• Title/Summary/Keyword: 기공 밀도

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고성능 전기화학 장치용 마이크로-나노 하이브리드 다공성 니켈 전극

  • Choe, U-Seong;Sin, Heon-Cheol
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.88.2-88.2
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    • 2012
  • 활성 물질의 원활한 확산을 위한 경사형 마이크로 기공과 넓은 반응 면적을 제공하는 나노 기공을 동시에 가지는 하이브리드 다공성 구리의 전기화학적 합성법이 보고된 이후, 이를 기능성 전기화학 장치에 활용하기 위한 많은 연구가 진행되고 있다. 하지만, 구리는 일반적으로 전기화학적 비활성 물질이기 때문에 전극 활물질로서 직접 활용되는 것은 극히 제한적이다. 또한, 전해 도금에 의하여 합성되므로 비전도성 기재 위에 형성이 불가능하여, 비전도성 기재가 기본이 되는 장치에 적용하는 것 역시 어렵다. 본 연구에서는 전해 도금법을 기본으로 하여 마이크로-나노 하이브리드 다공성 구조를 가지는 니켈을 전도성 및 비전도성 기재 위에 형성하였다. 전도성 기재 위에 제조된 니켈의 구조는 전반적으로 기존의 다공성 구리와 거의 유사하였으나 마이크로 기공의 밀도와 수지상의 형태에 있어 차이점을 보였다. 비전도성 기재 위에 형성된 니켈의 경우에는 중간 열처리 과정으로 인해 나노 수지상 구조의 다소간의 뭉침이 발견될 뿐 전도성 기재 위에 형성된 니켈과 구조가 동일하였다. 전도성 및 비전도성 기재 위에 형성된 니켈 다공성 구조를 기본을 하여 각각 전기화학적 캐패시터용 전극과 연료전지용 전극을 제작하였고, 기본적인 전기화학 특성을 파악하여 니켈 다공성 구조의 응용 가능성을 타진하였다.

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Influence of the Micropore Structures of PAN-based Activated Carbon Fibers on Nerve Agent Simulant Gas (DMMP) Sensing Property (PAN계 활성탄소섬유의 미세기공 구조가 신경작용제 유사가스(DMMP) 감응 특성에 미치는 영향)

  • Kang, Da Hee;Kim, Min-Ji;Jo, Hanjoo;Choi, Ye Ji;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.191-195
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    • 2018
  • In this study, the influence of microporous structures of activated carbon fibers (ACFs) on dimethyl methylphosphonate (DMMP) gas sensing properties as a nerve agent simulant was investigated. The pore structure was given to carbon fibers by chemical activation process, and an electrode was fabricated for gas sensors by using these fibers. The PAN based ACF electrode, which is an N-type semiconductor, received electrons from a reducing gas such as DMMP, and then electrical resistance of its electrode finally decreased because of the reduced density of electron holes. The sensitivity of the fabricated DMMP gas sensor increased from 1.7% to 5.1% as the micropore volume increased. It is attributed that as micropores were formed for adsorbing DMMP whose molecular size was 0.57 nm, electron transfer between DMMP and ACF was facilitated. In conclusion, it is considered that the appropriate pore structure control of ACFs plays an important role in fabricating the DMMP gas sensor with a high sensitivity.

Thermal properties of silica fume-SiO2 based porous ceramic fabricated by using foaming method (직접 발포법을 이용해 제조된 실리카 흄-SiO2계 다공성 세라믹의 열적 특성)

