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A Study on Organic/Inorganic Composite Membrane for Low humidity and High Temperature Polymer Electrolyte Membrane Fuel Cells (저가습 고온 고분자 연료전지용 유-무기 복합막에 관한 연구)

  • Choi, Young-Woo;Kim, Mi-Nai;Lim, Sung-Dae;Park, Seok-Hee;Yoon, Young-Gi;Yang, Tae-Hyun;Kim, Chang-Soo;Nam, Ki-Sook
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.135.1-135.1
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    • 2010
  • 최근 고온에서 사용 가능한 PEMFC용 고분자전해질 막 개발에 대한 연구가 활발히 진행되고 있다. PEMFC가 고온에서 작동하게 되면 높은 성능과 많은 장점을 갖게 된다. PEMFC를 $100^{\circ}C$ 이상에서 운전하게 될 경우 백금 전극 반응을 향상시켜 고가의 백금 촉매 양을 줄일 수 있게 되고, 수소연료 속에 미량 포함된 CO에 의한 촉매표면 피독현상에 대한 내구성을 높일 수 있어 저 순도 수소연료 사용이 가능해 진다. 또한 가습장치와 수소 연료 개질장치의 부피를 줄일 수 있게 되어 전체적인 PEMFC 시스템이 단순화 된다. 현재 연료전지용 고분자 전해질막으로 DuPont사의 과-불소계 고분자 전해질막인 Nafion$^{(R)}$이 가장 널리 사용되고 있다. Nafion$^{(R)}$은 유연한 분자구조 안에 소수성이 강한 주사슬과 친수성을 나타내는 술폰산이 결합된 곁사슬이 존재하여 술폰화 곁사슬의 클러스터 둘레에는 친수성 영역이 형성이 되기때문에 소수/친수 상 분리가 잘되어 이온 클러스터 형성이 용이하지만 제조비용이 높은 단점을 갖고 있다. 특히, 전해질 막내에서 Bronsted base 역할을 하는 물에 의해 이온전도가 이루어지기 때문에 고온에서는 수분증발로 인해 성능이 급격히 감소된다. 따라서, 본 연구에서는 고온 저가습 조건에서 운전이 가능하고 Nafion이 갖는 문제점을 해결하고자, 내열특성이 뛰어나며 높은 수소이온 전도도 학보가 용이한 Sulfonated Poly(aryl ether)sulfone(SPAES) 고분자 전해질에, 고온에서도 수화성이 유지될 수 있도록 지르코니아를 황산화한 sulfated zirconia(s-$ZrO_2$)를 함침하여 복합 고분자전해질막을 제조하여 고온 저가습 조건에서의 수소이온 전도 특성에 관한 연구를 수행하였다. 개발된 막의 물리/화학적 특성은 water content(Wup%), 이온교환 용량(IEC, meq $g^{-1}$), 수소이온전도도(s $cm^{-1}$) 열 중량 분석(TGA), X선 회절분석(XRD) 등을 통하여 분석 및 관찰하였다. 내화학 및 열적 특성분석 결과, 황산화 반응공정으로 $ZrO_2$에 술폰산기가 안정적으로 결합하고 있음이 관찰되었으며, 본 연구에서 개발된 유 무기 복합막이 $250^{\circ}C$이상 열적안정성을 확보하고 있는 것으로 판단되었다. $100^{\circ}C$ 이하의 저온 영역에서, 일정 비율의 s-$ZrO_2$/SPAES막에서 이온교환용량(IEC)이 순수 SPAES 막보다 낮음에도 불구하고, water uptake가 증가함과 동시에 수소이온 전도도가 향상된 것을 관찰하였다. 또한, 고온에서는 수소이온이 자유롭게 이동할 수 있는 water channel을 형성하는 free water는 증발 하지만 s-$ZrO_2$와 SPAES의 술폰산기 사이에 강력하게 결합하고 있는 bound Water는 $100^{\circ}C$ 이상의 고온 영역에서도 존재하여, 비록 무가습 조건에서도 일정 비율의 s-$ZrO_2$/SPAES50 전해질 막의 경우, 높은 전도도를 나타냄을 관찰할 수 있었다. 따라서 본 연구를 통해 저가습 고온 적용을 목적으로 개발된 s-$ZrO_2$/SPAES50막은 우수한 내열 특성을 나타냄과 동시에 저가습 고온 영역($120^{\circ}C$, $50RH{\downarrow}$)에서 높은 수소이온 전도도를 유지하여, 고온 저가습 연료전지 운전에 적합할 것으로 사료된다.

