• Title/Summary/Keyword: 기계-화학적 반응

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A study on the actual precision shooting training based on virtual reality (가상현실 기반 실전적 정밀사격훈련 구현 연구)

  • Lee, Byounghwak;Kim, Jonghwan;Shin, Kyuyoung;Kim, Dongwook;Lee, Wonwoo;Kim, Namhyuk
    • Convergence Security Journal
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    • v.18 no.4
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    • pp.62-71
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    • 2018
  • The rapid growth of virtual reality technology in the era of the 4th Industrial Revolution has accelerated scientification of combat training systems in addition to ICT(information and communications technology) in military field. Recently, research and development of simulators based on virtual reality have been actively conducted in order to solve sensitive issues such as increase of civil complaints due to the noise of a shooting range, prevention of shooting accident, and reduction of training cost. In this paper, we propose two key solutions: spatial synchronization method and modified point mass trajectory model with small angle approximation to overcome technical limitations of a current training simulator. A trainee who wears a haptic vest in a mixed reality environment built in MARS(medium-range assault rifle shooting simulator) is able to conduct not only precision shooting but also two-way engagement with virtual opponents. It is possible for trainee to receive more reliable evaluations in the MARS than an existing rifle simulator based on laser.

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Perfluorosulfonic Acid Composite Membranes Containing Antioxidant Grafted Graphene Oxide for Polymer Electrolyte Membrane Fuel Cell Applications (산화방지 작용기를 함유한 산화 그래핀이 도입된 과불소화계 복합 막의 고분자 전해질 막 연료전지로의 응용)

  • Inhyeok Hwang;Kihyun Kim
    • Membrane Journal
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    • v.33 no.6
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    • pp.416-426
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    • 2023
  • In this study, hindered amine-grafted graphene oxide (HA-GO) with antioxidant properties was prepared and incorporated into Nafion-based composite membranes as an effective filler material for polymer electrolyte membrane fuel cell applications. HA-GO was synthesized via a ring-opening reaction between amine groups in 4-amino-2, 2, 6, 6-tetramethyl piperidine and epoxy groups on the surface of GO. Nafion-based composite membranes containing different weight contents of HA-GO were fabricated to compare the polymer electrolyte membrane properties with those of the pure Nafion membrane. The composite membranes with HA-GO were found to have better mechanical properties, chemical stability, and proton conductivity than the pure Nafion membrane. In particular, the conductivity retention behavior confirmed by the decrease in proton conductivity after Fenton's test of the composite membranes was better than that of the pure Nafion membrane due to the incorporation of HA-GO with effective antioxidant properties.

Electrochemical Properties of Needle Coke through a Simple Carbon Coating Process for Lithium Ion Battery (침상 코크스의 피치 코팅에 따른 리튬 이차전지 탄소계 음극소재의 전기화학적 특성)

  • Hwang, Jin Ung;Lee, Jong Dae;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.514-519
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    • 2020
  • Graphite materials for lithium ion battery anode materials are the most commercially available due to their structural stability and low price. Recently, research efforts have been conducted on carbon coatings by improving side reactions at the edge site of carbon materials. The carbon coating process has classified into a CVD by chemical reaction, wet coating process with solvent and dry coating by mechanical impact. In this paper, the rapid crush/coating process was used to solve the problem of which only few parts of the carbon precursor (pitch) can be used and also environmental problems caused by solvent removal in the wet coating process. When the ratio of needle coke to pitch was 8 : 2 wt%, and the rapid crush/coating process was carried out, it was confirmed that the fracture surface was coated by pitch. The pitch-coated sample was treated at 2400 ℃ and 41.8% improvement in 10C/0.1C rate characteristic was observed. It is considered that the material simply manufactured through the simple crush/coating process can be used as an anode electrode material for a lithium ion battery.

Numerical Investigation of Deformation of Thin-walled Tube Under Detonation of Combustible Gas Mixture (가연성 연소 가스의 데토네이션에 의한 얇은 관 변형 모델링)

  • Gwak, Mincheol;Lee, Younghun;Yoh, Jai-Ick
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.1
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    • pp.11-19
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    • 2015
  • We present the results of a multi-material numerical investigation of the propagation of a combustible gas mixture detonation in narrow metal tubes. We use an experimentally tuned one step Arrhenius chemical reaction and ideal gas equation of state (EOS) to describe stoichiometric $H_2-O_2$ and $C_2H_4-O_2$ detonations. The purely plastic deformations of copper and steel tubes are modeled using the Mie-Gruneisen EOS and Johnson-Cook strength model. To precisely track the interface motion between the detonating gas and the deforming wall, we use the hybrid particle level-sets within the ghost fluid framework. The calculated results are validated against the experimental data because the results explain the process of the generation and subsequent interaction of the expansion wave with the high-strain-rate deformation of the walls.

