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Burning Characteristics of Nitramine Propellant Embedded with Metal Wires (금속선을 삽입한 니트라민계 추진제의 연소특성)

  • 유지창
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.4
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    • pp.50-58
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    • 2000
  • Burning rate of the matrix propellant($r_{sb}$) and burning rate along the metal wire($r_w$) were measured and analyzed for the HTPB/AP/Al propellant embedded with Ag wire($\phi$0.15mm) according to weight % of RDX(0~20%). Variation of burning rate increment ratio($r_w$/$r_{sb}$) and pressure exponent(n) was studied for the nitramine propellant having 10% RDX embedded with three kinds of metal(Ag, Cu, and Ni-Cr) of which diameter range is between 0.1~0.6mm. Maximum burning rate increment ratio of the nitramine propellant embedded with Ag wire($\phi$0.1mm) was 5.94 at $20^{\cire}C$, 1000 psia, 16.4% faster than that of HTPB/AP propellant, it is because that autoignition temperature of the nitramine propellant was higher than that of HTPB/AP propellant. Standard deviation of absolute ($r_{wc}$/$r_{we}$)/$r_{we}$ calculated by using new empiracal equation composed of four dimensionless groups, is 6.11% less than that calculated by using original empirical equation composed of three dimensionless group. The new empiracal equation is derived from Buckingham pi theorem using the parameters such as thermal diffusivity, melting temperature. wire diameter, propellant sample diameter, frame temperature, autoignition temperature and matrix burning rate which influence on $r_w$.

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Results of Cold Flow Test and Design of Injectors for Oxidizer-rich Preburner (산화제 과잉 예연소기용 분사기 설계 및 수류 시험 결과)

  • So, YoonSeok;Woo, SeongPil;Lee, Kwang-Jin;Yu, ByungIl;Kim, Jinhyung;Cho, Hwangrae;Bang, Jeongsuk;Han, YeongMin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.1
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    • pp.52-57
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    • 2018
  • This paper presents the design and cold flow test results of oxidizer-rich preburner injectors for a 9 tonf-class staged combustion engine cycle. Three types of coaxial swirl injectors were designed, and 12 injectors were designed for each type. The diameters of the fuel tangential holes are identical. The diameters of the oxidizer tangential holes were varied to investigate the influence of combustion in the oxidizer-rich preburner according to the momentum ratio of the gas oxidizer generated from combustion in the injector chamber and liquid oxidizer through the cooling channel. It will be verified through a powerpack and combustion test using an oxidizer-rich preburner. In the cold flow test, the fuel flow rate and oxidizer tangential hole flow rate reached the target value based on the designed differential pressure.

Synthesis of Dendritic Polystyrene-block-Linear Poly(t-butyl acrylate) Copolymers by an Amide Coupling (아미드 커플링을 통한 덴드리틱 Polystyrene-Block-Linear Poly(t-butyl acrylate) 공중합체의 합성)

  • Song, Jie;Cho, Byoung-Ki
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.158-163
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    • 2009
  • In this study, we synthesized a series of dendritic polystyrene-b-linear poly (t-butyl acrylate) copolymers with well-defined molecular architectures. The hydroxyl group located at the focal point of the second generation dendron bearing polystyrene ($M_n$ = 1000 g/mol) peripheries was converted into amine group via the following stepwise reactions: 1) tosylatoin, 2) azidation, and 3) reduction. On the other hand, the linear poly (t-butyl acrylate)s were prepared by an atom transfer radical polymerization (ATRP) of t-butyl acrylate where benzyl 2-bromopropanoate and Cu(I)Br/PMDETA were used as initiator and catalyst, respectively. To convert the end group of prepared poly (t-butyl acrylate) s into carboxylic acid, a debenzylation was performed using Pd/C catalyst under $H_2$ atmosphere. In the final step, dendritic-linear block copolymers were obtained through a simple amide coupling reaction mediated by 4-(dimethylamino) pyridine(DMAP) and N,N'-diisopropylcarbodiimide(DIPC). The resulting diblock copolymers were shown to have well-defined molecular weights and narrow molecular weight distributions as supported by $^1H$-NMR spectroscopy and gel permeation chromatography(GPC).

