• Korean Journal of Optics and Photonics
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• v.17 no.6
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• pp.556-563
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• 2006

We present a comprehensive study of a chirped pulse Ti:sapphire regenerative amplifier system operating at 1 kHz. Main constituents of the system are described in detail. The amplifier stage was first converted to a repetition rate-tunable kHz gain-switched nanosecond Ti:sapphire laser. Operation characteristics at different repetition rates such as build-up times of laser pulses, pump power-dependent output powers and pulse durations, damage thresholds, and tunability ranges were studied. Based on the results achieved, the switching time of the Pocket's cell used and the round trip numbers in the regenerative amplifier were optimized at 1 kHz. The output pulses with a pulse width of 50fs from a home-made Ken lens mode-locked Ti:sapphire oscillator were used as seed pulses. The pulses were expanded to 120ps in a grating stretcher prior to coupling into the 3-mirror amplifier cavity. After amplification and recompression, a stable 1kHz Ti:sapphire regenerative amplifier system, which delivers 85-fs, $320-{\mu}J$ pulses, was fully constructed.

• Journal of Wetlands Research
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• v.16 no.3
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• pp.303-313
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• 2014

The spatial distribution characteristic of fish community were investigated at the 10 habitat types in the Nonsan stream from August, 2008 to June, 2009. The collected species during the surveyed period were 26 species belong to 6 families. Korean endemic species were Sarcocheilichthys nigripinnis morii, Squalidus japonicus coreanus, Hemiculter eigenmanni, Pseudobagrus koreanus, and Odontobutis interrupta which showed 19.2% ratio of total species. Dominant species was Zacco platypus, and subdominant species was Tridentiger brevispinis. Dominant species according to habitat types were Micropterus salmoides(substrate type pool and rock type pool), Lepomis macrochirus(channel connected pool and channel unconnected pool/abandoned type pool), T. brevispinis(channel unconnected pool/overflow type and run) and Z. platypus(riffle, meander type pool, side channel, and dam type pool). As a results of community analysis in side channel, diversity index showed relatively high values, indicating that habitat types in the Nonsan stream have relatively stable community structure. Bray-curtis cluster analysis indicated that the meander type pool and riffle showed the most similar values(80.8%). Moreover, cluster and principal component analysis were classified as 2 groups(lotic and lentic habitats).

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.249-256
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• 2006

Catalytic combustion of toluene was investigated on the Cu-Mn oxide catalysts prepared by the impregnation(Imp) and the deposition-precipitation(DP) methods. The mixing of copper and manganese has been found to enhance the activity of catalysts. It is then found that catalytic efficiency of the Cu-Mn oxide catalyst prepared by the DP method on combustion of toluene is much higher than that of the Cu-Mn oxide catalyst prepared by Imp method with the same chemical composition. The catalyst prepared by the deposition-precipitation method observed no change of toluene conversion at time on stream during 10 days and at the addition of water vapor. On the basis of catalyst characterization data, it has been suggested that the catalysts prepared by the DP method showed uniform distribution and smaller particle size on the surface of catalyst and then enhanced reduction capability of catalysts. Therefore, we think that the DP method leads on progressive capacity of catalyst and promotes stability of catalyst. It was also presumed that catalytic conversion of toluene on the Cu-Mn oxide catalyst depends on redox reaction and $Cu_{1.5}Mn_{1.5}O_4$ spinel phase acts as the major active sites of catalyst.

• Geophysics and Geophysical Exploration
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• v.17 no.4
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• pp.216-230
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• 2014

Based on the interpretation of 3D seismic profiles acquired in the northwestern area of the Ulleung Basin, East Sea, the shallow sediments consist of five seismic units separated by regional reflectors. An anticline is present in the study area that documents activity of many faults. Bottom simulating reflectors are characterized by high RMS amplitude. Acoustic blanking with low RMS amplitude is distinctively recognized in the gas hydrate stability zone. Seismic attribute analysis shows that if gas hydrates are underlain by free gas, the high reflection strength and the low instantaneous frequency are displayed below the boundary between them. Whereas, if not, the reflection strength is low and instantaneous frequency is high continuously below the gas hydrate zone. Based on the spectral decomposition of the bottom simulating reflector, the high envelope at the specific high frequency range indicates the generation of the tuning effect due to the lower free gas content. Four models for the occurrence of the gas hydrate are suggested considering the slope of sedimentary layers as well as the presence of gas hydrate or free gas.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.42 no.6
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• pp.23-36
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• 2005

PLLs have been widely used for many applications including communication systems. This paper presents a VCO with an improved negative skewed delay scheme and a PLL using this VCO. The proposed VCO and PLL are intended for replacing traditional LC oscillators and PLLs used in communication systems and other applications. The circuit designs of the VCO and PLL are based on 0.18um CMOS technology with 1.8V supply voltage. The proposed VCO employs subfeedback loops using pass-transistors and needs two opposite control voltages for the pass transistors. The subfeedback loops speed up oscillation depending on the control voltages and thus provide a high oscillation frequency. The two voltage controls have opposite frequency gain characteristics and result in low phase-noise. The 7-stage VCO in 0.18um CMOS technology operates from $3.2GHz\~6.3GHz$ with phase noise of about -128.8 dBc/Hz at 1MHz frequency onset. For 1.8V supply voltage, the current consumption is about 3.8mA. The proposed PLL has dual loop-filters for the proposed VCO. The PLL is operated at 5GHz with 1.8V supply voltage. These results indicate that the proposed VCO can be used for radio frequency operations replacing LC oscillators. The circuits have been designed and simulated using 0.18um TSMC library.