Preparation of Flexible 3D Porous Polyaniline Film for High-Performance Electrochemical pH Sensor (고성능 전기 화학 pH 센서를 위한 유연한 3차원 다공성 폴리아닐린 필름 제조)

  • Park, Hong Jun;Park, Seung Hwa;Kim, Ho Jun;Lee, Kyoung G.;Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.539-544
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    • 2020
  • A three-dimensional (3D) porous polyaniline (PANI) film was fabricated by a combined photo-and soft-lithography technique based on a large-area nanopillar array, followed by a controlled chemical dilute polymerization. The as-obtained 3D PANI film consisted of hierarchically interconnected PANI nanofibers, resulting in a 3D hierarchical nanoweb film with a large surface and open porous structure. Using electrochemical measurements, the resulting 3D PANI film was demonstrated as a flexible pH sensor electrode, exhibiting a high sensitivity of 60.3 mV/pH, which is close to the ideal Nernstian behavior. In addition, the 3D PANI electrode showed a fast response time of 10 s, good repeatability, and good selectivity. When the 3D PANI electrode was measured under a mechanically bent state, the electrode exhibited a high sensitivity of 60.4 mV/pH, demonstrating flexible pH sensor performance.

Research Trends of Polybenzimidazole-based Membranes for Hydrogen Purification Applications (수소 분리 응용을 위한 폴리벤즈이미다졸 기반 분리막의 연구 동향)

  • Kim, Ji Hyeon;Kim, Kihyun;Nam, Sang Yong
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.453-466
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    • 2020
  • As the demand for eco-friendly energy increases to overcome the energy shortage and environmental pollution crisis, hydrogen economy has been proposed as a potential solution. Accordingly, an economical and efficient hydrogen production is considered to be an essential industrial process. Research on applying hydrogen separation membranes for H2/CO2 separation to the production of highly concentrated hydrogen by purifying H2 and capturing CO2 simultaneously from synthetic gas produced by gasification is in progress nowadays. In high temperature environments, the membrane separation process using glassy polymeric membrane with H2 selectivity has the potential for CO2 capture performance, and is an energy and cost effective system since polybenzimicazole (PBI)-based separators show excellent chemical and mechanical stability under high-temperature operation conditions. Thus, the development of high-performance PBI hydrogen separators has been rapidly progressing in recent years. This overview focuses on the recent developments of PBI-based membranes including structure modified, cross-linked, blended and carbonized membranes for applications to the industrial hydrogen separation process.

Effect of the Structure of MoO3/bismuth molybdate Binary Phase Catalysts on the Selective Oxidation of Propylene (MoO3/bismuth molybdate 혼합 2상 촉매의 구조에 따른 프로필렌 선택산화반응 특성)

  • Cha, T.B.;Choi, M.J.;Park, D.W.;Chung, J.S.
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.53-63
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    • 1992
  • M/BM -series catalysts, $MoO_3$ supported on ${\alpha}-Bi_2Mo_3O_{12}$ were also prepared by impregnation method. BM/M-series catalysts, ${\alpha}-Bi_2Mo_3O_{12}$ supported on $MoO_3$ were also prepared by coprecipitation. Structure and catalytic properties of the two phase catalysts were studied by means of using nitrogen adsorption, X-ray diffraction, and scanning electron microscopy. The reaction test for the selective oxidation of propylene to acrolein over Bi-molybdate catalysts was studied using a fixed-bed reactor system. In M/BM-series catalysts, $MoO_3$ was dispersed on ${\alpha}-Bi_2Mo_3O_{12}$, and the crystal structure of ${\alpha}-Bi_2Mo_3O_{12}$ remains unchanged by the presence of excess $MoO_3$. However the surface morphology and bulk structure of BM/M-series catalysts were altered probably because the precipitated $Bi(OH)_3$ reacted with $MoO_3$ during the calcination to form ${\alpha}-Bi_2Mo_3O_{12}$ phase. The results of propylene oxidation on both series catalysts showed that the reaction took place over the surface of ${\alpha}-Bi_2Mo_3O_{12}$ particle and the role of excess $MoO_3$ was to supply oxygen to ${\alpha}-Bi_2Mo_3O_{12}$. These increasing effects on activity were also observed in the mechanical mixtures of ${\alpha}-Bi_2Mo_3O_{12}$ and $MoO_3$.

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Histomorphometry and Stability Analysis of Loaded Implants with two Different Surface Conditions in Beagle Dogs (하중을 가한 두 가지 표면의 임플란트에 관한 조직형태학적 분석 및 안정성 분석 (비글견을 이용한 연구))

