• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.5
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• pp.462-465
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• 2004

After 6 month of using, cracking of gas exhaustion bag cage of Type 304 stainless steel wire for Al melting reverberatory furnace was founded in welds. Analysis of crack causes in the wire were tested by electrochemical method, SEM images of structure and analysis of composition. Resulted from the test, it could be observed that cracks in the welds were a accelerated by formed polythionic acid on surface of bag cage in sensitized region of HAZ, tensile stress and using environment.

• Journal of the Korean Applied Science and Technology
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• v.27 no.3
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• pp.361-369
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• 2010

A study on the corrosion inhibition of metals is important in many industrial applications (carbon steel, copper, aluminum, SUS 304, nickel). In this study, we investigated the C-V diagrams related to the surface corrosion of metals. It was observed through the SEM that the surface corrosion state of the various metals had the corrosion potential by the scan rate and the organic inhibitor containing an amine group. We determined to measure cyclic voltammetry using the three-electrode system. The measurement of oxidation and reduction ranged from -1350mV to 1650mV. The scan rate was 50, 100, 150, and 200mV/s. It turned out that the C-V characterization of SUS 304 was irreversible process caused by the oxidation current from the cyclic voltammogram. After adding organic inhibitors, the adsorption film was constituted, and the passive phenomena happened. As a result, it was revealed that the inhibition effect of metal corrosion depends on the molecular interaction, and the interaction has influence on the adsorption complex.

• Journal of Integrative Natural Science
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• v.2 no.4
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• pp.233-236
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• 2009

This study was undertaken to measure the electrochemical corrosion of amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ (at.%) alloy ribbon under various conditions, including 0.4 mM HCl solution, and for various values of the pH and the immersion time. The corrosion potentials($E_{corr}$) for the amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ alloy in 0.4 mM HCl decreased with increasing temperature; the corrosion current density($I_{corr}$) increased with increasing temperature in general. The polarization resistance($R_p$) was inversely proportional to the corrosion rate. While pH=7, 9, 11 was not as sensitive as pH=3, 5, pH=3 was more sensitive for amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ alloy than other pHs specially. The change of mass in the 70 mM $H_2SO_4$ solution with immersion time was the greatest in the first 100 h.

• Journal of Powder Materials
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• v.26 no.1
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• pp.16-21
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• 2019

In aluminum brazing processes, corrosive flux, which is used in preventing oxidation, is currently raising environmental concerns because it generates many pollutants such as dioxin. The brazing process involving non-corrosive flux is known to encounter difficulties because the melting temperature of the flux is similar to that of the base material. In this study, a new brazing filler material is developed based on aluminum and non-corrosive flux composite powder. To minimize the interference of consolidation aluminum alloy powder by the flux, the flux is intentionally embedded in the aluminum alloy powder using a mechanical milling process. This study demonstrates that the morphology of the composite powder can be varied according to the mixing process, and this significantly affects the relative density and mechanical properties of the final filler samples.

• Corrosion Science and Technology
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• v.21 no.4
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• pp.300-313
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• 2022

Interest in polymer electrolyte fuel cell is growing to replace fossil fuels. In particular, in order to reduce the cost and volume of the fuel cell, research on a metallic bipolar plate is being actively conducted. In this research, investigated the effects of temperature and chloride concentration on the electrochemical characteristics and damage behavior of 316L stainless steel in an accelerated solution simulating the cathodic operating condition of PEMFC(Polymer electrolyte membrane fuel cell). As a result of the experiments, the corrosion current density, damage size, and surface roughness increased as the temperature and chloride concentration increased. In particular, the temperature had a significant effect on the stability of the oxide film of 316L stainless steel. In addition, it was described that the growth of the pit was affected by the chloride concentration rather than the temperature. As a result of calculating the corrosion tendency to compare the pitting corrosion rate and the uniform corrosion rate, the uniform corrosion tendency became larger as the temperature increased. And the effects of chloride concentration on corrosion tendency was different according to temperature.

• Corrosion Science and Technology
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• v.22 no.4
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• pp.287-296
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• 2023

Li-ion batteries have been gaining increasing importance, driven by the growing utilization of renewable energy and the expansion of electric vehicles. To meet market demands, it is essential to ensure high energy density and battery safety. All-solid-state batteries (ASSBs) have attracted significant attention as a potential solution. Among the advantages, they operate with an ion-conductive solid electrolyte instead of a liquid electrolyte therefore significantly reducing the risk of fire. In addition, by using high-capacity alternative electrode materials, ASSBs offer a promising opportunity to enhance energy density, making them highly desirable in the automotive and secondary battery industries. In ASSBs, Li metal can be used as the anode, providing a high theoretical capacity (3860 mAh/g). However, challenges related to the high interfacial resistance between Li metal and solid electrolytes and those concerning material degradation during charge-discharge cycles need to be addressed for the successful commercialization of ASSBs. This review introduces and discusses the interfacial reactions between Li metal and solid electrolytes, along with research cases aiming to improve these interactions. Additionally, future development directions in this field are explored.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.496-496
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• 2023

