• Title/Summary/Keyword: 기계적합금화법

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Evaluations of Hydrogen Properties of MgHx-Nb2O5 Oxide Composite by Hydrogen Induced Mechanical Alloying (수소 가압형 기계적 합금화법으로 제조한 MgHx-Nb2O5 산화물 복합 재료의 수소화 특성 평가)

  • Lee, Nari;Lee, Soosun;Hong, Taewhan
    • Journal of Hydrogen and New Energy
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    • v.23 no.5
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    • pp.429-436
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    • 2012

  • Mg and Mg-based alloys are regarded as strong candidate hydrogen storage materials since their hydrogen capacity exceeds that of known metal hydrides. One of the approaches to improve kinetic is addition of metal oxide. In this paper, we tried to improve the hydrogenation properties of Mg-based hydrogen storage composites. The effect of transition metal oxides, such as $Nb_2O_5$ on the kinetics of the Magnesium hydrogen absorption kinetics was investigated. $MgH_x$-5wt.% $Nb_2O_5$ composites have been synthesized by hydrogen induced mechanical alloying. The powder fabricated was characterized by X-ray diffraction (XRD), Field Emission-Scanning Electron Microscopy (Fe-SEM), Energy Dispersive X-ray (EDX), BET and simultaneous Thermo Gravimetric Analysis / Differential Scanning Calorimetry (TG/DSC) analysis. The Absorption / desorption kinetics of $MgH_x$-5wt.% $Nb_2O_5$ (type I and II) are determined at 423, 473, 523, 573 and 623 K.

  • https://doi.org/10.7316/KHNES.2012.23.5.429 인용 PDF KSCI

The Magnetic Properties of Amorphus Phase in Mechanically Alloyed $Fe_{50}Zr_{50}$ Powders (기계적 합금화한 비정질 $Fe_{50}Zr_{50}$ 분말의 자기특성)

  • 이성의;나형용;김원태;유성초
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.7-12
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    • 1997

  • Amorphous $Fe_{50}Zr_{50}$ alloy has been manufactured by mechanical alloying from pure elemental powders of Fe and Zr in conventional ball mill under an Ar atmosphere. Structure and magnetic properties of the amorphous phase were studied by transmission electron microscopy and SQUID magnetometry. Selected area diffraction patterns taken from the mechanically alloyed powders showed two halo rings, indicating coexistence of Fe rich and Zr rich amorphous phases in mechanically alloyed powder. Curie temperature of the Fe rich amorphous phase, measured by Arrot plot, was 195 K. Fe content in the ferromagnetic amorphous phase, estimated from the Curie temperature, was about 65 at%. Spin wave stiffness constant of $Fe_{50} Zr_{50}$ alloys processed for 100 and 200 hrs were 52.2 and 63.8 meV, respectively. The higher spin wave stiffness constant in 200 hrs milled powders may arise from the precipitation of $\alpha$-Fe by partial crystallization of amorphous phase.

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A study on the synthesis and improvement of electrochemical properties of olivine-type phosphate cathode materials for lithium rechargeable batteries by mechanical alloying (기계적 합금화법에 의한 리튬 이차전지용 phosphate계 양극물질의 제조 및 전기화학적 특성 향상에 관한 연구)

  • 김철우;권상준;정운태;이경섭
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.216-216
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    • 2003

  • 현재 상용화되어 있는 리튬 이차전지용 양극재료로는 비교적 작동전압이 높은 층상 암염구조(LiCoO$_2$, LiNiO$_2$) 및 Spinet계(LiMn$_2$O$_4$) 전이금속 산화물이 대부분 이용되고 있다 하지만 LiCoO$_2$나 LiNiO$_2$ 같은 상용화 물질은 비교적 높은 비용과, 강한 독성 때문에 많은 문제점을 가지고 있다. 또 Spinel(LiMn$_2$O$_4$)는 낮은 비용과 환경친화적인 장점에도 불구하고 Jahn-Teller 변형과 관련된 구조적 변형이 심각하기 때문에 사이클시 비가역적인 용량의 감소가 심각하다. 이러한 관점에서 전이금속보다 그 양이 풍부하고 저렴할 뿐만 아니라 독성이 없는 Olivine 구조 (LiFePO$_4$)를 갖는 phosphate계 화합물에 관심을 가지게 되었다. LiFePO$_4$는 리튬 음극과 3.4V의 방전전압을 나타내며, 170mAh/g의 이론용량을 가지고 있어, Fe-base의 장점은 물론 안정적인 결정구조 및 현재 상용화된 재료들과 비슷한 에너지 밀도를 가진다. 따라서 본 연구에서는 양극물질의 기존 두 제조법인 고상반응법과 sol-gel법으로 대표되는 제조법의 단점을 상호 보완될 수 있다고 판단되는 기계적 합금화법(Mechanical Alloying, MA)공정을 도입하여 초미세립 분말 제조에 초점을 맞추어 Olivine phosphate계 양극물질의 제조 및 전기화학적 특성을 연구하였다.

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