• Title/Summary/Keyword: 교차 스펙트럼

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Optical spectroscopy of Tb3+ ions doped NaCa(PO3)3 phosphors (Tb3+ 이온이 첨가된 NaCa(PO3)3 형광체의 형광특성)

  • Yoon, Changyong
    • Journal of the Korean Society of Radiology
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    • v.12 no.4
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    • pp.451-457
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    • 2018
  • Luminescence properties of $NaCa(PO_3)_3$ doped with $Tb^{3+}$ ions are investigated by optical and laser excitation spectroscopy. The phosphors were prepared by solidstate reaction method The X-ray diffraction(XRD) was used to analyze the crystal structure and the crystallinity of the samples. The excitation and emission spectra and decay curve of $NaCa(PO_3)_3:Tb^{3+}$(0.01 ~ 30mol%) were measured at room temperature. The f - d band of $Tb^{3+}$ is observed in the excitation spectra of $NaCa(PO_3)_3:Tb^{3+}$ in the wave length region 205 ~ 245 nm. Strong emission lines due to the $^5D_4{\rightarrow}^7F_J$ transition and weak emission lines due to the $^5D_4{\rightarrow}^7F_J$ transition are observed in the emission spectra of $NaCa(PO_3)_3:Tb^{3+}$. The energy transfer and cross relaxation between $Tb^{3+}$ ions are discussed in $NaCa(PO_3)_3:Tb^{3+}$ in the emission spectra and life time.

Discrimination model for cultivation origin of paper mulberry bast fiber and Hanji based on NIR and MIR spectral data combined with PLS-DA (닥나무 인피섬유와 한지의 원산지 판별모델 개발을 위한 NIR 및 MIR 스펙트럼 데이터의 PLS-DA 적용)

  • Jang, Kyung-Ju;Jung, So-Yoon;Go, In-Hee;Jeong, Seon-Hwa
    • Analytical Science and Technology
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    • v.32 no.1
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    • pp.7-16
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    • 2019
  • The objective of this study was the development of a discrimination model for the cultivational origin of paper mulberry bast fiber and Hanji using near infrared (NIR) and mid infrared (MIR) spectroscopy combined with partial least squares discriminant analysis (PLS-DA). Paper mulberry bast fiber was purchased in 10 different regions of Korea, and used to make Hanji. PLS-DA was performed using pre-treated FT-NIR and FT-MIR spectral data for paper mulberry bast fiber and Hanji. PLS-DA of paper mulberry bast fiber and Hanji samples, using FT-NIR spectral data, showed 100 % performance in cross validation and the confusion matrix (accuracy, sensitivity, and specificity). The discrimination models showed four regional groups which demonstrated clearer separation and much superior score plots in the NIR spectral data-based model than in the MIR spectral data-based model. Furthermore, the discrimination model based on the NIR spectral data of paper mulberry bast fiber had highly similar score morphology to that of the discrimination model based on the NIR spectral data of Hanji.

Characteristics Analysis of the Time Selective Multipath Fading Channel Model for Mobile Communication (이동 통신을 위한 시간선택성 다중경로 페이딩 채널 모델의 특성 평가)

  • 박수진;고석준;이경하;최형진
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.26 no.5A
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    • pp.836-845
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    • 2001
  • 본 논문에서는 시간 선택성 다중경로 이동 무선 채널을 다양한 방법으로 모델링 하고 그에 따른 여러 가지 특성평가를 제시하였다. 모델링 방법에는 Jakes 방식과 시간 영역에서 독립적인 두 개의 가우시안 잡음 발생기와 정형필터(shaping filter)를 사용하는 방식 및 주파수 영역에서 필터링 하는 방식이 있다. 이 세 가지 모델링 방법의 성능을 진폭의 자기상관함수, 상호상관함수, 누적분포함수(Cumulative Distribution Function), 레벨 교차율(Level Crossing Rate), 평균 페이딩 지속 시간(Average Duration of Fades), 위상차의 확률 밀도, 위상차의 자기상관함수 등의 측면에서 시뮬레이션하고 그 결과치와 이론치 간의 특성 비교를 제시하였다. 특히, 확산 대역 시스템을 고려했을 때 이상적인 채널 추정을 가정한 레이크 수신기에서의 BER 성능을 다중경로 개수에 따라 보임으로써 여러 가지 채널 모델링 중에서 주파수 영역에서 필터링 하는 방식이 이동 무선 채널을 모델링 하는데 있어 가장 적합하다는 것을 보였다. 마지막으로 비대칭 도플러(Doppler) 스펙트럼을 모델링 하는 것도 주파수 영역에서 필터링 하는 방식이 편리하다.

