• Title/Summary/Keyword: 나노 재료

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A Study on the Preparation and Flame Retardancy of Compatibilized Blend/Layered Silicate Nanocomposites with Inorganic Flame Retardant (무기계난연제 첨가형 상용화블렌드/층상실리케이트 나노복합재료의 제조 및 난연특성에 관한 연구)

  • Kang, Young-Goo;Song, Jong-Hyeok
    • Journal of the Korean Society of Safety
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    • v.21 no.1 s.73
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    • pp.79-85
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    • 2006
  • Olefinic compatibilized blend(R-PP/R-PE)/layered silicate composites have been prepared by melt intercalation technique directed from $Na^{+}$ montmorillonite(MMT) or organophilic montmorillonites while using magnesium hydroxide as flame retardant. Morphology and flammability properties were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), thermogravimetry analysis(TGA), limiting oxygen index(LOI), UL94 test. It is found that the compatibilized blend/layered silicate(Cloisite 20A) nanocomposites have a mixed immiscible-intercalated structure and there is better intercalation when a compatibilizer is combined with the polymer and layered silicate to be melt blended. A very large increase in the LOI value was observed with hybrid filler addition and further enhancement in thermal stability and compatibility of blend was obtained for the compatibilized blend containing small amount of layered silicate.

Mechanical property of plated layer by Mg contents in the Zn-Mg plated steel by PVD process (PVD 방식을 통해 도금된 아연-마그네슘 도금 강판에서 Mg 함량에 따른 도금층의 기계적 특성)

  • Choe, Myeong-Hwan;Byeon, Jong-Min;Kim, Tae-Yeop;Jeong, U-Seong;Kim, Yeong-Do
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.53-53
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    • 2014
  • 아연-마그네슘 합금은 뛰어난 내식성으로 최근 코팅소재로 가장 많이 사용되는 아연 도금을 대체할 수 있는 재료로서 주목받고 있다. 특히 PVD 방식을 통해 도금강판을 제조할 경우 도금층의 두께 제어가 용이하여 아연의 사용량을 저감할 수 있다. 그러나 이러한 PVD 방식을 통해 제조된 아연-마그네슘 도금강판을 사용하기 위해서는 내식성 이외에도 일정수준의 기계적 특성 확보가 중요하다. 본 연구에서는 마그네슘 함량을 달리하여 제조된 아연-마그네슘 도금강판을 대상으로 XRD 분석, 나노인덴테이션 시험을 실시하여, 아연-마그네슘 도금강판 도금층의 기계적 특성에 미치는 상(Phase)의 영향을 분석하였다.

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Sensing performances of Semiconducting Carbon Nanomaterials based Gas Sensors Operating at Room Temperature (반도체 탄소 나노재료 기반 상온 동작용 가스센서)

  • Choi, Sun-Woo
    • Ceramist
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    • v.22 no.1
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    • pp.96-106
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    • 2019
  • Semiconducting carbon-based nanomaterials including single-walled carbon nanotubes(SWCNTs), multi-walled CNT(MWCNTs), graphene(GR), graphene oxide(GO), and reduced graphene oxide(RGO), are very promising sensing materials due to their large surface area, high conductivity, and ability to operate at room temperature. Despite of these advantages, the semiconducting carbon-based nanomaterials intrinsically possess crucial disadvantages compared with semiconducting metal oxide nanomaterials, such as relatively low gas response, irreversible recovery, and poor selectivity. Therefore, in this paper, we introduce a variety of strategies to overcome these disadvantages and investigate principle parameters to improve gas sensing performances.

Modelling the Tensile Instability of Nanocrystalline Metallic Materials (나노금속재료의 인장불안정에 대한 모델링)

  • Kim H. S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.10a
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    • pp.251-254
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    • 2001
  • In this paper, the effect of grain refinement on room temperature ductility of copper was addressed. Recent experimental results have shown that this material, as well as a number of other single-phase metals that are ductile when coarse-grained, loose their ductility with decreasing grain size in the sub micrometer range. A recently developed model in which such materials are considered as effectively two-phase ones (with the grain boundaries treated as a linearly viscous second phase) was applied to analyze stability of Cu against ductile necking. As a basis, Hart's stability analysis that accounts for strain rate sensitivity effects was used. The results confirm the observed trend for reduction of ductility with decreasing grain size. The model can be applied to predicting the grain size dependence of ductility of other metallic materials as well.

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Thermal Residual Stress Relaxation Behavior of Alumina/SiC Nanocomposites (Alumina/SiC 나노복합재료에서의 잔류 열응력 완화거동에 관한 연구)

  • Choa, Y.H.;Niihara, K.;Ohji, T.;Singh, J.P.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2002.04b
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    • pp.11-11
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    • 2002
  • Plastic deformation was observed by TEM around the intragranular SiC particles in the $Al_2O_3$ matrix for $Al_2O_3/SiC$ nanocomposite system. The dislocations are generated at selected planes and there is a tendency for the dislocations to form a subgrain boundary structure with low-angel grain boundaries and networks. In this study, dislocation generated in the $Al_2O_3$ matrix during cooling down from sintering temperatures by the highly localized thermal stresses within and/or around SiC particles caused from the thermal expansion mismatch between $Al_2O_3$ matrix and SiC particle was observed. In monolithic $Al_2O_3$ and $Al_2O_3/SiC$ microcomposite system. These phenomena is closely related to the plastic relaxation of the elastic stress and strain energy associated with both thermal misfitting inclusions and creep behaviors. The plastic relaxation behavior was explained by combination of yield stress and internal stress.

