• Title/Summary/Keyword: 기공량

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Analysis of Pore Structure for Porous Body with Coal Fly ash and Clay (석탄회-점토계 다공체의 기공구조 분석)

  • 이기강;박천주
    • Korean Journal of Crystallography
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    • v.9 no.1
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    • pp.64-70
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    • 1998
  • Porous body was prepared from coal fly ash 70 wt%0clay 30 wt% slip using DCC(Direct Coagulated Casting) method. Effect of the specific gravity of the slip on the pore size and distribution of the sintered body was examined by the SEM observation of microstructure and mercury porosimetry measurement of the pore size distribution. Average pore size of the porous sintered body was about 2.5μm for all slips with specific gravity of 1.55, 1.60 and 1.65g/cm3, respectively. Sintered body prepared from the slip of specific gravity of 1.60g/cm3 have the narrowest pore size distribution. slip of specific gravity of 1.55g/cm3 shows broader pore size distribution due to slow gellation process. Slip of specific gravity of 1.65g/cm3 required large amount of deflocculant and showed large variation of the viscosity with addition of coagulant which resulted in very unstable slip properties.

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Effect of Acid Catalyst Kinds on the Pore Structural Characteristics of Water Glass based Silica Aerogel (산 촉매가 물유리 기반 실리카 에어로겔의 기공구조에 미치는 영향)

  • Nah, Ha-Yoon;Jung, Hae-Noo-Ree;Lee, Kyu-Yeon;Ku, Yang Seo;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.3
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    • pp.13-18
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    • 2017
  • Water glass is much cheaper than silicon alkoxide, so it has advantage for commercialization. A condensation by acid catalyst makes considerable effect about the properties of water glass based silica aerogel among many factors in silica aerogel process. The pore structural properties of water glass based silica aerogel such as specific surface area and pore size distribution have been investigated through the changes in the amount and the kinds of acid catalyst. It has been confirmed that water glass based silica aerogel is affected by various conditions of catalyst in the condensation reaction such as the kind, concentration, and the amount of mole of acid catalyst on the properties of final products. Especially, it is checked that the effect of mole of acid is more prominent than that of concentration. In the case for conventional method with introducing 4M HCl in condensation step, the silica aerogel could be synthesized which has $394m^2/g$ of specific surface area, 2.20 cc/g of pore volume, 22.3 nm of average pore size, and 92.53% of porosity. On the other hand, when 4M sulfuric acid was used with 73 mmol at the condensation step of water glass based silica aerogel, the pore structural characteristics of water based silica aerogel showed better properties than the case of using HCl, for example, specific surface area was measured as $516m^2/g$, and pore volume, average pore diameter, and porosity were obtained as 3.10 cc/g, 24.1 nm, and 96.1%, respectively.

Selective Separation of $CO_2/CH_4$ by Pore Structure Modification of Activated Carbon Fiber (활성탄소섬유의 기공구조 변형을 이용한 $CO_2/CH_4$의 선택적 분리 기술)

  • Moon, S.H.;Park, S.Y.
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.1027-1034
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    • 2007
  • This research was focused on the selective separation of $CO_2$ or $CH_4$ from mixture of these gases, by controlling the size of pore or pore gate. Pitch based activated carbon fibers(ACF) were used as adsorbents. The size of pore gate was controlled by the molecule having similar size to that of pore opening. After the adsorption of adsorbate on pore surface, planar molecules such as benzene and naphthalene covered the pore gate. The slow release of adsorbate from the pores covered by planar molecules makes apertures between planar molecules covering pore gate and this structure can be fixed by rapid pyrolysis. The control of pore gate using benzene as covering molecules could not accomplished due to the simultaneous volatilization of benzene and adsorbate$(CO_2)$ caused by similar temperatures of benzene volatilization and adsorbate desorption. Therefore we replaced benzene with naphthalene looking for the stability at a $CO_2$ desorption temperature. The naphthalene molecule was adsorbed on the ACF up to 15% of ACF weight and showed no desorption until $100^{\circ}C$, indicating that the molecule could be used as a good cover molecule. Naphthalene could cover almost all the pore gate, reducing BET surface area from 753 $m^2/g$ to 0.7 $m^2/g$. A mixed gas$(CO_2:CH_4=50:50)$ was adsorbed on the naphthalene treated OG-7A ACF. The amount of $CO_2$ adsorption increased with total pressure, whileas thai of $CH_4$ was not so much influenced on the pressure, indicating that $CO_2$ made more compounds on the ACF surface along with total pressure increase. The most $CO_2$ and the least $CH_4$ were adsorbed in the condition of 0.4 atm, resulting in the highly pure $CH_4$ left in ACF.