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An Effective x-dB Bandwidth Measurement Method of FM Signals using moving Average (동적 평균을 이용한 FM 신호의 효율적인 x-dB 대역폭 측정방법)

  • 김영수;유익한;조병모
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.11 no.7
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    • pp.1233-1239
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    • 2000
  • In this paper, a new approach is proposed for effectively estimating the occupied bandwidth of frequency modulation (FM) signals. The proposed method makes use of the smoothing niter for removing the perturbation of spectrum envelope, which frequently occurs in FM signals having the instantaneous frequency. An effective procedure is derived for finding the relatively accurate bandwidth of FM signals combined with x-dB bandwidth measurement method, which International Telecommunication Union-Radiocommunication (ITU-R) recommended. It was shown that the proposed approach provides superior performance relative to the one obtained with the x-dB bandwidth measurement method in terms of sample bias and mean squared error of bandwidth estimates.

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A Study on the Synthesis of Korean Speech by Formant VOCODER (포르만트 VOCODER에 의한 한국어 음성합성에 관한 연구)

  • 허강인;이대영
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.14 no.6
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    • pp.699-712
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    • 1989
  • This paper describes a method of Korean speech synhes is using format VOCODER. The parameters of speech synthes is are a follows, 1) format F1, F2, and F3 by spectrum moment method and F4, F5 using the length of vocal tract. 2) pitch frequencies obtained by optimu, Comb method using AMDF. 3) short time average energy and short time mean amplitude. 4) The decision method of bandwidth reportd by Fant. 5) voicde/unvoiced discrimination using zerocrossing. 6) excitation wave reported by Rosenberg. 7) gaussian white noise. Synthesis results are in fairly good agreement with original speech.

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Liquid-Liquid Equilibria of Poly(4-vinylphenol)(PVPh)/Ethyl Acetate and PVPh/Butyl Acetate Solutions (Poly(4-vinylphenol)(PVPh)/Ethyl Acetate 및 PVPh/Butyl Acetate 용액계의 액-액 상평형)

  • Kim, Mi Kyung;Kim, Ki-Chang
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.704-714
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    • 2005
  • Phase separations of Poly(4-vinylphenol)(PVPh)/Ethyl Acetate and PVPh/Butyl Acetate solutions were measured using the thermal optical analysis (TOA) method. The experimental phase separation data were correlated with liquid-liquid equilibria relations based on PC-SAFT equation of state. The phase separations of these system showed the behaviors of LCST (lower critical solution temperature)-type. The measured cloud temperatures were lowered with increasing in molecular weights of polymer(PVPh), and cloud temperatures of PVPh/Ethyl Acetate solutions shifted to lower temperature regions, compared to the PVPh/Butyl Acetate solutions. Extents of cross-association between solvent molecule and polymer in the PVPh/Ethyl Acetate solutions were measured using the FT-IR spectrum analysis method, and cross-association parameters of PC-SAFT model were estimated from experimental extents of cross-association. By using the estimated cross-association parameters between PVPh and solvent molecule, binodal and spinodal curves of liquid-liquid equilibria in PVPh/Ethyl Acetate and PVPh/Butyl Acetate solutions were calculated from PC-SAFT equation of state. The calculated binodal curves of these system were shown to be well agreeable with the experimental cloud temperature curves.

A Study on High-Precision DEM Generation Using ERS-Envisat SAR Cross-Interferometry (ERS-Envisat SAR Cross-Interferomety를 이용한 고정밀 DEM 생성에 관한 연구)

  • Lee, Won-Jin;Jung, Hyung-Sup;Lu, Zhong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.28 no.4
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    • pp.431-439
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    • 2010
  • Cross-interferometic synthetic aperture radar (CInSAR) technique from ERS-2 and Envisat images is capable of generating submeter-accuracy digital elevation model (DEM). However, it is very difficult to produce high-quality CInSAR-derived DEM due to the difference in the azimuth and range pixel size between ERS-2 and Envisat images as well as the small height ambiguity of CInSAR interferogram. In this study, we have proposed an efficient method to overcome the problems, produced a high-quality DEM over northern Alaska, and compared the CInSAR-derived DEM with the national elevation dataset (NED) DEM from U.S. Geological Survey. In the proposed method, azimuth common band filtering is applied in the radar raw data processing to mitigate the mis-registation due to the difference in the azimuth and range pixel size, and differential SAR interferogram (DInSAR) is used for reducing the unwrapping error occurred by the high fringe rate of CInSAR interferogram. Using the CInSAR DEM, we have identified and corrected man-made artifacts in the NED DEM. The wave number analysis further confirms that the CInSAR DEM has valid Signal in the high frequency of more than 0.08 radians/m (about 40m) while the NED DEM does not. Our results indicate that the CInSAR DEM is superior to the NED DEM in terms of both height precision and ground resolution.

