• Title/Summary/Keyword: 다공물질

Search Result 417, Processing Time 0.031 seconds

The Effect of Ecklonia cava Extracts on Bone Turnover Markers in Ovariectomized Rats (갱년기 유도 흰쥐에서 감태 추출물이 골 대사 지표물질의 변화에 미치는 영향)

  • Kang, Sung-Rim;Kim, Mi-Hyang
    • Journal of Life Science
    • /
    • v.19 no.12
    • /
    • pp.1841-1846
    • /
    • 2009
  • Menopause is often associated with the incidence of several chronic diseases including osteoporosis, cardiovascular disease, and obesity. Hormone replacement therapy (HRT) is an effective regimen that has been found to prevent these diseases in postmenopausal women. However, HRT is accompanied by an increased risk of unfavorable outcomes. Therefore, this study was conducted to evaluate the effects of Ecklonia cava, a kind of seaweed, extract on bone turnover markers in symptomatic menopausal women. For this study, the following four groups of 9-week-old Sprague-Dawley rats were evaluated over 6 weeks: normal rats (SHAM), ovariectomized rats (OVX-CON) and ovariectomized rats that were treated with Ecklonia cava extracts. The optimum extraction temperature and solvent of Ecklonia cava were found to be $80^{\circ}C$ and 80% ethanol. We measured the osteocalcin and CTx content, enzyme ALP activity in serum and collagen content in the cartilage, bone, skin and lungs. We found that the levels of indicators of bone metabolism such as ALP, osteocalcin and CTx were lower in rats in the Ecklonia cava extract group than the OVX-CON group. In addition, the collagen contents in the bone, cartilage, skin and lungs decreased in response to ovariectomy, but the levels of collagen were greater in the bone of rats that were treated with Ecklonia cava extract than in the bone of rats in the OVX-CON group. According to these results, we were able to know the effects of Ecklonia cava extract on bone aging in ovariectomized rats. Consequently, we expect Ecklonia cava extract to have an effect on bone aging in postmenopausal women.

Condensable Gas Separation using Phenol! Alumina Composite Activated Carbon Hollow Fiber Membranes (페놀수지/알루미나 복합 활성탄소중공사막을 이용한 응축성 기체 분리)

  • Shin, Kyung-Yong;Park, You-In;Kim, Beom-Sik;Koo, Kee-Kahb
    • Membrane Journal
    • /
    • v.20 no.4
    • /
    • pp.312-319
    • /
    • 2010
  • Carbon membrane materials have received considerable attention for the gas separation including hydrocarbon mixture of ingredients of the volatile organic compounds(VOCs) because they possess their higher selectivity, permeability, and thermal stability than the polymeric membranes. The use of activated carbon membranes makes it possible to separate continuously the VOCs mixture by the selective adsorption-diffusion mechanism which the condensable components are preferentially adsorbed in to the micropores of the membrane. The activated carbon hollow fiber membranes with uniform adsorptive micropores on the wall of open pores and the surface of the membranes have been fabricated by the carbonization of a thin film of phenolic resin deposited on porous alumina hollow fiber membrane. Oxidation, carbonization, and activation processing variables were controlled under different conditions in order to improve the separation characteristics of the activated carbon membrane. Properties of activated carbon hollow fiber membranes and the characterization of a gas permeation by pyrolysis conditions were studied. As the result, the activated carbon hollow fiber membranes with good separation capabilities by the molecular size mechanism as well as selective adsorption on the pores surface followed by surface diffusion effective in the recovery hydrocarbons have been obtained. Therefore, these activated carbon membranes prepared in this study are shown as promising candidate membrane for separation of VOCs.

Characteristics of Biocellulose by Gluconobacter uchimurae GYS15 (Gluconobacter uchimurae GYS15 균주로부터 생산되는 Biocellulose의 특성 확인)

