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The Removal of Impurities from Domestic Graphite Concentrate by H2SO4 Solution and NaOH Solution Leaching (황산용액과 수산화나트륨용액의 침출에 의한 국내산 흑연 정광으로부터 불순물 제거)

  • Junseop Lee;Kyoungkeun Yoo;Hyunkyoo Park
    • Resources Recycling
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    • v.32 no.3
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    • pp.38-44
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    • 2023
  • Leaching tests were conducted using sulfuric acid and sodium hydroxide solutions to remove impurities from domestic graphite concentrate. As a result of the leaching experiment using sulfuric acid solution and sodium hydroxide solution, respectively, the difference of removal efficiency was insignificant when the concentration of sodium hydroxide or sulfuric acid was 2 mol/L or more. The fixed carbon content increased with increasing the temperature in the sulfuric acid solution leaching, while it remains constant above 150℃ in sodium hydroxide solution. For the repeated sequential leaching tests, the leaching conditions were 2 mol/L NaOH, 200℃, 1 hour in the sodium hydroxide solution leaching and 2 mol/L H2SO4, 100℃, 1 hour in the sulfuric acid solution leaching, respectively. When sulfuric acid leaching followed by sodium hydroxide solution leaching was repeated 5 times, the fixed carbon increased to 99.95% and ash content decreased to 0.048%, while the fixed carbon increased to 99.98% and ash content was reduced to 0.018 when sodium hydroxide solution leaching followed by sulfuric acid solution leaching was repeated 5 times.

Transfer of Arsenic and Mercury from Stabilized Farmland Soil to Lettuce using Calcium Sulfate Fertilizer with Different Physical Properties as a Stabilizing Agent (안정화제로 사용된 황산칼슘비료의 물리적 형태에 따른 토양 비소 및 수은의 안정화와 식물체 전이특성)

  • Il-Ha Koh;Yo Seb Kwon;Min-Hyeon Lee;Jung-Eun Kim;So-Young Park;Ju In Ko;Won Hyun Ji
    • Economic and Environmental Geology
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    • v.56 no.5
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    • pp.619-628
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    • 2023
  • In this study, we investigated the feasibility of calcium sulfate fertilizer as a stabilizing agent for As and Hg contaminated farmland soil and its stabilization characteristics in 3 different physical forms (particulate, powder, and solution) through a pot experiment including 34 days of lettuce growth. As and Hg contents of the lettuce grown in the stabilized soils were decreased by at least 70%. However the lettuce yield of the soil stabilized with the solution agent was decreased by 46% due to the overabundance of the nutrients from the solution agent. Thus, if a solution-type agent is planned for agricultural farmland soil stabilization, additional tests for optimal dosage are needed to preserve vegetation growth. In Hg fractionation, a lower concentration of elemental fractions and a higher concentration of residual/sulfide fractions were identified in the soils stabilized with the solution, powder, and pariculate agents in descending order while there were no significant changes in As fractionation. Overall results suggest that calcium sulfate fertilizer can be used as a stabilizing agent, and a solution-type agent could be used when the operation of heavy machinery for the soil stabilization process is impossible.

Estimation of the Amount of Mining and Waste Rocks at Musan Mine in North Korea Using a Historical Map and SRTM and Copernicus Global Digital Elevation Models (조선지형도와 SRTM 및 Copernicus 글로벌 수치지형모델을 이용한 북한 무산광산의 채광량 및 폐석 적치량 추정)

  • Yongjae Chu;Hoonyol Lee
    • Korean Journal of Remote Sensing
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    • v.39 no.5_1
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    • pp.495-505
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    • 2023
  • The Musan mine, situated in Musan County, Hamgyong Province, North Korea, stands as a prominent open-pit iron mine on the Korean Peninsula. This study focuses on estimating the mining and dumping activities within the Musan mine area by analyzing digital elevation model (DEM) changes. To calculate the long-term volume changes in the Musan mine, we digitized and converted the 1:200,000-scale third topographic map of the Joseon published in 1918 and compared with interferometric synthetic aperture radar (InSAR) DEMs, including Shuttle Radar Topography Mission DEM (2000) and Copernicus DEM (2011-2015). The findings reveal that over a century, Musan mine yielded around 1.37 billion tons of iron ore, while approximately 1.06 billion tons of waste rock were dumped. This study is particularly significant as it utilizes a historical topographic map predating the full-scale development of Musan mine to estimate a century's mining production and waste rock deposition. It is expected that this research provides valuable insights for future investigation of surface change of North Korea where the acquisition of in situ data remains challenging.

