• Title/Summary/Keyword: 다공성매질

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Derivation of the First-Order Mass-Transfer Equation for a Diffusion-Dominated Zone of a 2-D Pore (2차원으로 구현한 다공성 매질의 확산주도영역에 관한 1차 물질이동 방정식의 유도)

  • Kim, Young-Woo;Seo, Byong-Min;Hwang, Seung-Min;Park, Cha-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.99-103
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    • 2010
  • A new analytic solution was derived for the diffusion into or from an immobile zone of a rectangular 2-D pore. For a long time, the new solution converges to a traditional mobile-immobile zone (MIM) model, but only if the latter is used with an apparent initial concentration that is smaller by almost 20% than the true one. This is the tradeoff for using a simple MIM model instead of an exact model based on the diffusion equation. The mass-transfer coefficient was found to be constant for a sufficiently long time; it was proportional to the molecular diffusion and inversely proportional to the square of the pore depth. The mass-transfer coefficient was time-dependent for a sufficiently short time and may be significantly larger than its asymptotic value.

A Numerical Study on Spatial Behavior of Linear Absorbing Solute in Heterogeneous Porous Media (비균질 다공성 매질에서 선형 흡착 용질의 공간적 거동에 대한 수치적 연구)

  • Jeong, Woo Chang;Lee, Chi Hun;Song, Jai Woo
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.3
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    • pp.79-88
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    • 2003
  • This paper presents a numerical study of the spatial behavior of a linear absorbing solute in a heterogeneous porous medium. The spatially correlated log-normal hydraulic conductivity field is generated in a given two-dimensional domain by using the geostatistical method (Turning Bands algorithm). The velocity vector field is calculated by applying the two-dimensional saturated groundwater flow equation to the Galerkin finite element method. The simulation of solute transport is carried out by using the random walk particle tracking model with CD(constant displacement) scheme in which the time interval is automatically adjusted. In this study, the spatial behavior of a solute is analyzed by the longitudinal center-of-mass displacement, longitudinal spatial spread moment and longitudinal plume skewness.

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Development of 3-D Flow Model for Porous Media with Scenario-based Ground Excavation (지반굴착 시나리오 기반의 다공성 매질에 대한 3차원 유동해석모델 구축)

  • Cha, Jang-Hwan;Lee, Jae-Young;Kim, Woo-Seok
    • Journal of Korean Society of Disaster and Security
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    • v.10 no.1
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    • pp.19-27
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    • 2017
  • In recent years, ground subsidence has been frequently occurred by underground cavities due to the excessive groundwater inflow, caused by poor construction and management, during tunnel excavation and underground structure construction. In this study, a numerical model (SEEFLOW3D) was developed to estimate groundwater fluctuations for saturated-unsaturated poros media, evaluates the impact on ground excavation with open cut and non-open cut scenarios. In addition, the visual MODFLOW was applied to demonstrate the verification of the model compared with both results. Our results indicated that the RMSE and NRMSE was obtained to range over -3.95~5.7% and 0.56~4.62%, respectively. The developed model was expected to estimate groundwater discharges and apply analysis tool for optimum design of waterproof wall in future.

Estimation of Water Purification Ability with Applying Porous Concrete to Weir and Riverbed Materials (다공성 콘크리트의 보 및 하상재료 적용에 따른 하천 수질정화 능력 평가)

  • Choi, I-Song;Kim, Jin-Hong;Choi, Gye-Woon;Oh, Jong-Min
    • Journal of Korea Water Resources Association
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    • v.36 no.6
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    • pp.1013-1023
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    • 2003
  • This study was performed to improve water quality of stream by applying hydraulic structures (weir and river bed material) made of porous concrete. The physical and chemical characteristics of porous concrete were measured to estimate application possibility of it in hydraulic structures and it was considered as a proper material for the hydraulic structures. In the results of comparison for the component of matters attached on the hydraulic structures made of porous and ordinary concrete, DW (dry weight) amount attached on porous concrete was 1.6 times higher than that on ordinary concrete under the condition of the same flow rate but influence by flow rate (difference of 10 times) was not shown. Therefore, we could understand that the material of media was more important in DW amount than flow rate. The rate of AFDM (ash free dry mass) to DW also was more at porous concrete than at ordinary concrete. Especially, the high rates of nitrogen and phosphorous in matters attached on porous concrete verify that they were removed by assimilation, adsorption and metabolism of periphyton. The removal percentage of SS, BOD, COD, T-N and T-P by hydraulic structures applying porous concrete compared with ordinary concrete was increased by 34.6%, 36.9%, 33.9%, 18.3% and 21.6%, respectively. Therefore, applying porous concrete to hydraulic structure is expected to contribute to improvement of stream water quality.

