• 제목/요약/키워드: 나노 재료

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고전압 전력기기응용을 위한 에폭시-나노콤포지트의 전기장 분산기술연구 (A Study on Electric Field Dispersion Techniques of Epoxy-Nanocomposites for Application of High Voltage Power Apparatus)

  • 이창훈;김효철;조영화;김현;정훈;박재준
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.97-97
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    • 2010
  • A new electric application method was developed to prepare epoxy/organoclay nanocomposite for the electrical insulation in the AC electric fields and it could be also used in the field of various viscous polymer/organoclay systems. The applied AC electric field condition was as follows; (1) inter-electrode distance: 40 mm, (2) application voltage: 3-11 kV, (3) frequency: 60~1,000 Hz, and (4) application time: 0~60 min. To characterize the epoxy/clay nanocomposite, WAXS and TEM analyses were confirmed. In order to explain how the organic modifier affects the exfoliation phenomena, a mechanism of the oscillating collision of the quaternary ammonium head was proposed and the effects of the AC voltage and frequency and the organoclay content were studied.

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나노/마이크로 컴포지트를 이용한 엔지니어링 열가소성 플라스틱의 표면 절연 개선 (Improvement of surface insulation properties of engineering thermoplastics by using nano/micro composite)

  • 정의환;임기조;허준;정종훈;김평중;정수현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.29-29
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    • 2010
  • Engineering plastics have excellent electrical properties, mechanical strength and various characteristic which include chemical resistance, environmental resistance, weatherability at a wide temperature range. It has good characteristic(light weight, good productivity) as compare with epoxy or porcelain insulators. However, engineering plastics not suited to outdoor insulator because it isn't hydrophobic. Therefore, to over come these critical problems, we improve the surface insulation characteristics of engineering plastic by coating micro-, nano- size inorganic fillers added to RTV-SIR(Room temperature vulcanized-silicone rubber) at this plastic surface. The effect is analyzed through salt-fog test, tracking test. In conclusion, the engineering plastic coated RTV with micro-$Al_2O_3$20[phr], nano-Al(OH)3 1 ~ 3[phr] improved much better than the others.

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전자장치 응용을 위한 금속(은, 구리) 나노입자의 합성 (Synthesis of Metal Nanoparticles for the Application of Electronic Device)

  • 전병호;조수환;조정민;김성은;김동훈;김성진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.53-53
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    • 2010
  • The development of synthetic pathway to produce a highly yield nanoparticles is an important aspect of industrial technology. Herein, we report a simple, rapid approach to synthesize organic-soluble Cu and Ag nanoparticles in colloidal method for the application in a conductive pattern using inkjet printing. The silver nanoparticles have been synthesized in highly concentrated organic phase. The Cu nanoparticles have been synthesized by the reducing of the copper oxide materials using acid molecules in high concentrated organic phase. Their sintering and electric conductivity properties were investigated by melting process between $200^{\circ}C$ and $250^{\circ}C$ for application to printed electronics.

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나노컴퍼지트 에폭시 체적고유저항의 온도의존성 (Temperature Dependence of Volume Resistivity Characteristics for Nano Composit Epoxy)

  • 이동건;백승학;박태학;박홍규;정인범;김정식;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.91-91
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    • 2010
  • In this paper, nano composites material is produced by adding MgO with particle size of 5 [nm] into epoxy resign using as insulating material of power transformer apparatus and molding part to study the volume resistivity of nano composites used epoxy. We measured the volume resistivity using the High Resistance Meter(4329A) depending on changing the amount of addition and temperature in this experience. In result, we have confirmed that 1.0, 3.0, 5.0 and 10.0 [wt%] as about 2.9, 7.6, 7.5 and 6.1 times increased than virgin. Therefore, the characteristic of volume resistivity was relatively stable as specimen by added 3.0 [wt%] than the others.

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전도성 기판에 도입된 산화아연 나노월의 능동적 성장법과 전자소자

  • 김동찬;이주호;배영숙;최원철;조형균;이정용
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.54-54
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    • 2010
  • This article reports a spontaneous method for controlling the growth mode from vertically arrayed ultra-slim MgZnO nanowires to nanowalls through the Zn random motion of seeds formed by surface phase separation by Mg injection near an evaporation temperature of Zn. The random motion of single crystal MgZnO seeds with relative Zn rich phase played a vital role in the growth of the MgZnO nanowalls. The seeds were networked with increasing Zn flux compared with Mg flux and closing to the evaporation temperature of Zn on phase separation layers. We achieved fabrication of MgZnO nanowalls on various non- and conducting substrates by this advanced growth method. The MgZnO nanowalls hydrogen sensor showed an improved sensing performance compared to the MgZnO nanowires grown under the similar conditions. Based on the microstructural characterizations, the growth procedure and models for the evolution of the structure transition from MgZnO nanowires to nanowalls on the Si substrates are proposed for phased growth times.

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MgO를 첨가한 에폭시 나노 컴퍼지트의 절연파괴강도 온도의존성 (Temperature Dependence on dielectric breakdown strength of Epoxy Nano-Composites depending on MgO)

  • 정인범;한현석;이영상;조경순;신종열;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.48-48
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    • 2010
  • In this paper, we have investigated temperature dependence of dielectric breakdown voltage at epoxy with added nano-filler(MgO), which is used as a filler of epoxy additives for HVDC(high voltage direct current) submarine cable insulating material with high thermal conductivity and restraining tree to improve electrical properties of epoxy resin in high temperature region. In order to find dispersion of the specimen, the cross sectional area of nano-composite material is observed by using the SEM(Scanning Electron Microscope) and it is conformed that each specimen is evenly distributed without the cohesion. As a result, it is confirmed that the strength of breakdown of all specimen at 50 [$^{\circ}C$] decreased more than that of the dielectric breakdown strength at room temperature. When temperature increases from 50 [$^{\circ}C$] to 100 [$^{\circ}C$], we have confirmed that breakdown strength of virgin specimen decreases, but specimens with added MgO show constant dielectric breakdown strength.