Particulate Matter Removal of Indoor Plants, Dieffenbachia amoena 'Marianne' and Spathiphyllum spp. according to Light Intensity (광량에 따른 실내식물 디펜바키아와 스파티필럼의 미세먼지 제거능)

  • Kwon, Kei-Jung;Park, Bong-Ju
    • Journal of the Korean Institute of Landscape Architecture
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    • v.46 no.2
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    • pp.62-68
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    • 2018
  • This study investigated the effect of light intensity on the removal of particulate matter by Dieffenbachia amoena 'Marianne' and Spathiphyllum spp.. An acrylic chamber ($600{\times}800{\times}1200mm$, $L{\times}W{\times}H$) modeled as an indoor space and a green bio-filter ($495{\times}495{\times}1000mm$, $L{\times}W{\times}H$) as an air purification device were made of acrylic. The removal of particulate matter PM10 and PM1, the photosynthetic rate, stomatal conductance, and number of stomata of Dieffenbachia amoena 'Marianne' and Spathiphyllum spp. were measured according to three different levels of light intensity (0, 30 and $60{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}PPFD$). Regarding the length of time taken for PM10 to reach $1{\mu}g$, the Dieffenbachia amoena 'Marianne' showed a significant difference according to the presence or absence of light, and there was no significant difference shown between light intensity of 30 and $60{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}PPFD$. As for the Spathiphyllum spp., there was no significant difference between 0 and $30{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}PPFD$, while a significant difference was shown at $60{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}PPFD$. After 90 minutes, the PM1, PM10, and $CO_2$ residuals of the Spathiphyllum spp. were lowest at $60{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}PPFD$. The remaining amount of PM1 and PM10 was lower with the Spathiphyllum spp. than with the Dieffenbachia amoena 'Marianne', even at $0{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}PPFD$. With both plants, the higher the light intensity, the higher the photosynthetic rate, while the stomatal conductance did not show any significant difference. Spathiphyllum spp. showed a higher photosynthetic rate and stomatal conductance and a greater number of stomata than Dieffenbachia amoena 'Marianne', and stomata were observed in both the front and back sides of the leaves. The air purification effect of Spathiphyllum spp. is considered to be better than Dieffenbachia amoena 'Marianne' at the same light intensity due to such plant characteristics. Therefore, in order to select effective indoor plants for the removal of particulate contamination in an indoor space, the characteristics of plants such as the photosynthetic rate and the number and arrangement of stomata according to indoor light intensity should be considered.

Antioxidant activity and quality characteristics of Jeung-pyun containing Rudbeckia laciniata L. powder (삼잎국화 분말을 첨가한 증편의 항산화 활성 및 품질특성)

  • Yang, Eun Young;Kim, Myung Hyun;Han, Young Sil
    • Korean Journal of Food Science and Technology
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    • v.54 no.4
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    • pp.414-421
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    • 2022
  • The purpose of this study was to evaluate the quality characteristics and antioxidant activity of Jeung-pyun containing 0, 2.5, 5, 7.5, and 10% Rudbeckia laciniata L. powder. In this study, increase in the content of Rudbeckia laciniata L. powder led to an increase in pH, hardness, adhesiveness, chewiness, and gumminess while moisture of Jeung-pyun had decreased. Scanning electron microscopy analysis showed that the pores in Jeung-pyun merged leading to a decrease in the number of pores, while the pore size increased along with the increase in R. laciniata L. content. In the sensory evaluation tests, Jeung-pyun with 5% R. laciniata L. powder showed the best results. Moreover, the antioxidant activity of Jeung-pyun increased with the addition of R. laciniata L. powder. Based on these results, we conclude that R. laciniata L. has good quality characteristics and antioxidant activity, making it a good ingredient for Jeung-pyun.

Fabrication and characterization of porous hydroxyapatite scaffolds with PMMA addition using tertiary-butyl alcohol based freeze casting method (삼차부틸알코올 기반 동결주조 공정을 이용한 PMMA 첨가 다공질 수산화아파타이트 지지체의 제조 및 특성 평가)

  • Kim, Tae-Rim;Yoon, Seog-Young;Heo, Jin-Young;Lee, Chi-Seung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.5
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    • pp.235-242
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    • 2017
  • In order to prepare porous scaffolds capable of pore control, PMMA powder serving as a pore-forming agent was added to HA powder to synthesize a slurry containing TBA as a solvent. And then, porous HA scaffolds where pillarshaped pore channels interconnected with each other were fabricated by freeze-casting and sintering. The crystal structure of the HA scaffolds according to the addition amount of PMMA powder was measured by XRD and the surface and inner cross section of the scaffolds were analyzed through SEM. It was found that removal of PMMA during sintering affects the internal structure of the scaffolds and the crystallinity of the HA powder. Furthermore, through evaluating the physical and mechanical properties of the scaffolds, it was confirmed that the porosity, pore size and compressive strength can be controlled by controlling the addition amount of the pore-forming agent. It was also found that the HA scaffolds produced in this study were similar in structure and properties to the natural cancellous bone. This suggests that porous HA scaffolds with PMMA can be used as an alternative to autogenous bone for tissue engineering as an artificial bone scaffold.

