• Title/Summary/Keyword: 광택제

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Conservation Process of Large-earthen ware in Geumgangsa Temple Site - A Study on the Cyanoacrylate Adhesive Used for Large-earthen Ware Joining - (금강사지 출토 대형 토기의 보존 - 대형 토기접합에 사용된 순간 접착제에 대한 연구 -)

  • Lee, Dahae;Hwang, Hyunsung;Shin, Minkyeong
    • Conservation Science in Museum
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    • v.13
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    • pp.1-11
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    • 2012
  • While the project for registering the unregistered relics that had been stored in the relic storage warehouse was in progress, restoration operations were started for the large size pottery pieces that had been excavated from the Geumgangsa Temple Site and it is attempted to explain the pottery pieces and to introduce the process of the overall conservation treatment. About 600 pieces of large size pottery had been separately stored in more than 40 relic boxes in their original damaged condition without making it possible to figure out their shape, size, usage and quantity at all. Due to the enormous number and weight of the pottery pieces, they were, first of all, pre-classified largely into 6 groups of pottery pieces in consideration of the visible features such as pottery thickness, color sense and glaze brilliance, etc. for each kind of pottery raw material. However, as a result of making them adhere together on a temporary basis, they turned out to be only one piece of pottery in reality. In this restoring process, in order to see if the generally used cyanoacrylate adhesive was in fact safe when a very large, heavy and deformed pottery piece was to be put together, its safeness was checked by examining the adhesion velocity, adhesion strength and dissolution velocity for both from low to high viscosities through preliminary experiments. In order to restore the lost parts after putting the existing pieces together, diversified epoxy resins were used to fit their shapes. Considering that the bottom of the restored relic was shaped to be not flat but round without allowing it to stand alone, an exhibition mount was manufactured so that the relic could be stored stably and used readily for exhibition.

Study on the Chemically Method of Epoxy Restoration Material in Antic Ceramics and Stabilization of Their Materials (토기.도자기 복원에 사용된 에폭시 복원재료의 화학적 제거방법과 그 안정성에 관한 연구)

  • Han, Won-Sik;Bae, Jin-Soo;Park, Gi-Jung;Hong, Tae-Kee;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.26 no.1
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    • pp.25-32
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    • 2010
  • The yellowing is always occurred phenomena in epoxy restoration material of antic-ceramics. For re-restoration of remains with epoxy restoration material, the epoxy elimination step is the first one in all course of restoration In this paper, the chemically elimination treatments methods of epoxy in various antic-ceramics were discussed. We fabricated the epoxy elimination material for antic-ceramics restoration which were made up Dichloromethane and Dichlormethane based Dimethylformamide solution. Dichloromethane and Dichloromethane + Dimethylformamide mixture were applied to epoxy in various antic-ceramic sample. Particularly, Dichloromethane + Dimethylformamide solution had the best result in variation of color change, gloss, vending strength, weight, exfoliation time test after deposition in this solution. Dichloromrthane had the volume increase characteristics for epoxy material and Dimethylformamide had the mollification ones. So, Dichloromathane increased exfoliation in approximal surface of the epoxy material and antic ceramic, and Dimethylformamide decreased the surface hardness of epoxy. In this result, epoxy material even inside of ceramic that have very weak inside bonding is adaptable and stable eliminated. And in order to show the perfect elimination of this material, we successfully dissolve the epoxy restoration material in one antic pottery that is in one university museum's possession using this mixture. So, there is guarantee in the eternity and stabilization of restoration for antic-ceramics.

Surgical Treatment and Analysis of Esophageal Diseases (식도 질환의 외과적 치료 및 분석)

