• Title/Summary/Keyword: 기공 밀도

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Gas Metal Arc Welding of Aluminum Alloys (알루미늄 합금의 GMAW 용접)

  • 윤광희;한용섭
    • Journal of Welding and Joining
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    • v.12 no.1
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    • pp.16-27
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    • 1994
  • 1970년대 2번에 걸친 석유 파동 이후 재료의 경량화는 자동차, 우주항공분야에서 중요한 문제로 대두되었다. 알루미늄합금은 높은 강도/밀도비, 내식성, 인성 및 저온 특성을 보유하고 있어 일반 가정용품에서 자동차, 우주항공, 선박같은 수송장비까지 여러분야에 사용되고 있으며, 그 사용량과 적용분야는 해가 갈수록 증가하고 있다. 알루미늄합금의 용접특성과 용접 시공기술에 대한 연구결과는 상당히 많이 발표되어 있으나, 실제 현장용접시에는 기공, 불완전 용입 등의 예상치 못한 용접불양이 발생한다. 알루미늄합금의 용접 방법으로는 GTAW, GMAW 등의 보호가스 용접이 주로 사용되고 있다. 본 고에서는 알루미늄합금의 GMAW용접 특성과 용접시 용접 결함에 대하여 간단히 기술하고자 한다.

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Optimization of micro structure of solid oxide fuel cell electrode (고체산화물 연료전지 변수 조사 및 전극미세구조 최적화)

  • Jo, Dong Hyun;Chun, Jeong Hwan;Park, Ki Tae;Hwang, Ji Won;Kim, Sung Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.71.2-71.2
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    • 2010
  • 고체산화물연료전지는 청정에너지원으로써 기존의 발전방식을 대신할 차세대 에너지원으로 각광 받고 있다. 고체산화물 연료전지는 고온에서 작동하는 특성상 실험을 통하여 전극미세구조 및 구동조건을 최적화하는 것은 매우 어렵다. 본 연구는 전기화학식을 이용한 전산모사를 통해서 고체산화물 연료전지의 구동조건에 따른 성능 평가 및 전극의 미세구조 최적화 과정을 수행하였다. 전극 내 전달현상을 무시하고 오직 전기화학반응만을 고려한 전산모사는 단전지의 전극미세구조 및 구동조건에 따른 전지성능을 빠르게 예측할 수 있으며, 이를 기반으로 다양한 조건에서 얻은 전지 성능 데이터를 통해 전극미세구조를 최적화하였다. 개회로전압, 활성화분극, 저항분극, 물질수송손실을 표현하기 위하여 Nernst 식, Butler-Voler 식, 옴의 법칙, dusty-gas 모델을 각각 사용하였으며, 전극미세구조 및 구동조건의 변화는 물질확산계수 및 교환전류밀도를 통하여 그 영향이 전지성능에 반영된다. 온도, 압력, 주입 연료의 조성에 대한 성능평가가 수행되었으며, 1023K, 1 bar의 조건하에서 최적의 단전지 성능을 위한 기공도와 기공크기를 조사하였다. 더 향상된 단전지 성능 확보를 위해서 실험에서 쓰이는 기능층(functional layer)과 유사하게 넓은 반응 면적과 원활한 반응물 및 생성물의 이동을 보장하도록 기공도 및 기공크기를 그레이딩한 전극구조(graded-electrode)를 디자인하고 성능을 평가하였다. 그 결과 기존의 전지구조 대신에 그레이딩된 전극을 사용할 경우 50%이상 향상된 전지성능을 예측할 수 있었다.

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Sintering Behavior and Dielectric Properties of $Al_2O_3$/Glass/$Al_2O_3$ Ceramics by Glass Infiltration (Glass Infiltration법에 의한 $Al_2O_3$/Glass/$Al_2O_3$ 세라믹스의 소결거동 및 유전특성)

