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Effect of Molecular Weight Distribution of Intrinsically Microporous Polymer (PIM-1) Membrane on the CO2 Separation Performance (마이크로기공 고분자(PIM-1)의 분자량 분포에 따른 이산화탄소 기체 분리막의 성능 변화 연구)

  • Ji Min Kwon;Hye Jeong Son;Jin Uk Kim;Chang Soo Lee
    • Membrane Journal
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    • v.33 no.6
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    • pp.362-368
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    • 2023
  • This research article explores the application of Polymer of Intrinsic Microporosity (PIM-1) as a cutting-edge material for CO2 gas separation membranes in response to the escalating global concern over climate change and the imperative to reduce greenhouse gas emissions. The study delves into the synthesis, molecular weight control, and fabrication of PIM-1 membranes, providing comprehensive insights through various characterization techniques. The intrinsic microporosity of PIM-1, arising from its unique crosslinked and rigid structure, is harnessed for selective gas permeation, particularly of carbon dioxide. The article emphasizes the tunable chemical properties of PIM-1, allowing for customization and optimization of gas separation membranes. By controlling the molecular weight, higher molecular weight (H-PIM-1) membranes are demonstrated to exhibit superior CO2 permeability and selectivity compared to lower molecular weight counterparts (L-PIM-1). The study's findings highlight the critical role of molecular weight in tailoring PIM-1 membrane properties, contributing to the advancement of next-generation membrane technologies for efficient and selective CO2 capture-an essential step in addressing the pressing global challenge of climate change.

CRLH Rectangular Waveguide with Balanced Condition above Cut-off Frequency (차단 주파수 이상에서 평형 조건을 만족하는 CRLH 직각 도파관)

  • Kim, Dong-Jin;Lee, Jeong-Hae
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.9
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    • pp.912-918
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    • 2011
  • In this paper, a composite right-/left-handed(CRLH) rectangular waveguide satisfying a balanced condition above the cut-off frequency is presented. The proposed structure consists of one shorted stub and two twisted H-plane irises which produce an effectively negative permeability and permittivity, respectively. The CRLH structure can independently control the series and shunt resonance frequencies of a CRLH transmission line which determine the left-handed(LH) and right-handed(RH) bands due to a minimized coupling between a shorted stub and twisted H-plane irises. Thus, the design of the CRLH waveguide satisfying a balanced condition is possible. To analyze the CRLH structure, a crossly connected equivalent circuit is derived. The simulated and measured results confirm that the proposed CRLH waveguide has a transmission property without a band gap among the LH and RH bands.

Design of Q-Band LC VCO and Injection Locking Buffer 77 GHz Automotive Radar Sensor (77 GHz 자동차용 레이더 센서 응용을 위한 Q-밴드 LC 전압 제어 발진기와 주입 잠금 버퍼 설계)

  • Choi, Kyu-Jin;Song, Jae-Hoon;Kim, Seong-Kyun;Cui, Chenglin;Nam, Sang-Wook;Kim, Byung-Sung
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.3
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    • pp.399-405
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    • 2011
  • In this paper, we present the design of Q-band LC VCO and injection locking buffer for 77 GHz automotive radar sensor using 130 nm RF CMOS process. To improve the phase noise characteristic of LC tank, the transmission line is used. The negative resistance by the active device cross-coupled pair of buffer is used for high output power, with or without oscillation of buffer. The measured phase noise is -102 dBc/Hz at 1 MHz offset frequency and tuning range is 34.53~35.07 GHz. The output power is higher than 4.1 dBm over entire tuning range. The fabricated chip size is $510{\times}130\;um^2$. The power consumption of LC VCO is 10.8 mW and injection locking buffer is 50.4 mW from 1.2 V supply.

Cross-layer Design of Joint Routing and Scheduling for Maximizing Network Capacity of IEEE 802.11s based Multi-Channel SmartGrid NAN Networks (IEEE 802.11s 를 사용한 스마트그리드 NAN 네트워크의 최대 전송 성능을 위한 다중 채널 스케쥴링과 라우팅의 결합 설계)

