• Title/Summary/Keyword: 김남석

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Photoisomerization of Mixture LB Films of Fatty Acid and Phospholipid(DOPC) (지방산과 인지질(DOPC)의 혼합 LB막의 광이성질화 현상에 관한 연구)

  • Park, Keun-Ho;Shim, Kyoung-Jea;Kim, Nam-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.1
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    • pp.43-48
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    • 2002
  • We carried out this subject to observe photoisomerization using 1,2-dioleoyl-sn- glycero-3-phosphocholine(DOPC) mixed with fatty acid containing azobenzene group which has reversible to cis-trans by light irradiation. Spreading solutions for the LB films were prepared in chloroform($5.0{\times}10^{-5}$mol/L).We investigated the photoisomerization and property of the organic ultra thin film of fatty acid containing azobenzene was prepared on the hydrophilic ITO(idium tin oxide) glass plate by LB method. As a result, the absorption spectra of 8A5H and DOPC of mixture LB films was induced to photoisomerization by alternating irradiation of ultraviolet and visible light, because the condensation of pure azobenzene monolayers was loosened by the introduction of phospholipid into the monolayers, and the molecular high aggregation in pure azobenzene monolayers is also weakened by the introduction of phospholipid. We found that it was reversibly induced to cis-trans photoisomerization in several solvents and mixture LB films.

Synthesis of Inorganic/Organic Core-Shell Polymer (무기/유기 Core-Shell 에멀젼 고분자의 합성)

  • Kim, Nam-Seok;Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.4
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    • pp.265-272
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    • 2002
  • $CaCO_{3}$ absorbed sodium lauryl sulfate (SLS) surfactant was prepared, Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using styrene(St) as a shell monomer and potasium persulfate (KPS) as an initiator, We found that when $CaCO_{3}$; core prepared by adding 2,0 wt% SLS, $CaCO_{3}$ core/PSt shell polymerization was carried out on the surface of $CaCO_{3}$ particle without forming the new PSt particle during St shell polymerization in the inorganic/organic core-shell polymer preparation, The structure of core-shell polymer were investigated by measuring the degree of decomposition of $CaCO_{3}$ using HCl solution, thermal decomposition of polymer composite using thermogravimetric analyzer and morphology by scanning electron microscope.

Experimental Investigation about Optimum Smoke Extraction System for Underground Station (축소 모형 실험을 통한 정거장내 적정 배연방식에 관한 연구)

  • Lee, Ho-Keun;Kim, Myoung-Woo;Lee, Phill-Young;Kim, Nam-Suk
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.4
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    • pp.53-59
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    • 2008
  • If fire is occurred in the subway, the train must be moved to the closest station and make passengers get off the train. As a matter of fact, the Fire of Dae-gu Subway was coped with this way. But, the fire smoke extraction system of real subway stations have not designed to deal with fire of trains yet. Therefore, we have to establish a plan of station railroad for preventing from unexpected damage when the fired train comes to the station. The purpose of this study is to establish the effective smoke extraction measure that is to prevent stations from damage by the scale-down experiment.

The collection and preservation of national literature (국가문헌의 수집과 보존)

  • 김남석
    • Journal of Korean Library and Information Science Society
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    • v.15
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    • pp.79-111
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    • 1988
  • The purpose of this study has its meaning to indicate the direction on collection and preservation of national literature which is one of the must important functions of the Central National Library. The Central National Library is, however, a representative library of our country and collect every kind of literature and to meet the requests of its users, the present situation of The Central National Library can't be performed sufficiently on these actions. According to studies of this paper, it have suggested the following five methods as a method of collecting national literature. First, the method by registering copyright endowing the number of copyright like ISBN. Second, the method a n.0, pplied by revising and su n.0, pplementing present legal deposit system. Thirdly, the method that the central one institution secure national budget collect literature of nation i.e., central intensive collection one. Fouthly , method of collecting literature by partial charge through local library networks. Fifthly, method by subject intensive collecting. As the preserving method of national literature, this research has indicated the following two ways. First, to keep the literatures forever, the method of The Central National Library keeps records as a limited volume. Second, The method of dispersing records as the local libraries. To put these methods into practice, it must be preceded that not only national helps, budget secures are needed but special committee must be organized to keep and preserve national literatures and material range also be extended and bibliographies for information data issuing must be worked out.

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A Study on the Unstable behavior according to Lode and boundary condition of shelled space frame structure (쉘형 스페이스 프레임 구조물의 하중 및 경계조건에 따른 불안정 거동에 관한 연구)

  • Kim, Nam-Seok;Shon, Su-Deog;Kim, Seung-Deog
    • Proceeding of KASS Symposium
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    • 2008.05a
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    • pp.80-85
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    • 2008
  • This paper investigate the structure instability properties of the shelled space frame structure. The large structure must have thin thickness for build the large space structure there fore structure instability review is important when we do structural design. The structure instability of the shelled structure accept it sensitively by varied conditions. This come to a nonlinear problem with be concomitant large deformation. In this study, it is compared unstable behavior according to lode and boundary condition of the shelled space frame structure through numerical method which considered geometrical nonlinear and grasped influence for the instability phenomenon and investigated the fundamental collapse mechanism.