  • Jo, Tae-Jin;Yeo, Dong-Hun;Sin, Hyo-Soon;Hong, Yeon-Woo;Kim, Jong-Hee;Cho, Yong-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.177-177
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    • 2009
  • 이동통신 시스템의 소형화 경량화 다기능화 추세에 따라 세라믹 모듈의 정밀도 및 집적도가 중요한 요소로 부각되고 있다. 이러한 모듈의 고집적화 추세에 대응하기 위하여 세라믹 소성시 수축율 제어가 필수적인 요소로 부각되고 있으며, 이에 따라 X, Y축의 소성 수축율을 0에 근접하게 제어하는 무수축 소성 기술이 요구되고 있다. 선행연구를 통하여 $Al_2O_3$/Glass/$Al_2O_3$ 구조의 glass infiltration법에 의한 무수축 소성 기술 구현 가능성을 확인하였으나, 아직 해결해야 할 문제점들이 있다. glass가 $Al_2O_3$층으로 infiltration되는 과정에서 glass층이 de-lamination 되는 결함이 발견되었으며 이는 유전체 기판의 Q값을 낮추고 기판의 신뢰성에 악영향을 줄 수 있어 이에 대한 개선이 필요한 실정이다. 본 연구에서는 $Al_2O_3$/Glass/$Al_2O_3$ 구조의 glass infiltration법에 의한 선행 실험에서 관찰된 기판 내부의 de-lamination 현상에 대한 원인을 규명하고 해결책을 제시하고자 하였다. glass 유동과 바인더 burn-out이 동시에 진행됨에 따라 기공이 생성되며 glass가 점성유동함에 따라 이 기공이 glass층으로 모이게 되어 de-lamination 현상이 발생하는 것으로 사료된다. 이를 해결하기 위하여 de-lamination층에 $Al_2O_3$의 tamping을 시도하여 glass층의 기공이 빠져 나갈 수 있는 channel 을 형성하고, 남아있는 기공을 $Al_2O_3$로 채우는 효과를 얻을 수 있었다. 이에 따라 기판의 밀도와 Quality factor 값이 향상되었으며 미세구조가 치밀한 무수축 기판을 제작할 수 있었다.

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Molecular Approaches to Evaluate the Role of Some Genes Required for Plant Pathogenicity of Xanthomonas campestris pv. campestris (Xanthomonas campestris pv. campestris의 병원성 관련 형질 탐색에 관한 연구)

  • Bae, Dong-Won;Yun, Han-Dae;Kim, Hee-Kyu
    • Korean Journal Plant Pathology
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    • v.13 no.3
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    • pp.172-178
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    • 1997
  • Xanthmonas campestris pv. campestris, causal agent of Black rot of crucifers, were isolated and identified from crucifer host. In order to determine the characters of X. c. pv. campestris associated with pathogenicity, Tn5 mutagenesis was carried out by conjugating with E. coli pJB4J1. Transconjugants were plate- assayed for missing cellulase, protease and amylase activity. A cellulase negative mutant was selected and tested for pathogenicity. Light microscopy and Scanning electron microscopy revealed that substomatal tissues were colonized by mutant, but was far less extensive than those by wild type. Stomatal surface and substomatal tissue appeared to have degraded by only wild type in 24 hrs and progression of pathogenesis was distinct in 48 hrs. In 6 days, wild type proliferated well in the tissue facilitated by cellulase activity. As a result, cellulase was determined as the important factor in pathogenesis.

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Effects on the Properties of Cement Mortar with Various Molecular Structures of Polycarboxylate-Type Superplasticizers (폴리카복실레이트계 고유동화제의 분자구조가 시멘트 모르타르의 물성에 미치는 영향)

  • Song, Jong-Taek;Ryu, Ho-Seok
    • Journal of the Korean Ceramic Society
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    • v.41 no.4
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    • pp.302-312
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    • 2004
  • This paper presents the experimental results on the properties of the cement mortar with polycarboxylate-type superplasticizers PCA) which were synthesized by different mole ratio of methoxypoly(ethyleneglycol)monomethacrylate (MPEGMAA) and methacrylic acid (MAA) and by different length of polyethyleneoxide (PEO). As the PEO chain was longer and mole ratio of [MPEGMAA]/[MAA] was lower, the fluidity of cement mortar was better. The setting time of mortar with PCA was retarded, and as PEO chain was shorter and [MPEGMAA]/[MAA] was lower, it was more retared. Espeacially, when the molecular weight of MPEGMAA was 475(repeat unit of ethylene oxide=l0), the degree of retardation was the highest of them. The surface tensions of PCA solutions were lower than that of water due to the effect of PEO chain, and also the pore size distribution of cement mortar was influenced by it. The pores in cement mortar with PCA at 28 days were macropores in the range of 7 to 370$\mu\textrm{m}$, and accordingly, the densities and compressive strengths of mortar were lower than those of OPC mortar.

Fabrication of Tungsten Nano Dot by Using Block Copolymer Thin Film (블록 공중합체 박막을 이용한 텅스텐 나노점의 형성)

  • Kang, Gil-Bum;Kim, Seong-Il;Kim, Yeung-Hwan;Park, Min-Chul;Kim, Yong-Tae;Lee, Chang-Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.3 s.40
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    • pp.13-17
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    • 2006
  • Dense and periodic arrays of holes and tungsten none dots were fabricated on silicon oxide and silicon. The holes were approximately 25 nm wide, 40 nm deep, and 60 nm apart. To obtain nano-size patterns, self-assembling resists were used to produce layer of hexagonally ordered parallel cylinders of polymethylmethacrylate(PMMA) in polystyrene(PS) matrix. The PMMA cylinders were degraded and removed with acetic acid rinse to produce a PS mask for pattern transfer. The silicon oxide was removed by fluorine-based reactive ion etching(RIE). Selectively deposited tungsten nano dots were formed inside nano-sized trench by using a low pressure chemical vapor deposition(LPCVD) method. Tungsten nano dot and trenched silicon sizes were 26 nm and 30 nm, respectively.