Investigation of USGS Short-Wave Infrared Databases and Comparison with Domestic Cases - Focusing on the Availability for the Mineralogical Analyses and an Application on the Domestic Illite - (USGS 단파장 적외선 데이터베이스 분석 및 국내 사례와 비교: 광물학적 활용도 고찰 및 국내 산출 일라이트로의 적용 사례)

  • Chang Seong Kim;Raeyoon Jeong;Soon-Oh Kim;Ji-man Cha
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.4
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    • pp.259-271
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    • 2023
  • Since the short-wave infrared spectrum has a significant range of variation depending on the production environment, countries with advanced resource exploration are collecting the spectrum and building a database. Representative organizations include the USGS and CSIRO, and they are currently carrying out a project in China that can synthesize and use a large number of existing data. The USGS library provides a total of 2,457 spectra targeting not only minerals but also various materials that respond to infrared radiation. Among these, there are 1,276 mineral spectra, which are about half of the total. The spectrum title includes information, such as analysis devices (NIC4, BECK, ASDNG, etc.), purity codes (a, b, c, d, u), and measurement methods (AREF, RREF, RTGC, TRAN). Analyzed raw data are provided in ASCII and GIF format. The CSIRO library has a total of 502 spectra, of which the majority, 493, correspond to mineral spectra. The USGS library is a free, publically available resource, while the CSIRO library is bundled with TSG8 or must be purchased separately. Among these, when comparing the eight spectra whose spectral shapes can be analyzed with the spectra of domestic illite, the positions of the absorption peaks are significantly different from those of domestic illite, except for one Japanese illite. Additional research will be needed to determine the causes of such differences, and the domestically relevant databases should be established as well.

A Study on the need to strengthen safety and health activities of private construction contractors (건설공사 민간 발주자의 안전보건활동 강화 필요성에 관한 고찰)

  • Keun-Kyu Lee;Min-Je Choi;Guy-Sun Cho
    • Industry Promotion Research
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    • v.9 no.2
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    • pp.69-75
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    • 2024
  • Korea has entered the ranks of advanced countries in terms of economic size and technological competitiveness. However, its industrial accident fatality rate remains among the lowest in OECD countries, and recent incidents such as various building collapses have resulted in numerous deaths of workers or citizens, reminiscent of accidents in developing countries. According to the 2022 Industrial Accident Status Analysis by the Ministry of Employment and Labor, out of the 874 fatalities in work-related accidents in 2022 across all industries, 402 were in the construction industry, accounting for approximately 46% of all fatalities. In particular, the construction industry's fatality rate stands at 1.61, significantly higher than the overall industry fatality rate of 0.43, indicating its severity. Construction ranks highest in terms of fatality rates, with mining at 12.18 and fishing at 1.80. When categorizing construction projects into private and public, private projects show significantly higher figures in terms of contracts, contract amounts, accident numbers, and fatalities compared to public projects. However, unlike public agencies, many private clients lack adequate safety and health activities and lack established safety and health systems. This study aims to raise awareness among private clients about the need to establish safety and health systems and enhance safety and health activities, and to discuss the direction of future development of advanced safety and health practices among private clients.

Strategies for Development of Seafloor Polymetallic Sulphides in Consideration of International Progress (해저열수광상 개발동향과 우리나라의 대응방안)

  • Park, Seong-Wook;Yang, Hee-Cheol;Jeong, Hyeong-Su
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.3
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    • pp.271-279
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    • 2008
  • Polymetallic sulphides means hydrothermally formed deposits of sulphide minerals which contain concentrations of metals including, inter alia, copper, lead, zinc, gold and silver. Nautilus is the first company to commercially explore the seafloor polymetallic sulphide deposits. The Company holds exploration licences and exploration applications for more than 370,000 $km^2$ in the jurisdictional seas of Papua New Guinea, Fiji, Tonga, the Solomon Islands and New Zealand along the western Pacific Ocean's Rim of Fire. Neptune Minerals is also a leading explorer and developer in this field, with exploration licences awarded totalling more than 270,000 $km^2$ in the territorial seas or EEZ of New Zealand, Papua New Guinea and the Federated States of Micronesia. These two companies now carry out the most active investment activities for seafloor polymetallic sulphide deposits with a goal of commercial production by 2010. China and Japan carry out exploration activities for the seafloor polymetallic sulphide deposits to secure supplies of strategic metals. China carries out national R&D projects relating to deep sea mineral resources in the world ocean through China Ocean Mineral Resources R&D Association(COMRA). And Japan investigates her own EEZ for exploration of the seafloor polymetallic sulphide deposits. In consideration of aforementioned international activities of coastal nations as well as private companies for exploring the sulphide deposits, Korea shall prepare strategic plans : First, consolidation of the authorities concerned and legislative support; second, determination of main entity of the project; third, securing government's decisive investment of sufficient budget; and lastly, establishment of the mid, long-term plan for development of seafloor polymetallic sulphides deposits.

