• Korean Journal of Mineralogy and Petrology
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• v.37 no.2
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• pp.47-57
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• 2024

Jarosite, a mineral belonging to the alunite family, is found in various low pH environments and can incorporate cations or oxyanions into its structure, either by coprecipitation or substitution. This mineral is sensitive to pH changes and can easily transform into goethite upon geochemical changes, such as an increase in pH. This transformation can release toxic ions from the jarosite, potentially causing additional environmental damage. In addition to potassium (K), sodium (Na) and ammonium (NH₄) can also substitute for cations in jarosite. The formation of jarosites containing these and other cations is significant not only for acid mine drainage but also for the smelting industry. In this study, three different types of jarosites containing various cations were synthesized and the phase transformation of each jarosite to goethite upon pH change were compared. All the jarosites were sensitive to pH changes, showing much higher rates of phase change at pH 8 than at pH 4. At the relatively low pH of 4, the phase transformation of K-jarosite, which is most stable in structure, to goethite was the slowest. For the other two jarosites, the cations have either smaller or larger radii than K ions, resulting in differences in structural stability and they showed more rapid transformations to goethite. However, at pH 8, K-jarosite exhibited a much more rapid transformation to goethite than the other jarosites, which was also evident from the rapid increase in K ions in aqueous solution. The mineral transformation behavior of K-jarosite at higher pH is significantly different from that at lower pH, indicating that the mechanism of the transformation to goethite differs between these conditions, which requires further investigation. The results of this study indicate that the mineral transformation of jarosite in acid mine drainage or smelter waste disposal may significantly influence the behavior of heavy metals. This research provides valuable insights for predicting the behavior of heavy metals in smelting industry waste disposal.

• Korean Journal of Ecology and Environment
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• v.45 no.3
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• pp.302-313
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• 2012

Long-term trends (e.g. 1997~2010) of chlorophyll a and water quality properties of the Yeongsan River were analyzed by using water quality monitoring data collected by the water information system, ministry of environment. Nine monitoring stations were selected along the main channel of the river, and parameters of BOD, COD, TN, TP, conductivity, TSS and chlorophyll a were collected for surface water monthly through the monitoring system. Trends of water quality and chlorophyll a were analyzed by the Seasonal Mann-Kendall Test and LOWESS (Locally Weighted Scatter-plot Smoother). The results showed that the water quality parameters, including chlorophyll a, were improved in all stations except Station WC in the most-upper region, where water quality data for the determined parameters were increased, indicating a reduction in water quality. Based on the results from LOWESS analysis, chlorophyll a (algal blooms), BOD and COD recently began to increase after 2007 suggesting that an additional study on the cause of these increases in organic pollution, as well as a better management system for the region are required.

• Journal of the Korean Geotechnical Society
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• v.19 no.6
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• pp.39-47
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• 2003

Rockbursts are mainly caused by a sudden release or the stored strain energy in the rock mass. They have been the major hazard in deep hard rock mines but rarely occur in tunnels. Due to the short history and limited information on rockbursts, the topic has rarely been studied in Korea. Some cases of rockbursts, however, have been reported during construction of a mountain tunnel for waterway. This study focuses on analyzing data on rockbursts obtained from a TBM (Tunnel Boring Machine) tunnel and suggests methods for a comprehensive understanding on rockbursts. From the analysis of the field data of rockbursts, it was found that most rockbursts mainly occurred at the section between the tunnel face and the TBM operating room, and the rock bursting phenomena lasted up to 20 days after excavation in certain areas. The data also show that the bursting spots are located all around the tunnel surface including the face, the wall, and the roof, The maximum size of bursting spots is usually less than 100cm. This study also suggests new scale systems of brittleness and uniaxial compressive strength to evaluate the possible tendency for a rockburst. These systems are scaled based on the scale system of strain energy density. In addition, with these scale systems, this research shows that there are potentially higher tendencies for rockbursts in this specific tunnel. Moreover this research suggests that properties of rock and rock mass, RMR (Rock Mass Rating) value, tunneling method, excavating speed, and depth of tunnel have a strong correlation with rockbursts.