상수도관의 노후화 등으로 발생하는 누수는 안정적인 급수운영을 저해하고 경제적 손실을 발생시킬 뿐만 아니라 지반 침하 등 2차 피해가 발생할 수 있다. 상수도관 누수는 배관 내·외부 부식으로 발생하는 핀홀(Pin Hole)로 인한 관통누수, 강관 용접 시 발생하는 시공불량, 볼트 및 고무패킹 등 부자재의 노후화, 굴착 등 작업에서 발생하는 물리적 충격 등 여러 원인으로 발생할 수 있다. 상수도관에서 누수가 발생할 경우, 관 내부수가 관 밖으로 유출되어 발생하는 파열음, 유출수와 지반과의 마찰로 인한 진동 및 소음 등이 발생할 수 있다. 청음식, 상관식 누수탐사와 같은 기존 누수탐사 방식은 전문가의 경험에 대한 의존도가 매우 높으며, 기존 장비의 특성상 비금속관 및 대구경관 등 특정 환경에서는 적용이 어려우며, 효율적인 탐사가 쉽지 않은 실정이다. 이에 대한 해결책으로 본 논문에서는 상수도 누수가 의심되는 구간을 대상으로 실시간 누수음 데이터 수집 및 인공지능(Artificial Intelligence) 분석을 실시하여 기존 조사방법보다 효율적이고 신뢰성 있는 누수탐사를 수행한 사례를 분석하고자 한다.

• Korean Journal of Heritage: History & Science
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• v.5
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• pp.53-61
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• 1971

현재상태(現在狀態)에서 기온(氣溫)과 그 관계(關係)의 영역을 결정(決定)함에 있어서 우리는 아직도 실험(實驗)에 의한 충분(充分)한 자료(資料)를 우리 수중(手中)에 갖고 있지 않은데 그 자료(資料)는 극히 방대하고 시간(時間)이 소요되는 것으로서 그 자료(資料)를 모으는 일은 이런 자료(資料)를 현실화(現實化)시키는데 필요(必要)할 것이다. 현재(現在)의 예술품(藝術品)에서 부식(腐蝕)을 관찰(觀察)함으로서 이미 지금(至今)까지 얻어진 실험(實驗)에 의한 사실(事實)들로부터 또 물질(物質)은 락(落)한다는 일반적(一般的)인 인식(認識)과 더불어 이미 고려한 특별(特別)한 자연현상(自然現象)으로부터 우리는 문화재(文化財)의 보호(保護)에 합리적(合理的)으로 알맞다고 여겨지는 기후조건(氣候條件)의 영역을 결정(決定)할 수 있다. 일본(日本)에서는 곤충(昆蟲)과 곰팡이 때문에 발생(發生)하는 손해(損害)도 결코 무시(無視)되어지지 않으며 이 손해(損害)들을 피하기 위하여 20℃ 이하(以下)의 기온(氣溫)과 60% 이하(以下)의 상대습도(相對濕度)의 제한은 바람직하다. 물질(物質)은 형태(形態)에 있어서 보다 낮은 기온(氣溫)과 보다 낮은 습도(濕度)의 변화(變化)에 관(關)한 이론(理論)상의 일반적(一般的)인 상식(常識)과 실험(實驗)에 의한 사실(事實)들은 보다 낮은 기온(氣溫)은 문화재(文化財)를 이루는 물질(物質)의 상태(狀態)에 변화(變化)를 일으키지 않는다는 것을 말해준다. 금속이나 일본(日本)칠기와 같은 몇몇 특별(特別)한 예외는 있지만 권위자는 일반적(一般的)으로 그 물체(物體)를 위해서 10~20℃의 기온(氣溫)과 50~60%의 상대습도(相對濕度)의 영역을 추천(推薦)한다.

• Corrosion Science and Technology
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• v.23 no.3
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• pp.235-245
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• 2024

DLC coatings have been widely applied in industrial fields that require high corrosion resistance due to their excellent mechanical characteristics and chemical stability. In this research, effects of DLC coating thickness and defects on corrosion resistance were investigated for application of metallic bipolar plates in polymer membrane electrolyte fuel cells (PEMFCs). Results revealed that a DLC coating thickness of 0.7 ㎛ could lead to a defect size reduction of about 75.9% compared to that of 0.3 ㎛.As a result of potentiodynamic polarization experiments, the current density under a potential of 0.6 V was measured to be less than 1 ㎂/cm²,which was an excellent value. Inparticular, the delamination ratio and the decrease rate of maximum pitting depth were up to 84.8% and 63.3%, respectively, with an increase in the DLC coating thickness. These results demonstrate that DLC coating thickness and defects are factors that can affect corrosion resistance of DLC coating and its substrate.

• Corrosion Science and Technology
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• v.23 no.4
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• pp.302-309
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• 2024

The purpose of this study was to elucidate effects of a thin (tens to hundreds of nanometers) Ni-flash coating layer on hydrogen embrittlement (HE) and liquid metal embrittlement (LME) in ultra-high-strength electrogalvanized steel with a tensile strength of more than 1 GPa. Various experimental and analytical methods, including thermal desorption spectroscopy, slow strain rate testing, resistance spot welding, X-ray diffraction, and metallographic observation, were employed. Results showed that an increase in Ni target amount for flash coating resulted in a decrease in diffusible hydrogen content during electrogalvanizing, resulting in a significant decrease in HE sensitivity. Moreover, a Ni target amount of more than 1000 mg/m² drastically reduced the occurring frequency and average depth of LME. This reduction could be primarily attributed to formation of Zn-Ni intermetallic phases during the welding process that could inhibit liquefaction of intermetallic phases in the heat-affected zone. This study provides a desirable Ni target amount for Ni-flash coating on ultra-high-strength steels conducted in a continuous galvanizing line or a high-speed batch line to achieve high resistance to both HE and LME.