Case Study on Revising Curriculum of a Industrial High School through Analysis of Manufacturing Workforce demand focused on Chungnam Province in Korea (지역 기반 산업의 인력 수요 분석을 통한 공업 계열 특성화 고등학교의 교육과정 개편 사례 연구)

  • Yi, Sangbong;Choi, Jiyeon
    • 대한공업교육학회지
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    • v.38 no.1
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    • pp.221-238
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    • 2013
  • The purpose of this study was to revise and reorganize the direction of the department of ${\bigcirc}{\bigcirc}$Industrial High School though analysis of manufacturing status and workforce demand in Chungnam province focused on the Geumsan Area. In the study, ${\bigcirc}{\bigcirc}$Industrial High School of the status and actual conditions were identified through interview, literature review and data analysis. Surveys of the school teachers, parents and students was conducted in order to investigate the awareness of renaming and reorganization of school departments, curriculum revision of the school. Statistical data was collected and analyzed in order to figure out manufacturing industry and its workforce demand of Chungnam Province in Korea. Findings of the study were as follows: Small and medium enterprises of manufacturing industry have been developed a lot in Geumsan Area in Chungnam province. Four major industries including (1) automobile parts, (2) electronic and information equipment, (3) Cutting edge culture, and (4) Agricultural-livestock and bio are intensively fostered as regional strategic industries in the Chungnam province. The manufacturing industry has a 33.6-percent, and then service-mining and manufacturing industry has a 80.0-percent of total number of employee in Geumsan Area. It is expected that industrial workforce demand of Geumsan Area come out of manufacturing and service-mining industrial sector. The following is recommended for the school curriculum revision: (1) focussing on mechanical control for the revision of computer applying mechanical department, (2) focussing on automation electric equipment for the revision of electric control department, (3) focussing on food process control for revising of bio-food industrial department. It's helpful to make a progress of the school that establish identification of industrial specialized high school as an institution of vocational education at the secondary level through supplying qualified workforce to Manufacturing industry in Chungnam Province.

A Study of on the Method to Select Manufacturing Activities Sensitive to Regional Characteristics by Analyzing the Locational Hierarchy (입지계층분석을 활용한 산업단지 유치 업종 결정에 관한 연구)

  • So, Jin-Kwang;Lee, Hyeon-Joo;Kim, Sun-Woo
    • Land and Housing Review
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    • v.2 no.4
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    • pp.559-568
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    • 2011
  • This study aims at listing up those manufacturing activities sensitive to regional characteristics by analyzing locational hierarchy designed on the urban rank-size rule. This locational hierarchy by manufacturing activities is expected to provide a ground for the proper supply of an industrial complex. The analysis of the locational hierarchy by manufacturing activities can work as a method of observing the characteristics of the distribution of location for each economic activity by analyzing the trend in the change of manufacturing location. Consequently, it can be used to determine the appropriate manufacturing activities for the industrial complex of a particular region. Here, the locational hierarchy is analyzed depending on the base of the basic local government such as Gun(district level) and Si(city level), and manufacturing activities are categorized by Korea Standard Industry Code. Those activities demonstrating growth pattern are Manufacture of Electronic Equipment(KSIC 26), Manufacture of Medical Precision Optical Instruments Watch(KSIC 27), Manufacture of Motor Vehicles (KSIC 30, 31), etc. With proper infrastructures, these activities can be located everywhere. Those sectors on the decline pattern in the locational hierarchy can be summarized as Manufacture of Tobacco Products(KSIC 12), Manufacture of wearing apparel Fur Articles(KSIC 14), etc. Those sectors scattered widely in the locational hierarchy are Manufacture of Food Products(KSIC 10), Manufacture of Coke Petroleum Products(KSIC 19), Manufacture of Chemical Products(KSIC 20), Manufacture of Electronic Equipment(KSIC 26). These particular manufacturing activities can be operated in those regions in a sufficient supply of unskilled workers regardless of proper infrastructures. Those activities that have a tendency to reconcentrate on larger cities are Manufacture of Textiles(KSIC 13), Manufacture of Wearing Apparel Clothing Fur Articles(KSIC 14), Manufacture of Other Transport Equiptmen(KSIC 31). In most cases, these sectors tend to favor their existing agglomerated areas and concentrate around large cities. Therefore, it is inefficient to promote these sectors in small or medium-sized cities or underdeveloped regions. The establishment of developmental strategies of an industrial complex can gain greater competitiveness by observing such characteristics of the locational hierarchy.