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Effect of Cu content on Microstructure and Mechanical Properties of Al2O3/Cu Nanocomposites (Cu 첨가량이 Al2O3/Cu 나노복합재료의 미세조직과 기계적 성질에 미치는 영향)

  • Oh Sung-Tag;Yoon Se-Joong
    • Journal of Powder Materials
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    • v.13 no.1 s.54
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    • pp.33-38
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    • 2006
  • The effect of Cu content on microstructure and mechanical properties of nano-sized Cu dispersed $Al_2O_3(Al_2O_3/Cu)$ nanocomposites was investigated. The nanocomposites with Cu content of 2.5 to 10 vol% were prepared by reduction and hot-pressing of $Al_2O_3/CuO$ powder mixtures. The nanocomposites with Cu content of 2.5 and 5vol% exhibited the maximum fracture strength of 820MPa and enhanced toughness compared with monolithic $Al_2O_3$. The strengthening was mainly attributed to the refinement of $Al_2O_3$ matrix grains. The toughening mechanism was discussed by the observed microstructural feature based on crack bridging.

Superhydrophobic Nano Patterning Techniques for Enhanced Performance of Naval Underwater Vessels (군용 수중 운동물체의 성능강화를 위한 초소수성 나노 패터닝 기술)

  • Hong, Soon-Kook;Lee, Ki-Young
    • Journal of Ocean Engineering and Technology
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    • v.27 no.2
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    • pp.114-120
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    • 2013
  • A superhydrophobic surface means that the contact angle between the solid surface and a water droplet is more than $150^{\circ}$. Materials with a superhydrophobic surface have a self-cleaning function because of the Lotus effect, in which water is not absorbed by the material but rolls off of it. If such a Lotus effect can be applied to the surface of underwater vessels, submarines, torpedos, and so on, enhanced vessels can be made based on this lubricant effect reducing the friction coefficient for the liquid. Because polymer composites can be easily applied in various nanotechniques, they are more advantageous than conventional materials like iron in terms of a superhydrophobic surface. Furthermore, a superhydrophobic surface bring enhanced anticorrosion and ecotechnology because no paint is needed on underwater vessels.

Thermal Properties of XLPE Insulatorl Nano Semiconducting Materials in Power Cable (전력케이블용 XLPE절연체/ 나노 반도전층 재료의 열적 특성)

  • Yang, Jong-Seok;Choi, Sung-Hun;Park, Jabg-Hyeon;Sung, Baek-Ryong;Lee, Jae-Hyeung;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.30-31
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    • 2006
  • To improve the mean-life and the reliability of power cable, we have investigated specific heat (Cp). Specific-heat measurement temperature ranges of XLPE insulator were from $20[^{\circ}C]$ to $90[^{\circ}C]$, and the heating rate was $1[^{\circ}C/min]$. In case of semiconducting materials, the measurement temperature ranges of specific heat were from $20[^{\circ}C]$ to $60[^{\circ}C]$ and the heating rate was $1[^{\circ}C/min]$. From these experimental results, both specific heat were increased by heating rate because volume of materials was expanded according to rise in temperature. We could know that a small amount of CNT has a excellent thermal properties.

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$Ni_{1-x}-Zn_x ferrite$ ferrite nano-particles prepared by the auto-conbustion method and the charateristics of the coated permallroy (자동 연소 법에 의한 $Ni_{1-x}-Zn_x ferrite$ 나노 입자의 합성 및 Permalloy 코팅 특성)

  • 최광보;김영식;김병철;김성배
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.104-105
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    • 2002
  • Ni$_{1-x}$-Zn$_{x}$ ferrite는 매우 큰 저항과 적은 eddy current loss를 가지고 있어 transfomer core나 radio frequency coil같은 high power device등의 전자 재료로 이용된다[1]. Ni$_{1-x}$-Zn$_{x}$ ferrite의 합성에는 여러 가지 방법이 이용되고 있으나 oxide/carbonate를 이용하여 120$0^{\circ}C$ 이상의 고온의 열을 가해 하소하는 solid-state reation과 diethylamine을 이용하여 metal nitrate를 공침 하는 coprecipition방법, sol-gel 방법 등의 wet chemical method가 가장 일반적이다[2-3]. (중략)

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Fracture Toughness of $Al_2O_3$/5vol.%Cu Nanocomposites Fabricated by PECS (PECS에 의해 제조된 $Al_2O_3$/5vol.%Cu 나노복합재료의 파괴인성)

  • 민경호;홍대희;김대건;김영도;문인형
    • Journal of Powder Materials
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    • v.7 no.3
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    • pp.149-153
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    • 2000
  • In this study, the fabrication of $Al_2O_3$/5vol.%Cu nanocomposite and its mechanical property were discussed. The nanocomposite powders were produced by high energy ball milling of $Al_2O_3$ and Cu elemental powders. The ball-milled powders were sintered with Pulse Electric Current Sintering (PECS) facility. The relative densities of specimens sintered at $1200^{\circ}C$ and $1250^{\circ}C$ after soaking process at $900^{\circ}C$ were 96% and over 97%, respectively. The sintered microstructures were composed of $Al_2O_3$ matrix and the nano-sized Cu particles distributed on grain boundaries of $Al_2O_3$ matrix. The nanocomposite exhibited the enhanced fracture toughness compared with general monolithic $Al_2O_3$. The toughness increase was explained by the crack deflection and bridging by dispersed Cu particles.

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