Study on the Hindered Diffusion Within Disordered-Fibrous Membrane and Gels(I) (불규칙 섬유상(disordered-fibrous) 멤브레인이나 젤(gel)에서의 제한적 확산(hindered diffusion) 현상에 관한 연구(I))

  • 전명석;김재진
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.139-140
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    • 1997
  • 1. 서론 : 한외 및 정밀여과의 분리메카니즘에 연관된 물리적 현상에 대해 현재까지 진행된 많은 연구들은, 막기공이 갖는 복잡하고 불규칙한 구조를 단순하고 규칙적인 well-defined 구조인 실린더형이나 슬릿형 기공으로 가정하여 문제를 전개하고 있다. 본래, 다공성 매질(porous media)에서의 유체흐름을 다루는 이론 및 실험연구자들에 의해 제안된 섬유상 매질(fibrous media)에 대한 해석은 계의 미세구조(microstructure)에 추계적 개념을 적용시키려는 최근의 추세에 따라 점차 관심이 높아가고 있다.(생략)

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A New Structural Model for Predicting Effective Thermal Conductivity of Variably Saturated Porous Materials (포화도에 따른 다공성 매질의 유효열전도도 변화 예측 모델)

  • Cha, Jang-Hwan;Koo, Min-Ho;Keehm, Young-Seuk
    • Journal of the Korean earth science society
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    • v.32 no.6
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    • pp.629-639
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    • 2011
  • Based on Maxwell-Eucken(ME) model, which is one of structural models, a new model for predicting the effective thermal conductivity of variably saturated porous materials is proposed. The new model is a linear combination of three ME models having matrix, water, and air as a continuous phase. The coefficient of the corresponding linear equation is defined by a parameter referred to as 'the continuity coefficient', which provides a relative degree of continuity of each phase. The continuity coefficient of matrix is assumed to be linearly proportional to porosity. The model can be linear or nonlinear depending on how the continuity coefficients of water and air vary with water saturation. The feasibility of the proposed model was examined by both numerical and experimental results. Both linear and nonlinear models showed a high accuracy of prediction with $R^2$ values of 0.86-0.98 and 0.88-0.99, respectively. The numerical and experimental results also showed that the continuity coefficient of matrix was linearly proportional to porosity. Therefore, the proposed prediction model can be effectively used to estimate effective thermal conductivity of unsaturated porous materials by measuring porosity, water content and mineralogical compositions of matrix.

Flow Analysis of the Oxidizer Manifold for a Liquid Rocket Combustor using OpenFOAM (OpenFOAM을 이용한 액체 로켓 연소기의 산화제 매니폴드 내 유동 해석)

  • Joh, Mi-Ok;Han, Sang-Hoon;Kim, Seong-Ku;Choi, Hwan-Seok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.9
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    • pp.781-788
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    • 2012
  • Flow in the oxidizer manifold of a liquid rocket combustor has been analysed using an open source CFD toolbox, OpenFOAM. The applicability of OpenFOAM to the problems with complex geometries involving porous media zones for simulating the pressure drop induced by the injectors has been evaluated by performing turbulent, incompressible steady-state flow analysis. The usefulness and applicable area of the OpenFOAM as a design evaluation and analysis tool will be confirmed and enlarged by further evaluation with various computational cases representing major physical phenomena in rocket combustion devices.

Polydispersed Colloid Transport in Porous Media : An Experiment and Modeling (다공성 매질에서의 크기 분포를 갖는 콜로이드 이동 : 실험과 모델)

  • Park, Hee-Ju;Lee, Kon-Jae
    • Nuclear Engineering and Technology
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    • v.27 no.1
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    • pp.1-7
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    • 1995
  • The mechanism of radionuclide colloid transport in porous media was studied through modeling and experiment. A nondestructive column scanning system was developed to improve the traditional destructive core slicing method. With an aid of this system we could get much more results from one experiment. Neutron activated clay soaked with soluble isotopes was used as colloid suspension. Filtration coefficients obtained through the experiments show two families of colloids despite their size distribution. New modeling of polydispersed colloid transport was made with two lumped parameters. This new model simulates well. Among the soluble isotopes $^{l37}$Cs mowed mainly as a form of colloid, but $^{85}$ Sr did not.t.

