• Journal of the Korean Chemical Society
• /
• v.33 no.2
• /
• pp.208-214
• /
• 1989

A method for the simultaneous determination of copper and cobalt by spectrophotometry has been described. The procedure involves the co-extraction of Cu(Ⅱ) and Co(Ⅱ) from 0.3M HCl into methyl isobutyl ketone as the ion-pairs formed between their thiocyanate complexes and high molecular alkylamines such as Amberlite LA1, Alamine 336, and Aliquat 336. The extract shows the color development to have the maximum absorbances at two different wavelengths i.e., 480 nm for copper and 625 nm for cobalt. Since the spectra of the ion-pairs overlap each other, two simultaneous equations are used to obtain the concentrations from absorbances. Even small amount of Fe(Ⅲ) and Ni(Ⅱ) interferes with the determination of copper. The results of the analysis of samples are in good agreement with the results determined by separate methods within RSD 5.9%.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.14 no.2
• /
• pp.317-324
• /
• 1994

The circulation of Lake Paldang is analysed numerically as an ultimate goal to develop a vehicle predicting the dispersion and concentration of pollutants and sediment flowed into the lake. In finite difference formulation of 2-D depth averaged governing equations. Abbott's 3-time level scheme is employed and for nonlinear terms time centering iteration technique in time and space is used. Model parameters for shear stresses and eddy diffusivities are determined through measured data in and near the lake. Predicted velocities for steady flow are shown to be close to the measured velocities and further improved by taking into account of wind effect. This indicates that the wind effect is needed for proper circulation analysis and it calls for the inclusion of the wind effect. Simulated results of unsteady flow caused by flood inflows and release through Paldang dam are found to characterize the flow features quite well as expected. This implies that the developed model can be used as a tool to analysing the circulation in the lake.

• Journal of the Institute of Electronics Engineers of Korea SD
• /
• v.45 no.11
• /
• pp.1-7
• /
• 2008

In this work, a two dimensional, self-consistent Poisson-$Schr{\ddot{o}}dinger$ solver has been implemented to study C-V characteristics in nanometer scale MuGFETs with considering quantum effects. The quantum-mechanical effects on gate-channel capacitance for different device dimension and gate configurations of nanometer scale MuGFETs have been analyzed. It has been found that 4he gate-channel capacitance per unit gate area is increased as the device dimension decreases. For different gate configurations, the gate-channel capacitance is decreased with increase of effective gate number. Those resu1ts have been explained by the distribution profile of electron concentration in the silicon surface and inversion capacitance. The length of inversion-layer centroid has been calculated from inversion capacitance with device dimension and gate configurations.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.4 no.1
• /
• pp.79-92
• /
• 1984

The analysis of total load was carried out by using the theory of unit stseam power (USP). The dimensionless USP equation of $S_R$ which was the rate of suspended load and bed load was derived from the USP function by applying the Einstein's reference concentration and Stokes' fall velocity. And the R relationship between the water discharge and Reynolds number (Re) was discussed, and it was shown that USP was closely related with Re. The value of $S_R$ was determined from the experimental data of Han River downstream and Mantz. And it was tested to several observatories of Korean Rivers. A good correlation among USP, suspended load and $S_R$ was shown and USP was increased with the increment of the turbulent intensity. Judging from the above results, it is considered this study can be contributed to estimate the total load.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.37 no.4
• /
• pp.405-413
• /
• 2013

The char oxidation characteristics of high ash coal were experimentally investigated at several temperatures (from 900 to $1300^{\circ}C$) for 4 types of coals (Gunvor, Glencore, Noble, and ECM) under atmospheric pressure in a drop tube furnace (DTF). The char reaction rate was calculated from the exhaust gas concentrations (CO and $CO_2$) using FT-IR, and the particle temperature was measured using the two-color method. In addition, the activation energy and pre-exponential factor for high ash coal char were calculated based on the Arrhenius equation. The results show that as the ash content increases, the particle temperature and area reactivity decreases. This is because in high ash coal, the large heat capacity of the ash, ash vaporization, and relatively low fixed carbon content of ash suppress combustibility during char oxidation. As a result, the higher ash content of coal leads to high activation energy.

• Analytical Science and Technology
• /
• v.24 no.6
• /
• pp.467-476
• /
• 2011

Solubility data of carbon dioxide ($CO_2$) in the imidazolium-based ionic liquids with methylsulfate anion are presented at pressures up to about 45 MPa and at temperatures between 303.15 K and 343.15 K. The ionic liquids studied in this work were 1-ethyl-3-methylimidazolium methylsulfate ([emim][$mSO_4$]), 1-butyl-3-methylimidazolium methylsulfate ([bmim][$mSO_4$]). The solubilities of $CO_2$ were determined by measuring the bubble point or cloud point pressures of the binary mixtures using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. The equilibrium pressure increased very steeply at high $CO_2$ compositions. The $CO_2$ solubility in ionic liquids increased with increase of the total length of alkyl chains attached to the imidazolium cation of the ionic liquids. The phase equilibrium data for the $CO_2$ + ionic liquid systems have been correlated using the Peng-Robinson equation of state.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2011.10a
• /
• pp.41.1-41.1
• /
• 2011

