• Journal of the Korean Geographical Society
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• v.43 no.1
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• pp.1-19
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• 2008

This study intends to clarify the characteristics and causes of current changes in wintertime precipitation in Korea and to predict the future directions based on surface observational $(1973/04\sim2006/07)$ and modeled (GFDL 2.1) climate data. Analyses of surface observation data demonstrate that without changes in the total amount of precipitation, snowfall in winter (November-April) has reduced by 4.3cm/decade over the $1973\sim2007$ period. Moreover, the frequency and intensity of snowfall have decreased; the duration of snow season has shortened; and the snow-to-rain day ratio (STDR) has decreased. These patterns indicate that the type of wintertime precipitation has changed from snow to rain in recent decades. The snow-to-rain change in winter is associated with the increases of air temperature (AT) over South Korea. Analyses of synoptic charts reveal that the warming pattern is associated with the formation of a positive pressure anomaly core over northeast Asia by a hemispheric positive winter Arctic Oscillation (AO) mode. Moreover, the differentiated warming of AT versus sea surface temperature (SST) under the high pressure anomaly core reduces the air-sea temperature gradient, and subsequently it increases the atmospheric stability above oceans, which is associated with less formation of snow cloud. Comparisons of modeled data between torrent $(1981\sim2000)$ and future $(2081\sim2100)$ periods suggest that the intensified warming with larger anthropogenic greenhouse gas emission in the $21^{st}$ century will amplify the magnitude of these changes. More reduction of snow impossible days as well as more abbreviation of snow seasons is predicted in the $21^{st}$ century.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.2
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• pp.207-217
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• 2016

Permeability can not be expressed as a function of porosity alone, it depends on the porosity, pore size and distribution, and tortuosity of pore channels in concrete. There has been considerable interest in the relationship between microstructure and transport in cementitious materials, however, it is very rare to deal with the theoretical study on gas permeability coefficient in connection with carbonation of concrete and the effect of volumetric fraction of cement paste or aggregate on the permeability coefficient. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on the permeability coefficient of concrete. In this study, fundamental approach to compute gas permeability of (non)carbonated concrete is suggested. For several compositions of cement pastes, the gas permeability coefficient was calculated with the analytical formulation, followed by a microstructure-based model. For carbonated concrete, reduced porosity was calculated and this was used for calculating the gas permeability coefficeint. As the result of calculation of gas permeability for carbonated concrete, carbonation leaded to the significant reduction of gas permeability coefficient and this was obvious for concrete with high w/c ratio. Meanwhile, the relationship between gas permeability and water permeability has a linear function for cement paste based on Klinkenberg effect, however, which is not effective for concrete. For the evidence of the modeling, YOON's test was accomplished and these results were compared to each other.

• Journal of Mushroom
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• v.16 no.3
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• pp.131-139
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• 2018

The king oyster mushroom (Pleurotus eryngii) is widely consumed because of its flavor, texture, and its functional properties such as antioxidant activity and prebiotic effects. However, long-term product storage and transportation (e.g., export) are difficult because of its limited durability. The shelf-life of king oyster mushroom is affected by environmental factors such as temperature, humidity, gas composition, and ventilation, which may affect sensory characteristics including respiration rate, texture, moisture, flavor, color, and pH. The major problems regarding storage of mushrooms are browning, flavor changes, and softening. To address these problems, novel preservation techniques were developed, and more durable variants were bred. Different drying methods, gamma irradiation, chitosan coating, modified atmosphere (MA) packaging, and controlled atmosphere (CA) storage were evaluated in order to extend the shelf-life of king oyster mushrooms. Freeze drying showed better results for the preservation of mushrooms than other drying methods. Irradiation with 1 kGy was more effective for extending mushroom shelf-life than higher doses. The preservative performance of chitosan-based films was improved by combining the compound with other hydrocolloids, such as oil, protocatechuic acid, and wax. The CA storage conditions recommended for king oyster mushrooms are 5kPa $O_2$ and 10 to 15kPa $CO_2$ at temperatures below $10^{\circ}C$. Active MA packaging with microperforated PP film was also effective for maintaining quality during storage.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.696-701
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• 2018