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Static Bending Strength Performance of Domestic Wood-Concrete Hybrid Laminated Materials (국내산 목재-콘크리트 복합적층재의 정적 휨 강도성능)

  • Byeon, Jin-Woong;Cho, Young-June;Lee, Je-Ryong;Park, Han-Min
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.1
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    • pp.48-56
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    • 2016
  • In this study, to develop the lattice materials with a low environmental load for restoring the destroyed forest, 7 types of wood-concrete hybrid laminated materials were manufactured with domestic four softwoods, three hardwoods and concrete, and the effects of density of wood species on static bending strength performances were investigated. Bending MOEs of wood-concrete hybrid laminated materials increased with increasing density of wood species on the whole, and the values were higher than that of concrete by hybrid-laminating woods on the concrete. It was found that the measure values of bending MOEs were slightly lower than the calculated values calculated using equivalent cross-section method from MOE of each laminae of hybrid laminated materials and the difference between them was less than 10%. Bending proportional limit stresses of hybrid laminated materials showed 1.2-1.6 times higher than that of concrete by hybrid-laminating. Bending strength (MOR) of hybrid laminated materials increased with the density of wood species. By hybrid-laminating, the MOR of concrete was considerably increased. Therefore, it is considered that wood-concrete hybrid laminated materials can be applied as a materials with a low environmental load and durability for ecological restoration.

Field Application on Mass Concrete of Combined Coarse Particle Cement and Fly-Ash in Mat Foundation (조분(粗粉) 시멘트와 플라이애시를 복합 치환한 매트 기초 매스콘크리트의 현장적용)

  • Han, Cheon-Goo;Jang, Duk-Bae;Lee, Chung-Sub
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.4
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    • pp.11-20
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    • 2010
  • This study carried out a Mock-up test to apply Low-heat Cement (CF) that is adjusted to a fineness of $3,000\;{\pm}\;200\;cm^2/g$ by substituting Coarse particle Cement (CC) and fly ash with ordinary Portland Cement (OPC), then applied it on-site. The result of the test is as follows. The Mock-up test showed that the amount of admixture in CF increased SP agent and AE agent slightly more compared to OPC, while temperature history showed that the highest temperature of CF was around $6{\sim}10^{\circ}C$ lower than that of OPC. Compressive strength in CF was low compared to that of OPC, but the strength width became narrow at the age of 28 days, which is not considered to be significant. In on-site application, slump, air content and chloride content all satisfied the target values, while the temperature history showed that the highest temperature in the center by each cast was about $34^{\circ}C$ in the first cast, $42^{\circ}C$ in the second cast, and $39^{\circ}C$ in the third cast. Compressive strength of specimen for strut management showed low value compared to standard curing, but its strength was reduced at the age of 28 days.

A Study on the Recording Technology of Fire Propagation Prevention Wall Using Horticultural Plants (원예식물을 식재한 화재확산 방지용 벽면녹화 기술연구)

