• Journal of Korean Society of Environmental Engineers
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• v.30 no.10
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• pp.984-991
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• 2008

This paper reports experimental results, demonstrating the feasibility of horseradish peroxidase(HRP) and H$_2$O$_2$ to reduce phenol transport in saturated porous media. A laboratory-scale packed column reactor(ID: 4.1 cm, sand-bed height 12 cm) column was utilized to simulate injection of HRP and H$_2$O$_2$ into an aquifer contaminated with phenol. Effluent concentrations of phenol and polymerization products were monitored before and after enzyme addition under various experimental conditions(enzyme dose: 0$\sim$2 AU/mL, [ionic strength]: 5$\sim$100 mM, pH: 5$\sim$9). The concentration of phenol in the column effluent was found to decrease by nearly 90% in the presence of HRP(2 AU/mL) and H$_2$O$_2$ in the continuous flow system at pH 7 and ionic strength 20 mM. The influent phenol was converted in the system to insoluble precipitate, which deposited in pore spaces. The remains were discharged as soluble oligomers. About 8% of total pore volume in column system was decreased by deposition of polymer produced.

• Journal of Korea Water Resources Association
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• v.31 no.4
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• pp.459-467
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• 1998

The existing methods to analyze the heterogeneous porous media based on the similar media concept are the microscopic Miller similitude(MiS), the macroscopic Miller similitude(MaS) and the Warrick similitude(WS). The inter-relationship is found such that MiS ⊂ MaS ⊂ (⊂:subset). The proposed method is based ont eh assumption that the scale variables $\alpha$=w and the moisture content is dimensionless by introducing the effective degree of saturation instead of the degree of saturation into WS. The method, without the loss of generality in view of the inspectional analysis, can explain the heterogeneity of the media by using the scale variable $\alpha$ only. The media of $\alpha$=1 (average of $\alpha$) means the equivalent media corresponding to the heterogeneous media, while the standard deviation of $\alpha$ may explain the degree of the heterogeneity of the media under consideration. The hydraulic conductivity of the media with $\alpha$>1 is greater than that of the equivalent media, and the effective moisture content of the media with $\alpha$>1 is also greater. Based on these properties of the scale variable $\alpha$, the ideal vertical one-dimensional heterogeneous porous media is generated by using the technique of random number generation.

• Proceedings of the Korea Water Resources Association Conference
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• 1993.07a
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• pp.183-190
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• 1993

• Journal of the Korean earth science society
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• v.32 no.6
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• pp.629-639
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• 2011

Based on Maxwell-Eucken(ME) model, which is one of structural models, a new model for predicting the effective thermal conductivity of variably saturated porous materials is proposed. The new model is a linear combination of three ME models having matrix, water, and air as a continuous phase. The coefficient of the corresponding linear equation is defined by a parameter referred to as 'the continuity coefficient', which provides a relative degree of continuity of each phase. The continuity coefficient of matrix is assumed to be linearly proportional to porosity. The model can be linear or nonlinear depending on how the continuity coefficients of water and air vary with water saturation. The feasibility of the proposed model was examined by both numerical and experimental results. Both linear and nonlinear models showed a high accuracy of prediction with $R^2$ values of 0.86-0.98 and 0.88-0.99, respectively. The numerical and experimental results also showed that the continuity coefficient of matrix was linearly proportional to porosity. Therefore, the proposed prediction model can be effectively used to estimate effective thermal conductivity of unsaturated porous materials by measuring porosity, water content and mineralogical compositions of matrix.

• Water for future
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• v.28 no.5
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• pp.129-140
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• 1995

In this study we derived steady-state relationships between surface saturation area and subsurface outflow, and between surface saturation area and soil moisture storage through numerical experiments with Richards equation on a hillslope. Numerical experiments analyzed the sensitivity of topographic and soil hydraulic properties on steady-state relationships between surface saturation area and subsurface outflow. And the power law for the extent of surface saturation area was determined as a function of subsurface outflow or soil moisture storage.