• 한국지구과학회:학술대회논문집
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• 2010.04a
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• pp.110-110
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• 2010

2009년 7월 23일-24일 양일간의 APEC MTF 컨퍼런스는 APEC 회원 경제가 아시아-태평양지역에서 광업부문의 지속가능한 발전의 주제를 토의할 기회를 제공했다. 본 컨퍼런스는 APEC의 광업부문의 지속가능한 발전이라는 프로젝트의 중요 부분이며 컨퍼런스의 활발한 참여는 프로젝트의 성공을 증진시켰다. 지속가능한 발전에 대한 안건이 수년간 APEC의 핵심부분이었으며, 특히 광업장관(MRM)회의에 상정되어 왔다. 2004년 6월 칠레 안토파가스타의 제1차 회의에서, 광업장관들은 APEC 지역에서 광업 및 금속산업의 지속가능한 발전은 부를 창출하고, 환경사업을 창출하며, 사회적으로 책임있는 발전을 도모하며 사회를 위한 향상된 가치를 만들어낸다는데 동의했다. 초기의 action item들 중에서 지속가능한 발전에 있어서 광물 및 금속의 기여를 규명하는 것도 있었다. 광업에 있어서 지속가능한 발전에 대한 안건의 토의는 2005년 10월 한국의 경주 제2차 APEC MRM 회의에서 속계되었다. 관련된 action task는 채광 후 토지운영 뿐만 아니라 에너지 효율기술, 광업 오염 통제 기술과 같은 환경친화적인 채광기술에 대한 정보교환 및 협조를 독려하는 것이었다. 2007년 호주 퍼스의 제3차 회의에서 APEC MRM 회의는 특히 지구화의 시대에 APEC 지역 광물자원의 지속가능한 발전에 대한 긴밀한 지역적 협조에 대한 필요성을 인지하고 있다. 장관들은 역시 광업부문에서 지속가능한 발전에 대한 APEC 위상을 정립하기 위한 작업을 주도하기로 했으며 APEC 경제의 공통관심사를 UNCSD에 반영키 위한 자료제공을 하기로 결정했다. APEC 광업분야의 지속 가능한 개발에 관한 APEC MTF회의는 호주, 캐나다, 칠레, 중국, 인도네시아, 일본, 말레이시아, 파푸아 뉴기니, 페루, 필리핀, 한국, 러시아, 싱가포르, 타이완, 태국, 미국, 베트남에서 자신들의 지속 가능한 개발을 위한 활동에 관한 발표나 의견을 제시하였다. 세계 은행이나 AIM에서도 발표를 하였다. 중요한 소주제들은 다음과 같다. $\cdot$ APEC MTF가 APEC 광업분야의 지속 가능한 발전을 추구하는데 있어 적절한 포럼이라는 것 $\cdot$ 기업들이 사회적 책임(CSR)을 성실히 이행할 필요가 있다는 것 $\cdot$ 수자원과 인적자원의 부족을 다룰 필요가 있다는 것 $\cdot$ 적절한 광산 복구가 필요하다는 것이다. 한국은 "광업분야의 지속가능한 발전을 위한 환경과 광업간의 균형"이라는 프로젝트 아이디어를 제안했다. 인도네시아와 말레이시아는 한국측 프로젝트 수행의 중요성을 강조했다. 러시아 연방은 "광업에 있어 투자 활성화"라는 프로젝트 아이디어를 제안했다. 이 관점에서 MTF는 APEC 투자전문가 그룹과의 협력을 지지했으며 이 포럼간 활동을 활성화시키기 위하여 APEC 사무국에 요청했다. 이 프로젝트는 세계 광업분야의 투자를 증진시키는 최적관행 분석에 따라 제안될 것이고 수행될 것이다. 말레이시아는 광업 및 광업 산업의 지속가능한 발전지시자를 위한 역량구축 프로젝트를 제안했다. 태국은 말레이시아의 제안을 지지했으며 공동프로젝트를 제안했다.