  • Choe, Yeong-Ho;Jo, Seong-Jun;Jo, Won-Min;Kim, Gwang-Taek
    • Journal of Chest Surgery
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    • v.29 no.10
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    • pp.1123-1128
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    • 1996
  • A clinical study was performed on 152 cases of surgical esophageal disease treated by the Department of Thoracic & Cardiovascular Surgery of Korea University Hospital from Jan. 1989 through July 1994. The most common esophageal disease was cancer which was seen in 73 cases (48%) among 152 cases. All were treated surgically' 52 patients (71%) were managed by curative or palliative resection with reconstruction and feeding gastrostomy or jejunostomy, otherwise Celestine tube insertion was performed on the remaining 21 patients for palliatio'n. Esophageal leiomyoma occurred in 6 cases(3.9%), among them 1 case was performed with trio recoscopic enucleation . Achalasia were in 7 cases (4.6%) and was treated with modified Heller's m otomy and with Belsey Mark IV operation. Diverticulum were in 11 cases (7.2%). Esophageal stricture occurred in 20 cases (14.1 %) and 17 of 20 cases were managed with bypass surgery. Esophageal perforation was seen in 20 cases, its cause was instrumental trauma in 7 cases, stab wound in 4 cases, foreign body in 4 cases, spontaneous perforation in 3 cases, and others 1 case Other disease including congenital lesion was seen In 1 Scases.

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Preparation and characterization of CoAl2O4 blue ceramic nano pigments by attrition milling (어트리션밀을 이용한 CoAl2O4 나노 무기 안료의 제조 및 특성 평가)

  • Lee, Ki-Chan;Yoon, Jong-Won;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.5
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    • pp.255-264
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    • 2013
  • Cobalt aluminate ($CoAl_2O_4$) is a highly stable pigment with excellent resistance to light, weather, etc., which has resulted in widespread use as a ceramic pigment. Due to the unique optical characteristics, $CoAl_2O_4$ is generally used as a coloring agent to decorate porcelain products, glass, paints and plastics. Here, $CoAl_2O_4$ pigments were synthesized by polymerized complex method and solid state reaction. Then $CoAl_2O_4$ pigment were grinded using the attrition milling with 1 mm size zirconia ball for 3 hours. The attrition milling process was performed at the constant speed of 800 rpm and ball to powder weight ratio (BPR) was 100 : 1. The characteristics of synthesized pigment were analyzed by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), particle size analyser (PSA) and CIE $L^*a^*b^*$. The XRD patterns of $CoAl_2O_4$ show single phase spinel structure. The particle size of $CoAl_2O_4$ measured by FE-SEM, TEM and PSA analysis was in the range of 100~200 nm. The blue color of obtained $CoAl_2O_4$ pigments could be confirmed through CIE $L^*a^*b^*$ measurement.

Breeding of ‘Gommany’ Cultivar of Gomchwi with Disease Resistant, High Quality, and Yield (고품질 내병 다수성 곰취 신품종 ‘곰마니’ 육성)

  • Suh, Jong Taek;Yoo, Dong Lim;Kim, Ki Deog;Lee, Jong Nam;Kwon, Young Seok;Kim, Won Bae
    • Korean Journal of Plant Resources
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    • v.29 no.5
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    • pp.625-629
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    • 2016
  • A new Gomchwi cultivar ‘Gommany’ was bred by crossing between Gomchwi (Ligularia fischeri (Ledeb.) Turcz.) and Handaeri-gomchwi (Ligularia fischeri var. spiciformis Nakai). The selection and investigation of growth and yield characteristics were conducted from 2006 to 2011 in field and greenhouse of Highland Agriculture Research Institute, NICS, Rural Development Administration. The color of petiole ear was purple. Petiole trichome existed, but light of leaf back did not. Density of leaf vein was 5 degree in a newly developed cultivar ‘Gommany’. Plant height, leaf length, leaf width and petiole length were 47.7, 16.3, 21.2, and 31.4 ㎝, respectively in the 3 year of growth characteristics. Plant size was also higher than that of ‘Gondalbi’. Bolting and flowering time were Aug. 5 and Sept. 10, respectively. In contrast, Bolting time of ‘Gondalbi’ showed 25 days quite earlier bolting time compared to ‘Gommany’, Which led to earlier flowering time. ‘Gommany’ showed higher number of leaves (138) per plant compared to ‘Gondalbi’ (130). Furthermore, yield was 97% higher in ‘Gommany’ (1,575 g/plant) than in ‘Gondalbi’ (798 g/plant). ‘Gommany’ showed higher leaf thickness (0.69㎜) than ‘Gonalbi’ (0.46 ㎜), and consequently showed more hardness in leaf characteristics (24.3 ㎏/㎠) compared to ‘Gondalbi’ (23.0㎏/㎠). ‘Gommany’ showed higher resistance in the susceptibility of powdery mildew compared to ‘Gondalbi’. ‘Gommany’ cultivar was registered as a novel variety with number 90 in The Minister of the Korea Forest Service on December 2015.