  • Moon, Jong-Wook;Lim, Seo-Hyung
    • Journal of the Society of Disaster Information
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    • v.14 no.2
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    • pp.107-114
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    • 2018
  • Purpose : This study is to develop walls using wall recording technology applied on roofs to prevent fire spread in traditional markets. Method : The spray head installed on the developed wall was designed so that the fire does not spread to adjacent buildings after being used for plants. In addition, a spray head was attached to the upper section and some sections for the growth of plants planted on the wall to prevent the spread of fire. Results : These technologies suggested the development of walls that can be installed at the upper level of buildings, such as traditional markets, and separate isolation facilities were not necessary because they are integrated with structures and sprinklers. In addition, sprinklers can perform both the plant spray and fire spread prevention functions. It is believed that this is the only alternative technology proposed in Korea to prevent the spread of fire. Conclusion : In this study, the wall design, designed directly to derive the quantitative performance of the fire spread reduction effect, demonstrated the fire suppression method of the wall system, the durability of the wall itself, and the flame retardability performance.

An Experimental Study on the Binder Adhesion Performance and Mixture Deformation Strength of Polymer Asphalt (폴리머 아스팔트의 유제 부착성능 및 혼합물 변형강도에 관한 실험적 연구)

  • Choi, Jae-Min;Kim, Kyeong-Jin;Lee, Seung-Yong;Kim, In-Joong;Jeong, Yong-Hwi
    • Journal of the Society of Disaster Information
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    • v.16 no.3
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    • pp.602-610
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    • 2020
  • Purpose: This paper aims to develop an asphalt pavement system with reduced cracks, structural stability and waterproofing at sub-zero temperature conditions. Method: Under various temperature conditions, SIS polymer asphalt, normal asphalt, and guss asphalt were tested for adhesion strength of the binder and deformation strength of the mixture. Result: The adhesion strength of asphalt binder was higher in SIS polymer asphalt than that of normal asphalt and guss asphalt. The deformation strength of the asphalt mixture was almost the same as that of SIS polymer asphalt and normal asphalt. The energy absorption of the SIS polymer asphalt mixture was relatively higher than that of the normal asphalt mixture and the guss asphalt mixture. Conclusion: The maximum load of the SIS polymer asphalt mixture was lower than that of the guss asphalt mixture. However, in sub-zero temperature conditions, sufficient energy absorption was secured by stable load reduction. Therefore, it is expected to improve the durability of asphalt pavement by reducing the occurrence of microcracks with stable fracture behavior.

AFTL: An Efficient Adaptive Flash Translation Layer using Hot Data Identifier for NAND Flash Memory (AFTL: Hot Data 검출기를 이용한 적응형 플래시 전환 계층)

  • Yun, Hyun-Sik;Joo, Young-Do;Lee, Dong-Ho
    • Journal of KIISE:Computer Systems and Theory
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    • v.35 no.1
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    • pp.18-29
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    • 2008
  • NAND Flash memory has been growing popular storage device for the last years because of its low power consumption, fast access speed, shock resistance and light weight properties. However, it has the distinct characteristics such as erase-before-write architecture, asymmetric read/write/erase speed, and the limitation on the number of erasure per block. Due to these limitations, various Flash Translation Layers (FTLs) have been proposed to effectively use NAND flash memory. The systems that adopted the conventional FTL may result in severe performance degradation by the hot data which are frequently requested data for overwrite in the same logical address. In this paper, we propose a novel FTL algorithm called Adaptive Flash Translation Layer (AFTL) which uses sector mapping method for hot data and log-based block mapping method for cold data. Our system removes the redundant write operations and the erase operations by the separating hot data from cold data. Moreover, the read performance is enhanced according to sector translation that tends to use a few read operations. A series of experiments was organized to inspect the performance of the proposed method, and they show very impressive results.

