• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.2B
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• pp.165-173
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• 2011

In this study, FESWMS FST2DH model was used to analyze the change of flow characteristics after making the riparian forest. The additional flow resistance is calculated based on the drag-force concept acting on each tree and the lateral momentum transfer between planted and non-planted zone could be satisfactorily reproduced by parabolic turbulence model in this depth-averaged 2-D numerical model. For model validation, the simulated velocities were compared with the measured data, showing good agreement in both tree density cases of experiments. The previous method using a proper Manning's n coefficient gives reasonable solutions only to evaluate the conveyance, but the calculated approach velocity at each tree was different from realistic value. The proposed procedure could be widely used to evaluate hydraulic effects of riparian trees in practical engineering.

• Journal of the Korean Chemical Society
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• v.22 no.5
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• pp.320-325
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• 1978

In order to elucidate the mechanism associated with the solvent extraction of uranium(VI) using DEPA and DPPA as extractant the uranium(VI) complexes formed during the solvent extraction were isolated and characterized by means of IR, NMR, chemical analysis and molecular weight determination. It has been found that uranium(VI) replaces the acidic hydrogen ions of the extractants DEPA and DPPA to form chelated polynuclear complexes, the molecular weight of U(VI)-DEPA complex being $2.1{\times}10^4$. The isolated U(VI)-DEPA complex has been found to be the same chemical species as is formed during the solvent extraction process. In case of DEPA the distribution coefficient of uranium is the largest of the pure aqueous uranium solution and is increasing for the acidic solutions in the order of $H_3PO_4.

• Journal of the Korean Chemical Society
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• v.31 no.5
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• pp.375-381
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• 1987

Rates for the aquation of trans-[Cr(tn)$_2Cl_2]^+$ and trans-[Cr(en)(tn)Cl$_2$]^+$ ions in aqueous acidic solution have been measured by spectrophotometric method at various temperatures and pressures. Activation volumes are negative and lie in the limited range -1.7 ∼ -2.9cm$^3$mol$^{-1}$ or the complex ions. Activation entropies and activation compressibility coefficients are small negative values. From the results of thermodynamic parameters, it can be inferred that the aquation of the complex ions proceed through an associative interchange(Ia) mechanism. Furthermore, the information on possible transition state structure and reaction paths can be obtained by considering total stabilization energy of the hypothetical intermediates within the framework of angular overlap model. It is found that the theoretically predicted mechanism is consistent with the experimentally observed results.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.204-204
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• 2011

최근에 들어 도시화와 이상기후의 영향으로 유역에서의 유출특성과 오염물질 발생특성이 변화하고 있어 이에 따라 체계적인 유역 관리가 요구되고 있다. 우리나라는 하천 및 호소에 대한 수질 관리를 생활하수, 공장폐수 등 점오염원을 중심으로 수질관리정책 및 대책을 추진하여 왔으나, 오염물질의 상당량은 비점오염원에서 유발되고 있다. 또한 오염총량제의 실시 이후 국내에서는 비점오염원 관리의 중요성이 점오염원에 비해 상대적으로 높아짐으로서 유역수질모델링의 중요성을 인식하고 있으며, 비점오염원에 관련된 연구도 활발히 진행되고 있다. 이를 위해 유역의 유출 및 수질 분석을 효율적으로 하기 위해 유역간 물질의 교환 및 전달이 유역 규모에 따라 얼마나 높은 정확성을 나타내는지를 분석하고 이를 검토하여 효과적인 유역수질모델링의 방법이 제시되어야 한다. 본 연구에서는 이러한 통합적 수질관리의 필요성 증대에 따라, 유역 내 수문 순환 및 비점 오염원의 발생 거동을 정량적으로 분석할 수 있는 HSPF(Hydrologic Simulation Program - Fortran) 모형을 통해 오염총량 단위유역을 각각의 소유역으로 순차적으로 모의하여 검 보정을 수행 후 그 결과로 계산된 매개변수들을 단위유역 전체에 대한 분석에 입력하여 수행한 모의 결과와 비교 평가하였다. 또한, 이를 바탕으로 비점오염원에 의한 유역 내 하천 수질 영향도를 파악하였다. 유량 및 수질해석을 위하여 남강유역의 2004년부터 2007년까지 강우와 기상자료, 유량과 오염원 자료를 수집하여 입력 자료를 구축하였다. 또한, 대상유역에 해당되는 환경기초시설의 방류 유량 및 수질을 유입시킴으로써 HSPF모의가 진행되었다. 하천수질에 영향을 줄 수 있는 비점오염원은 강우 및 기상 관련 자료의 입력을 통하여 유역 내 유출 조건의 초기입력을 수행하였으며, 강우 입력에 따른 유출에 영향을 고려하기 위하여 토지이용 및 토양도를 고려하였다. 그리고 유역의 규모를 고려하였을 때 오염총량 단위유역의 유역 규모에 따라 모의를 실시한 결과를 바탕으로 HSPF 모형의 정확성 여부를 판단하여 정확성이 높은 방법을 선택할 수 있도록 하였다. 모의결과 소유역을 순차적으로 모의한 결과(CaseA)가 전체유역을 모의한 결과(CaseB)보다 실측치와 더 높은 상관계수를 나타냄을 알 수 있었다. 본 연구에서의 평가방법을 바탕으로 유역수질모델링이 이루어진다면 추후 비점오염원에 대한 효과적인 관리에 도움이 될 것이며, 모니터링 기법 및 GIS기반 유역관리모델 개발, 4대강 비점오염원 최적관리기법 연구 등에 활용할 수 있을 것으로 사료된다.

