• Journal of Korea Foundry Society
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• v.43 no.5
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• pp.260-263
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• 2023

이 보고서에서는 무기 공정에서의 무기 인공 재생 모래의 특성을 중심으로 다음과 같이 정리할 수 있다. 1) ICP 발광 분광 분석을 통한 재생 모래의 Na⁺ 용출량, TP 휨강도 및 충전 밀동에는 높은 상관 관계가 확인되었다. 2) 현행 재생 방법 대비, 습식 연마 처리를 첨가함으로써 잔류 점결재가 제거되고 Na+ 용출량이 저감된 결과, 재생 모래의 TP 휨강도를 보다 개선 가능한 것이 확인되었다. 3) 재생 처리 공정 순서를 건식 연마 → 습식 연마 → 배소 처리로 함으로써, 가장 Na⁺ 용출량이 낮고, 높은 휨강도를 얻을 수 있는 것이 확인되었다. 4) 습식 연마 단계를 거치지 않고 배소 처리 온도와 처리 시간을 궁리함으로써 충분한 품질의 재생 모래를 얻을 수 있는 가능성이 시사되었다. 마지막으로, 무기 공정은 유기 공정에 비해 압도적으로 냄새가 적고 생산성이 높으며 인공 모래와의 병용을 통한 재생 처리시의 폐기물량 저감, 주조품의 고품질화 등 이점이 기대되는 공정이다.

• Journal of the Korean Wood Science and Technology
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• v.42 no.4
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• pp.460-466
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• 2014

To evaluate wood charcoal as raw material for mineral water production, dissolution of inorganic ions from charcoal to water, pH and adsorption ability of chlorine in water were investigated as main variables. More potassium ion was dissolved in water as higher temperature manufactured charcoal but other ions showed no difference with different charcoal making temperatures. Highest dissolved cation was potassium followed by calcium and sodium. Among wood species, charcoal from Quercus variabilis and Platanus occidentalis showed significantly higher potassium content in water than that of larch, red pine and white pine. Other cations had similar pattern to the potassium but their difference was not apparent as much as potassium. pH value of water treated with charcoal was higher for wood charcoals from Platanus occidentalis (pH 8.5) and Quercus variabilis (pH 8.4) which contained higher inorganic cations. In chlorine removal in water by charcoal, all wood charcoals showed greater chlorine removal than that of the control, but softwood charcoals resulted in higher removal than those of hardwoods. There was no significant difference in the dissolution of cations and pHs between particle charcoal and whole charcoal. With easy of control, whole charcoal is better for mineral water making raw material than particle charcoal does.

• The Korean Journal of Rheology
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• v.3 no.2
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• pp.175-185
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• 1991

Sodium octylbenzenesulfonate(SOBS)와 sodium dodecylbenzenesulfonate(SDBS)를 폴리프로필렌(PP) 용융액에 각각 균일하게 서로 다른 함량으로 섞어 넣은 후에 용융압착법 으로 PP 필름을 제조하였다. 저장 점성도(η＇) 저장탄성률(G＇) 및 손실 탄성률(G＂)을 진 동식 레오미터를 사용하여 170~195$^{\circ}C$에서 측정하였다. 실험온도 범위내에서 첨가제를 함유 한 PP와 순PPrks에 Cole-Cole 플롯(G＇에 대한 G＂의 log-log 플롯)에는 차이가 없었다. 그러나 광범위한 전단속도에서 SOBS의 첨가량이 8%를 넘어서면서 η＇과 G＇은 증가하였 다. 이러한 현상은 PP 중에서의 첨가제의 응집효과로 설명되었으며 이것은 SOBS와 SDBS 를 함유하는 PP 필름의 시차 주사열량법 및 주사전자 현미경 관찰결과로 확인되었다. SDBS를 8% 미만 함유하는 PP로부터 섬유의 용융방사가 가능하였으나 SDBS3% 이상 함 유PP 방사섬유는 연신 과정중에 섬유의 절단이 이따금 일어났다. PP 기질내에 있어서의 SDBS의 뜨거운 물에대한 견뢰성을 SDBS와 C. I. Basic blue 41사이의 이온결합 형성 거동 에 바탕을 두어 가시분광법에 의하여 검토하였다.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.7
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• pp.704-712
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• 2006

This research was designed to investigate the removal of heavy metals, such as $Al^{3+}$, $Cu^{2+}$, $Mn^{2+}$, $Pb^{2+}$ and $Zn^{2+}$, by adsorption on clay minerals. Bentonite(Raw-Bentonite), $Ca^{2+}$ and $Na^+$ ion exchanged bentonite(Ca- and Na-Bentonite) and montmorillonite, such as KSF and K10 from Sigma Aldrich, were used as adsorbents. The component of five inorganic adsorbents was analyzed by XRF, and the concentration of metal ions was measured by ICP. The cation exchange capacity(CEC) and the particle charge of adsorbents were measured. The initial concentration range of metal ions was $10{\sim}100$ mg/L. From the experimental results, it was shown that the adsorption equilibrium was attained after $1{\sim}2$ hours. The maximum percentage removal of $Al^{3+}$, $Cu^{2+}$, $Pb^{2+}$ and $Zn^{2+}$ on Na-Bentonite were more than 98% and that of $Mn^{2+}$ was 66%. $Al^{3+}$ was leached out from KSF with the higher concentration of hydrogen ion. Percentage removals of $Pb^{2+}$ and $Zn^{2+}$ on KSF were 88% and 59%, respectively. In general, the percentage removal of metal ions was decreased with the higher initial concentration of metal ions. The adsorption capacity of metal ions on Na-Bentonite was $1.3{\sim}19$ mg/g. Freundlich equation was used to fit the acquired experimental data. As the results, the adsorption capacity of metal ions was in the order of Na-Bentonite$\gg$Raw-Bentonite$\cong$K10>Ca-Bentonite>KSF. Freundlich constant, K of Na-Bentonite was the largest for metal ions. The order K of Na-Bentonite was Al>Cu>Pb>Zn>Mn, and the adsorption intensity(1/n) was determined to be $0.2{\sim}0.39$.