  • Kim, Sang-Mi;Kim, Dae-Gon;Cho, Lee-Ra;Park, Chan-Jin
    • Journal of Dental Rehabilitation and Applied Science
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    • v.24 no.4
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    • pp.337-349
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    • 2008
  • Despite an improved bone reactions of Mg-incorporated implants in the animals, little yet has been carried out by the experimental investigations in functional loading conditions. This study investigated the clinical and histologic parameters of osseointegrated Mg-incorporated implants in delayed loading conditions. A total of 36 solid screw implants (diameter 3.75 mm, length 10mm) were placed in the mandibles of 6 beagle dogs. Test groups included 18 Mg-incorporated implants. Turned titanium Implants served as control. Gold crowns were inserted 3 months. Radiographic assessments and stabilitytests were performed at the time of fixture installation, $2^{nd}$ stage surgery, 1 and 3 months after loading. Histological observations and morphometrical measurements were also performed. Of 36 implants, 32 displayed no discernible mobility, corresponding to successful clinical function. There was no statistically significant difference between test implants and controls in marginal bone levels (p=0.413) and RFA values. The mean BIC % in the Mg-implants was $54.4{\pm}20.2%$. The mean BIC % in the turned implant was $48.9{\pm}8.0%$. These differences between the Mg-implant and control implant were not statistically significant (P=0.264). In the limitation of this study, bone-to-implant contact (BIC) and bone area of Mg-incorporated oxidized implant were similar to machine-turned implant. The stability analysis showed no significantly different ISQ values and marginal bone loss between two groups. Considering time-dependent bone responses of Mg-implant, it seems that Mg-implants enhanced bone responses in early loading conditions and osseointegrated similarly to cp Ti implants in delayed loading conditions. However, further investigations are necessary to obtain long-term bone response of the Mg-implant in human.

Characterization of PET films coated with organic-inorganic hybrid coating system containing surface modified zirconia (표면 개질된 지르코니아를 함유한 유-무기 하이브리드 코팅액으로 도포된 PET 필름의 특성)

  • Lee, Soo;Kim, Sang Yup;Kim, Young Jun
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.595-605
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    • 2018
  • In recent years, researches on organic-inorganic coating films have conducted a nanocomposite system composed of organic resin matrices having excellent flexibility and chemical stability and inorganic materials having excellent mechanical properties. The o-phenylphenoxyethyl acrylate (OPPEA) used as the acrylate monomer has a high refractive index of 1.58, and the bisphenol A ethoxylate diacrylate (BAEDA) has a low refractive index but improves the chemical stability of the organic resin. In addition, zirconia used as an inorganic material exhibits excellent durability and optical properties. In this study, the BAEDA contents in acrylate monomer were controlled to produce a film with suitable optical transparency. And optimum conditions were established by comparing the changes in surface properties of PET films detected with pencil hardness tester, Abbe's refractometer, and UV-vis spectrophotometer. The hydrophobicity and the dispersibility of zirconia in acrylate monomer were much improved after modification with ${\gamma}$-methacryloxypropyltrimethoxysilane (MPS), which is a silane coupling agent. And the existence of ester C=O bond peak at $1716cm^{-1}$ introduced by MPS through FT-IR ATR spectrophotometer confirmed the completion of surface modification of zirconia with MPS. In addition, the presence of silicon atom on the surface modified zirconia was also proved using X-ray fluorescence spectrometer. When the photocurable hybrid coating was prepared by introducing chemically modified zirconia into acrylate monomer, the refractive index of this coated PET film was improved by 1.2%, compared to the only acrylate coated PET film. The homogeneous distribution of zirconia in acrylate coating layer on PET film was also identified through SEM/EDS mapping analysis technique.

플라즈마를 활용한 최근의 대기환경기술

  • Song, Yeong-Hun;Heo, Min;Lee, Dae-Hun;Gang, U-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.119.2-119.2
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    • 2014
  • 대기환경 규제가 강화됨에 따라 기존 기술 대비 획기적인 성능과 가격 경쟁력을 갖춘 새로운 대기환경 기술에 대한 수요가 지속적으로 요구되고 있다. 특히 최근에는 종래의 분진, 이산화황가스 및 질소산화물에 대한 규제와 더불어 지구온난화가스인 이산화탄소, 과불화화합물 (Perfluorocompounds, PFCs), 메탄가스 등에 대한 규제가 강화되면서 이에 대응할 수 있는 대기환경 기술의 수요가 늘고 있다. 한국기계연구원에서는 지난 10 여 년간 지구온난화가스이자 난분해성 가스인 메탄 및 PFCs 가스를 플라즈마 화학반응 공정을 통해 분해하는 연구를 수행해왔으며, 이를 바탕으로 산업에 적용할 수 있는 기술개발도 병행하여 수행하였다. 현재 개발된 기술 가운데 일부는 산업에 실제로 적용되고 있으며, 이를 통해 산업현장에서는 지구온난화가스는 물론 질소산화물과 같은 다른 종류의 규제물질도 동시에 저감할 수 있었다. 본 발표에서는 플라즈마를 활용하여 난분해성 가스인 메탄과 PFCs를 분해하는 기술의 특성을 살펴보았으며, 이를 바탕으로 산업현장에 적용된 대기환경기술이 어떻게 활용되고 있는지를 소개하고 있다. 본 발표에서 다루게 될 플라즈마 발생기술은 펄스 코로나, 유전체장벽방전, 마이크로웨이브 토치, 아아크 토치 등이며, 플라즈마 발생조건은 수 torr 이하의 진공조건부터 및 대기압 조건에 이르고 있다.

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