• Polymer(Korea)
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• v.35 no.2
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• pp.176-182
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• 2011

Liquid crystalline aromatic polyesters (LCPs) are representative examples of thermotropic liquid crystalline polymers, whose structure-property relationships have been the subject of many researches. In this study, we synthesized organo-soluble liquid crystalline aromatic polyesters, and their composites with acetylene-terminated thermoset resins were prepared and characterized. Soluble LCPs were synthesized by employing 6-hydroxy-2-naphthoic acid, terephthalic acid, isophthalic acid, and 4-aminophenol as monomers via condensation polymerization based on transesterfication and transamidation. Acetylene-terminated thermoset resins were synthesized by the reaction of 4-ethynylaniline with terephthaloyl dichloride, isophthaloyl dichloride or 4,4'-biphenyldicarbonyl dichloride. We prepared the soluble LCP/thermoset composites by solution blending followed by thermal treatment. The thermal stability, thermal expansion coefficient, and dielectric properties of the composite were studied.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.12
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• pp.1093-1099
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• 2010

For Very High Temperature Reactors (VHTR), the designs of the Intermediate Heat Transport Loop (IHTL) and the Intermediate Heat Exchanger (IHX) are particularly difficult because of the high-temperature operation (up to $950^{\circ}C$). In this study, Flinak molten salt, a eutectic mixture of LiF, NaF, and KF (46.5:11.5:42.0 mole %) is considered as the heat transporting fluid in the IHTL. To evaluate the flow and heat transfer performance of the Flinak molten salt in small channels with hydraulic diameters in the millimeter range, a double-pipe heat exchanger was constructed using small-diameter tubes for the heat exchange between the Flinak and the gas flow. The experimental data showed that, for laminar Flinak flow, the measured friction factors were close to the 64/Re curve and the Nusselt numbers were generally between 3.66 and 4.36.

• Solar Energy
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• v.15 no.1
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• pp.29-38
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• 1995

This paper concerns the study of a two-stage binary absorption cycle employing the refrigerant/absorbent combinations of $LiBr/H_2O$ and $NH_3/H_2O$. This cycle consists of coupling two single-effect absorption cycles so that the first stage absorber and condenser produces heating water to evaporate refrigerant in the evaporator of the second stage. The effect of operating variables such as evaporator temperature, condenser and absorber temperature, and generator temperature on the coefficient of performance and temperature lift have been studied for two-stage binary absorption heat pump systems. It is found that this cycle has a large temperature lift at $105^{\circ}C$ of optimum generator temperature to obtain $50^{\circ}C$ of condenser temperature.

• Journal of the Institute of Electronics Engineers of Korea SP
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• v.42 no.6
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• pp.27-32
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• 2005

An effective video watermarking algorithm is proposed to protect the copyright. The watermarking procedure is based on a three-dimensional discrete wavelet transform (3D DWT) and spread spectrum sequences. Two perceptual binary watermarks are preprocessed using mixing and pseudorandom permutation. After dividing the video sequence into video shots, the 3D DWT is performed, then the preprocessed watermarks are embedded into the 3D DWT coefficients, while considering robustness and invisibility, using two spread spectrum sequences defined as the user key. Experimental results show that the watermarked frames are subjectively indistinguishable from the original frames, plus the proposed video watermarking algorithm is sufficiently robust against such attacks as low pass filtering, frame dropping, frame average, and MPEG coding.

• Journal of the Korean Geotechnical Society
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• v.20 no.1
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• pp.29-36
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• 2004

Batch and column tests were performed to develop the design factors for permeable reactive barriers(PRBs) against the contaminated groundwater with ammonium from unsanitary landfill. Clinoptilolite, one of natural zeolites having excellent cation exchange capacity(CEC), was chosen as the reactive material. In batch test, the reactivity of clinoptilolite to ammonium was examined by varying the initial concentration of ammonium and the particle size of clinoptilolites. One gram of clinoptilolite showed removal efficiency about 80% against the ammonium except in very high initial concentration of 80 ppm, but the effect of particle size of clinoptilolite was not noticeable. Permeability test was performed for the specimens made of clinoptilolite and Jumunjin sand with 20 : 80 weight ratio. Flexible wall permeameter was employed far permeability test. The specimen containing the washed 0.42-0.85mm clinoptilolite showed the highest permeability of about $10^{-3}$/s. In column test, the reactivity of mixed materials against ammonium in flowing condition was examined with the landfill leachate. With the test results, clinoptilolite was found to be a suitable material for PRBs against the contaminated groundwater with ammonium.

• The Journal of Engineering Geology
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• v.16 no.2 s.48
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• pp.153-159
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• 2006

The discharges of time, technology and finance was increased and it was difficult to use water resources effectively by serious water pollutions. Thus the main aim of this work was focused on effectiveness of water treatment process using non-controlled indicators such as UV absorbance($E_{260}$) and particle counts that provided analytical results with simple and rapid. The soluble aluminum was increased by the increase of aluminum doses for turbidity removals It means that the water quality was not controlled by only turbidity monitoring cause maximum turbidity removal did not guarantee minimum residual aluminum in an aluminum-based coagulation. E removal efficiency appeared to be the promising indicator for monitoring the effectiveness of the water quality process such as coagulation and nanofiltration membranes for arsenic(V). On the basis of the particle monitoring, it was also found that the particle counts could be used very useful for changing the coagulants in real water treatments.