• Title/Summary/Keyword: 내부개질

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Convergent Study on the Hydro-Gas Reforming Cyclo-Incinerator (물 가스 개질 고속선회 소각로에 관한 융합연구)

  • Han, Doo-Hee
    • Journal of the Korea Convergence Society
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    • v.11 no.10
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    • pp.231-236
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    • 2020
  • A water reforming reaction high-speed turning incinerator test facility was prepared. The reforming reaction chamber and the combustion chamber were directly connected. The incinerator and dust collecting device were integrated and made into a double bulkhead type air cooling structure. The blower is built into the dust collector to improve spatial efficiency. An axial flow type multi-stage dust collector was applied by collecting dust by using a plurality of dust collecting bins attached to the side of the dust collecting part. As a result of measuring dioxin among the exhausted gases, results below the standard value were obtained. As a result of measuring exhaust gas and heavy metals, results were obtained below the environmental standard.

Reactive Dispersion and Mechanical Property of Dicyanate/Montmorillonite Nanocomposite (반응이 수반된 Dicyanate/Montmorillonite Nanocomposite의 분산과 물성특성 연구)

  • 장원영;이근제;남재도
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.75-83
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    • 2003
  • Dicyanate-clay nanocomposite has been prepared by a melt in-situ polymerization method for different modifiers and cation exchange capacity (CEC) values in order to study dispersion and mechanical property. Various dicyanate nanocomposites were prepared by using different MMT systems containing different intercalants which led to different initial gallery heights and packing density. Depending on compatibility between dicyanate and clays, the degree of dispersion varied. Dispersion of clay plates in dicyanate resin depended mainly on CEC and aliphatic chain length of modifier. The lower CEC and shorter aliphatic chain length of modifier gave the exfoliation structure. It was also found that the reactivity of intercalant with dicyanate resin was one of the key factors facilitating the intercalation/exfoliation process of dicyanate/MMT nanocomposites. Shear modulus of reaction-induced dicyanate nanocomposite was significantly increased.

A Study on the Effects of Ultrasonic forced to a Twin-Fluid Spray (2유체 분무에 가진된 초음파 영향에 관한 연구)

  • 나우정;주은선;정진도;송민근;이경열
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2002.02a
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    • pp.98-103
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    • 2002
  • 초음파 비가진 시인 상용분무와 초음파가진 시인 개질분무, 간접진동분무, 간접진동 및 개질의 겸용분무의 네가지 경우 모두에서 분무액적의 평균직경 및 SMD가 전 영역에 걸쳐서 노즐 글에서 분무방향으로 멀어질수록 조금씩 증가했으며, 또한 초음파 비 가진시인 상용분무 경우가 초음파 가진 세경우에 비해 크게 나타났다. 초음파 가진 세가지 경우에서는 간접진동 및 개질법 겸용의 경우에서 분무액적의 미세화가 가장 우세하게 나타났다. 이는 초음파가 분무 축방향 전영역에 걸쳐서 분무액적의 미세화에 친화적임을 입증한다. 나. 분무 방향 축에서 반경 방향으로 갈수록 분무 액적의 평균 직경과 SMD는 감소하고 있으며, 반경방향 전 영역에 걸쳐서 상용 분무시의 액적이 가장 크게, 초음파겸용 경우에서 가장 작게 나타나고 있다. 이는 초음파가 분무 내부 전 영역에 걸쳐 액적의 미세화에 친화적임을 증명한다. 다. 분무액적의 크기에 따른 분무 분포도 비교에서 네가지 경우 모두에서 축 방향 거리가 멀수록 분무액적의 크기가 다소 증가함을 보였고, 축에서 반경 방향으로는 분무액적의 크기가 다소 감소함을 보이고 있다. 상용 분무와 초음파 분무의 비교에서 초음파 겸용 가진시는 상용 분무 때 보다 분무 영역 전반에 걸쳐서 미세화가 뚜렷이 우세함을 보였다.