  • Min, Seok Hong;Kim, Bong Gyu;Lee, Jae Yong;Kim, Byung Chul
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.5
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    • pp.25-36
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    • 2016
  • The goal of the SmartGrid is to maximize energy efficiency by exchanging bi-directional real-time power information with the help of ICT(Information and Communication Technology). In this paper, we propose a "JRS-MS" (Joint Routing and Scheduling for Multi-channel SmartGrid) algorithm that uses numerical modeling methods in IEEE 802.11s based STDMA multi-channel SmartGrid NAN networks. The proposed algorithm controls the amount of data transmission adaptively at the link layer and finds a high data-rate path which has the least interference between traffic flows in multi-channel SmartGrid NAN networks. The proposed algorithm improve transmission performance by enhancing network utilization. By comparing the results of performance analysis between the proposed algorithm and the JRS-SG algorithm in the previous paper, we showed that the JRS-MS algorithm can improve transmission performance by maximally utilizing given network resources when the number of flows are increasing in the multi-hop NAN wireless mesh networks.

Selectivity and Permeability Characteristics of Pure CO2 and N2 Gases through Plasma Treated Polystyrene Membrane (플라즈마 처리된 폴리스티렌 막을 통한 순수한 CO2 와 N2 기체의 선택·투과 특성)

  • Hwang, Yui-Dong;Shin, Hee-Yong;Kwak, Hyun;Bae, Seong-Youl
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.588-596
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    • 2006
  • The surface of polystyrene membrane treated by Ar, $O_2$ plasma, and the effects were observed before and after the treatment and permeability of $CO_2$, $N_2$ and selectivity of $CO_2$ relative to $N_2$ was measured using continuous flow gas permeation analyzer (GPA). The mole ratio of O over C in the surface was increased from 0 to 0.179 with Ar plasma treatment and route mean square of surface was increased from $15.86{\AA}$ to $71.64{\AA}$. Therefore the contact angle was decreased from $89.16^{\circ}$ to $18.1^{\circ}$. Thus Plasma treatments made surface of membrane tend to be highly hydrophilic. The optimum condition for the $CO_2$ permeability and ideal selectivity of the plasma treated membrane was as follows: the measurement of Ar (60 W, 2 min, $70^{\circ}C$) plasma treatment was $1.14{\times}10^{-12}[m^3(STP){\cdot}m/m^2{\cdot}sec{\cdot}atm]$ and 4.22. In the case of $O_2$ plasma treatment, the contact angle was decreased at $13.56^{\circ}$ with increase of O/C ratio ($0.189{\AA}$) and route mean square of surface ($57.10{\AA}$). The optimum condition for the $CO_2$ permeability and ideal selectivity of the plasma treated membrane was as follows: the measurement of $O_2$ (90 W, 2 min, $70^{\circ}C$) plasma treatment was $7.1{\times}10^{-12}[m^3(STP){\cdot}m/m^2{\cdot}sec{\cdot}atm]$ and 11.5. After plasma treatment, the changes of membrane surface were all subtly linked with both cross-linking and etching effects. Finally, it was confirmed that the gas permeation capacity and selectivity of the modified membrane with plasma could be improved by an appropriate control of the plasma conditions such as treatment time, the power input and sort of plasma gas.

Comparative Study on the Methodology of Motor Vehicle Emission Calculation by Using Real-Time Traffic Volume in the Kangnam-Gu (자동차 대기오염물질 산정 방법론 설정에 관한 비교 연구 (강남구의 실시간 교통량 자료를 이용하여))

  • 박성규;김신도;이영인
    • Journal of Korean Society of Transportation
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    • v.19 no.4
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    • pp.35-47
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    • 2001
  • Traffic represents one of the largest sources of primary air pollutants in urban area. As a consequence. numerous abatement strategies are being pursued to decrease the ambient concentration of pollutants. A characteristic of most of the these strategies is a requirement for accurate data on both the quantity and spatial distribution of emissions to air in the form of an atmospheric emission inventory database. In the case of traffic pollution, such an inventory must be compiled using activity statistics and emission factors for vehicle types. The majority of inventories are compiled using passive data from either surveys or transportation models and by their very nature tend to be out-of-date by the time they are compiled. The study of current trends are towards integrating urban traffic control systems and assessments of the environmental effects of motor vehicles. In this study, a methodology of motor vehicle emission calculation by using real-time traffic data was studied. A methodology for estimating emissions of CO at a test area in Seoul. Traffic data, which are required on a street-by-street basis, is obtained from induction loops of traffic control system. It was calculated speed-related mass of CO emission from traffic tail pipe of data from traffic system, and parameters are considered, volume, composition, average velocity, link length. And, the result was compared with that of a method of emission calculation by VKT(Vehicle Kilometer Travelled) of vehicles of category.

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