• Journal of the Korean GEO-environmental Society
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• 제11권10호
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• pp.33-39
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• 2010

A self-organized nano-structured, photocatalytic $TiO_2$ membrane with large surface area of anatase crystallites was successfully fabricated by anodization. The nano-structured anodized $TiO_2$ membrane was characterized using EDX, SEM and XRD techniques and the effect of electrolyte type and concentration to fabricate $TiO_2$ metal membrane was also investigated. Regular nano tubular arrays were obtained By the EDX, SEM and XRD patterns, the anodized $TiO_2$ membrane showed the enhanced photocatalytic properties of anatase phase. Photocatalytic activities of fabricated $TiO_2$ metal membrane was also experimentally investigated as model compound of humic acid.

• Journal of Korean Society of societal Security
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• 제4권2호
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• pp.49-56
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• 2011

The hydroxide precipitation method is appropriate to distinguish free metal ions with complexed metal ions with amino acids. Optimum pH conditions of hydroxide precipitation were investigated using mixed amino acids which have similar composition ratio with hydrolyzed amino acids. When applied to soil samples immobilities of Hg, Cr, and Cu ion with mixed and hydrolyzed amino acids were reasonable. But those of Cd and Zn were not sufficient.

• Proceedings of the KWS Conference
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• 대한용접접합학회 2010년도 춘계학술발표대회 초록집
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• pp.69-69
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• 2010

최근 컨테이너 선박의 초대형화로 극후물 고장력 강재인 항복응력 460MPa급 고장력강인 EH47이 개발되었다. 두께 80mm의 극후물 용접에서 용접생산성 향상을 위하여 EGW/FCAW로 양면 용접이 검토되고, 입열량은 최대 300kJ/cm의 대입열 용접이 요구된다. 이를 위해서는 강재 및 용접재료 모두 300kJ/cm 용접부 성능이 선급 규격을 만족하여야 함은 물론 마지막 조립단계에서 적용되기 때문에 용접재료의 용접작업성도 매우 크게 요구되고 있다. 먼저 대입열 용접금속에서 요구되는 저온 충격인성($vE_{-20^{\circ}C}{\geq}57J$)을 만족하기 위하여는 용접금속의 미세조직 제어가 필요하며, 특히 조대한 입계페라이트 생성을 억제하고 미세한 입내 페라이트를 균일 분포하는 것이 중요하지만, 이를 위해 용접금속의 소입성이 지나치게 높이면 경화조직인 베이나이트 분율이 증가하여 오히려 용접금속 저온 충격인성을 저하시키므로, 적절한 용접금속의 성분 제어가 중요하다. 한편 용접부는 선급에서 요구하는 최소 강도인 570MPa를 만족하기 위하여 용접금속의 소성구속 현상을 활용하여 용접부 인장강도를 확보 할 수 있음을 확인했다. 이를 위해서는 용접금속의 적정한 경화도 확보가 필요하였다. 전술한 바와 같이 대입열 용접금속 저온 충격인성 확보와 용접부 강도 측면을 고려하여 용접금속 최적의 탄소당량 범위를 제시코자 하였다. 한편 용접재료의 용접작업성은 EGW용접의 용적이행 현상은 자유비행이행으로 이루어지고 있으며 특성상 용접중 용적과 용융지 사이에 많은 순간단락 현상을 동반하고 있으며, 슬래그 유동이 불안정하면 아크 꺼짐 현상도 관찰되고 있다. 따라서, 현장용접시 원할한 용접작업성을 확보할 수 있는 평가 기준으로써 아크 전류 및 전압의 변동 정도를 설정하고, 용접재료의 용접작업성 확보 기준을 제시코자 하였다.

• Applied Chemistry for Engineering
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• 제31권4호
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• pp.423-428
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• 2020

In this work, we investigated the effect of the concentration of medium components on microbial growth and ethanol production in order to improve ethanol productivity in the Clostridium autoethanogenum culture process using syngas as a sole carbon source. Molybenum, nickel and cobalt (as heavy metal ions) were selected as examined components, and the effects of components concentration on the cell growth and ethanol production was examined. Among molybdenum concentrations of 0, 0.001, 0.01 and 0.1 g/L. a slight increase in ethanol production was observed at 0.001 g/L, but significant differences in the microbial growth and ethanol production were not observed in the examined concentration range. In the case of nickel concentration of 0, 0.001, 0.01 and 0.1 g/L, the change in the microbial growth and ethanol production was investigated, and it was found that the ethanol production using 0.001 g/L increased by 26% compared to that of using the basal medium concentration (0.01g/L). The effect of cobalt concentrations (0, 0.018, 0.18 and 1.8 g/L) on the microbial growth and ethanol production was also investigated, and the inhibition of microbial growth was observed when the cobalt usage was over 0.18 g/L. In conclusion, cobalt did not show any further improvement of ethanol production by changing concentration, however, molybdenum and nickel showed increases in the produced ethanol concentration compared to that of using 1/10 times of the basal medium concentration.

