• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.256-256
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• 2022

레이놀즈 분해법은 유속을 비롯한 변수를 평균 성분과 변동 성분으로 분해하는 분석 방법으로, 난류 분석의 기본이 되는 방법이다. 그러나 유체 내에 장애물이 존재할 경우, 흐름에 큰 와류가 존재하여 난류 변동 성분과 구분되는 고유 구조가 형성되는데, 이러한 경우에 레이놀즈 분해법을 적용하면 고유 구조의 변동 성분이 난류로 처리되어 난류 강도가 과다하게 책정될 수 있다는 한계점이 있다. 이에 대한 대안으로 제안된 것이, 변수를 평균 성분, 파동 성분, 변동 성분으로 분해하는 삼중 분해법이다. 삼중 분해법은 흐름 내의 고유 구조를 추출하는 것을 가능하게 하여 다양한 연구에서 사용되어왔다. 삼중 분해법을 구현하기 위해 이용되는 방법론 중 하나로, 공분산 행렬을 이용하여 유속장을 분해하는 방법인 적합 직교 분해법이 많이 사용된다. 본 연구에서는 원기둥 후류에 적합 직교 분해법을 사용하여 삼중 분해법을 시행하고, 후류의 흐름 구조를 분석하는 것을 목표로 하였다. 영상 유속계를 사용하여 실험을 통해 원기둥 후류의 수평 유속장을 측정하였고, 측정 자료에 적합 직교 분해법을 적용한 결과, 첫 두 모드에서 큰 규모의 와류가 파동 형태로 전파되는 것이 관찰되어 고유 구조의 존재를 확인할 수 있었다. 해당 성분을 삼중 분해법의 파동 성분으로 상정하였고, 푸리에 분석을 적용한 결과에서도 원기둥 후류의 고유 진동수가 뚜렷하게 나타나는 것을 확인하였다. 또한, 원기둥 후류의 에너지 전달 구조를 확인하기 위하여 에너지 방정식에 삼중 분해법을 적용하여 식을 유도하고, 실험 자료로부터 각 항을 계산하여 비교해보았다.

• Proceedings of the KSEEG Conference
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• 1999.04a
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• pp.181-183
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• 1999

• The Microorganisms and Industry
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• v.27 no.1
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• pp.2-17
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• 2001

Cyclomaltodextrinase(CDase, EC 3.2.1.54), maltogenic amylase(EC 3.2.1.133). neopullulanase(EC 3.2.1.135)는 cyclomaltodextrin(CD), pullulan 및 전분을 가수분해하는 효소들이다. 이 효소들은 $\alpha$-1,4-Ο-glycosidic 결합에 작용하여 CD와 전분을 말토오스로 pullulan을 panose로 가수분해할 뿐만 아니라 올리고당들을 다양한 당 수용체 분자들의 C-3, C-4. C-6 수산기로 전이시키는 활성도 갖고 있다. 이러한 특성들은 기존의 $\alpha$-amylase를 비롯한 판수화물 분해효소들과 뚜렷이 구별되는 것으로 전분 분해효소들의 분류체계에 새로운 기준점을 제시한다고 하겠다. 본 총설에서는 CDase, maltogenic amylase, neopullulanase처럼 pullulan이나 전분보다 CD를 훨씬 더 잘 분해하는 효소들과 Thermoactinomyces vulgaris amylase II(TVA II)처럼 CD를 분해하기는 하나 pullulan을 더 잘 분해하는 효소들의 생화학적, 효소적, 구조적 특성들을 종합하여 소개하고자 하였다. 이 효소들은 40~60% 정도로 아미노산 서열이 동일하고, 세포 내에 존재하며, 분자량이 62~90 kDa로 $\alpha$-amylase보다 다소 크다. 아미노산 서열 비교분석 및 maltogenic amylase와 TVA II 등의 3차구조 분석 결과, 이 효소들은 아미노 말단에 보통 $\alpha$-amylase에는 존재하지 않는 약 130개 아미노산으로된 영역을 갖고 있어 이를 매개로 이합체를 형성할 수 있는 것으로 나타났다. 이합체-단위체 평형은 염 농도, 효소 농도, 산도 등에 의해 조절되고 단위체와 이합체 모두 효소환성을 갖고 있으나, 기질 특이성이 다르며 단위체는 전분을, 이합체는 CD를 선호하는데 이는 이합체 형성 시 활성부위의 구조적 변화에 따른 것으로 분석되었다. 본 총설에서는 CD 분해효소들의 다양한 기질 특이성을 올리고머 형성 등의 구조적 특성과 관련하여 논함으로써 관련 효소들의 분류체계를 보다 명확히 할 수 있는 자료를 제공하고자 하였으며, 이러한 효소들의 생리적 기능 및 산업적 이용에 대해 제안하고자 하였다.

• Environmental and Resource Economics Review
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• v.23 no.2
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• pp.305-330
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• 2014

There has been a lot of studies to identify the driving forces of energy consumption. Many of them decomposed the final energy consumption into the intensity effect, structural effect, and production effect. Those approach, however, could not consider the transformation loss during the electric power generation. Therefore, in this study, we conducted a decomposition analysis on the primary energy use basis to reflect that transformation loss. Log mean Divisia index and refined Laspeyres methods were used for the index decomposition. As results, we could find out that the difference between two approaches were definite. The intensity effect in 2011 is -0.607 times against 1981 in the final energy case, but -0.236 times in the primary energy case. The structure effect in 2011 is 0.227 times against 1981 in the final energy case, but 0.434 times in the primary energy case. Therefore, an analysis on the primary energy basis is essential when conducting a decomposition analysis.