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A Study about Effectiveness and Usefulness of a FEM Slug Test Model (유한 요소기법을 이용한 Slug시험 모델의 타당성 및 유용성 연구)

  • 한혜정;최종근
    • Journal of the Korean Society of Groundwater Environment
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    • v.7 no.2
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    • pp.89-96
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    • 2000
  • Slug tests are the most widely used field method for quantification of hydraulic conductivity of porous media. Well recovery is affected by well casing, borehole radii, screened length, hydraulic conductivity, and specific storage of porous media. In this study, a new slug tests model was developed through finite element approximation and the validity and usefulness of the model were tested in various ways. Water level fluctuation in a well under slug test and cons-equent groundwater flow in the surrounding porous medium were appropriately coupled through estimation of well-flux using an iteration technique. Numerical accuracy of the model was verified using the Cooper et al. (1967) solution. The model has advantages in simulations for monitored slug tests, partial penetration, and inclusion of storage factor. Volume coverage of slug tests is significantly affected by storage factor. Magnitude and speed of propagation of head changes from a well increases as storage factor becomes low. It will be beneficial to use type curves of monitored head transients in the surrounding porous formation for estimation of specific storage. As the vertical component of groundwater flow is enhanced, the influence of storage factor on well recovery decreases. For a radial-vertical flow around a partially penetrated well, deviations between hydraulic estimates by various methods and data selection of recovery curve are negligible on practical purposes, whereas the deviations are somewhat significant for a radial flow.

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전해환원 금속전환체 잔류염 제거 기초 실험

  • Park, Byeong-Heung;Jeong, Myeong-Su;Jo, Su-Haeng;Heo, Jin-Mok
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.06a
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    • pp.296-296
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    • 2009
  • 산화물 사용후핵연료를 대상으로 하는 파이로 공정은 고온 용융염 매질에서 산화물을 금속으로 전환시키는 전해환원 공정으로부터 시작된다. 이후, 전해정련 공정이 도입되어 전해환원 공정에서 금속으로 환원된 생성물을 처리하게 된다. 전기화학적 공정인 이 두 공정에는 전류전달 매질인 전해질로 용융염이 사용된다. 그러나 전해환원 공정은 LiCl 염을 기반으로 하는 반면 전해정련은 LiCl-KCl 공융염 조건에서 운전하여 두 공정의 연계성 향상 및 공정 안정성 확보를 위해서는 전해환원 공정에서 생성되는 금속전환체에 존재하는 잔류염을 제거하는 공정의 도입이 두 공정사이에 고려되고 있다. 전해환원 공정에서 산화물이 금속으로 환원되는 동안 고체입자의 외형이 유지되며 따라서 제거된 산소에 의해 금속전환체에는 공극이 발생하게 된다. 또한, 전해환원에 도입되는 산화물의 물리적 형태가 분말 또는 펠렛 등 다양한 형태로 도입 가능하여 단위 입자들 사이에 많은 공극이 발생하게 된다. 이렇게 기존재하거나 또는 공정 운전에 의해 새롭게 생성된 공극에는 전해환원 매질인 LiCl 염이 침투하여 금속전환체는 염에 의해 젖게 되며 공정 종료시 고화되어 금속전환체에 포함된다. LiCl을 제거하기 위해서는 가열에 의한 증류가 연구되고 있다. 그러나 LiCl의 낮은 증기압에 의해 비교적 낮은 온도에서 증발시키기 위해서는 감압조건이 필수적으로 고려되어야 한다. 한국원자력연구원에서는 다공성 모의 금속전환체를 사용하여 LiCl에 의한 Wetting 후 적절한 증발 조건 결정을 목적으로 온도 및 압력 조건 설정을 위한 기초실험에 결과를 수행하였다. 본 연구의 기초 실험 결과 $700^{\circ}C$온도 조건과 감압조건이 잔류염 제거를 위한 공정조건임을 밝혔다. 또한 모의 금속전환체를 담고 있는 미세 다공성 Basket은 고온조건에서 공극의 변형에 의해 증발에 대한 저항으로 작용하여 증발 효율을 저하시키는 것으로 나타났다. 따라서 잔류염 제거를 위해서는 전해환원 Basket이 비교적 큰 공극을 지녀야 할 것으로 판단된다.

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