Processing and MAP(modified atmosphere packaging) Storage of Fresh-cut Apples using CA Stored Apples (CA저장 사과를 이용한 Fresh-cut Apple의 제조 및 MAP저장)

  • 정헌식;문광덕;최종욱
    • Food Science and Preservation
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    • v.6 no.4
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    • pp.351-356
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    • 1999
  • To develop and extend the shelf-life of vitamin C enriched fresh-cut apples using CA stored Fuji apples, dipping in 10% L-ascorbic acid and packaging with 0.03 mm LDPE, 0.04 mm PP and 0.08 mm Nylon/PE film(N$_2$displacement) were carried out. The changes of gas concentrations in the packaging and quality attributes of fresh-cut apples were examined during storage at 10$^{\circ}C$. The concentrations of O$_2$was maintained lower in Nylon/PE film than the other film, the level of O$_2$was in the range of 1∼3%. The increase of C$_2$H$_4$ concentrations in Nylon/PE film bag was more suppressed than the others. The vitamin C content of fresh-cut apples was enriched by dipping in L-ascorbic acid solution up to 241 mg$.$100 g-1 f.w., and the loss or that content was retarded differently by the package conditions of lower O$_2$level during storage. Browning in fresh-cut apples was shown after 6 days of storage in LDPE and PP film. but it was not shown by 14 days of storage in Nylon/PE film. Spoilage and off odor in fresh-cut apples were not detected up to 14 days of storage in Nylon/PE film. The results indicated that the vitamin C enriched fresh-cut apples can be processed from the long-term CA stored apples, and maintaining high quality of the products ill be possible in cases of the application of sealing packaging after O$_2$removal with film having low O$_2$permeability.

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A Study on the Thermal Flow of Waste Heat Recovery Unit (WHRU) for Ship's Organic Rankine Cycle Power Generation System using CFD Method (CFD를 활용한 선박고온도차발전용 WHRU의 열유동 해석에 관한 연구)

  • Whang, Dae-jung;Park, Sang-kyun;Jee, Jae-hoon;Bang, Eun-shin;Oh, Cheol
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.5
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    • pp.647-655
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    • 2021
  • The IMO (International Maritime Organization) is discussing the improvement of energy ef iciency of ships in order to reduce greenhouse gas emissions from ships. Currently, by applying an ORC power generation system using waste heat generated from ships, high energy conversion efficiency can be expected from ships. This technology uses an organic medium based on Freon or hydrocarbons as the working fluid, which evaporates at a lower temperature range than water. Through this, it is possible to generate steam (gas) and generate power at a low and low temperature relatively. In this study, the analysis of heat flow between the refrigerant and waste heat in the ORC power generation system, which is an organic Rankine cycle, is analyzed using 3D simulation techniques to determine the temperature change, velocity change, pressure change, and mass change of the fluid flowing of the WHRU (Waste Heat Recovery Unit) inside and the outside the structure. The purpose of this study is to analyze how the mass change affects the structure, and this study analyzed the heat transfer of the heat exchanger from the refrigerant and the exhaust gas of the ship's main engine in the ORC power generation system using this technique.

Development of Primary Reference Gas Mixtures for Liquid Propane (혼합 액체 프로판 표준가스 개발)

  • Jeong, Yun-sung;Kim, Jin-seog;Bae, Hyun-kil;Kang, Ji-hwan;Lee, Seung-ho;Kim, Yong-doo
    • Journal of the Korean Institute of Gas
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    • v.25 no.4
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    • pp.49-56
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    • 2021
  • Liquefied Petroleum Gas is divided into liquefied gases containing propane (C3H8) and butane (C4H10). The quality of LPG varies greatly depending on the composition of the mixture, so it is important to measure the composition accurately. It is difficult to determine the composition of the mixture because liquid and gas coexist at room temperature. Therefore, the uncertainty in determining the concentration of hydrocarbons by component is high, and there are many problems that differ from the actual content standard. Therefore, it is necessary to develop a mixed liquid propane standard gas for the composition and accurate concentration of hydrocarbon substances. Mixed liquid propane standard gas is manufactured into bellows-type constant-pressure cylinders by ISO-6142 (2015). The homogeneity of the four standard gases manufactured was confirmed to be GC-FID. The manufacturer's uncertainty of expansion was 0.01 % to 0.30 % and homogeneity was 0.03 % to 0.25 %. In this mixed liquid propane standard gas, the relative expansion uncertainty of weight method, manufacturing consistency, cylinder adsorption and long-term stability was developed within 0.26 %-1.3 9% (95% of confidence level, k=2).