  • Lee, Young Sun;Kim, Jae Young;Cha, Mi Yeon;Kang, Hee Cheol
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.42 no.3
    • /
    • pp.247-255
    • /
    • 2016
  • In order to select a strain that forms a Biocellulose (BC), strain producing acetic acid was selected from commercially available kombucha. Through SM broth it was confirmed that the strain is a gram negative bacteria in the form of rods having no motility through a phase contrast microscope. The result of phylogenetic inference analysis based on 16S rDNA sequence analysis for the identification of strains was most closely related to Gluconobacter uchimurae (G. uchimurae) and was named G. uchimurae GYS15 strain. The strain showed the highest degree of growth when cultured for 14 days under the conditions of pH 5 and $25^{\circ}C$. Moreover, it showed the highest degree of growth in a Glucose addition disaccharide as the optimum carbon source sucrose and fructose. Also, 0.5% NaCl, upon the addition of Malto extract, showed the highest degree of growth. Based on investigation by the optimum growth conditions to confirm the physical properties of BC obtained by culturing G. uchimurae GYS15 strains. The surface structure was observed through an scanning electron microscope (SEM) showed a high networks structure. It until $8.6{\pm}0.38$ times when the water holding capacity is re-absorbed and re-absorbed holding oil up to $6.6{\pm}0.51$ times confirmed. In conclusion, using these material properties, it was possible to confirm the possibility of a variety of cosmetic materials and mask pack materials.

The Microstructure Control of SiC Ceramics Containing Porcelain Scherben (자기파를 함유한 SiCwlf 세라믹스의 미세구조 제어)

  • 이성희
    • Journal of the Korean Ceramic Society
    • /
    • v.32 no.5
    • /
    • pp.626-634
    • /
    • 1995
  • The SiC-porcelain powder mixtures containing 51.9wt% SiC are produced as by-products from the surface abrasion process of porcelain cores. This raw powders were used as starting materials for the synthesis of SiC containing ceramics. The specimen, which was fired at 135$0^{\circ}C$ from raw powders, had SiC, $Al_{2}O_{3}$, , cristobalite, mullite as crystalline phases, and the fractured microstructure showed dispersed SiC crystalline particles almost wetted with glassy matrix and spherical pores. Although the oxidation of SiC containing powder compacts wetted with glassy matrix and spherical pores. Although the oxidation of SiC containing powder compacts started at the range of 600~80$0^{\circ}C$ form the analysis of weight gain, the presence of $SiO_{2}$ crystallien phase and cristobalite was confirmed at 100$0^{\circ}C$ by XRD analysis. Mullitization of specimens was accelerated by preheating before the final firing. The specimen sintered at 135$0^{\circ}C$ after 100$0^{\circ}C$ preheating consisted of SiC, cristobalite, mullite as crystalline phases, and revealed 2.24g/$cm^{3}$ bulk density, 11.73% water adsorption, porous microstructure with small amount of glassy phase. SiC contents of specimens, which was 51.9 wt% in the raw powders, reduced to 37~22 wt% after firing at 135$0^{\circ}C$ depending on the preheating condition.

  • PDF

Reservoir Modeling for Carbon Dioxide Sequestration and Enhanced Oil Recovery (이산화탄소 지중저장과 원유 회수증진 공정을 위한 저류층 모델링)

  • Kim, Seung-Hyok;Lee, Jong-Min;Yoon, En-Sup
    • Journal of the Korean Institute of Gas
    • /
    • v.16 no.3
    • /
    • pp.35-41
    • /
    • 2012
  • Manifold researches for carbon capture and storage (CCS) have been developed and large scale-carbon capture system can be performed recently. Hence, the technologies for $CO_2$ sequestration or storage become necessary to handle the captured $CO_2$. Among them, enhanced oil recovery using $CO_2$ can be a solution since it guarantees both oil recovery and $CO_2$ sequestration. In this study, the miscible flow of oil and $CO_2$ in porous media is modeled to analyze the effect of enhanced oil recovery and $CO_2$ sequestration. Based on Darcy-Muskat law, the equation is modified to consider miscibility of oil and $CO_2$ and the change of viscosity. Finite volume method is used for numerical modeling. As results, the pressure and oil saturation changes with time can be predicted when oil, water, and $CO_2$ are injected, respectively, and $CO_2$ injection is more efficient than water injection for oil recovery.