• Journal of the Korean GEO-environmental Society
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• v.4 no.3
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• pp.79-88
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• 2003

This paper presents a numerical study of the spatial behavior of a linear absorbing solute in a heterogeneous porous medium. The spatially correlated log-normal hydraulic conductivity field is generated in a given two-dimensional domain by using the geostatistical method (Turning Bands algorithm). The velocity vector field is calculated by applying the two-dimensional saturated groundwater flow equation to the Galerkin finite element method. The simulation of solute transport is carried out by using the random walk particle tracking model with CD(constant displacement) scheme in which the time interval is automatically adjusted. In this study, the spatial behavior of a solute is analyzed by the longitudinal center-of-mass displacement, longitudinal spatial spread moment and longitudinal plume skewness.

• Journal of Korean Society of Disaster and Security
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• v.10 no.1
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• pp.19-27
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• 2017

In recent years, ground subsidence has been frequently occurred by underground cavities due to the excessive groundwater inflow, caused by poor construction and management, during tunnel excavation and underground structure construction. In this study, a numerical model (SEEFLOW3D) was developed to estimate groundwater fluctuations for saturated-unsaturated poros media, evaluates the impact on ground excavation with open cut and non-open cut scenarios. In addition, the visual MODFLOW was applied to demonstrate the verification of the model compared with both results. Our results indicated that the RMSE and NRMSE was obtained to range over -3.95~5.7% and 0.56~4.62%, respectively. The developed model was expected to estimate groundwater discharges and apply analysis tool for optimum design of waterproof wall in future.

• Journal of the Korean Electrochemical Society
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• v.2 no.2
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• pp.98-105
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• 1999

In the present study, buoyant force and its stabilizing effects in an electrostatic field were examined systematically in order to reduce the effect of natural convection with thermal stratification in a horizontal fluid-saturated porous layer. The correlation of ionic mass transport induced by double-diffusive convection in a horizontal porous layer has been derived theoretically. And the theoretical model was examined by electrochemical experiments. The theoretical correlation for mass transport which is satisfying Forchheimer's flow equation and based on the micro-turbulence model is derived as a function of soltual Darcy-Rayleigh number, thermal Darcy-Rayleigh number and Lewis number. In the experiment, the mass transport of copper ions in $CuSO_4-H_2SO_4$ solution is measured by electrochemical technique. By assembling theoretical correlation and experimental results, the mass transport correlation induced by double-diffusive convection is proposed as $$Sh=\frac{0.03054(Rs_D-LeRa_D)^{1/2}}{1-3.8788(Rs_D-LeRa_D)^{-1/10}}$$ The present correlation looks flirty reasonable with comparing experimental results, and very promising for the applications of its prototype into various systems involving heat transfer as well as mass transfer, in order to control the effects of natural convection effectively.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.5
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• pp.1137-1143
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• 1994

Through the numerical analysis of the capillary pressure-based Richards equation with and without the effect of the capillary hysteresis under the boundary condition having an antecedent rainfall. the moving tendency of the wetting front, the redistribution of the moisture content, infiltration rate, cumulative infiltration etc, were computed. The effect of the capillary hysteresis cannot be neglected in analyzing an unsaturated flow, and the more accurate results may be obtained by the consideration of the hysteresis effect. If the effect of the hysteresis cannot be considered, the analysis by the use of the main wetting curve may give more reliable result than that of the main drying curve.

• Water for future
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• v.27 no.3
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• pp.107-113
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• 1994

The analysis of Richards eq. requires data of the soil water retention function and the unsaturated hydraulic conductivity. The soil water retention function was measured through the use of the developed apparatus and the saturated hydraulic conductivity was measured by the constant head method for each soil sample corresponding to the A, B, C types of SCS. In order to obtain one water retention function and one unsaturated hydraulic conductivity which represent each soil group, van Genuchten's eq. and Mualem's pore-structure model was chosen respectively. Parameters of van Genuchten's eq. are estimated for each soil group using data obtained in the experiments, and estimated values give a basis to analyze the unsaturated flow in the non-measured region efficiently.