• Journal of the Korean Chemical Society
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• v.52 no.6
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• pp.601-607
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• 2008

• Journal of the Korean Chemical Society
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• v.51 no.4
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• pp.312-317
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• 2007

Performing random number simulations, we approximated that the distribution of the number of ways for arranging molecules randomly on a lattice is a normal distributon for N12, the number of interactions between the nearest neighbors of different molecules. From this distribution, an approximate equation of the excess Gibbs energy GE for a lattice solution of nonrandom mixing was derived. Using the equation, liquid-vapor equilibria of several binary solutions were calculated and compared with the calculated result of other equations.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.663-670
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• 2009

Performing random number simulations, we obtained an approximate distribution of the number of ways arranging molecules in a binary lattice solution of nonrandom mixing with a specific interaction. From the distribution an approximate equation of excess Gibbs energy for a binary lattice solution was derived. Using the equation, liquid-vapor equilibrium at constant pressure for 15 binary solutions were calculated and compared with the result from Wilson equation, Van Laar equation and Redlich-Kister equation.

• Journal of the Mineralogical Society of Korea
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• v.21 no.4
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• pp.415-423
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• 2008

Earth outer core is composed of iron mainly with some diluent elements, which account for the observed ca. 10% density deficit compared to the pure iron. Among candidates as the light diluents, hydrogen and oxygen were selected, and the thermodynamic stability of the following reaction was calculated; hematite + hydrogen $\to$ goethite + iron. At ambient conditions, Gibb's free energy of this reaction is 12.62 kJ/mol. On increasing pressure at room temperature, it decreases to zero at 0.068 GPa. This energy decreases at constant rate down to 200 GPa, which shows -208.26 kJ/mol at that pressure. From these results, this chemical reaction prefers the reduction environment forming the iron element and iron oxyhydroxide, so possible presence of iron oxyhydroxide with iron at proto-core can not be ruled out.

• Geophysics and Geophysical Exploration
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• v.26 no.4
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• pp.157-170
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• 2023

In South Korea, carbon capture and storage (CCS) techniques have attracted considerable attention as part of efforts to achieve the 2030 Korean Nationally Determined Contribution. However, owing to delays in large-scale CCS projects in South Korea, interest in cross-border CCS projects, wherein CO₂ captured in South Korea is stored in overseas CCS facilities, has increased. In this study, we investigated the development status of the CarbonNet project in the Gippsland Basin, Australia. First, we provide a brief overview of sedimentary basins and CCS projects in Australia. Subsequently, we review the geological history of the Gippsland Basin, the site of the large-scale CCS project. Finally, we summarize the site selection process for the CarbonNet project and discuss the suitability of the Pelican site for large-scale CCS projects.

• Investigative Magnetic Resonance Imaging
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• v.2 no.1
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• pp.58-66
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• 1998

Purpose : This paper introduces a new three dimensional magnetic Resonance Image classification which is based on Mar kov Random Field-Gibbs Random Field with a line model. Material and Methods : The performance of the Gibbs Classifier over a statistically heterogeneous image can be improved if the local stationary regions in the image are disassociated from each other through the mechanism of the interaction parameters defined at the local neighborhood level. This usually involves the construction of a line model for the image. In this paper we construct a line model for multisignature images based on the differential of the image which can provide an a priori estimate of the unobservable line field, which may lie in regions with significantly different statistics. the line model estimated from the original image data can in turn be used to alter the values of the interaction parameters of the Gibbs Classifier. Results : MRF-Gibbs classifier for volumetric MR images is developed under the condition that the domain of the image classification is $E^{3}$ space rather thatn the conventional $E^{2}$ space. Compared to context free classification, MRF-Gibbs classifier performed better in homogeneous and along boundaries since contextual information is used during the classification. Conclusion : We construct a line model for multisignature, multidimensional image and derive the interaction parameter for determining the energy function of MRF-Gibbs classifier.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.70.2-70.2
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• 2010

고순도 금속규소는 반도체, 태양전지 및 규소화 화합물 등의 원료로 사용되어왔으며, 최근 태양전지 시장 확대로 인해 고순도 금속규소의 수요가 증가하고 있다. 그러나 전량 수입 중인 고순도 금속규소의 수급 안정성과 품질 균일성 등이 문제가 되고 있어, 고순도 생산 공정 및 생산 에너지를 절감 공정에 관한 연구 개발이 필요한 실정이다. 이에 본 연구에서는 금속규소의 원료인 규석(SiO2)과 카본(C)의 환원반응을 온도와 압력별로 살펴보고, 평형 상태의 금속규소수율 조건을 알아보았다. 그리고 아크로 내부 위치에 따른 산화/환원 반응식을 고찰하여 주요 반응식의 깁스 자유 에너지를 비교 분석 하였다. 본 해석을 통한 실험용 아크로 제작과 기초실험을 통해 금속 규소 생산 수율 및 순도를 평가하였으며, 생산된 실리콘의 최대 순도는 약 99.8%로 측정되었다.

• Journal of the Korean Chemical Society
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• v.53 no.5
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• pp.585-608
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• 2009

The aim of this study was to research the characteristics of science teachers' thinking related to dissolution and diffusion. For this study, five science teachers who majored in chemistry or chemistry education were selected and interviewed. These teachers have been teaching on average for 2$\sim$6 years. From the study, it was discovered that the science teachers didn't recognize the necessity of sorting out diffusion from dissolution. The teachers divided in various mixing phenomena with diverse criteria. The science teachers had difficulty in sorting out diffusion from dissolution based on solubility and Gibbs' energy. The teachers didn't see the linkage between the contents that were divided into chapters, and didn't find omitted contents themselves in the chapters that introduced applicable principles. During the interviews, the teachers felt the need to understand the principles for understanding phenomena. But they did not have the ability to teach these principles after learning about the principles themselves. Therefore, it is necessary to develop teacher education programs, as well as a science curriculum, that helps in linking the knowledge between natural phenomena and principles.

• Proceedings of the KIPE Conference
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• 2015.07a
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• pp.381-382
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• 2015

배터리의 열역학적 인자, 즉, 엔탈피, 엔트로피, 깁스 자유 에너지는 배터리의 상태인 SOH (State Of Health)를 추정하는 데 있어서 매우 밀접한 관련이 있으며, 정밀한 측정을 필요로 한다. 이러한 열역학적 인자 중 엔트로피의 측정이 중요한데 ETM (Electrochemical thermodynamics measurements) 방법이 대표적으로 사용되고 있다. 본 논문에서는 기존 ETM 방법을 설명하고, 이를 보완한 새로운 엔트로피 측정 방법을 제안하며, 실험을 통해 유효성을 입증한다.

• Journal of the Korean Applied Science and Technology
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• v.31 no.4
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• pp.602-611
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• 2014

The critical micelle concentration (CMC) of the zwitterionic surfactant of dodecyldimethyl(3-sulfopropyl)ammonium hydroxide(LSB, $CH_3(CH_2)_{11}N^+(CH_3)_2(CH_2)_3SO{_3}^-$) and LSB/Tween-20, LSB/Tween-40, LSB/Tween-80 and LSB/DTAB, LSB/TTAB, LSB/CTAB mixed surfactant systems were determined by using the UV/Vis absorbance method from 284 K to 312 K. And the effects of temperature on the micellization have been measured for the thermodynamic study. The results show that the measured values of gibbs free energy are all negative in the whole measured. The values of enthalpy are positive Tween-20, And negative other surfactants. but the values of entropy are positive in the whole measured temperature region. The results show that all of the thermodynamic parameters are dependent on temperature and alkyl-group's length.