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Characteristic of Partial Oxidation of Methane and Ni Catalyst Reforming using GlidArc Plasma (GlidArc 플라즈마를 이용한 메탄 부분산화 및 Ni 촉매 개질 특성)

  • Kim, Seong-Cheon;Chun, Young-Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1268-1272
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    • 2008
  • Low temperature plasma applied with partial oxidation is a technique to produce synthesis gas from methane. Low temperature plasma reformer has superior miniaturization and start-up characteristics to reformers using steam reforming or CO$_2$ reforming. In this research, a low temperature plasma reformer using GlidArc discharge was proposed. Reforming characteristics for each of the following variables were studied: gas components ratio (O$_2$/CH$_4$), the amount of steam, comparison of reaction on nickle and iron catalysts and the amount of CO$_2$. The optimum conditions for hydrogen production from methane was found. The maximum Hydrogen concentration of 41.1% was obtained under the following in this condition: O$_2$/C ratio of 0.64, total gas flow of 14.2 L/min, catalyst reactor temperature of 672$^{\circ}C$, the amount of steam was 0.8, reformer energy density of 1.1 kJ/L with Ni catalyst in the catalyst reactor. At this point, the methane conversion rate, hydrogen selectivity and reformer thermal efficiency were 66%, 93% and 35.2%, respectively.

Availability of SOFC systems equipped with a recycled steam reforming fuel processor (재순환수증기 연료개질형 SOFC시스템의 효용성 평가)

  • Oh, Jin-Suk;Jung, Chang-Sik;Park, Sang-Kyun;Kim, Myoung-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.7
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    • pp.569-573
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    • 2016
  • Strengthened regulations for atmospheric emissions from ships have created a need for new and alternative power systems that offer low emissions and high energy efficiency. Recently, new types of propulsion power systems, such as fuel cell systems that use hydrogen as an energy source, have gained serious consideration in applications requiring emission control. The purpose of this work is to certify the availability of solid oxide fuel cell (SOFC) systems equipped with recycled steam reforming fuel processors, and to compare their performance with that of extra steam reforming systems. The results demonstrate that the recycled steam reforming system has a slightly lower cell voltage and higher energy efficiency than the extra steam reforming system.

Pore Structure Modification and Characterization of Porous Alumina Filter with Chemical Vapor Infiltration (CVI) SiC Whisker (화학증착 탄화규소 휘스커에 의한 다공성 알루미나 필터의 기공구조 개질 및 특성 평가)

  • 박원순;최두진;김해두
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.518-527
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    • 2004
  • In this study, SiC whiskers were grown in porous alumina substrate in order to enhance the filtering efficiency, performance, and durability by controlling pore morphology. This experiment was performed by Chemical Vapor Infiltration (CVI) in order to obtain the whiskers on the inside of pores as well as on the surface of porous the A1$_2$O$_3$ substrate. The deposition behavior was changed remarkably with the deposition position, temperature, and input gas ratio. First, the mean diameter of whisker was decreased as the position of observation moved into the inside of substrate due to the reactant gas depletion effect'. Second, the deposition temperature caused the changes of the deposition type such as debris, whiskers and films and the change in morphology affect the various properties. When SiC films were deposited. the gas permeability and the specific surface area decreased. However, the whisker showed the opposite result. The whiskers increase not only the specific surface area and minimizing pressure drop but also mechanical strength. Therefore it is expected that the porous alumina body which deposited the SiC whisker is the promising material for the filter trapping the particles.

Promoter Effect on Ni/YSZ Anode Catalyst of Solid Oxide Fuel Cell for Suppressing Coke Formation in the Methane Internal Reforming (고체산화물 연료전지용 Ni/YSZ 음극 촉매에서의 메탄 내부개질 반응 시 탄소 침적 억제를 위한 첨가제 영향)

  • Kim, Hye-Roung;Choi, Ji-Eun;Youn, Hyun-Ki;Chung, Jong-Shik
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.813-818
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    • 2008
  • Various additives were added in small amounts on Ni/YSZ anode of SOFC (solid oxide fuel cell) in order to improve reactivity and to inhibit deactivation due to coke deposition during methane reforming using a low mole ratio steam ($H_2O/CH_4=1.5$) at $800^{\circ}C$. Ni/YSZ catalysts added with various perovskites did not show any improvement but exhibited a gradual decrease in the methane conversion. K-doped Ni/YSZ showed a steady increase and maintenance of the conversion up to 42 hours, after which there was an abrupt deactivation of catalyst owing to potassium loss by volatilization. Addition of 5% of $K_2Ti_2O_5$ on Ni/YSZ showed a stable maintenance of the conversion without K loss, and was able to prevent coke formation during a long time operation. Deactivation of catalyst during the reaction was mainly caused by the accumulation of graphidic carbon on the catalyst surface.