Optimal Design Standard and Application of Low Cost, High Performance Scrubber for Absorbing Hazardous Gas (유해가스 흡수처리를 위한 저비용 고효율 스크러버의 최적 설계기준 및 현장적용 방안)

  • Jung, Ga-Young;Lim, Kyung-Min;Ma, Byung-Chol
    • Journal of the Korean Institute of Gas
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    • v.25 no.3
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    • pp.39-45
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    • 2021
  • Scrubbers that treat hazardous materials at workplaces have high treatment efficiency; however, the design is complex, and pumps need to be operated 24 hours a day, which can be costly. Therefore, to minimize the operating costs, small businesses do not install scrubbers, or operate them while circulation pumps are suspended. Hence, this study investigated the application of low-cost, high-performance scrubbers that can be used economically in small businesses. Low-cost, high-efficiency scrubbers are applied to bubble columns to utilize devices for hazardous chemical absorption treatment purposes, and for the development of these scrubbers, absorption performance was reviewed and the optimal application method was studied under certain conditions. The changes in the absorption performance of hazardous gas were studied in certain environments by varying the physical conditions, and the optimal application methods were analyzed. The results showed that, while it was possible to treat some of the gas flowing into the low cost, high performance scrubber, the treatment capacity was reduced. Performance degradation was prevented by supplying an absorption liquid, and a certain level of absorption was maintained depending on the amount of circulation. Based on this, three types of site application methods of low cost, high performance scrubbers were presented. In addition, the appropriate timing of circulation and anti freezing measures were also discussed.

Fast Pyrolysis Characteristics of Jatropha Curcas L. Seed Cake with Respect to Cone Angle of Spouted Bed Reactor (분사층 반응기의 원뿔각에 따른 Jatropha Curcas L. Seed Cake의 급속열분해 특성)

  • Park, Hoon Chae;Lee, Byeong-Kyu;Kim, Hyo Sung;Choi, Hang Seok
    • Clean Technology
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    • v.25 no.2
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    • pp.161-167
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    • 2019
  • Several types of reactors have been used during the past decade to perform fast pyrolysis of biomass. Among the developed fast pyrolysis reactors, fluidized bed reactors have been widely used in the fast pyrolysis process. In recent years, experimental studies have been conducted on the characteristics of biomass fast pyrolysis in a spouted bed reactor. The fluidization characteristics of a spouted bed reactor are influenced by particle properties, fluid jet velocity, and the structure of the core and annulus. The geometry of the spouted bed reactor is the main factor determining the structure of the core and annulus. Accordingly, to optimize the design of a spouted bed reactor, it is necessary to study the pyrolysis characteristics of biomass. However, no detailed investigations have been made of the fast pyrolysis characteristics of biomass in accordance with the geometry of the spouted bed reactor. In this study, fast pyrolysis experiments using Jatropha curcas L. seed shell cake were conducted in a conical spouted bed reactor to study the effects of reaction temperature and reactor cone angle on the product yield and pyrolysis oil quality. The highest energy yield of pyrolysis oil obtained was 63.9% with a reaction temperature of $450^{\circ}C$ and reactor cone angle of $44^{\circ}$. The results showed that the reaction temperature and reactor cone angle affected the quality of the pyrolysis oil.

Bibliometric Analysis of Scientific Papers on Chemical Oceanography published in the Journal of the Korean Society of Oceanography (한국해양학회지에 출판된 화학해양학 분야 연구논문의 서지학적 분석)

  • KANG, DONG-JIN
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.24 no.3
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    • pp.457-474
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    • 2019
  • Since 1966 when the Journal of the Korean Society of Oceanography was founded, more than 1,200 scientific papers have been published. Among them, papers for the biological oceanography constitute the largest portion of 37%, followed by the physical oceanography with 25%, and then the geological oceanography with about 17%. Papers on the chemical oceanography (CO) accounts for about 20% with around 250 papers. The field of the chemical oceanography generally occupied more than 20% since the first issue, but it declined down to 10% from the 1980s to the 1990s, and has regained to more than 20% since the late 1990s. Most of the CO research sites were at Korean coastal area, and 1/3 of the papers were on the South Sea, 1/4 on the Yellow Sea and another 1/4 on the East Sea. Nearly 60% of the CO papers were on seawater studies and about 30% on sediment studies. The main topic of the CO research was nutrients, followed by metals, isotopes, environmental pollution, organic pollution, organic matter, and gases. Most of the first authors belonged to the university, but the Korea Institute of Ocean Science and Technology (including the whole body) was the affiliation with the single largest group of the first authors.