Measurements and Data Processing for Blast Vibrations and Air-blasts (발파진동 및 발파소음의 측정 및 자료처리)

  • Choi, Byung-Hee;Ryu, Chang-Ha
    • Explosives and Blasting
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    • v.33 no.3
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    • pp.29-50
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    • 2015
  • Safe blast criteria based on the concept of scaled distances can be obtained from the statistical analysis on measured peak particle velocity data of blast vibrations. Two types of scaled distance widely used in Korea are the square root scaled distance (SRSD) and cube root scaled distance (CRSD). In contrast to SRSD scheme, however, the function of maximum charge per delay for CRSD increases without bound after the intersection point of these two functions despite of the similar goodness of fits. To prevent structural damage that may be caused by the excessive charge in the case of CRSD, it is suggested that CRSD be used within a specified distance slightly beyond the intersection point. On the other hand, there are several attempts that predict vibration level(VL) from the peak particle velocity(PPV) or estimate VL based on the scaled distances without considering their frequency spectra. It appears that these attempts are conducted in blasting contracts only for the purpose of satisfying the environment-related law, which mainly deals with the annoyance aspects of noises and vibrations in human life. But, in principle there could no correlation between peaks of velocity and acceleration over entire frequency spectrum. Therefore, such correlations or estimations should be conducted only between the waves with the same or very similar frequency spectra. Finally, it is a known fact that structural damage due to ground vibration is related to PPV level, the safety level criteria for structures should be defined by allowable PPV levels together with their zero crossing frequencies (ZCF).

A SPECTROSCOPIC STUDY OF THE CLOSE BINARY AG VIRGINIS (근접쌍성 AG Virginis의 분광학적 연구)

  • Kim, Ho-Il;Lee, Chung-Uk;Lee, Jae-Woo;Sohn, Mi-Rim
    • Journal of Astronomy and Space Sciences
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    • v.22 no.4
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    • pp.353-362
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    • 2005
  • We performed a new high-resolution spectroscopy of AG Vir for 4 nights from 25 March 2004 using the BOES (Bohyunsan Optical Echelle Spectrograph) attached to the 1.8-m reflector at Bohyunsan Optical Astronomy Observatory, and obtained a total of 59 spectra where all orbital phases are covered. To get the radial velocities of the binary system, both method of the CCF (Cross-Co..elation Function)and the BF (Broadening Function) were applied to the analysis of all the observed spectra. From these, the CCF could calculate the radial velocities of the primary star alone, while the BF could determine those of the primary and the secondary components. New absolute dimensions were deduced with the combination of our spectroscopic orbital elements ($K_1=90.5km/s$$K_2=258.8$) and the photometric solutions of Bell, Rainger, & Hilditch (1990): $A_1,=1.99M_\bigodot,\;M_2=0.62M_\bigodot,\;R_1=2.21R_\bigodot,\;R_2=1.36R_\bigodot,\;L_1=13.17L_\bigodot,\;and\;L_2=3.47L_\bigodot$. Our absolute parameters are larger and brighter than those derived from Bell, Rainger, & Hilditch (1990). We re-analyzed all the previous radial-velocity curves of AG Vir and, as a result, can see that its system velocity scatters largely up to ${\pm}8km/s$. However, we, at present, cannot determine this as the light-time effect due to the third body, which was suggested as a cause of the orbital period changes by Qian (2001).

Electrical and Magnetic Properties of Magnetite Powder during a Verwey Transition (Verwey 전이와 마그네타이트의 전기적 및 자기적 특성)

  • Yoon, Sunghyun
    • New Physics: Sae Mulli
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    • v.68 no.12
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    • pp.1302-1307
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    • 2018
  • The crystallographic, electrical and magnetic behaviors of magnetite powder in the vicinity of its Verwey transition were investigated in this study. Magnetite was prepared by synthesizing a nanoparticle precursor and then annealing it at $800^{\circ}C$ for 1 h under a dynamic vacuum. Crystallographic and morphology analyses were done by using scanning electron microscope (SEM) and X-ray diffraction (XRD). The electrical and the magnetic properties were examined by using $M{\ddot{o}}ssbauer$ spectroscopy, vibrating sample magnetometer (VSM) and resistivity measurement. Both the magnetic moment and the resistivity showed discontinuous changes at the Verwey transition temperature ($T_V$). The temperature dependence of magnetic anisotropy constant showed a monotonic decrease with increasing temperature, with slight dip near $T_V$. $M{\ddot{o}}ssbauer$ spectra showed the superposition of two sextets, one from the tetrahedral (A) and the other from the octahedral (B) sites. The results revealed that identical charge states existed in the B site at temperatures both above and below $T_V$. A coordination crossover resulted in a transition from an inverse to a normal spinel at or close to $T_V$.