Effect of Additive Ball Clay on Physical Properties of Porous Ceramic (볼 클레이 첨가에 따른 세라믹 다공체의 물리적 특성변화)

  • Kang, Young-Sung;Kim, Sang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.109-112
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    • 2014
  • A porous ceramic which has fine porosity and small specific gravity is made with Cenosphere and Ball Clay under condition of $1,250^{\circ}C$ in calcination temperature and 30 minutes of calcination time. The average size of porous ceramic was about $2.5{\times}10^{-5}$ m and pores are well developed. The void-fraction of porous ceramic was 67.1% under the input of Cenosphere and Ball clay with the weight ratio of 100 to 5. However, as weight ratio of Ball Clay increased to 20, 40, 100, the void fraction decreased to 58.4, 56.7, 47% respectively. When the weight ratio of Cenosphere and Ball Clay was 100 to 100, the apparent density of porous ceramic was $1.04g/cm^3$. which is twice the density when the weight ratio of Ball Clay was 5. On the other hand, absorption rate decreased by at least 100%. In condition of weight ratio of Cenosphere and Ball Clay was 100 to 100, compressive strength of porous ceramic was 30 (MPa), improve by about 76% or more when the weight ratio of Ball Clay was 5.

Characteristics of Mine Liner According to the Replacement Ratio of Nano-Silica and Silica-Fume (나노실리카 및 실리카흄 대체율에 따른 차수재의 특성)

  • Kang, Suk-Pyo;Lee, Hee-Ra;Kang, Hye-Ju;Nam, Seong-Young;Kim, Chun-Sik
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.66-73
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    • 2019
  • Approximately 80% of the mines are vacated or abandoned mines and are mostly left without suitable environmental treatment facilities. In the area around the abandoned mine site, problems such as drainage of acidic city drainage and leakage of leachate occur, and ground subsidence caused by this can cause a safety accident due to sink hole occurrence. In this study, flow, compressive strength, water uptake, pore and hydration characteristics were investigated to investigate the basic properties of liner and cover material based on the replacement ratio of nano silica and silica fume in the existing blast - furnace slag fine powder. As a result, as the substitution ratio of nano silica and silica fume increased, the flow and compressive strength of nano silica specimens increased and the absorption rate decreased. In the case of pore characteristics, the amount of pores decreased as the substitution ratio of nano silica and silica fume increased. Especially, the capillary porosity of 10-1,000 nm diameter decreased. Ray diffraction analysis and SEM measurement showed that the peak positions of the hydration products were almost the same when compared with the 5% alternative test samples of Plain and silica fume.

Effect of a Qigong-Based Stress Management Program on Emotion of Pregnant Women (기공에 기초한 스트레스 관리 프로그램이 산모의 정서에 미치는 영향)

  • Lee, Sang-Hyuk;Kim, Mu-Jin-Haeng;Lee, Eun-Hee;Suh, Shin-Young;Yook, Ki-Whan;Choi, Tae-Kyou
    • Korean Journal of Psychosomatic Medicine
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    • v.12 no.2
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    • pp.135-144
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    • 2004
  • Objectives: The aim of this study was to examine the effectiveness of a qigong-based stress management program in pregnant women. Method: A 8 week controlled clinical trial compared 52 pregnant women assigned qigong-based stress management program to 40 pregnant women assigned pregnancy health education program. Edinburgh postnatal depression scale(EPDS), Beck depression inventory(BDI), Spielberger trait state inventory-1(STAI-1), Hamilton depression rating scale(HAM-D), Hamilton anxiety scale(HAM-A) were used to measure anxiety and depression level. Result : Qigong-based stress management group showed significant improvement compared to the education control group on four measures above. Qigong-based stress management group also showed significant improvement at 8 weeks termination on all measures of anxiety and depression compared to pretreatment level. Conclusion : This study showed that qigong-based stress management program can be an effective method for pregnant women.

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Effect of MAD Snoring Design on Pharyngeal Airway Dimension (하악전방이동 코골이 장치의 수직 교합량이 상기도에 미치는 영향)

  • Ra, In-Sil;Lee, Jang-Hoon
    • Journal of Digital Convergence
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    • v.15 no.10
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    • pp.307-314
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    • 2017
  • In this study, a minimum amount of the vertical occlusion was secured differently in each type of mandibular advance devices snoring and Class I malocclusion patients wore these devices. This study analyzes, after the use of devices, a different amount of the vertical occlusion results in a change of the area of upper airway by additional changes such as mandibular position, muscle changes, tongue position. The higher the vertical amount, the area of the upper airway was shown smaller, And if the patient's tongues was prevented from the distal movement, the area of the upper airway had increased, To reduce snoring, doctors should accurately diagnose patients' occlusal relationships and select a MAD snoring that is appropriate for the occlusion. The dental technician who builds the selected device should also consider design settings such as the amount of vertical occlusion, the finish lines, and the thickness of the device to increase the effectiveness of the device.