Effect of Postharvest CO2 Treatment and Packaging Materials on the Quality of 'Gonji-7ho' Oyster Mushroom (Pleurotus ostreatus) during Storage (수확후 CO2 처리 및 포장필름 종류가 '곤지-7호' 느타리버섯의 저장 중 품질에 미치는 영향)

  • Choi, Ji-Weon;Lee, Ji-Hyun;Kim, Chang-Kug;Shin, Il Sheob;Bae, Yeoung-Seuk
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2019.04a
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    • pp.108-108
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    • 2019
  • 느타리버섯은 전남 장흥군에서 병재배로 재배된 '곤지 7호' 느타리버섯 품종을 $3^{\circ}C$에서 1일간 냉각시킨 후 실험에 사용하였다. 이산화탄소 처리는 10mm 두께의 아크릴로 제작한 밀폐 챔버($40{\times}70{\times}40cm$)를 이용하여 CO2가스를 주입하여 내부의 CO2 농도를 $30{\pm}1%$로 조정하여 3시간 동안 밀폐시켰으며 $3^{\circ}C$ 저온 저장고에서 수행하였다. 처리 후 포장필름은 3처리로 하여 PVC랩, 재배농가에서 이용하는 필름인 $20{\mu}m$ OPP필름, $30{\mu}m$ OPP필름을 재료로 하여 산소투과율을 $5,000cc/m2{\cdot}day{\cdot}atm$로 조정한 필름(OPP5)을 사용하였다. PVC랩 처리는 스티로폼 트레이에 옮긴 후 균일하게 한 겹으로 둘렀고, OPP와 OPP5는 봉지에 옮겨 봉지 입구 4cm 안쪽을 비닐접착기로 열접착하여 밀봉하였으며 $3^{\circ}C$에 저장하면서 필름내부의 기체조성, 경도, 색도, 이취, 종합선도 변화를 조사하였다. 포장된 느타리버섯의 포장재 내 이산화탄소 농도는 저장초기 0.03%에서 점차 증가하여 저장 3일 후 PVC랩은 3.5~3.9%, 나머지 처리는 18%이상으로 증가하였으며 OPP필름보다 OPP5필름의 경우 포장재 내 이산화탄소 농도가 더 낮게 유지되었다. 생체중 감소는 PVC랩에서 저장 26일 후 9.9% 이하로 육안으로 보이는 시들음이 관찰되었으며 나머지 처리들은 저장 26일 후까지 1.6% 이하의 중량감소율을 보였다. 느타리버섯 갓 경도는 유지되었으며 줄기표면의 황색도 $b^*$값은 PVC랩에서는 증가 경향을, OPP나 OPP5에서는 유지 경향을 보였다. 느타리버섯의 이취 및 전체적인 품질은 무처리 후 PVC랩 포장은 저장 6일 후에 이취가 상품성 한계로 발생하였고 OPP5 포장은 포장재 중 가장 이취발생이 늦게 발생하였으며 CO2 처리에 의해 지연되는 것을 알 수 있었다. 이런 결과를 종합하여 느타리버섯의 $3^{\circ}C$ 저장 중 품질유지기간은 각 PVC랩(6일) ${\rightarrow}$ 30% CO2+PVC랩(7일) ${\rightarrow}$ OPP(10일) ${\rightarrow}$ 30% CO2+OPP(17일) ${\rightarrow}$ OPP5(20일) ${\rightarrow}$ 30% CO2+OPP5(22일)로 조사되었다. CO2처리 후 산소투과율을 $5,000cc/m2{\cdot}day{\cdot}atm$으로 조정한 미세천공(OPP5)필름이 가장 높은 전체적 품질점수를 나타내었으며 상대적으로 낮은 이취발생, 갈변과 갓무름이 적어 높은 점수를 얻는데 영향을 준 것으로 보인다.

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