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A Systematic Study of Korean Rutaceae(I) - Mainly Treated with Venation and Stomatal Type - (한국산(韓國産) 운향과(芸香科)의 계통분류학적(系統分類學的) 연구(硏究)(I) - 엽맥(葉脈)과 기공형태(氣孔形態)를 중심(中心)으로 -)

  • Lee, Jeong Hwan;Kim, Sam Sik
    • Journal of Korean Society of Forest Science
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    • v.82 no.3
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    • pp.260-270
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    • 1993
  • This study was carried out to clarifyed a taxonomical relationships of Rutaceae on the subfamily, genus and species level in Korea using venation pattern and stomata types. The results are summarized as follows : The leaf venation of the Rutaceae has revealed three major venation types. Semicraspedodromous, Brochidodromous and Cladodromous. The leaf ufmations type of the genus Evodia and Phellodendron were similar to Cladodromous type. They showed gradual evolution from brochidodromous type of Aurantioideae to cladodromous type of Toddaloideae. The stomata ypes were reconized Anomocytic and Actinocytic type, and epidermal cells were Ansio. Polygonal and Medium type. In the correlation analysis, there were highly significant correlation between frequency and length (r=-0.822), frequency and width (r=-0.780), and length and width(r=0.909) at 1% level.

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Ceramic Foams by the Self-Blowing of Polymer (고분자의 자체발포를 이용한 세라믹 다공질체)

  • 백종원;김득중
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.555-559
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    • 2004
  • Ceramic foams were prepared by a self-blowing process of a polysiloxane with A1$_2$O$_3$ as a filler. The release of water and ethanol vapor during the condensation reaction of the polymer triggered the pores in the polymer melt. The size. interconnectivity and shape of the pores in the ceramic foams were strongly dependent on the viscosity of the polymer melt, which could be varied by the content and size oi the filler. When the content of the filler inceased and the size of the filler decreased. the size of the pores were decreased and the thickness between the pores were increased. In the addition, the viscosity of polymer melt increased by the pretreatment at 130$^{\circ}C$ for Ire intermolecular cross linking thereby stabilizing the foam structure. The density and compressive strength of the ceramic foams were affected by the heating rate during the blowing process.

Application of Hierarchically Porous Fe2O3 Nanofibers for Anode Materials of Lithium-ion Batteries (계층적 다공구조를 갖는 Fe2O3 나노섬유의 리튬 이차전지 음극소재 적용)

  • Jo, Min Su;Cho, Jung Sang
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.267-273
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    • 2019
  • Hierarchically porous $Fe_2O_3$ nanofibers with meso- and macro- pores are designed and synthesized by electrospinning and subsequent heat-treatment. The macro pores are generated by selectively decomposition of polystyrene as a dispersed phase in the as-spun fibers containing $Fe(acac)_3$/polyacrylonitrile continuous phases during heat-treatment. Additionally, meso-pores formed by evaporation of infiltrated water vapor during electrospinning process interconnected the macro-pores and results in the formation of hierarchically porous $Fe_2O_3$ nanofibers. The initial discharge capacity and Coulombic efficiency of the hierarchically porous $Fe_2O_3$ nanofibers at a current density of $1.0A\;g^{-1}$ are $1190mA\;h\;g^{-1}$ and 79.2%. Additionally, the discharge capacity of the nanofibers is $792mA\;h\;g^{-1}$ after 1,000 cycles. The high structural stability and morphological benefits of the hierarchically porous $Fe_2O_3$ nanofibers resulted in superior lithium ion storage performance.

Development of Al-SiC Metal Matrix Composites by using Hot Press Forming Technologies (열간가압성형기술을 이용한 Ai-SiC 금속기 복합재료 개발)

  • Jeon, Ho-Jin;Kim, Tae-Won
    • Composites Research
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    • v.20 no.4
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    • pp.9-17
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    • 2007
  • Powder metallurgy has been employed for the development of SiC particle reinforced aluminum metal matrix composites by means of hot isotropic pressing and vacuum hot pressing. A material model based on micro-mechanical approach then has been presented for the processes. Densification occurs by the inelastic flow of matrix materials during the consolidation, and consequently it depends on many process conditions such as applied pressure, temperature and volume fraction of reinforcement. The model is implemented into finite element software so that the process simulation can be performed enabling the predicted relative density to be compared with experimental data. In order to determine the performance of finished products, further tensile test has been conducted using the developed specimens. The effect of internal void of the materials on mechanical properties therefore can be investigated.