A Study on Connection of Fuel Processor and NG blower for Small Commercial Fuel Cell System (건물용 연료전지 시스템용 연료처리장치와 연료승압 블로워 연계 특성에 관한 연구)

  • Kim, Jaedong;Jang, Sejin;Kim, Bonggyu;Kim, Jinwook;Han, Sienho;Park, Dalryung
    • Journal of the Korean Institute of Gas
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    • v.21 no.5
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    • pp.36-44
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    • 2017
  • The small commercial fuel cell is a new energy system that produces electricity and heat through electrochemical reaction between air and hydrogen. In Korea, hundreds of domestic small commercial fuel cell systems have been installed and operated every years and many parts in fuel cell systems depend on overseas products. KOGAS(Korea Gas Corporation) has developed the fuel processor which is an important part of fuel cell system and has evaluated the long-term durability. And KOGAS has evaluated domestic and overseas NG blower and fuel processor connected to NG blower. The fuel processor developed by KOGAS have maintained an efficiency of 76% and constant performance over 3,000 hours. The NG blower developed in Korea showed similar characteristics as overseas NG blower in the evaluation of power consumption according to rear pressure and outside temperature. The fuel processor module, fuel processor connected to BOP showed excellent performance.

전기유동유체(ERF)를 이용한 지능구조물 시스템의 구성 및 응용

  • 최승복;박용군
    • Journal of KSNVE
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    • v.5 no.3
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    • pp.275-283
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    • 1995
  • 본 글에서는 지능구조물의 개념설명과 더불어 ERF의 특성, ERF를 함유란 함유 한 지능구조물 시스템의 구성, 동적 모델링과 진동제어 그리고 그 응용성에 관한 연구 현황과 방향에 대해 살펴보았다. 설명한 바와 같이 지능구조물은 새로운 차원의 신생 하는 첨단분야로서, 소음 및 진동에 관련된 무한한 잠재력과 다양한 응용성으로 미루 어 볼때 아주 매력적인 연구 분야이다. 그러나, 여러 응용 시스템의 상품화 단계로의 도약에 있어서 각 시스템 구성 요소 분야별 해결해야할 연구 사항들이 있다. 먼저, 액추에이팅을 수행하는 ERF 자체의 내구성 문제로서 고온에서 ERF의 효과 하락과 장시간 사용시 ERF에 의한 마멸, 고체 입자의 침전에 의한 초기 상태 불안정 등이 있다. 아울러 기존의 장치의 성능을 능가하기 위해 보다 큰 효과를 나타내는 새로운 차원의 ERF개발이 요구된다. 그리고 센서기술 분야에서는 호스트 재료에 보다 쉽게 결합이 되고 여러가지 형태의 요구조건을 만족시킬 수 있으며 외부 환경조건에 강건 하고 다양한 센서 개발이 요구된다. 또한, 보다 일번적인 동적 모델링을 통해 적용 시스템에 적합하고 강건한 제어기에 대한 연구가 진행되어야 한다. 마지막으로 능동 제어기를 실제로 구현하기 위한 호스트 재료 각 요소마다 센서의 설치, 페회로 피드백 시스템 장착, 상호간의 인터페이스 등의 기술 발전이 요구되며, 아울러 보다 효율적 인 시스템의 성능 특성을 실현할 수 있는 호스트 재료와 기계 메카니즘이 필요로 된다. 이상의 설명에서 알 수 있듯이 지능구조물에 대한 연구는 어느 한 분야에서만 아니라 기계, 전기전자, 토목, 물리, 재료과학 등 통합형식에 의한 접근 방향으로 추진되어야 할 것이다.서 세탁기의 진동 소음을 저감시키기 위해 진동 소음원에 대해 논술하고, 진동해석을 위해 컴퓨터 시뮬레이션 결과를 이용한 저진동 기술 개발에 대하여 기술하고자 한다.rotary piston)식 압축기는 약 20여년 전 부터 냉방용 압축기에서부터 널리 쓰이게 되었다. 약 10여년전부터 상용화 된 스크롤(scroll) 형 압축기도 현재 상대적으로 용량이 큰 가정용 냉방기를 중심으로 많이 쓰이고 있다. 스크류형 압축기는 보통 중대형 상업용에 주로 쓰인다. 해결하려 하였고, 수치해석은 피스톤의 운동을 배제한 단순화한 흡배기계의 정상상태 유동해석이 주를 이루어왔다. Taghaui and Dupont 등[5]은 KIVA코드를 사용하여 흡기포트와 연소실 그리고 밸브의 움직임을 동시에 고려한 수치해석을 도입하였다. 하지만 이들이 밸브의 운동을 고려하기 위해 사용한 이동격자는 격자점은 시간에 따라 변화하지만 그 격자의 수가 일정하게 유지되어 있어서 밸브의 완전개폐를 해석할 수가 없다. 강희정[6]은 단일 실린더와 단일 배기밸브를 갖는 문제로 단순화하여 피스톤과 밸브의 움직임을 고려하므로써 배기행정 후 소음이 어떻게 전파해 나가는가를 연구하였다. 본 연구에서도 최소밸브간격과 최대밸브간격 사이에서만 계산이 가능하나 흡기의 경우는 밸브가 닫힐 때 생기는 압력파가 중요하므로 실린더와 밸브사이에 벽면조건을 주어 밸브의 개폐를 모사하였다.술을 보유하고자 한다. 이용한 해마의 부피측정은 해마경화증 환자의 진단에 있어 육안적인 MR 진단이 어려운 제한된 경우에만 실제적 도움을 줄 수 있는 보조적인 방법으로 생각된다.ofile whereas relaxivity at high field is not affected by τS.