본 연구에서는 MOCVD법으로 사파이어 기판위에 u-GaN를 성장한 후 Mg을 도핑시켜 p-GaN를 성장하고, RF 스퍼터를 이용하여 n-ZnO를 도포하여 n-ZnO/p-GaN 이종접합을 형성한 후 진공증착기를 이용하여 Au/Ni를 증착시켜 발광다이오드(LED)를 제작하고 전기 광학적 특성을 조사하였다. 두께가 500 nm인 u-GaN 위에 성장된 p-GaN의 운반자 농도는 $1.68{\times}10^{17}\;cm^{-3}$ 이었다. 그리고 150, 300 nm 두께의 p-GaN에 대하여 측정된 DXRD 반치폭은 각각 450 arcsec, 396 arcsec 이었고, 상온에서 2.8~3.0 eV 영역에서 Mg 억셉터와 관련된 광루미네센스가 검출되었다. RF 스퍼터링에 의해 0.7 nm/min의 속도로 증착된 n-ZnO 박막은 증착 두께에 따라 비저항이 27.7 $m{\Omega}{\cdot}cm$ 에서 6.85 $m{\Omega}{\cdot}cm$ 까지 감소하였다. 그리고 n-ZnO 박막은 (0002)면으로 우선 배향되었으며, 상온에서 에너지갭 관련된 광루미네센스가 3.25 eV 부근에서 주되게 검출되었다. n-ZnO/p-GaN 이종접합 LED의 전류전압 특성곡선은 다이오드 방정식에 만족하는 특성을 나타내었다. 다이오드 지수는 3 V 이하 영역에서 1.64, 3~5 V 영역에서 0.85이었다. 그리고 5 V 이상 영역에서 공간전하의 제한을 받았으며, 다이오드 지수는 3.36이었다. 한편, 역방향 전류전압 특성은 p-GaN 박막의 두께에 영향을 받았으며, p-GaN 박막의 두께가 150, 300 nm 일 때 각각의 누설 전류는 $1.3{\times}10^{-3}$ mA와 $8.6{\times}10^{-5}$ mA 이었다. 상온에서 측정된 EL 스펙트럼의 주된 발광피크는 430 nm이었고, 반치폭은 49.5 nm이었다.

• Fire Science and Engineering
• /
• v.13 no.4
• /
• pp.20-29
• /
• 1999

This paper describes the smoke filling process of a fire field model based on a self-developed SMEP(Smoke Movement Estimating Program) code to the simulation of fire induced flows in the two types of atrium space containing a ceiling heat flux. The SMEP using PISO algorithm solves conservation equations for mass, momentum, energy and species, together with those for the modified k- epsilon turbulence model with buoyancy term. Compressibility is assumed and the perfect gas law is used. The results of the calculated upper-layer average temperature and smoke layer interface height has shown reasonable agreement compared with the zone models. The zone models used are the CFAST developed at the Building and Fire Research Laboratory NIST U.S.A. and the NBTC one-room of FIRECALC developed at CSIRO, Australia. The smoke layer interface heights that are important in fire safety were not as sensitive as the smoke layer temperature to the nature of ceiling heat flux condition.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.19 no.6
• /
• pp.1399-1404
• /
• 2015

This paper analyzed the phenomenon of drain induced barrier lowering(DIBL) for the ratio of channel length vs. thickness of asymmetric double gate(DG) MOSFET. DIBL, the important secondary effect, is occurred for short channel MOSFET in which drain voltage influences on potential barrier height of source, and significantly affects on transistor characteristics such as threshold voltage movement. The series potential distribution is derived from Poisson's equation to analyze DIBL, and threshold voltage is defined by top gate voltage of asymmetric DGMOSFET in case the off current is 10^-7 A/m. Since asymmetric DGMOSFET has the advantage that channel length and channel thickness can significantly minimize, and short channel effects reduce, DIBL is investigated for the ratio of channel length vs. thickness in this study. As a results, DIBL is greatly influenced by the ratio of channel length vs. thickness. We also know DIBL is greatly changed for bottom gate voltage, top/bottom gate oxide thickness and channel doping concentration.

• Journal of the Korean Institute of Gas
• /
• v.18 no.3
• /
• pp.1-12
• /
• 2014

In this paper, we developed an explosion proof type and portable combustible gas leak detector and proposed an algorithm to improve the accuracy for measuring gaseous concentrations. The nation's first we developed an infrared gas leak detector with explosion proof standard(Ex d ib) and improved measuring accuracy by using linearization recursion equation and 2nd Lagrange interpolation polynomial. Together, we advanced their performances and added their easy functions after investigating field demands. To compare our and other company's detectors, we performed measurement tests with eight standard gases made by Korea Gas Safety Corporation. We demonstrated the excellence of our instruments in measuring accuracy other than detecters through experimental results.