The nitrogen oxides generated during combustion reactions have a great influence on the generation of acid rain and fine dust. As an NOx reduction method, exhaust gas recirculation combustion using Coanda nozzles capable of recirculating a large amount of exhaust gas with a small amount of air has recently been utilized. In this study, for the burner outlet with dual end opening, the use of a recirculation burner was investigated for the distribution of the pressure, streamline, temperature, combustion reaction rate and nitrogen oxides using computational fluid analysis. The gas mixed with the combustion air and the recirculated exhaust gas flow in the tangential direction of the circular cylinder burner, so that there is a region with low pressure in the vicinity of the fuel nozzle exit. As a result, a reverse flow is formed in the central portion of the burner near the center of the circular cylinder burner and the exhaust gas is discharged to the outside region of the circular cylinder burner. The combustion reaction occurs on the right side of the burner and the temperature and NOx distribution are relatively higher than those on the left side of the burner. It was found that the average NOx production decreased from an air flow ratio of 1.0 to 1.5. When the air flow ratio is 1.8, the NOx production increases abruptly. It is considered that the NOx production reaction increases exponentially with temperature when the air ratio is more than 1.5 and the NOx production reaction rate increases rapidly on the right-hand side of the burner.

• Journal of the Korean Chemical Society
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• v.27 no.3
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• pp.183-188
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• 1983

The catalytic oxidation of $SO_2$ has been investigated in the presence of vacuum-activated 10 mol % Ni-doped ${\alpha}-Fe_2O_3$ under various partial pressures of $SO_2\;and\;O_2$ at temperatures from 320 to $440{\circ}C$. Over the temperature range $320{\sim}440{\circ}C$, the activation energy is 13.8 $kcal{\cdot}mol^{-1}$. The oxidation rates have been correlated with 1.5 order kinetics; first order with respect to $SO_2$ and 0.5 order with respect to $O_2$. From the kinetic data and conductivity measurements, the adsorption, oxidation mechanism of $SO_2$ and the defect structure of vacuum-activated 10 mol % Ni-doped {\alpha}-Fe_2O_3$ are suggested. $O_2\;and\;SO_2$ appear to be adsorbed essentially as ionic species. Two surface sites, probably an $O^{2-}$ lattice and an oxygen vacancy which is induced by Ni-doping, might be required to adsorb $SO_2\;and\;O_2$. The conductivity measurements and kinetic data indicate that the adsorption process of $SO_2\;{(SO_2+O^{2-}}_{(latt)}{\rightleftharpoons}{{SO_3}^-}_{(ads)}+e')$ is the rate-determining step.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.6
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• pp.625-631
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• 2014

In this study, according to increase of thermoelectric power plants that use LNG, LNG-FSRU(Floating-Storage and Regasification Unit) appeared and it is installed on the Topside in order to deliver in a gaseous state to consumers who are in the shore. This study about the study on the characteristics analysis of the system depending on changes in performance with the vaporization and temperature of the heat source. For the characteristics analysis of the system, we devided vaporization method into Ethylene glycol water vaporization method and sea water as a heat source. Then the system that can vaporize 200ton per hour of LNG of $-157.9^{\circ}C$ and 10,400kPa was configured, and according to the temperature of supplied sea water, required minimum flow rate value was calculated. Also in case of using Ethylene glycol Water as a vaporization method, providing for regional and seasonal factors such as decrease of temperature of water. The system is configured by adding a steam boiler of $174.5^{\circ}C$, 775kPa as heat source. The generation amount of the steam required according to the performance of the vaporizer compared to the water temperature changes in the steam boiler and the amount of required evaporative performance due to changes in the quantity of steam and Ethylene glycol Water was confirmed.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.7
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• pp.655-662
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• 2016