Microleakage and Anticariogenic Effect of S-PRG Filler-containing Pit and Fissure Sealant (S-PRG filler를 함유한 치면열구전색제의 미세누출 및 항우식효과)

  • Shin, Seungwoo;Kim, Jongsoo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.40 no.4
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    • pp.247-252
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    • 2013
  • Pit and fissure sealant prevents biofilm accumulation, plays a role in forming a barrier to acidic substance made by the bacteria. The Surface reaction-type pre-reacted glass ionomerI(S-PRG) filler was developed in 1999. S-PRG filler releases fluoride continuously and does not decompose under wet conditions. The aim of this study was to test the microleakage and anticariogenic effect to adjacent enamel of S-PRG filler-containing pit and fissure sealant. Sound premolars and molars were used in this study. A S-PRG filler-containing pit and fissure sealant, Beautisealant$^{(R)}$(Shofu, Japan) was used for this experiment, the composite resin sealant Concise$^{(R)}$(3M ESPE, USA) was used as control. For the microleakage test, all teeth surface were double coated with finger nail varnish, with the exception of a 1.0 mm window around the restoration margins. The teeth were immersed in 2% methylene blue solution for 24 hours and then rinsed in tap water. For the anticariogenic effect evaluation, all tooth were immersed in artificial carious solution for 9 days and rinsed with tap water. Each tooth was embedded in orthodontic acrylic rein and subsequently sectioned longitudinally in a bucco-lingual direction with a low-speed diamond saw. The cut sections were examined using a stereomicroscope. Differences in microleakage between the two groups were not different significantly. But the S-PRG filler-containing pit and fissure sealant showed higher anticariogenic effect than that of flowable resin sealant.

A Study on Tree-ring Dating and Speciation of Charcoal found in Pumiceous Deposit of the Quaternary Nari Caldera, Ulleung Island, Korea (신생대 제4기 울릉도 나리칼데라 부석층에서 산출된 탄화목의 연륜연대 및 수종식별 연구)

  • Im, Ji Hyeon;Choo, Chang Oh
    • Economic and Environmental Geology
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    • v.48 no.6
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    • pp.501-508
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    • 2015
  • The purpose of this study is to provide an inquiry into paleovegetation (paleoenvironment), eruption age and inferred emplacement temperature of pyroclastic deposit using charcoal occurred in the Quaternary Nari Caldera, Ulleung Island. In order to obtain the data, we carried out species identification and tree-ring analysis, radiocarbon dating for the charcoal. This sample was collected from pumiceous deposit in lowermost member(Member N-5) of the Nari Tephra Formation, which corresponds to the wood branch that has well preserved the tree-ring structure. Speciation and outermost tree-ring of wood reveal Picea spp. and $263+{\alpha}$ years. The calibrated ages from the center(pith) to the outermost tree-ring are $20,260{\pm}230$, $19,995{\pm}245$, and $19,975{\pm}265cal\;BP$, respectively, which are accordant with the tree-ring position. The youngest age, <19,710 cal BP would have implications for the eruptive age of Member N-5. Our results indicate that Picea spp. is the paleovegetation representing that Nari Caldera was under cold and wet climate conditions during the late Pleistocene. Based on the silky luster, brittleness, color, and streak of charcoal, etc., the lowest emplacement temperatures of pyroclastic flow are interpreted to have been at least as high as $350{\sim}500^{\circ}C$.

Synthesis of indium hydroxide powders by a precipitation method (침전법을 이용한 Indium hydroxide 분말의 합성 연구)

  • Choi, Eun-Kyoung;Lee, Won-Jun;Han, Kyu-Sung;Kim, Ung-Soo;Kim, Jin-Ho;Hwang, Kwang-Teak;Kim, Jong-Young;Hwang, Hae-Jin;Shim, Kwang-Bo;Cho, Woo-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.3
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    • pp.122-129
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    • 2017
  • For the production of a high-density ITO target, $In_2O_3$ powders with a small particle size and low agglomeration should be synthesized. The purpose of this study is to control the size and shape of the Indium hydroxide precursor which affects the properties of the $In_2O_3$ powder. As a starting raw material, Indium metal was dissolved in a Nitric acid ($HNO_3$) solution. The effect of concentration, pH, and temperature on the properties of Indium hydroxide was investigated using ammonium hydroxide as a precipitant. Crystallite size of each sample was analyzed by X-ray diffraction and the shape and the size of the powder was analyzed by transmission electron microscopy. As a result, the particle size of Indium hydroxide was increased with increase in the concentration of $In(NO_3)_3$ and the particle size and shape of the Indium hydroxide remained unchanged with increase in the pH of the solution. The particle size increased with increase in the precipitation temperature during precipitation.

