanine dye)

  • 박태곤;권영수;강도열
    • 대한전기학회논문지
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    • 제44권7호
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    • pp.889-894
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    • 1995
  • The structural changes of the merocyanine monolayer LB (Langmuir Blodgett) films were investigated. These changes were compared with the typical changes of the molecular structures of merocyanine solutions. The structural changes of quinoid/benzenoid were attained by exposure to atmosphere gases (HCl gas, N $H_{3}$ gas). The photoisomerization was not observed for the monolayer LB film due to their state of $M_{trans}$. But we could obtain the cis/trans photoisomerization characteristics reversibly, after the films were changed to M $H^{+}$$_{trans}$ structure by exposure to HCl gas. We also found that the cis/trans photoisomerization of the LB monolayer films show the memory characteristics.s.

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