This study proposes that a diving supervisor, who can perform the role of both a field manager and a supervisor, be introduced in the national qualification system. The goal was achieved by surveying the general status of the commercial diving sector, including the statistics of an underwater construction company, commercial diving equipment operation condition, diver working hours, diver supply and demand status, and underwater construction market size. The national qualification and national competency standard (NCS) systems were also analyzed to deduce the role definition and work scope of the diving supervisor. Consequently, the following proposition is made: the diving supervisor should be an "on-site manager with the highest job skill in the commercial diving field, who can perform the on-site process management as well as guide, supervise, and educate project participants and serve as an intermediary between the contractor and the workers." The responsibilities of the diving supervisor are proposed to include "diving planning and operation of the diving team," "diving with surface-supplied air and mixed-gas diving system," "chamber operation," "underwater construction," and "ship salvage." The persistent issues in commercial diving sectors, such as diver career development, management, and worker supervision, are expected to be largely resolved with the introduction of this qualification.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.109-110
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• 2014

주사전자현미경(Scanning Electron Microscopy: SEM)은 고체상태에서 미세조직과 형상을 관찰하는 데에 가장 다양하게 쓰이는 분석기기로서 최근에 판매되고 있는 고분해능 SEM은 수 나노미터의 분해능을 가지고 있다. 그리고 SEM의 초점심도가 크기 때문에 3차원적인 영상의 관찰이 용이해서 곡면 혹은 울퉁불퉁한 표면의 영상을 육안으로 관찰하는 것처럼 보여준다. 활용도도 매우 다양해서 금속파면, 광물과 화석, 반도체 소자와 회로망의 품질검사, 고분자 및 유기물, 생체시료 nnnnnnnnn와 유가공 제품 등 모든 산업영역에 걸쳐 있다(Fig. 1). 입사된 전자빔이 시료의 원자와 탄성, 비탄성 충돌을 할 때 2차 전자(secondary electron)외에 후방산란전자(back scattered electron), X선, 음극형광 등이 발생하게 되는 이것을 통하여 topography (시료의 표면 형상), morphology(시료의 구성입자의 형상), composition(시료의 구성원소), crystallography (시료의 원자배열상태)등의 정보를 얻을 수 있다. SEM은 2차 전자를 이용하여 시료의 표면형상을 측정하고 그 외에는 SEM을 플랫폼으로 하여 EDS (Energy Dispersive X-ray Spectroscopy), WDS (Wave Dispersive X-ray Spectroscope), EPMA (Electron Probe X-ray Micro Analyzer), FIB (Focus Ion Beam), EBIC (Electron Beam Induced Current), EBSD (Electron Backscatter Diffraction), PBMS (Particle Beam Mass Spectrometer) 등의 많은 분석장치들이 SEM에 부가적으로 장착되어 다양한 시료의 측정이 이루어진다. 이 중 결정구조, 조성분석을 쉽고 효과적으로 할 수 있게 하는 X선 분석장치인 EDS를 SEM에 일체화시킨 장비와 EDS 및 PBMS를 SEM에 장착하여 반도체 공정 중 발생하는 나노입자의 형상, 성분, 크기분포를 측정하는 PCDS(Particle Characteristic Diagnosis System)에 대해 소개하고자 한다. - EDS와 통합된 SEM 시스템 기본적으로 SEM과 EDS는 상호보완적인 기능을 통하여 매우 밀접하게 사용되고 있으나 제조사와 기술적 근간의 차이로 인해 전혀 다른 방식으로 운영되고 있다. 일반적으로 SEM과 EDS는 별개의 시스템으로 스캔회로와 이미지 프로세싱 회로가 개별적으로 구현되어 있지만 로렌츠힘에 의해 발생하는 전자빔의 왜곡을 보정을 위해 EDS 시스템은 SEM 시스템과 연동되어 운영될 수 밖에 없다. 따라서, 각각의 시스템에서는 필요하지만 전체 시스템에서 보면 중복된 기능을 가지는 전자회로들이 존재하게 되고 이로 인해 SEM과 EDS에서 보는 시료의 이미지의 차이로 인한 측정오차가 발생한다(Fig. 2). EDS와 통합된 SEM 시스템은 중복된 기능인 스캔을 담당하는 scanning generation circuit과 이미지 프로세싱을 담당하는 FPGA circuit 및 응용프로그램을 SEM의 회로와 프로그램을 사용하게 함으로 SEM과 EDS가 보는 시료의 이미지가 정확히 일치함으로 이미지 캘리브레이션이 필요없고 측정오차가 제거된 EDS 측정이 가능하다. - PCDS 공정 중 발생하는 입자는 반도체 생산 수율에 가장 큰 영향을 끼치는 원인으로 파악되고 있으며, 생산수율을 저하시키는 원인 중 70% 가량이 이와 관련된 것으로 알려져 있다. 현재 반도체 공정 중이나 반도체 공정 장비에서 발생하는 입자는 제어가 되고 있지 않은 실정이며 대부분의 반도체 공정은 저압환경에서 이루어지기에 이 때 발생하는 입자를 제어하기 위해서는 저압환경에서 측정할 수 있는 측정시스템이 필요하다. 최근 국내에서는 CVD (Chemical Vapor Deposition) 시스템 내 파이프내벽에서의 오염입자 침착은 심각한 문제점으로 인식되고 있다(Fig. 3). PCDS (Particle Characteristic Diagnosis System)는 오염입자의 형상을 측정할 수 있는 SEM, 오염입자의 성분을 측정할 수 있는 EDS, 저압환경에서 기체에 포함된 입자를 빔 형태로 집속, 가속, 포화상태에 이르게 대전시켜 오염입자의 크기분포를 측정할 수 있는 PBMS가 일체화 되어 반도체 공정 중 발생하는 나노입자 대해 실시간으로 대처와 조치가 가능하게 한다.