Studies on the Quaternization of Tertiary Amines (Ⅱ). Kinetics and Mechanism for the Reaction of Substituted Phenacyl Bromides with Substituted Pyridines (3차 아민의 4차화반응에 관한 연구 (제2보). 치환 브롬화페나실류와 치환 피리딘류와의 반응에 관한 반응속도론적 연구)

  • Yoh Soo Dong;Kwang Taik Shim;Lee Kyung A
    • Journal of the Korean Chemical Society
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    • v.25 no.2
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    • pp.110-118
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    • 1981
  • Kinetics and mechanism for the reaction of substituted phenacyl bromides with substituted pyridines have been determined at 25, 35 and $45^{\circ}C$ in methanol and dimethylformamide by the conductivity method. The rate constants for the reaction of various pyridines with phenacyl bromide shown that electron-donating substituents in the pyridine increase the rate, while electron-attracting one decrease in both solvents. The effect of substituents in substrate, the rate being increased by electron-attracting substituents. This is as expected for nucleophilic attack of amines on the carbon atom. Isokinetic and $Br{\psi}nsted$ linear relationship were shown in the reaction of phenacyl bromide with pyridines in both solvent in which isokinetic temperature were obtained 614, $202^{\circ}K$ and ${\beta}$ values were 0.29, 0.36 in methanol and dimethylformamide respectively. In the case of the reaction of substituted phenacyl bromide with pyridines, isokinetic temperature decreases with increasing electron-attracting ability of the substituents in the phenacyl bromide, while the ${\beta}$ values were reverse. From the above results, it can be inferred that N…C bond formation decreases progressively from p-chloro- to p-methoxyphenacyl bromide and the bond formation predominates in DMF than methanol. The ${\rho}$ values of Hammett equation of the reaction of phenacyl bromide with substituted pyridines are negative in both solvent, but its value was larger negative in DMF than methanol and the ${\rho}$ value of that of substitutted substrates with pyridine was 0.3, the low value is ascribed to direct $S_N2$ attack of the nitrogen atom in pyridine ring at the methylene carbon.

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Mungbean Cultivar, 'Munpyeong', with a Short Stem and High Yield (단경 다수성 녹두 품종 '문평')

  • Kim, Dong-Kwan;Choi, Jin-Gyung;Kwon, Oh-Do;Lee, Kyung-Dong;Seo, Min-Jung;Kim, Hyun-Tae
    • Korean Journal of Breeding Science
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    • v.50 no.4
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    • pp.485-489
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    • 2018
  • A mungbean cultivar "Munpyeong" (Vigna radiata (L.) Wilczek) was derived as a cross between "Keumseong" and "IT163157" at the Jeollanamdo Agricultural Research and Extension Services (JARES) in 2013. "Munpyeong" has an erect growth habit, heart leaflet, green hypocotyls, black and straight pods when matured, and a dull green seed surface. The stem length of "Munpyeong" was 60 cm, which was 6 cm shorter than that of the control cultivar "Owool." The pod number per plant was 25, which was 3 more than that of the control cultivar. The 1000 seed weight of "Munpyeong" was 45 g, which was 4 g lighter than that of the control cultivar "Owool." Its field resistance to mungbean mottle virus, cercospora leaf spot, and powdery mildew are similar to the control cultivar, whereas its field resistance to lodging was slightly stronger. The hard seed rate of "Munpyeong" was 3.2%, which was similar to that of the control cultivar. The sprout yield ratio was 7.54 times, which was 9% more than that of the control cultivar. The average yield of "Munpyeong" was 1.93 ton/㏊, which was 21% more than that of the control cultivar "Owool" (Cultivar registration number: 5878).