New demand forecast for vocational high school graduates in regional strategic industries: Focusing on comparison between Daejeon and Jeonnam (지역전략산업에 따른 특성화고 졸업자 신규수요 예측: 대전과 전남 지역 비교를 중심으로)

  • Kim, Jin-Mo;Choi, Su-Jung;Jeon, Yeong-Uk;Oh, Jin-Ju;Ryu, Ji-Eun;Kim, Seon-Geun
    • Journal of vocational education research
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    • v.36 no.1
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    • pp.47-75
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    • 2017
  • The purpose of this study was to provide basic data for policy making for secondary vocational education in each region and transformation in vocational high schools. To achieve this, the regional strategic industries in Daejeon and Jeonnam were selected, new demand for vocational high school graduates was forecasted in each industry and occupation. The results of the study are as follows. First, locational quotient analysis and regional shift-share analysis revealed that Daejon and Jeonnam have different strategic industries. Daejon, unlike Jeonnam strategically develops 'manufacturing food, beverage and tobacco', 'manufacturing timber and paper, printing and copying', 'public service and administration of national defense and social security' and 'manufacturing electrical devices, electronics and precision devices'. Jeonnam has specialized industries distinguished from Daejon's, which are 'manufacturing of machinery transportation equipments and etc', 'manufacturing of non-metallic minerals and metal products', 'electric, gas, steam and water supply systems/industries', 'manufacturing coal and chemical products, refining petroleum', 'mining' and 'agriculture, forestry and fishery'. Second, new demand for vocational high school graduates by occupations and industries showed regional differences(in Daejon and Jeonnam). According the forecast, Daejon will have many workforce demands based on manufacturing industries, on the other hand Jeonnam's focused on service industries. Analysis by occupations was also different, Daejon showed high demands on professional and related workers, while Jeonnam requested many new office and service workers. Third, new workforce demand by occupations in regional strategic industries is big part of overall new workforce demand both in Daejon and Jeonnam. Forth, according to the results of analyzing the new demand for vocational high school graduates in Daejeon and Jeonnam in terms of industry location quotient and change effect, there was high demand in industries with positive total change effects. In terms of location quotient, Daejeon and Jeonnam showed different results.

Spectral Response of Red Lettuce with Zinc Uptake: Pot Experiment in Heavy Metal Contaminated Soil (아연섭취에 따른 적상추의 분광학적 반응: 중금속 오염토양에서의 반응실험)

  • Shin, Ji Hye;Yu, Jaehyung;Kim, Jieun;Koh, Sang-Mo;Lee, Bum Han
    • Economic and Environmental Geology
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    • v.52 no.2
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    • pp.129-139
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    • 2019
  • This study investigates the spectral response of red lettuce (Lactuca sativa var crispa L.) to Zn concentration. The control group and the experimental groups treated with 1 mM(ZnT1), 5 mM(ZnT2), 10 mM(ZnT3), 50 mM(ZnT4), and 100 mM(ZnT5) were prepared for a pot experiment. Then, Zn concentration and spectral reflectance were measured for the different levels of Zn concentration in red lettuce. The Zn concentration of the control group had the range of 134-181 mg/kg, which was within the normal range of Zn concentration in uncontaminated crops. However, Zn concentration in the experimental group gradually increased with an increase in concentration of Zn injection. The spectral reflectance of red lettuce showed high peak in the red band due to anthocyanin, high reflectance in the infrared band due to the scattering effect of the cell structure, and absorption features associated with water. As Zn concentration in red lettuce leaves increased, the reflectance increased in the green and red bands and the reflectance decreased in the infrared band. The correlation analysis between Zn concentration and spectral reflectance showed that the reflectance of 700-1300 nm had a significant negative correlation with Zn concentration. The spectral band is a wavelength region closely related to the cell structure in the leaf, indicating possible cell destruction of leaf structure due to increased Zn concentration. In particular, 700-800 nm reflectance of the infrared band showed the strongest correlation with the Zn concentration. This study could be used to investigate the heavy metal contamination in soil around mining and agriculture area by spectroscopically recognizing heavy metal pollution of plant.