단일벽 탄소나노튜브의 직경 분포에 미치는 합성 템플레이트 및 공정변수의 영향

  • Gwak, Eun-Hye;Yun, Gyeong-Byeong;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.250-250
    • /
    • 2013
  • 단일벽 탄소나노튜브(Single-walled nanotubes, SWNTs)는 나노스케일의 크기와 우수한 물성으로 인하여, 전자, 에너지, 바이오 분야로의 응용이 기대되고 있다. 특히 SWNTs의 직경을 제어하게 되면 튜브의 전도성 제어가 훨씬 수월하게 되어, 차세대 나노전자소자의 실현을 앞당길 수 있으며 이러한 이유로 많은 연구들이 현재 행해지고 있다. SWNTs의 직경제어 합성을 위해서는 현재 열화학기상증착법(Thermal chemical vapor deposition; TCVD)이 가장 일반적으로 이용되고 있으며, 합성 촉매와 합성되는 튜브의 직경과의 크기 연관성이 알려진 후로는, 촉매의 크기를 제어하여 SWNTs의 직경을 제어하고자 하는 연구들이 활발하게 보고되고 있다. 특히, 촉매 나노입자의 직경이 1~2 nm 이하로 감소될 경우, SWNTs의 직경 분포가 어떻게 변화할 것인지가 최근 가장 중요한 관심사로 남아 있으나, 이러한 크기의 금속입자는 나노입자의 융점저하 현상이 발현되는 영역이므로, SWNTs의 합성온도 영역에서 촉매 금속입자는 반액체(Semi-liquid) 상태로 존재할 것으로 추측하고 있다. 본 연구에서는 고온의 SWNTs 합성환경에서 금속나노촉매의 유동성을 제한하기 위하여 나노사이즈의 기공이 규칙적으로 정렬된 다공성 물질인 제올라이트를 촉매담지체로 이용하였고, 이 때 다양한 합성변수가 SWNTs의 직경에 미치는 영향을 살펴보고자 하였다. SWNTs의 합성을 위해 실리콘 산화막 기판 위에 제올라이트를 도포한 후, 합성 촉매로서 전자빔증발법을 통하여 수 ${\AA}$에서 수 nm 두께의 철 박막을 증착하였다. 합성은 메탄을 원료가스로 하여 TCVD법으로 실시하였다. 주요변수로는 제올라이트 종류, 증착하는 철 박막의 두께, 합성온도를 설정하였으며, 이에 따라 합성된 SWNTs의 합성수율 및 직경분포의 변화를 체계적으로 살펴보았다. SWNTs의 전체적인 합성수율의 변화는 SEM 관찰결과를 이용하였으며, SWNTs의 직경은 AFM 관찰 및 Raman 스펙트럼의 분석에서 도출하였다. 실험결과, 제올라이트 종류에 따라서는 명확한 튜브직경 분포의 변화 없이 비교적 좁은 직경분포를 갖는 SWNTs가 합성되었으며, 합성온도가 $850^{\circ}C$ 이하로 감소되면 합성수율이 현저히 감소되는 것을 알 수 있었다. 촉매박막의 두께가 1 nm 이상인 경우에서는 직경 5 nm 전후의 나노입자가 형성되었으며, 이때 SWNTs의 합성수율은 높았으나 다양한 직경의 튜브가 합성이 된 것을 확인할 수 있었다. 반면, 촉매입자의 크기가 2 nm 이하에서는 합성수율은 다소 저하되었으나, SWNTs의 직경분포의 폭이 상대적으로 훨씬 좁아지는 것을 알 수 있었다. 추후, 극미세 촉매와 저온합성 환경에서의 합성수율 향상을 위한 합성공정의 개량이 지속적으로 요구된다.

  • PDF

Effect of Irrigation Frequency on Growth of Tomato Plug Seedlings in Media Containing Cellular Glass Foam and Peatmoss (Cellular Glass Foam과 Peatmoss를 함유한 혼합배지에서 관수빈도가 토마토 플러그묘의 생육에 미치는 영향)

  • 박정호;정병룡
    • Journal of Bio-Environment Control
    • /
    • v.12 no.1
    • /
    • pp.7-11
    • /
    • 2003
  • Cellular glass foam (CGF), the reprocessed glass, has a possibility to be used as a medium component in plug culture of horticultural crops due to the its excellent air and water permeability as comparable to perlite. An experiment was conducted to investigate growth of plug seedlings of Lycopersicum esculentum 'Segye' as influenced by irrigation frequency in various medium combinations of CGF (2.0-4.0 mm particle size) and peatmoss. Seeds were sown in 200-cell plug trays, filled with mixtures of CGF and peatmoss either at 33:67 or 25:75 (%. v/v) and were germinated on a fogged propagation bed. The irrigation frequencies used were one, two or three times per every two days. A commercial plug medium (Tosilee medium) was used as the control, and the irrigation frequency in the control was one time per day. Growth of seedlings, and medium pH and EC were measured at 33 days after sowing. The medium composition had little influence on overall growth of seedlings. Irrigation frequency very significant affected number of leaves, leaf area, chlorophyll concentration, fresh and dry weights of shoots and roots, and dry matter. Growth of seedlings was the greatest with the highest irrigation frequency in the 25% CGF+75% peatmoss mixture.