  • Ha, Taewan;Kang, Seunggu;Kim, Kangduk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.4
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    • pp.182-189
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    • 2021
  • Porous ceramics were manufactured using the foaming method for the development of inorganic insulating materials. Silica fume and SiO2 were used as main raw materials, and bentonite was used as a rapid setting agent for uniform structure formation of porous ceramics. The porous ceramics were sintered at 1200℃, and porosity, density, compressive strength, microstructure and thermal conductivity were analyzed. As the content of silica fume to SiO2 of the porous ceramics increased 70 to 90 %, the specific gravity increased from 0.63 to 0.69, and the compressive strength increased from 9.41 Mpa to 12.86 Mpa. But, the porosity showed a tendency to decrease from 72.07 % to 70.82 %, contrary to the specific gravity. As a result of measuring the thermal conductivity, the porous ceramic with a silica fume content of 70 % showed a thermal conductivity of 0.75 to 0.72 W/m·K at 25 to 800℃, respectively, and, another that a silica fume content of 90 % showed a 0.66~0.86 W/m·K. So the lower the silica f ume content, the lower the thermal conductivity, which was conf irmed to be consistent with porosity result. As a result of microstructure analysis using SEM (Scanning Electron Microscope), pores in the range of tens to hundreds ㎛ were observed inside and outside the porous ceramic, and it was confirmed that the pore distribution was relatively uniform.

Development of Porous Support with Mine Waste Materials (광산 폐기물을 활용한 다공성 담체 개발)

  • 정문영;정명채;최연왕
    • Economic and Environmental Geology
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    • v.37 no.1
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    • pp.143-151
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    • 2004
  • This study focused on examining the possibility of recycling mine solid waste as environmental materials, especially for porous media. Basic properties including mineralogical compositions, chemical compositions, and particle size distribution of the tailings from the Sangdong W mine were checked. The mineralogical and chemical compositions of the tailings samples were not much different in depth. According to Korean Standard Leaching Test for Wastes(KSLT), concentrations of heavy metals leached from the tailings were below the standard values. As a result of particle size analysis, the median diameter (d$_{50}$) of the tailings was in the range of 10 to 30 ${\mu}{\textrm}{m}$. The stable tailings slurry made up of 3 ${\mu}{\textrm}{m}$ in d$_{50}$ was prepared using Attrition Mill. The milling condition was 40 vol% in slurry concentration, 700 rpm in stirring speed, and 1 hour in milling time. PEI was added as dispersing agent. Concentrated slurry was extended to 3 times by foaming method. In the case of 3 times foamed slurry, the total and open porosity of ceramic supports sintered at 1,075$^{\circ}C$ for 90 minutes was about 80% and 72%, respectively. Pore size was in the range of 30∼350${\mu}{\textrm}{m}$. Therefore, the tailings could be recycled starting material for environmental materials such as macroporous ceramic support.

The Variation in Needle Characteristics of Natural Population of Abies koreana Wilson (구상나무 천연집단(天然集団)의 침엽형질(針葉形質) 변이(變異))

  • Lee, Kang Young;Kim, Hyun Kwon
    • Journal of Korean Society of Forest Science
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    • v.57 no.1
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    • pp.39-44
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    • 1982
  • These studies were carried out to know the variation of needle characteristics of Abies Koreana distributed in Korea. The results are summarized as follows. The differences of needle length and number of stomata row among the population were shown one percent level, but not in each individual tree. Correlations coefficients between the D.B.H. and needle length or needle width of mother trees were not correlated all populations respectively. It was found that correlation coefficient between needle length and needle width was positive in two populations. of Mt. Doukyou and Mt. Hanla, but it was not in Mt Jiri. Correlation coefficient between needle length and the number of stomata row positive correlation in Mt. Doukyou. Correlation coefficient between needle width and the number of stomata row was shown positive in all populations, but it was not that correlation coefficient between needle width and density of serrations, and between number of stomata row and density of serrations. The coefficients of variations were shown higher density of serration than needle length, needle width and stomata row.