• Journal of the Korean Geotechnical Society
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• v.21 no.5
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• pp.83-92
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• 2005

The aim of this study was to investigate damage conditions of cut slope structures due to acid rock drainage (ARB) and to assess the acid production potential of various rocks. Acid rock drainage is produced by the oxidation of sulfide minerals contained in coal mine zone and mineralization belt of Pyeongan supergroup and Ogcheon group, pyrite-bearing andesite, and Tertiary acid sulfate soils in Korea. Most of cut slopes producing ARB have been treated with shotcrete to reduce ARD. According to the field observations, ARD had an adverse effect on slope structures. The corrosion of shotcrete, anchors and rock bolts and the bad germination and growth diseases of covering plants due to ARD were observed in the field. The concentration of heavy metals and pH of ARD from cut slope exceeded the environmental standard, indicating a high potential of environmental pollution of surrounding soil, surface water and ground water by the ARD. According to acid base accounting (ABA) of the studied samples, hydrothermally altered volcanic rocks, tuffs, coaly shales, tailings of metallic mine had a relatively high potential of acid production but gneiss and granite had no or less acid production potential. It is expected that the number of cut slopes will increase hereafter considering the present construction trend. In order to reduce the adverse effect of ARD in construction sites, we need to secure the data base for potential ARD producing area and to develop the ARD reduction technologies suitable.

• Economic and Environmental Geology
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• v.49 no.3
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• pp.167-179
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• 2016

Water quality of Oseepchun, Dogye area, was investigated quantitatively for its origin and hydrogeochemistry in relation to the influence of groundwater. Groundwater appears to be the principal source of Oseepchun from the water-quality monitoring data including redox potentials, composition of dissolved ions and their correlations, hydrogen and oxygen stable isotopic ratios, and the distribution and occurrence of contaminants. Water-quality type of the surface water was grouped by the water-rock interactions as $Ca-HCO_3$ type originated from carbonated bed-rocks in the Joseon Supergroup, (Ca, Mg)-$SO_4$ type related with dissolution of surfide minerals in coal beds of Pyeongan Supergroup, and (Ca, Mg)-($HCO_3$, $SO_4$) type of the mixed one. Locally water pollution occurs by high $SO_4$ from mine drainage and $NO_3$ from waste-treatment facility. Intensive precipitation in summer has no effect on the water type of Oseepchun, but increases the inflow of nitrate and chloride originated from land surface. Results of this study direct that groundwater-surface water interaction is intimate, and thus surface-water resource management should begin with groundwater characterization.

• Journal of the Korean Institute of Landscape Architecture
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• v.47 no.5
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• pp.28-40
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• 2019

In order to resolve the imbalances in the supply of living SOCs according to socio-economic status, location, and population groups, the discussions on inclusive city policies are expanding. The purpose of this study is to propose an Index of Park Derivation (IPD) as an alternative indicator for the promotion of an inclusive urban park policy that can be applied in the 7 major metropolitan cities to select a region with a relatively high park needs. The main research results are as follows. First, the concept of an inclusive urban park policy is defined as "a policy to supply to manage high-quality park services with priority given to areas with low socio-economic and environmental status, such as a large amount of elderly, children, low-income families, areas vulnerable to disasters, such as heat and fine dust, and population groups." Second, we developed the index of park derivation (IPD), which is a combination of 17 variables including park service level, demographic characteristics, economic and educational level, health level, and environmental vulnerability. The variables that constitute the index of park deprivation (IPD) can be applied to SOC policies outside the parks, such as sports facilities, daycare centers, kindergartens, and public libraries. Third, applying index of park deprivation (IPD) to 1,148 Eup/Myeon/dong areas of the 7 metropolitan cities resulted in areas with relatively high park service needs. This study implies that the central and the local government suggest an alternative index to promote an inclusive urban park policy based on statistical and geographical information and data that can be easily accessed and utilized.