Analysis of a Gas Mask Using CFD Simulation (CFD모사기법을 이용한 가스 여과기 성능 해석)

  • Jeon, Rakyoung;Kwon, Kihyun;Yoon, Soonmin;Park, Myungkyu;Lee, Changha;Oh, Min
    • Korean Chemical Engineering Research
    • /
    • v.57 no.4
    • /
    • pp.475-483
    • /
    • 2019
  • Special chemical warfare agents are lethal gases that attack the human respiratory system. One of such gases are blood agents that react with the irons present in the electron transfer system of the human body. This reaction stops internal respiration and eventually causes death. The molecular sizes of these agents are smaller than the pores of an activated carbon, making chemical adsorption the only alternative method for removing them. In this study, we carried out a Computational Fluid Dynamics simulation by passing a blood agent: cyanogen chloride gas through an SG-1 gas mask canister developed by SG Safety Corporation. The adsorption bed consisted of a Silver-Zinc-Molybdenum-Triethylenediamine activated carbon impregnated with copper, silver, zinc and molybdenum ions. The kinetic analysis of the chemical adsorption was performed in accordance with the test procedure for the gas mask canister and was validated by the kinetic data obtained from experimental results. We predicted the dynamic behaviors of the main variables such as the pressure drop inside the canister and the amount of gas adsorbed by chemisorption. By using a granular packed bed instead of the Ergun equation that is used to model porous materials in Computational Fluid Dynamics, applicable results of the activated carbon were obtained. Dynamic simulations and flow analyses of the chemical adsorption with varying gas flow rates were also executed.

High Performance Separator at High-Temperature for Lithium-ion Batteries (고온 싸이클 성능이 우수한 리튬 이차전지 분리막)

  • Yoo, Seungmin
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.22 no.2
    • /
    • pp.789-793
    • /
    • 2021
  • A lithium secondary battery is the most promising candidate for future energy storage devices. On the other hand, the battery capacity decreases gradually due to the small amount of water and decomposition of the salts during the charging and discharging process, which deteriorates at high temperatures. Many researchers focused on increasing the cycling performance, but there have been few studies on the fundamental problem that removes water and HF molecules. In this study, silane molecules that are capable of absorbing water and HF molecules are introduced to the separator. Firstly, silica-coated amino-silane (APTES, 3-aminopropyltriethoxysilane) was synthesized, then the silica reacted with epoxy-silane, GPTMS ((3-glycidyloxypropyl)trimethoxysilane). A ceramic-coated separator was fabricated using the silane-coated silica, which is coated on porous polyethylene substrates. FT-IR spectroscopy and TEM analysis were performed to examine the chemical composition and the shape of the silane-coated silica. SEM was performed to confirm the ceramic layers. LMO half cells were fabricated to evaluate the cycling performance at 60 ℃. The cells equipped with a GPTMS-silica separator showed stable cycling performance, suggesting that it would be a solution for improving the cycling performance of the Li-ion batteries at high temperatures.

Evaluation of NOx Reduction Performance by Photocatalytic (TiO2) Coating of Cement Mortar Mixed with Zeolite and Activate Hwangtoh (제올라이트와 활성 황토를 혼입한 시멘트 모르타르의 광촉매(TiO2) 코팅에 따른 NOx 저감성능평가)

  • Park, Jang-Hyun;Kim, Hyeok-Jung
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.8 no.4
    • /
    • pp.483-489
    • /
    • 2020
  • Particulate matter is divided into PM10 (particle diameter of 10 ㎛ or less) and PM2.5 (particle diameter of 2.5 ㎛ or less), which are approximately 1/5 of the thickness of the hair. Due to its effect on the human body, lung disease, arteriosclerosis and heart It is known as a carcinogen that causes various diseases such as diseases. It is known that the main cause of such fine dust is nitrogen dioxide (NOx), which is emitted from automobiles in about 57.3% of urban roadsides. Therefore, in this study, as part of the development of functional construction materials to reduce NOx generated from road transport pollutants, comparative evaluation of NOx reduction performance was conducted according to the replacement rate of cement mortar in which cement was replaced with a porous material. In addition, the NOx reduction performance of cement mortar according to the photocatalyst application method and the number of applications was compared an d evaluated. As a result of the experiment, when activated ocher was substituted by 30%, it showed a reduction effect of about 32.7%, showing the best reduction performance.