Sulfonated Polyethersulfone membrane의 투과 특성

  • 김인철;권영남;전종영;탁태문
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.69-70
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    • 1996
  • Polyethersulfone(PES)은 열적 특성이 우수하고 넓은 pH 범위에서 사용이 가능하며 특히, 막 제조 특성이 우수하여 막 소재로서 지금까지 널리 사용되어 오고 있다. Polysulfone(PSf)에 비하여 구조적으로 친수성이 우수하고 열적 특성이 더 뛰어난 장점이 있지만, 친수화를 시키기가 어려워서 지금까지는 주로 PSf의 친수화 연구로 한정되었었다. PES가 PSf에 비해 친수성이 좋다고는 하지만 PES 자체가 여전히 소수성을 띠므로 막 운전시 막의 내부나 표면에 투과 물질이 흡착되어 일어나는 Fouling으로 인해 막의 수명을 단축시키며 운전 효율도 크게 떨어진다. 이러한 Fouling을 줄이기 위한 방법으로 여러 가지 방법이 있지만 본 연구에서는 막의 재질을 친수성으로 개질시켜서 Fouling억제를 시도하였다.

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High temperature oxidation behavior and surface modification of Ni-based superalloys (니켈기 초합금의 고온산화거동과 표면개질에 관한 연구)

  • Seol, Gyeong-Won
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.166-176
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    • 1994
  • Ni base superalloys are composed of solid sohltion hardening elements(Co, Cr. Mo. W and so on) and $\gamma '$ precipitation hardening elements(A1, Ti, Nb, Ta and so on). To Improve the mechanical properties and oxidation resistanre of superalloys, rare earth elements(%r, Hf, Y and so on) are added to the inner substrate, or are used as coating materials. Their pffects on the growth rate and adhes~on of oxide are changed according to the kinds of oxides such as $AI_2O_3$ and $Cr_2O_3$. The effect of yttrium on the oxidation rate, grain size of oxide, internal structure, and crack resistance was investigated for two kinds of Ni-base superalloys. One in AF'115 superalloy containing Hf and the other is MA6000 superalloy containing $Y_2O_3$. They werr owid~zed at high temperature after yttrium surface modification using ion coater. Yttrium coating on the AF115 and MA6000 superalloys results in a marked change in the growth of the inner oxide. For AF115 superalloy, the degree of gram boundary segregation of $Cr_2O_3$, and prefer en^ tial oxidation of Hf are decreased, and the shape of inner oxidation layer was changed from triangle to plate type. For MA6000 superalloy, $Cr_2O_3$ oxide scale was transformed as outer oxidation layer of CrZOI and inner oxidation layer of $Cr_2O_3$.

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Fuel methanol as an alternative fuels (대체연료로서의 메타놀)

  • 장병주
    • Journal of the korean Society of Automotive Engineers
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    • v.6 no.1
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    • pp.11-20
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    • 1984
  • 이글에서는 메타놀의 성상과 재래의 내연기관에 메타놀을 사용하였을 때의 특성을 몇 가지 관 점에서 살펴보았다. 유리한 점으로 판단되는 사실은, 1)옥탄가가 높아 고압축비의채용으로 열 효율을 높일 수 있다. 2)기화참열이 크고 물과의 친화성이 좋다. 이러한 점은 내부냉각방식의 채용으로 이상적인 충상혼합기를 형성할 수가 있을 것이며, 현재의 내연기관의 냉각계통, 즉 방 열기, 물펌프, 냉각휜 등을 줄일 수 있을 것으로 본다. 또 NO.chi.의 배출을 저하시키는 이점도 있다. 3)단일성분 연료이므로 배기가스 조성이 단순하며 깨끗하다. 이는 배기공해상 메타놀연료가 석유계연료보다 유리하다. 그러나 메타놀기관은 앞으로 기술적 연구, 개선을 필요로 하는 점도 있다. 1) 메타놀의 가솔린과 비교하여 인화점이 높고 기화잠열이 커서 시동성이 나쁘고 2) 메타놀은 어느 종류의 금속, 프라스택, 도료 등을 부식시킨다. 3) 메타놀은 세탄가가 낮아, 압축점화는 무리이며 4) 발열량은 석유계 연료의 약 절반이다. 따라서 시동성, 재료, 착화방법, 개질 가스의 이용법, 내부냉각 등의 기술적인 문제가 개발된다면 질, 량, 가격적인 면에서도 내연기관용에는 메타놀이 유리하다고 본다. 그러나 현시점에서는 기관측으로 보아 자동차용연료로는 가솔린에 혼합하는 방법이고 그렇게 된다면 20-30%의 연료가 절감되리라고 믿는다.

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