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층상 실리케이트 첨가에 따른 HDPF/$Mg(OH)_2$/Clay 나노복합재의 특성연구 (Effect of Layered Silicates on Flame retardant and Mechanical Properties of HDPF/$Mg(OH)_2$/Clay Nanocomposites)

  • 민경대;이경용;이호림;김도영;강승훈
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.260-260
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    • 2010
  • In recent years, polymer/clay nanocomposites have generated a great interest, both in industry and in academia, because they often exhibit remarkable improvement in material properties when compared with the virgin polymer or conventional micro and macro-composites. Among these properties are stiffness, strength, dimensional stability and permeability. [1-3] The dispersion of hydrophilic silicates in a hydrophobic matrix like Polyethylene (PE) is difficult because of the difference in character between PE and Montmorillonite (MMT). Therefore, it is necessary to modify PE with polar groups, which can increase the hydrophilicity of PE. In this study, High density polyethylene (HDPE)/$Mg(OH)_2$/Montmorillonite (MMT) nanocomposites having a various compositions were prepared by a melt blending technique with an internal mixer and properties namely mechanical, morpology, rheological and thermal properties were investigated

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$Fe^{3+}$ 환원제로서 흑설탕이 $LiFePO_4$ 합성 및 특성에 미치는 영향 (Effect of Black Sugar as a Reducing Agent of $Fe^{3+}$ on the Synthesis and Properties of $LiFePO_4$)

  • 김우현;이민우;강찬형
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.248-248
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    • 2010
  • 리튬이온 2차전지의 대체 양극 후보 물질인 $LiFePO_4$를 합성하기 위하여 출발원료로 $Li_2CO_3$, $Fe_2O_3$, $NH_4H_2PO_4$를 사용하여 볼밀 방법으로 혼합 분쇄한 후 열처리를 실시하였다. 합성 시에 3가 Fe를 2가로 환원시키기 위하여 $C_{12}H_{22}O_{11}$(흑설탕)을 출발원료와 함께 5 ~ 12 wt%로 나눠서 첨가하였다. 합성 후 XRD로 결정구조의 양질성을 확인하였고. FE-SEM으로 나노미터 크기의 구형 입자를 관찰하였다. XRF를 이용하여 3 ~ 10 wt%의 탄소 잔량을 확인하였다. 전기화학적 특성을 충 방전시험기로 평가한 결과, 8wt%의 탄소원을 첨가한 $LiFePO_4$에서 가장 좋은 수명 특성을 얻었고, 최대 145 mAh/g의 방전용량을 얻었다.

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ITO/CNT 나노 복합체의 염료감응형 태양전지의 이용 (ITO/CNT Nano Composites as a Counter Electrode for the Dye-Sensitized Solar Cell Applications)

  • 박종현;;정현준;조태연;윤순길
    • 한국전기전자재료학회논문지
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    • 제24권1호
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    • pp.76-80
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    • 2011
  • The ITO/Cabon Nano Tube (CNT) nano composites were deposited by nano cluster deposition (ITO) and arc discharge deposition (CNT) on glass substrates. The structural, optical and photovoltaic performance of ITO/CNT nano composites as a counter electrode of dye-sensitized solar-cells (DSSCs) such films were investigated. At low temperature below $250^{\circ}C$, the ITO films deposited on CNT. The ITO/CNT nano composit showed a good optical and electrical property for the counter electrode of DSSCs. When the as-prepared ITO/CNT nano composites are used for the counter electrodes, the photovoltaic parameters are $V_{OC}$ = 0.69 V, $J_{SC}$ = 5.69 mA/$cm^2$, FF = 0.32, and $\eta$ = 0.53 %. The ITO/CNT nano composites showed the possibility for the counter electrode applications of DSSCs.

빔의 입사모드가 금 나노입자의 국소표면플라즈몬 산란광에 미치는 영향 (Effects of Light Incident Mode on Optical Scattering of Au Nanoparticle by Localized Surface Plasmon Resonance)

  • 이택성;이경석;김원목;이장교;변석주
    • 한국전기전자재료학회논문지
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    • 제22권4호
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    • pp.307-313
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    • 2009
  • Quantitative analysis of optical scattering intensities from a Au nanoparticle with a diameter of 100 nm, which is effected by the localized surface plasmon resonance (LSPR), were numerically carried out by using a dark-field detection scheme on prism basal plane for two different beam incident modes of reflectance (R-mode) and transmittance (T-mode). Two-dimensional finite difference time domain (FDTD) algorithm was adopted, and its applicabilibility was verified by comparing the simulation results with the theoretical ones. Simulation results of the scattered light intensities from a Au nanoparticle revealed that the scattered intensity of the T-mode was much stronger than that of R-mode. Comparison of the calculated results with the theoretical intensity distribution on the prism showed that the scattered intensity is marimized when the evanescent field, which is generated from the interface of prism and air at TIR angle, is coupled with Au nanoparticle.