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Removal of Suspended Solids from Stormwater Runoff Using a Fabric Filter System (섬유필터를 사용한 강우유출수의 부유물질 제거 방법의 개발)

  • Koo, Young Min;Kim, Jaeyoung;Kim, Byung Ro;Seo, Dongil
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.3
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    • pp.165-174
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    • 2015
  • Non-point source pollution associated with suspended solids in stormwater has been known to often adversely affect surface water ecosystems. Various methods of treating stormwater in the basin area before the stormwater reaches the receiving body of water have been developed. However, these treatment methods tend to be costly to install and also to maintain. In this study, an economical way of removing TSS (total suspended solids) from stormwater runoff with a fabric filter system was developed. Polyester was chosen as a fabric-filter material, because it was found to be economical in cost and relatively resistant to various chemicals. An experimental device was developed and used to determine filtration rates through polyester fabric samples of a series of several pore-opening sizes ($20{\mu}m$ to $94{\mu}m$) under a series of water-heads (0.25 to 1 m). It was found that the filtration rate increased as the size of water head increased. It was also found that the smaller the pore size of the fiber filter was, the higher the TSS removal efficiency was. However, the TSS removal efficiency was not found to be much different among the filters with different sizes of pore opening due to the fact that most mass of TSS was associated with large particles.

Structural performance evaluation of precast concrete segment using synthetic fibres (프리캐스트 콘크리트 세그먼트의 합성섬유 보강재 적용에 따른 구조적 성능 평가)

  • Lee, Hoseong;Kim, Changyong;Lee, Sean S.;Kim, Seungjun;Lee, Kyeongjin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.2
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    • pp.469-483
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    • 2018
  • Steel bars have been widely used as the primary reinforcement for Precast Segmental Concrete Lining for TBM Tunnels. Previously, studies have been carried out to gauge the potential for steel fiber reinforcement to replace the use of steel bar reinforcements in the segmental lining to reduce the amount of the steel bar reinforcement. Steel fiber reinforcements have been investigated and widely applied to SFRC TBM linings to improve the constructability of SFRC TBM linings worldwide. However, the steel fiber reinforcement often caused punctures to the water membranes inside tunnel lining and had long-term durability deterioration issues caused by steel corrosion, as well as cosmetic problems. Therefore, this paper sought to gauge the potential of synthetic fiber reinforcements, which have proven to be very attractive substitutes for steel fiber reinforcements. This study analyzed the performance of both steel and synthetic fiber reinforcements in segmental linings and evaluated the applicability of the fiber reinforcements to the TBM Precast Concrete Segmental Linings of TBM tunnels. As a conclusion, this study demonstrates that the potential use of steel and synthetic fibers in various combination, can substitute the rebar reinforcement in the concrete mix for segmental concrete linings.