• Polymer(Korea)
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• v.27 no.5
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• pp.464-469
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• 2003

In this work, the fragrant oil release behavior of poly($\varepsilon$-caprolactone) (PCL) microcapsules containing SiO$_2$ was investigated. The SiO$_2$ was chemically treated in 10, 20, and 30 wt% hydrochloric acid and sodium hydroxide. The acid and base values were determined by Boehm's titration technique and $N_2$/77 K adsorption isotherm characteristics, the specific surface area and total pore volume were studied by BET. The PCL microcapsules containing SiO$_2$ and fragrant oil were prepared by oil-in-water (o/w) emulsion solvent evaporation method. The shape and surface of PCL microcapsules were observed using image analyzer and scanning electron microscope (SEM). The fragrant oil release behavior of PCL microcapsules was characterized using UV/vis. spectra. The average diameters of PCL microcapsules were decreased from 35 to 21 $\mu$m with increasing stirring rate. It was found that in the case of acidic treatment the fragrant oil adsorption capacity and release rate were increased due to the increase of specific surface area and acid value. In the case of basic treatment, the fragrant oil adsorption capacity and release rate were decreased due to the decrease of sp ecific surface area and the increase of acid-base interactions between SiO$_2$-NaOH and fragrant oil with increasing base value of SiO$_2$.

• Membrane Journal
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• v.16 no.2
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• pp.115-122
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• 2006

In this study the membrane preparation and water vapor permeation of the hydrophilic polymer materials, polyaminosiloxane and polyhydroxylsiloxane, used as the coating materials for the preparation of asymmetric flat and hollow fiber membranes were investigated. And the water vapor permeation towards air permeation and their permselectivity were intensively studied for the resulting Resin A/Resin C (coupling agent) and Resin B/Resin C membranes. The water vapor permeability for 3 wt% Resin C introduced into Resin A (Resin A/Resin C) membrane was higher than for 1 and 5 wt% membranes and also water vapor permeability increased with increasing operating temperatures. In addition, at this content of 3 wt% Resin C, the absorption capability became maximum through dynamic equilibrium absorption experiment. Water vapor permeability, 43578 Barrer (1 Barrer = $10^{-10}cm^3(STP){\cdot}cm/cm^2{\cdot}s{\cdot}cmHg$) and 53000 Barrer, and the selectivity of $P(H_2O)P(Air)$, 101.3 and 102.6 were shown at 25 and $35^{\circ}C$, respectively.