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Dissolution Phenomenon in BaO-B2O3-ZnO Glass System by Acid Etching (산 에칭에 의한 BaO-B2O3-ZnO계 유리조성물의 용출 현상)

  • Kim, Jae-Myung;Hong, Kyung-Jun;Kim, Nam-Suk;Kim, Hyung-Sun
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.33-37
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    • 2006
  • For producing the fine ribs structure of plasma display panel, the metal ions of barrier materials during the etching process should be understood on the etching mechanism with etching conditions. Etching was done on bulk glasses of the $BaO_B_2O_3-ZnO$ system with $HNO_3$ solution at $40^{\circ}C$. The surface structure of glasses and ion dissolution were analyzed by ICP (Inductive Coupled Plasma measurement). The structure and surface of the etched bulk glass were investigated by using scanning electron microscopy and nanoindenter. As a result, Ba (3-35 ppm/min) and Zn (2-27 ppm/min) ions as major components were leached in the solution and the leached layers were found to be phosphor-rich surface layers. A decrease of the bridge oxygen and relative increase of non bridge oxygen in the etched glass were found by X-ray photoelectron spectroscopy.

Electrochemical Properties and Photoisomerization of DOPC-8A5H Mixture Langmuir-Blogett Films (인지질(DOPC)과 지방산(8A5H)의 혼합 LB막의 광이성질화 현상과 전기화학적 특성)

  • Park, Keun-Ho;Choi, Sung-Hyun;Kim, Nam-Seok;Kim, Duck-Sool
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.874-877
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    • 2004
  • We carried out this subject to observe electrochemical properties of 1,2-dioleoyl-sn- glycero-3-phosphocholine(DOPC) mixed with fatty acid containing azobenzene group by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution. We investigated the photoisomerization and electrochemical property of the organic ultra thin film of fatty acid containing azobenzene was prepared on the hydrophilic ITO(idium tin oxide) glass plate by LB method. As a result, the absorption spectra of BASH and DOPC of mixture LB films was induced to photoisomerization by alternating irradiation of ultraviolet and visible light. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of BASH-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.

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A study on the Accurate Comparison of Nonlinear Solution Which Used Tangent Stiffness Equation and Nonlinear Stiffness Equation (접선 강성방정식과 비선형 강성방정식을 이용한 비선형 해의 정확성 비교에 관한 연구)

  • Kim, Seung-Deog;Kim, Nam-Seok
    • Journal of Korean Association for Spatial Structures
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    • v.10 no.2
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    • pp.95-103
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    • 2010
  • This paper study on the accuracy improvement of nonlinear stiffness equation. The large structure must have thin thickness for build the large space structure there fore structure instability review is important when we do structural design. The structure instability of the shelled structure is accept it sensitively by varied conditions. This come to a nonlinear problem with be concomitant large deformation. Accuracy of nonlinear stiffness equation must improve to examine structure instability. In this study, space truss is analysis model Among tangent stiffness equation and nonlinear stiffness equation is using nonlinearity analysis program. The study compares an analysis result to investigate accuracy and convergence properties improvement of nonlinear stiffness equation.

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A Study on the Human body Model shocked Electric installation in Underwater (수중에서의 인체에 가해지는 전기적 현상에 관한 연구)

  • Woo, J.H.;Park, H.Y.;Song, W.C.;Kim, N.S.
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1338-1339
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    • 2008
  • In this paper, charging part by basic from Andrew's body model research to second a danger have affect on remaining and rehabilitation humans in space under water. The construction of a circuit make to Andrew's body model. It compare that voltages measure a hand, a breast, a groin and electric currents measure an arm, a breast, a leg with safety a limit of body through an electric current. Out of result, it research that magnitude and wave of body passing an electric current give the effect to the heart control a signal and it have affect on direct the ventricle of the heart in detail motion. A thing of this sort get through to the simulation by the ATP-Draw program. The results from above, it is publish one's research work with safety a limit electric angle take measurement of resistance a body in under water and to the voltage and electric current passing each parts.

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A Study on Thermal Characteristics on Polymeric Floorings (고분자물질 바닥재의 열적특성에 관한 연구)

  • Lee, Nae-Woo;Kim, Nam-Seok;Moon, Byoung-Soo
    • Journal of the Korean Society of Safety
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    • v.21 no.6 s.78
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    • pp.38-45
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    • 2006
  • Polymeric floorings mainly consisted of PVC are easily decomposed by many kinds of hot environmental factors, then generate hazardous asphyxiate gases and/or toxic gases etc. Therefore the mechanism of decomposition and quantitative toxic indices of products are very important for preventing safety and health disasters, especially in case of confined area. So we have investigated decomposition kinetics, numbers of process involved, toxicity indices of product and so on, using DSC, TGA, FT-IR and Pyrolyzer-GC/MS. The thermal decomposition process of polymeric floorings can be mainly divided by dehydrochlorinated reaction and polyene decomposition step, and activation energies of those are approximately $53.93{\sim}62.42kcal/mol$. Especially lethal concentration($LC_{50}$), fractional effective dose (FED) are calculated by measuring the amount of decomposition product. The values on $LC_{50}$ of sample G are ranged $2,003{\sim}2,019(mg/m^{3})$ in case of sample K and H are $1,877,\;1,998(g/m^{3})$ respectively. Even if the results are estimated by calculation method without animal test and/or clinical demonstration, these values could be very useful data for occupational health, hygiene and safety control.