• 보존과학연구
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• 통권27호
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• pp.129-143
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• 2006

This report is on a scientific investigation of 3 pairs of 금제태환이식 which were excavated from 황남대총 납분. 태환 is a main part of 태환이식 and it could be classified with 4 types in how to produce, especially how many the golden petal was used. In this investigation, they,3 pairs of 금제태환이식 from 황남대총 남분, were in 3 of 4 types and also I could find that this result was not on the technical progress but on the ingredient of metal. Also, In the result of ingredient assay, I could find that although they were in one pair of 태환 one piece was made in gold and silver alloy and the other piece was made in 99.5 percent of pure Ag with gold amalgam plating. And the another pair was getting red from others because of making in 33percent of Ag and 77 percent of gold, high Ag content. And All pairs of 태환 have a small quantity of Copper. As above, although they are one pair they have the difference of how to produce and the difference of volume and ingredient content, it means that these pairs of 태환 from 황남대총 남분 were made in pressure of time. From now on, if we investigate the ingredient and how to produce of 태환이식 in the local comparative analysis, namely natural science method, we can find out the metal art technique and the social aspect of the ancient times as not analogical inference but scientific basis.

• Korean Chemical Engineering Research
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• 제45권4호
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• pp.378-383
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• 2007

A novel fabrication method for the multi-component metal oxides such as zirconium titanate($Zr_xTi_{1-x}O_2$) has been suggested, which would yield the uniform film characteristics and control the film composition at relatively low process temperature. The method has the basic concept that firstly layer-by-layer structure is constructed with the primitive oxide layers, which are components of the desired multi-component oxides, and secondly the film is annealed at appropriate thermal conditions for the transformation to a single-phase multi-component oxides. In this study, PRTMOCVD(pulsed rapid thermal metalorganic chemical vapor deposition) possessing the superior thickness controllability was introduced to prepare $ZrO_2$ and $TiO_2$ thin film for zirconium titanate. Single-phase zirconium titanate thin films have been prepared successfully by the interdiffusion of oxide multilayers having several alternating layers of $ZrO_2$ and $TiO_2$. The Zr/Ti ratio of zirconium titanate could be controlled easily by altering the thickness of $ZrO_2$ and $TiO_2$ thin film.

• Resources Recycling
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• 제12권1호
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• pp.55-64
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• 2003

Presently, the reuse of waste FCC catalysts, which generated from the refining process of crack oil, after the removal of con-taminated metallic impurities have not been attempted domestically yet because the separation technology f3r the impurities from waste catalysts has not been established. As a basic study far the reusable portion from the waste FCC catalysts and treatment of metallic impurities are assured, there will be invoked an significant contribution not only in the recycling of abandoned wastes up to date but also in the treatment efficiency of wastes and extraction of economical benefits from them. The magnetic separation of impurities such as Fe, Ni, and V, from waste FCC catalyst has been attempted with or without its pre-oxidation at high temperature for the purpose of its reuse. The results showed that the separability of impurities by magnetic force was high far non-preoxidized catalysts compared with preoxidized ones, and employment of screen-type matrix showed a higher separation efficiency than ball-type matrix. The separability increased with the strength of magnetic field, and the method of ball matrix has separation efficiency of maximum 51.10%. The amount of metallic impurities was in the decreasing order of V, Ni, and Fe depending upon ICP analysis.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 한국항해항만학회 2022년도 춘계학술대회
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• pp.108-109
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• 2022

In this study analyzed experimental data on noise interference caused by engine operating apply surface wave communication in the engine room. For the experiment, 7 areas of the engine room on 256 ton tug boat and measured noise during engine on off using signal analyzer for effect surface wave communication. In order to construct and actual communication network based on the analysis of the noise and confirm the characteristics of surface wave communication in the area made metal bulkheads the actual communication network installed communication equipment between three metal bulkheads and conducted a comparative experiment with wireless communication. The difference was confirmed. As a result, in the case of surface wave communication, there was no significant difference in the transmission and reception rates before and after engine operation in an environment with three bulkheads, but in the case of Wi-Fi using wireless, the performance deteriorated significantly during operation. was confirmed. As a result of analyzing the experimental data, it was confirmed that noise caused by engine operation affects wireless communication but does not affect surface wave communication. Therefore, even in the area with a lot of electromagnetic wave noise in the ship, when the surface wave communication system is configured using the ship's metal structure, it is possible to replace the wireless communication and furthermore, it is possible to apply the surface wave communication in the enclosed space and the engine room in the ship.

• Journal of the Korean Applied Science and Technology
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• 제30권4호
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• pp.649-655
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• 2013

Methanol was directly produced by the partial oxidation of methane with perovskite and mixed oxide catalysts. Perovskite ($ABO_3$) catalysts were prepared by the malic acid method with changing A and B site components. Three-component mixed oxide catalysts that have Mo and Bi as a main component were prepared by the co-precipitation method. Among the perovskite catalysts, $SrCrO_3$ showed the highest methanol selectivity of 11% at $400^{\circ}C$. For the three-component mixed oxide catalysts, there were no remarkable changes in methane conversion. Among the mixed oxide catalysts, Mo-Bi-Cr mixed oxide catalyst showed the highest methanol selectivity of 15.3% at $400^{\circ}C$. The catalytic activity and methanol selectivity of the three-component mixed oxide catalysts were directly proportional to the surface area of the catalysts.

• Economic and Environmental Geology
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• 제12권2호
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• pp.79-93
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• 1979

Twenty five samples of the scheelite-powellite series from twelve Korean tungsten deposits of various geologic settings were studied mineralogically and geochemically. Variations in the trace-element contents of the scheelite minerals are considered in relation to geologic settings and mineralogic properties. Scheelites from ore deposits developed in similar geologic settings and under similar physicochemical conditions are characterized by specific combinations of trace elements.