• Analytical Science and Technology
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• v.27 no.6
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• pp.292-299
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• 2014

Iopromide is an X-ray contrast agent that has been detected frequently with high concentration level in surface waters. Structural characterization of degradation products and measurement of degradation efficiency of iopromide by an electron beam irradiation were performed. For the fortified sample with iopromide, electron beam irradiation (UELV-10-10S, klysotrn, 10 MeV, 1 mA and 10 kW) was performed. The chemical structures of I_D_665 and I_D_663, which are degradation products of iopromide, were proposed by interpretation of mass spectra and chromatograms by LC/ESI-MS/MS. The mass fragmentation pathways of mass spectra in tandem mass spectrometry were also proposed. Iopromide was degraded 30.5~98.4% at dose of 0.3~5 kGy, and 97.8~30% in the concentration range $0.5{\sim}100{\mu}g/kg$ at electron beam dose of 0.3 kGy, respectively. Thus, increased degradation efficiency of iopromide by electron beam irradiation was observed with a higher dose of electron beam and lower concentration.

• Environmental and Resource Economics Review
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• v.20 no.2
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• pp.229-254
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• 2011

In this paper, we decomposed Greenhouse-Gas emissions of Korea's manufacturing industry using LMDI (Log Mean Divisia Index) method. Changes in $CO_2$ emissions from 1991 to 2007 studied in 5 different factors, industrial production (production effect), industry production mix (structure effect), sectoral energy intensity (intensity effect), sectoral energy mix (energy-mix effect), and $CO_2$ emission factors (emission-factor effect). By results, the structure effect and intensity effect has a role of reducing GHG emissions and The role of structure effect was bigger than intensity effect. The energy mix effect increased GHG emissions and emission-factor effect decreased GHG emissions. By time series analysis, IMF regime affected the GHG emission pattern. the structure effect and intensity effect in that regime was getting worse. After 2000, in the high oil price period, the structure effect and intensity effect is getting better.

• Journal of Sericultural and Entomological Science
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• v.37 no.2
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• pp.142-153
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• 1995

This study is undertaken to investigate proper condition and dissolution method of silk fibroin to use it functional material as powder or membrane. Silk fibroin was dissolved with calcium chloride ethanol aqueous solution and hydrochloric acid. When silk fibron was dissolved with calcium chloride ehanol aqueous solution, main chain of silk fibroin was degradaded and molecular conformation was changed. Silk fibroin powder was made from silk fibroin solution. It showed lower thermal decomposition temperature and crystallinity than those of native silk fibroin. And Its molecular conformation was random coil structure. By acid gydrolysis, main chain of silk fibroin was attacked randomly. Silk fibroin powder from hydrolysate showed high crystallinity and thermal decomposition temprature. $\beta$-form molecular conformation was found by IR and X-ray diffraction. Silk fibroin powder form dissolved part with hydrochloric acid showed low thormal decomposition temperature but high crystallinity. During acid hydrolysis, transition of molecular structure of silk fibroin occurred, and it changed to $\alpha$-helix. Silk fibroin film was achieved by casting silk fibroin solution by ehanol solution or saturated vapor treatment, and its molecular conformation changed to $\beta$structure.

• Environmental and Resource Economics Review
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• v.31 no.4
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• pp.825-848
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• 2022

This paper analyzed the factors for increasing energy consumption in the domestic manufacturing sector using the LMDI (Log mean division index) decomposition method for the period from 1999 to 2019. Among the LMDI decomposition analysis methods, both additive and multiplicative factor decomposition methods were used. in this analysis. According to the result of the analysis, the factor that increased energy consumption in the domestic manufacturing industry was the production effect, and the structure effect and intensity effect were found to be the factors that decreased energy consumption. In particular, the reduction of energy consumption due to the structure effect was greater than that of energy consumption effect due to the intensity effect. By period, it can be seen that energy consumption increased rapidly due to the production effect until 2011, but after that, the increase in energy consumption due to the production effect slowed down. On the other hand, after that, the energy reduction effect due to the structure effect and the intensity effect became prominent. In order to save energy in the manufacturing sector in the future, energy diagnosis and management through EMS (Energy management system) and FEMS (Factory energy management system) are more necessary. In addition, restructuring into a low-energy consumption industry seems more necessary.

• Rubber Technology
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• v.22 no.2
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• pp.150-177
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• 2021

• Journal of the Korean Wood Science and Technology
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• v.41 no.4
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• pp.287-292
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• 2013

Reaction of glucose and xylose to secondary hydrolysis of concentrated acid hydrolysis was quantitatively analyzed by $^1H$-NMR spectroscopic method. Anomeric hydrogen, furan and formic acid peaks were selected for quantitative analysis. The glucose was converted to the formic acid and the levulinic acid via the 5-hydroxymethylfurfural (HMF) but the xylose was converted to the fufural, which further degraded to the formic acid. The conversion to furans was slower for the glucose than the xylose. But the 5-HMF formed from the glucose was unstable in acidic aqueous medium, resulted in fast conversion to the levulinic acid and the formic acid. The furfural was relatively stable than 5-HMF at acidic aqueous medium.