• Journal of the Korean Chemical Society
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• v.37 no.1
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• pp.119-130
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• 1993

The stereochemistry of 1,3-thiazolidine sulfoxides 1 in which 3 chiral centres are present in a molecule was elucidated by deuterium exchange and trapping reactions. 3-Acetoxy-1,3-thiazolidines 5 was oxidized to 6 and 8, corresponding $\alpha$-cis 10, $\alpha$-trans 11, $\beta$ -cis 12, and $\beta$ -trans 13 isomers were separated from their diasteromeric mixtures. Sulfoxide 10 was isomerized to more thermodynamically stable isomer 13 under neutral conditions in refluxing benzene or toluene. The methyl hydrogens of 2-methyl group in the sulfoxide 13 and those of the sulfoxide 11 were deuterated by the deuterium incorporation reactions. The intermediate sulfenic acids 25 and 26 derived from the sulfoxides 10 and 12 via sigmatropic rearrangement were trapped by 2-mercaptobenzothiazole (2-MBT) to give disufides 27 and 28 respectively. However, the sulfoxides 11 and 13 were transformed to ring expansion product dihydro-1,4-thiazine 29 under the same reaction conditions. In the presence of acid catalyst, the sulfoxides 10, 11, and 12 were converted to dihydro-1,4-thiazine 29 through the sulfoxide 13 quantitatively. The mechanisms of isomerization of sulfoxides and the formation of 29 were also discussed.

• Journal of the Korean Electrochemical Society
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• v.1 no.1
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• pp.45-51
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• 1998

[ $AB_2-type$ ] alloy, one kind of hydrogen storage alloys used as an anode of Ni-MH batteries, has large discharge capacity but has remaining problems regarding initial activation, cycle life and self-discharge. This study investigates the effects of Cr-addition and fluorination after La-addition on $Zr_{0.7}Ti_{0.3}V_{0.4}Mn_{0.4}Ni_{1.2}$, composition $AB_2-type$ alloy. EPMA and SEM surface analysis techniques were used and the crystal structure was characterized by XRD analysis. In addition, electrodes were fabricated out of the alloys and characterized by constant current cycling test, electrochemical impedance spectroscopy and potentiodynamic polarization. Cr-addition was found to be effective to cycle life and self-discharge but ineffective to initial activation due to formation of stable oxide film on surface. Fluorination after La-addition to the alloys improved initial activation remarkably due to formation of highly reactive particles on surface.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.3 no.1
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• pp.66-74
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• 1993

Potassium-Graphite Intercalation Compounds(K-GICs) have been prepared from purified natural graphite by transformed two-bulb method with variations of reaction temperature ($T_g:450^{\circ}C$, $400^{\circ}C$, $350^{\circ}C$, $300^{\circ}C$, $250^{\circ}C$).Prepared K-GICs were identified to stage transition process by X-ray diffraction data. At these results, d values of (00l) diffraction at 1 stage and 2 stage were corresponded to $5.35\AA$ and $8.73\AA$ respectively. The stage stability and energy states of K-GlCs were obtained by UV /VIS Spectrophotometric data. We found that the minimum value of reflectance was 2.67 eV(465nm) at $250^{\circ}C$and it's moved to higher energy than original graphite's. And X-ray diffraction and UV /VIS spectrophotometric datas suggest that K-GICs were formed lower stage and many charge carriers exist between C atoms of graphite. And then, these results also provide informations on the electrical and other physical properities of K-GICs.Especially, according to studied reports, d values differ from them of each author, but accurate values were established through this study.

• Clean Technology
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• v.20 no.4
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• pp.433-438
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• 2014

There is an increasing interest in the development of rechargeable batteries suitable for use in both hybrid electric vehicles and energy storage systems that require higher charge & discharge rates, bigger battery sizes and increased safety of the batteries. Spinel-type lithium titanium oxide ($Li_4Ti_5O_{12}$) as a potential anode for lithium ion batteries has many advantages. It is a zero-strain materials and it experiences no structural change during the charge/discharge precess. Thus, it has long cycle life due to its structural integrity. It also offers a stable operation voltage of approximately 1.55 V versus $Li^+/Li$, above the reduction potential of most organic electrolyte. In this study, Ru added $Li_4Ti_5O_{12}$ composites were synthesized by solid state process. The characteristics of active material were investigated with TGA-DTA, XRD, SEM and charge/discharge test. The capacity was reduced when Ru was added, however, the polarization decreased. The capacity rate of $Li_4Ti_5O_{12}$ with Ru (3%, 4%) addition was reduced during the charge/discharge precess with 10 C-rate as a high current density.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.3D
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• pp.363-373
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• 2011

With rapid economic development, general demand and interest in surroundings that consist of our lives have grown gradually. In addition, as there has been increased social interest in creating landscape of roads, which considers all important factors from the user's view including accessibility, safety, and psychological stability, efforts to improve quality of roads are required. Therefore it is needed to establish standards on safe and comfort road design based on sensibility satisfaction of road users rather than based on standardized road design guidance from the engineering perspective. To this end, research was carried out to analyze sensibility satisfaction of users about road landscape focused on elements of road cross section in a city. It identified relation between sensibility satisfaction and the elements by using principal and cluster analysis, and the multiple regression models. It also found that user's satisfaction about roads and a road landscape is high with road width (3~5 meters), clear zone (2.2~3.9 meters), road central garden (1.05~1.9 meters), shoulder (0.55~1.43 meters), median (0.65~1.625 meters), the number of travel lanes (2~5), height of trees at the central garden (6.4~15 meters) and height of buildings surrounding roads (18~44 meters or 6~15 floors).