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Fabrication and Physical Properties of Tiles Recycled Waste Glass (폐유리를 재활용한 타일 제조 및 물리적 특성)

  • Kim, Young-Kil;Jung, Yeon-Gil;Song, Jun-Baek;Shin, Min-Chul;Lee, Hee-Soo
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.193-197
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    • 2005
  • Wall and floor tiles were fabricated by a dry pressing method using waste glass and clay. The physical properties of the tiles such as absorption, bulk density, porosity, compressive strength, and abrasion loss are investigated with the firing temperature and glass contents. The physical properties are improved with increasing the firing temperature and glass contents. The composition containing the glass of $70 wt%$ and fired at $1050^{\circ}C$ for 2 h has the good properties. The optimal properties obtained in the tiles are the water absorprion of about $0.9\%$, the bulk density of about $2.3\;g/cm^3$, the apparent porosity of about $2.1 \%$, the compressive strength of about 210 MPa, and the abrasion loss of about 0.022 g, when the composition containing the glass of $70\;wt\%$ is fired at $1050^{\circ}C$. The physical proper1ies of tiles fabricated were enhanced compared to the commercial clay tiles, due to easy melting and densification of glassy phase during the firing process.

The study on effects of porosity, strain and grain size on B-H Hysteresis Ioop (기공율, 응력 및 입자 크기가 B-H Hysteresis loop 특성에 미치는 영향 연구)

  • 김성재;정명득;백종규
    • Journal of the Korean Magnetics Society
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    • v.4 no.2
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    • pp.89-93
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    • 1994
  • Effects of density, inner-stress, and grain size on B-H hysteresis loop properties of Mg-ferrite were investigated. As the sintered bulk density increase, coercive force($H_c$) decreasand squareness ratio increase. Coercive force was very dependent on inner-stress in sintered body, so coercive force increase from 1.95[Oe] to 4.35[Oe] when inner stress present in bulk, however, the squareness ratio was almost not changed Coercive force and squareness ratio were independent on grain size of sintered body which is between 6-11[$\mu\textrm{m}$]

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ELECTRICAL PROPERTIES OF ELECTRIC DOUBLE LAYER CAPACITOR USING ORGANIC SOLUTION CONTANING TETRAETHYLAMMONIUM TETRAFLUOROBORATE AS ELECTROLYTE (Tetraethylammonium tetrafluoroborate를 함유한 유기 전해액을 사용한 전기 이중층 콘덴서의 전기적 특성)

  • Park, H.W.;Kwon, S.S.;Jeong, S.H.;Lee, U.Y.;Lim, K.J.;Park, S.G.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1520-1522
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    • 1996
  • 전기 이중층 콘덴서는 일반적인 콘덴서와 백업용 이차 전지의 중간적 성격을 갖는 디바이스로서 직류 전압 인가시 전하는 진해액과 활성탄의 계면에 전기이중층을 이루며 축적된다. 본 논문에서는 탄화 및 활성화 조건을 달리하여 활성탄 전극을 제조하고 세공 면적, 비표면적, 겉보기 밀도차 기공율을 측정,검토하였으며 여러가지 유기 용매에 tetraethylammonium tetrafluoroborate를 각각 첨가하여 제조한 전해액의 전기전도도를 정하고 이들 전해액과 활성탄 전극을 이용하여 전기 이중층 콘텐서를 제작한 후 정전용량, 활성탄 전극의 안정 전위, 체적용량 밀도, 중량용량 밀도 등을 검토하였다.

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Development of the 925 Silver Alloyed Tension Jewelry with Press Forming Process (가압성형법을 이용한 925 은합금의 텐션형 주얼리 개발)

  • Song, Oh-Sung;Kim, Sang-Yeob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.5
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    • pp.805-810
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    • 2006
  • Defects in the conventional casting process of silver jewelry can result in famished products of mediocre hardness. To overcome the shortcomings of conventional methods, we proposed new press forming process, which involves applying uniaxial pressure on casting 92.5%Ag-6.5%Cu-1%Zn ring elements and shaping with a lath. We investigated Vickers hardness, density, and microstructure evolution by changing the applied uniaxial pressure. We report that our newly proposed process can increase the hardness up to 2.3 times and decrease average grain size by 50%. Our method leads to drastic mechanical property enhancements, and is thus suitable for casting tension-style jewelry.

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