• The Journal of Engineering Geology
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• v.33 no.1
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• pp.39-49
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• 2023

Soil contaminants measured and managed in Korea include those of geologic origin such as arsenic, cadmium, copper, lead, zinc, nickel, mercury, and fluoride. This study identifies the distribution of these contaminants using GIS modeling to analyze the spatial probability of soil contamination originating from geology. The modeling found that cadmium, copper, lead, nickel, and mercury often exceed the regulated standard by <1%. Concentrations of arsenic and zinc greatly exceeded the standard in the vicinity of mines and industrial complexes: mining and industry seemed to have substantial effects on the concentrations of these metals. Although fluoride was sampled at the lowest number of points, its frequency of exceeding the standard was the highest. No obvious source of artificial contamination has been identified, and fluoride's distribution characteristics showed continuity over a wide area, suggesting a strong correlation between geological characteristics and fluoride concentration. The highest frequencies of fluoride exceeding the standard were in Jurassic granite (40.00%) and Precambrian banded gneiss (34.12%). As these rocks contributed to the formation of soil through their weathering, high fluoride concentrations can be expected in soil in areas where these rocks are distributed.

• The Journal of Engineering Geology
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• v.34 no.3
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• pp.381-401
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• 2024

To predict the ground subsidence caused by mines, various evaluation methods were applied to cases of ground subsidence in Korea, and the results were compared and analyzed. Continuous subsidence, which is relatively easily and accurately predicted, was excluded in this analysis. The stress arch - volumetric expansion method, limit equilibrium method, numerical analysis, probabilistic method, and evaluation method of the Korea Mine Rehabilitation and Mineral Resources Corporation (KO MIR) were applied to 36 subsidence cases, including subsidence location, width, and depth, and goaf width, depth, and incline data. The stress arch - volumetric expansion method was the most accurate with an accuracy of ~92%. In the case of the KOMIR method, the regression model is 86.1% accurate, but somewhat lower in accuracy using a triangular pyramidal volume. The stress arch - volumetric expansion and KOMIR methods have the disadvantage of evaluating whether subsidence occurs or not. In the case of the numerical analysis, the accuracy is 72.3% when estimating the subsidence depth, but is slightly lower (55.8%) when estimating the subsidence width. The probabilistic and limit equilibrium methods have similar accuracies of 50.8~63.7%. Given it is possible to determine whether subsidence occurs, and the subsidence location, width, and depth with each method, it is recommended to apply various methods when evaluating sinkhole-type subsidence.

• The Journal of Engineering Geology
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• v.14 no.1
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• pp.29-46
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• 2004

It is important to identify geometries of fracture that act as a conduit of fluid flow for characterization of ground water flow in fractured rock. Fracture geometries control hydraulic conductivity and stream lines in a rock mass. However, we have difficulties to acquire whole geometric data of fractures in a field scale because of discontinuous distribution of outcrops and impossibility of continuous collecting of subsurface data. Therefore, it is needed to develop a method to describe whole feature of a target fracture geometry. This study suggests a new approach to develop a method to characterize on the whole feature of a target fracture geometry based on the Fourier transform. After sampling of specimens along a target fracture from borehole cores, effective frequencies among roughness components were selected by the Fourier transform on each specimen. Then, the selected effective frequencies were averaged on each frequency. Because the averaged spectrum includes all the frequency profiles of each specimen, it shows the representative components of the fracture roughness of the target fracture. The inverse Fourier transform is conducted to reconstruct an averaged whole roughness feature after low pass filtering. The reconstructed roughness feature also shows the representative roughness of the target subsurface fracture including the geometrical characteristics of each specimen. It also means that overall roughness feature by scaling up of a fracture. In order to identify the characteristics of permeability coefficients along the target fracture, fracture models were constructed based on the reconstructed roughness feature. The computation of permeability coefficient was performed by the homogenization analysis that can calculate accurate permeability coefficients with full consideration of fracture geometry. The results show a range between $10^{-4}{\;}and{\;}10^{-3}{\;}cm/sec$, indicating reasonable values of permeability coefficient along a large fracture. This approach will be effectively applied to the analysis of permeability characteristics along a large fracture as well as identification of the whole feature of a fracture in a field scale.